Femtosecond laser bidirectional texturing with different laser energy densities and inclination angles was performed on zirconia (ZrO2) surfaces. The laser bidirectional texturing models under different inclination angles were constructed to predict the water contact angles (WCAs), and the superhydrophobicity induced antibacterial adhesion mechanism was analyzed. The results revealed that under the combined effect of the optimal laser energy density (7.0 J/cm2) and inclination angle (90°), the laser-textured ZrO2 surface could obtain a micro-nano dual-scale structure composed of periodic regular micro-cones and nanoparticles. This structure not only promoted the adsorption of carbon-containing hydrophobic groups from the stearic acid and the air to form a superhydrophobic surface with excellent chemical/mechanical durability and anti-fouling/self-cleaning abilities, but also minimized the contact area with the bacterial suspension (solid/liquid contact area ratio of 6 %) to enhance antibacterial ability. The optimal stearic acid-modified laser-textured ZrO2 surface exhibited an extremely low adhesive force (Fadhesive=6.69 μN) to the bacterial suspension, and thus achieved the highest antibacterial ratio of 85.3 %. This study is expected to enrich the application of ZrO2 ceramics in the medical field.
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