With the increasing integration of stochastic sources and loads, ensuring the flexibility of AC/DC hybrid distribution networks has become a pressing challenge. This paper aims to enhance the operational flexibility of AC/DC hybrid distribution networks by proposing a flexibility-oriented optimization framework that addresses the growing uncertainties. Notably, a comprehensive evaluation method for operational flexibility assessment is first established. Based on this, this paper further proposes a flexibility-oriented operation optimization model using the distributionally robust chance-constrained (DRCC) method. A customized solution method utilizing second-order cone relaxation and sample average approximation (SAA) is also introduced. The results of case studies indicate that the flexibility of AC/DC hybrid distribution networks is enhanced through sharing energy storage among multiple feeders, adaptive reactive power regulation using soft open points (SOPs) and static var compensators (SVCs), and power transfer between feeders via SOPs.