Optical Transparency Window Research Articles

Integrated chirped photonic-crystal cavities in gallium phosphide for broadband soliton generation

Chirped mirrors have underpinned advances in ultra-fast lasers based on bulk optics but have yet to be fully exploited in integrated photonics, where they could provide a means to engineer otherwise unattainable dispersion profiles for a range of nonlinear optical applications, including soliton frequency comb generation. The vast majority of integrated resonators for frequency combs make use of microring geometries, in which only waveguide width and height are varied to engineer dispersion. Here, we present an integrated photonic-crystal Fabry–Pérot resonator made of gallium phosphide (GaP), a material exhibiting a Kerr nonlinearity 200 times larger than that of silicon nitride and a high refractive index that permits the creation of strongly chirped photonic-crystal mirrors. Leveraging the additional degrees of freedom provided by integrated chirped mirrors, we disentangle optical losses from dispersion. We obtain an overall dispersion that is more anomalous than that achievable in both silicon nitride and gallium phosphide ring resonators with the same free-spectral range (FSR), while simultaneously obtaining higher quality factors than those of GaP ring resonators. With subharmonic pulsed pumping at an average power of 23.6 mW, we are able to access stable dissipative Kerr frequency combs in a device with a FSR of 55.9 GHz. We demonstrate soliton formation with a 3-dB bandwidth of 3.0 THz, corresponding to a pulse duration of 60 fs. This approach to cavity design based on photonic-crystal reflectors offers nearly arbitrary dispersion engineering over the optical transparency window of the nonlinear material.

Efficient second-harmonic generation in a lithium niobate metasurface governed by high-Q magnetic toroidal dipole resonances.

Lithium niobate (LN) is an excellent nonlinear optical material due to its large nonlinear coefficient, low loss, and broad optical transparency window. So, it is widely used in the generation of nonlinear harmonics. Magnetic toroidal dipole (MTD) resonance is a special optical resonance mode, which can effectively localize the light field inside the device, thus enhancing the nonlinear effects of the materials. In this work, we numerically study the second-harmonic generation (SHG) effect of the LN metasurface based on the MTD mode with a high quality factor (Q-factor). The designed LN nanorod dimer metasurface supports high Q-factor MTD guided mode resonances (GMRs), which are excited by varying the center spacing of the two nanorods, and the Q-factor can be controlled by the offset distance. The excited MTD can effectively confine the electric field within the device, which enables the LN metasurface SHG conversion efficiency to reach 1.15 × 10-2. In addition, by adjusting the structural parameters, it is possible to effectively modulate the wavelength and conversion efficiency of the SHG. Our results provide a new route for high-quality nonlinear light sources.

Optical Transparency Windows in Near-Infrared and Short-Wave Infrared for the Skin, Skull, and Brain: Fluorescence Bioimaging Using PbS Quantum Dots.

Fluorescence imaging (FI) employing near-infrared (NIR) light within the range of ~750-1350 nm enables biomedical imaging several millimeters beneath the tissue surface. More recent investigations into the short-wave IR (SWIR) transparency windows between ~1550-1870 and 2100-2300 nm highlight their superior capabilities. This research presents a comparison of IR-FI of PbS quantum dots, emitting at 990, 1310, and 1580 nm, through the mouse scalp skin, skull, and brain. The SWIR fluorescence is the most effectively transmitted signal, showing particularly significant enhancement when passing through the skull, which causes high light scattering. For the analysis of the imaging results and light propagation through the organs, their spectra of attenuation, absorption, and scattering coefficients are measured. In view of biomedical imaging, attenuation due to light scattering is a more destructive factor. Hence, the spatial resolution and imaging contrast can be improved by operating in SWIR due to decreased light scattering.

Tuning the Transparency Window of SrVO3 Transparent Conducting Oxide.

Correlated transparent conducting oxides (TCOs) have gained great attention, because of their unique combination of transparency and metallic character. SrVO3 (SVO) was identified as a high-performance TCO in the visible range. Few studies have investigated band structure engineering through chemical doping to enhance the optical properties of SVO. Here, we use two different strategies by exploiting the band-filling and width of the bands derived from Vanadium to tune the screened plasma frequency ωp* and the interband transition Ep-d energy, corresponding to the optical transparency window edges. For control of the band-filling strategy, it is found that Titanium doped SVO has a wide transparency window, but such a composition does not maintain the high electrical conductivity required for TCO applications. Concerning the bandwidth strategy, the doping of SrVO3 by Calcium shows that ωp* remains located in the IR range (1.12 eV), while Ep-d is blue-shifted into the UV region (3.43 eV) due to reinforced electronic correlations. By an appropriate choice of dopant, we successfully increased the size of the transparency window by around 11% from 1.94 eV (SVO) to 2.30 eV (Calcium-doped SVO), while retaining high conductivity of around 2.30 × 104 (S·cm-1) and high charge carrier density of 2.93 × 1022 cm-3.

P‐250: Highly Transparent Optical Window Film with Outstanding Mechanical Strength and Folding Reliability for Flexible Displays

This research presents a new approach to developing an optical window film, leveraging the concept of charge‐transfer complex (CTC) intensification of colorless polyimide The window film demonstrates exceptional characteristics, including a tensile modulus of 8.4 GPa, a high total light transmittance of approximately 90%, and a yellow index below 3. This is the best‐recorded balance between mechanical strength and optical properties for a highly flexible optical film. Furthermore, the resulting film exhibits a pencil hardness grade surpassing 2H, alongside remarkable folding reliability, sustaining over 200,000 cycles of folding and unfolding. The excellent properties are ascribed to the unique supramolecular structure characterized by multiple hydrogen bonding and salt complexation interactions, significantly enhancing CTC intensification.

Lanthanide-based nanothermometers for bioapplications: excitation and temperature sensing in optical transparency windows

Review article summarizing the current state of knowledge on remote optical nanothermometers based on the properties of lanthanide ions, both excitable and emitting within the biological windows range.

Merocyanines form bacteriorhodopsins with strongly bathochromic absorption maxima

There is a need to shift the absorbance of biomolecules to the optical transparency window of tissue for applications in optogenetics and photo-pharmacology. There are a few strategies to achieve the so-called red shift of the absorption maxima. Herein, a series of 11 merocyanine dyes were synthesized and employed as chromophores in place of retinal in bacteriorhodopsin (bR) to achieve a bathochromic shift of the absorption maxima relative to bR’s λmaxa\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\lambda }_{\\mathrm{max}}^{a}$$\\end{document} of 568 nm. Assembly with the apoprotein bacterioopsin (bO) led to stable, covalently bound chromoproteins with strongly bathochromic absorbance bands, except for three compounds. Maximal red shifts were observed for molecules 9, 2, and 8 in bR where the λmaxa\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\lambda }_{\\mathrm{max}}^{a}$$\\end{document} was 766, 755, and 736 nm, respectively. While these three merocyanines have different end groups, they share a similar structural feature, namely, a methyl group which is located at the retinal equivalent position 13 of the polyene chain. The absorption and fluorescence data are also presented for the retinal derivatives in their aldehyde, Schiff base (SB), and protonated SB (PSB) forms in solution. According to their hemicyanine character, the PSBs and their analogue bRs exhibited fluorescence quantum yields (Φf) several orders of magnitude greater than native bR (Φf 0.02 to 0.18 versus 1.5 × 10–5 in bR) while also exhibiting much smaller Stokes shifts than bR (400 to 1000 cm−1 versus 4030 cm−1 in bR). The experimental results are complemented by quantum chemical calculations where excellent agreement between the experimental λmaxa\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\lambda }_{\\mathrm{max}}^{a}$$\\end{document} and the calculated λmaxa\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\lambda }_{\\mathrm{max}}^{a}$$\\end{document} was achieved with the second-order algebraic-diagrammatic construction [ADC(2)] method. In addition, quantum mechanics/molecular mechanics (QM/MM) calculations were employed to shed light on the origin of the bathochromic shift of merocyanine 2 in bR compared with native bR.Graphical abstract

Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence.

An optically anisotropic alkali-earth-metal gallium fluoroiodate, Ba2[GaF5(IO3F)] (1), was ingeniously obtained by integrating fluoride and fluoroiodate functional units under moderate hydrothermal conditions. It features a three-dimensional (3D) structure constructed by the highly polarizable fluoroiodate unit [IO3F] and the fluoride groups [GaOF5] and [BaO3Fx] (x = 6, 7). The compound is stable at temperatures up to 500 °C. With the synergistic interaction between [IO3F] and the fluoride groups, the mixed-metal fluoroiodate induces a short ultraviolet cutoff edge at about 230 nm, a medium measured birefringence of 0.068 @ 550 nm, and a wide optical transparent window (0.34-11.9 μm), indicating that 1 has potential applications as a birefringent material from near-UV to mid-infrared. Theoretical calculations prove that the optical characteristics of the compound are mainly attributed to [IO3F] and the fluoride functional groups. This work demonstrates that the presence of various specific functional groups in compounds will help to develop promising inorganic functional materials possessing good optical performance.

Giant Mid‐Infrared Second‐Harmonic Generation Response in a Densely‐Stacked Van Der Waals Transition‐Metal Oxychloride

AbstractSecond‐harmonic generation (SHG) is a fundamental optical property of nonlinear optical (NLO) crystals. Thus far, it has proved difficult to engineer large SHG responses, particularly in the mid‐infrared region, owing to the difficulty in simultaneously controlling the arrangement and density of functional NLO‐active units. Herein, a new assembly strategy employing functional modules only, and aimed at maximizing the density and optimizing the spatial arrangement of highly efficient functional modules, has been applied to the preparation of NLO crystals, affording the van der Waals crystal MoO2Cl2. This exhibits the strongest powder SHG response (2.1×KTiOPO4 (KTP) @ 2100 nm) for a transition‐metal oxyhalide, a wide optical transparency window, and a sufficient birefringence. MoO2Cl2 is the first SHG‐active transition‐metal oxyhalide effective in the infrared region. Theoretical studies and crystal structure analysis suggest that the densely packed, optimally‐aligned [MoO4Cl2] modules within the two‐dimensional van der Waals layers are responsible for the giant SHG response.

Giant Mid-Infrared Second-Harmonic Generation Response in a Densely-Stacked Van Der Waals Transition-Metal Oxychloride.

Second-harmonic generation (SHG) is a fundamental optical property of nonlinear optical (NLO) crystals. Thus far, it has proved difficult to engineer large SHG responses, particularly in the mid-infrared region, owing to the difficulty in simultaneously controlling the arrangement and density of functional NLO-active units. Herein, a new assembly strategy employing functional modules only, and aimed at maximizing the density and optimizing the spatial arrangement of highly efficient functional modules, has been applied to the preparation of NLO crystals, affording the van der Waals crystal MoO2 Cl2 . This exhibits the strongest powder SHG response (2.1×KTiOPO4 (KTP) @ 2100 nm) for a transition-metal oxyhalide, a wide optical transparency window, and a sufficient birefringence. MoO2 Cl2 is the first SHG-active transition-metal oxyhalide effective in the infrared region. Theoretical studies and crystal structure analysis suggest that the densely packed, optimally-aligned [MoO4 Cl2 ] modules within the two-dimensional van der Waals layers are responsible for the giant SHG response.

(Invited) Near Infrared Fluorescence Lifetime Imaging of Biomolecules with Carbon Nanotubes

Single wall carbon nanotubes (SWCNTs) are versatile building blocks for biosensors. Their near infrared (NIR) fluorescence enables detection of biomolecules in the optical tissue transparency window. Their surface chemistry can be tailored to selectively interact with analytes, which typically changes the fluorescence intensity. However, such signals are affected by external factors such as sample movement or fluctuations in excitation light. Here, we demonstrate fluorescence lifetime imaging microscopy (FLIM) of SWCNT-based sensors in the NIR as absolute and calibration-free method.For this purpose, we use a tailored laser scanning confocal microscope (LSCM) optimized for NIR signals (>800 nm) and time correlated single photon counting (TCSPC). (GT)10-DNA modified SWCNTs serve as sensor of the important neurotransmitter dopamine. The detected fluorescence signal > 900 nm increases in lifetime up to 25 %. These lifetime sensors are used as paint to cover cells and report extracellular dopamine in 3D. We therefore show the potential of using fluorescence lifetime in combination with confocal microscopy as readout for SWCNT-based sensors.

Tunable ultra‐wideband NIR emission and irradiation resistance in novel Er3+/Tm3+/Pr3+ tri‐doped La2O3‐ Ga2O3‐Ta2O5 glasses synthesized using aerodynamic levitation method

AbstractGlasses with ultra‐wideband near‐infrared emission and superior irradiation resistance are important for the potential applications in optical communications under harsh environments. Here, transparent 35La2O3‐(65‐x)Ga2O3‐xTa2O5 (LGT) and Er3+/Tm3+/Pr3+ tri‐doped LGT glasses are fabricated using the levitation method. LGT glasses exhibit a wide glass‐formation region, low largest vibration energy, high refractive indices, and excellent mechanical properties. Additionally, Er3+/Tm3+/Pr3+ tri‐doped LGT samples with varying Pr3+ contents are characterized by possessing good thermal stability (Tg>849°C), wide transparent optical window, strong radiation resistance, excellent compatibility between low wavelength dispersion (vd>31.2), and large refractive index (nd>2.048). By optimizing the doping content of Er3+, Tm3+, and Pr3+ in an appropriate ratio, the ultra‐wideband near‐infrared luminescence ranging from 1250 to 1640 nm (FWHM = 251 nm) has been acquired under 808 nm pumping. Furthermore, decay curves are measured to reveal the fluorescence dynamics, and then the related emission mechanism is elaborated systematically. Meanwhile, the effects of gamma irradiation doses on microstructure, transmittance spectra, and fluorescence characteristics are studied. This work may offer a valuable reference for doping optimization and new design strategy of multifunctional materials.

1.37×102 S·cm-1 p-type conductivity LaCuOS films with a very wide optical transparency window of 400-6000 nm

The absence of highly conductive p-type transparent semiconductors has blocked the development of transparent p-n junction devices and electronics, and it is a well-known challenge to achieve highly conductive p-type transparent materials. In this paper, we report the achievement of large area p-type LaCuOS single phase semiconducting and conducting thin films with record high conductivity of 136.7 S·cm-1 and very good optical transparency of 80% at 600 nm and 40% at 5000nm. The optical gap is about 3.15 eV. The LaCuOS film can be semiconductor or conductor by controlling sulphuration. The optical transparency window of 400-6000 nm is amazingly wide, covering wavelengths from visible to middle infrared lights, indicating its potential applications in visible and infrared semiconductor devices and electronics. The Fermi level is very close to the valance band upper edge, suggesting that this material can be an excellent candidate of high work function transparent electrodes for photovoltaic and optoelectronic devices.

Cd2 Nb2 Te4 O15 : A Novel Pseudo-Aurivillius-Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability.

Oxides are emerging candidates for mid-infrared (mid-IR) nonlinear optical (NLO) materials. However, their intrinsically weak second harmonic generation (SHG) effects hinder their further development. A major design challenge is to increase the nonlinear coefficient while maintaining the broad mid-IR transmission and high laser-induced damage threshold (LIDT) of the oxides. In this study, it is reported on a polar NLO tellurite, Cd2 Nb2 Te4 O15 (CNTO), featuring a pseudo-Aurivillius-type perovskite layered structure composed of three types of NLO active groups, including CdO6 octahedra, NbO6 octahedra, and TeO4 seesaws. The uniform orientation of the distorted units induces a giant SHG response that is ≈31 times larger than that of KH2 PO4 , the largest value among all reported metal tellurites. Additionally, CNTO exhibits a large band gap (3.75eV), a wide optical transparency window (0.33-14.5µm), superior birefringence (0.12@ 546nm), high LIDT (23×AgGaS2 ), and strong acid and alkali resistance, indicating its potential as a promising mid-IR NLO material.

Integrated photonics on the dielectrically loaded lithium niobate on insulator platform

Thin-film lithium niobate on insulator (LNOI) is emerging as one of the promising platforms for integrated photonics due to the excellent material properties of lithium niobate, which includes a strong electro-optic effect, high second-order optical nonlinearity, a large optical transparency window, and low material loss. Although direct etching of lithium niobate has been adopted more widely in recent years, it remains to be seen if it will be adopted in foundry processes due to the incompatibility with standard CMOS fabrication processes. Thus, the scalability of the LNOI platform is currently still limited when compared with other platforms such as silicon photonics. Dielectrically loaded LNOI waveguides may present an alternative. These waveguides have been used to demonstrate a range of optical components with a simplified fabrication process while demonstrating competitive performance. In this contribution, we review the recent progress in dielectrically loaded LNOI waveguides, summarize the advantages and disadvantages of different loading materials, compare the performance of different platforms, and discuss the future of these platforms for photonic integrated circuits.

Broadband circular dichroism in chiral plasmonic woodpiles

The circular dichroism (CD) of a material is the difference in optical absorption under left- and right-circularly polarized illumination. It is crucial for a number of applications, from molecular sensing to the design of circularly polarized thermal light sources. The CD in natural materials is typically weak, leading to the exploitation of artificial chiral materials. Layered chiral woodpile structures are well known to boost chiro-optical effects when realized as a photonic crystal or an optical metamaterial. We here demonstrate that light scattering at a chiral plasmonic woodpile, which is structured on the order of the wavelength of the light, can be well understood by considering the fundamental evanescent Floquet states within the structure. In particular, we report a broadband circular polarization bandgap in the complex band structure of various plasmonic woodpiles that spans the optical transparency window of the atmosphere between 3 and 4 upmum and leads to an average CD of up to 90% within this spectral range. Our findings could pave the way for an ultra-broadband circularly polarized thermal source.

Spectral comparison of nanoporous silica-adsorbed organic molecules with gaseous and liquid states using a new waveguide technology

Nanoporous materials play an important role in many applications including separations and sensing, therefore understanding surface interactions, molecular adsorption, and nanoconfinement phenomena are important. Here we use near-infrared spectroscopy to measure spectra of volatile organic compounds (VOCs) adsorbed inside a nanoporous silica waveguide and compare to the spectral features of the VOCs’ gas and liquid phase spectra. The 10 mm long nanoporous waveguide has a transparent optical window between 1200 and 2200 nm that allows sensitive near-infrared measurements of a range of polar and non-polar VOCs. For the non-polar compounds, the spectra of the molecules adsorbed in the nanopores have similar spectral features to those of the gas molecules in free space. However, for the polar compounds, there are more prominent spectral similarities between the adsorbed molecules and their corresponding liquid spectra. Interestingly, we also observed that the 10 mm path length porous waveguide was capable of sensing gas concentration at least one order of magnitude lower compared to a 400 mm path length conventional gas-cell. The novel optical waveguide allows for sensitive measurement in the near-infrared, demonstrating a strong potential to be used as a tool to study adsorption in nanoporous materials and as a gas sensor.

Interferometric Fiber Optic Probe for Measurements of Cavitation Bubble Expansion Velocity and Bubble Oscillation Time.

Cavitation bubbles are used in medicine as a mechanism to generate shock waves. The study of cavitation bubble dynamics plays a crucial role in understanding and utilizing such phenomena for practical applications and purposes. Since the lifetime of cavitation bubbles is in the range of hundreds of microseconds and the radii are in the millimeter range, the observation of bubble dynamics requires complicated and expensive equipment. High-speed cameras or other optical techniques require transparent containers or at least a transparent optical window to access the region. Fiber optic probe tips are commonly used to monitor water pressure, density, and temperature, but no study has used a fiber tip sensor in an interferometric setup to measure cavitation bubble dynamics. We present how a fiber tip sensor system, originally intended as a hydrophone, can be used to track the expansion and contraction of cavitation bubbles. The measurement is based on interference between light reflected from the fiber tip surface and light reflected from the cavitation bubble itself. We used a continuous-wave laser to generate cavitation bubbles and a high-speed camera to validate our measurements. The shock wave resulting from the collapse of a bubble can also be measured with a delay in the order of 1 µs since the probe tip can be placed less than 1 mm away from the origin of the cavitation bubble. By combining the information on the bubble expansion velocity and the time of bubble collapse, the lifetime of a bubble can be estimated. The bubble expansion velocity is measured with a spatial resolution of 488 nm, half the wavelength of the measuring laser. Our results demonstrate an alternative method for monitoring bubble dynamics without the need for expensive equipment. The method is flexible and can be adapted to different environmental conditions, opening up new perspectives in many application areas.

From CdPb8(SeO3)4Br10 to Pb3(TeO3)Br4: the first tellurite bromide exhibiting an SHG response and mid-IR transparency

NCS Pb3(TeO3)Br4 was obtained based on the CS CdPb8(SeO3)4Br10 by mild hydrothermal reactions. Pb3(TeO3)Br4 can exhibit an SHG response equivalent to KDP, appropriate birefringence, wide optical transparency window and high thermal stability.

Upconversion rare Earths nanomaterials applied to photodynamic therapy and bioimaging.

Light-based therapies and diagnoses including photodynamic therapy (PDT) have been used in many fields of medicine, including the treatment of non-oncological diseases and many types of cancer. PDT require a light source and a light-sensitive compound, called photosensitizer (PS), to detect and destroy cancer cells. After absorption of the photon, PS molecule gets excited from its singlet ground state to a higher electronically excited state which, among several photophysical processes, can emit light (fluorescence) and/or generate reactive oxygen species (ROS). Moreover, the biological responses are activated only in specific areas of the tissue that have been submitted to exposure to light. The success of the PDT depends on many parameters, such as deep light penetration on tissue, higher PS uptake by undesired cells as well as its photophysical and photochemical characteristics. One of the challenges of PDT is the depth of penetration of light into biological tissues. Because photon absorption and scattering occur simultaneously, these processes depend directly on the light wavelength. Using PS that absorbs photons on "optical transparency windows" of biological tissues promises deeper penetration and less attenuation during the irradiation process. The traditional PS normally is excited by a higher energy photon (UV-Vis light) which has become the Achilles' heel in photodiagnosis and phototreatment of deep-seated tumors below the skin. Thus, the need to have an effective upconverter sensitizer agent is the property in which it absorbs light in the near-infrared (NIR) region and emits in the visible and NIR spectral regions. The red emission can contribute to the therapy and the green and NIR emission to obtain the image, for example. The absorption of NIR light by the material is very interesting because it allows greater penetration depth for in vivo bioimaging and can efficiently suppress autofluorescence and light scattering. Consequently, the penetration of NIR radiation is greater, activating the biophotoluminescent material within the cell. Thus, materials containing Rare Earth (RE) elements have a great advantage for these applications due to their attractive optical and physicochemical properties, such as several possibilities of excitation wavelengths - from UV to NIR, strong photoluminescence emissions, relatively long luminescence decay lifetimes (µs to ms), and high sensitivity and easy preparation. In resume, the relentless search for new systems continues. The contribution and understanding of the mechanisms of the various physicochemical properties presented by this system is critical to finding a suitable system for cancer treatment via PDT.