We investigate the stellar and nebular properties of nine H ii regions in the spiral galaxy M101 with far-ultraviolet (FUV; ∼900–2000 Å) and optical (∼3200–10,000 Å) spectra. We detect significant C iii] λλ1907,1909 nebular emission in seven regions, but O iii] λ1666 only in the lowest-metallicity region. We produce new analytic functions of the carbon ionization correction factors as a function of metallicity in order to perform a preliminary C/O abundance analysis. The FUV spectra also contain numerous stellar emission and P-Cygni features that we fit with luminosity-weighted combinations of single-burst Starburst99 and BPASS models. We find that the best-fit Starburst99 models closely match the observed very-high-ionization P-Cygni features, requiring very hot, young (≲3 Myr), metal-enriched massive stars. The youngest stellar populations are strongly correlated with broad He ii emission, nitrogen Wolf–Rayet (WR) FUV and optical spectral features, and enhanced N/O gas abundances. Thus, the short-lived WR phase may be driving excess emission in several N P-Cygni wind features (λ955, λ991, λ1720) that bias the stellar continuum fits to higher metallicities relative to the gas-phase metallicities. Accurate characterization of these H ii regions requires additional inclusion of WR stars in the stellar population synthesis models. Our FUV spectra demonstrate that the ∼900–1200 Å FUV can provide a strong test bed for future WR atmosphere and evolution models.
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