Optical Response Research Articles

Elucidating the Photophysics and Nonlinear Optical Properties of a Novel Azo Prototype for Possible Photonic Applications: A Quantum Chemical Analysis.

The photophysics and nonlinear optical responses of a novel nitrothiazol-methoxyphenol molecule were investigated using density functional theory (DFT) and time-dependent density functional theory (TD-DFT) methods with the polarizable continuum model to take the solvent effect into account. Special attention is paid to the description of the lowest absorption band, characterized as a strong π → π* state in the visible region of the spectrum. The TD-DFT emission spectrum analysis reveals a significant Stokes shift of more than 120 nm for the π → π* state in gas phase condition. The results show a great influence of the solvent polarity on the nonlinear optical (NLO) response of the molecule. Specifically, the second harmonic generation hyperpolarizability β(-2ω; ω, ω) shows a large variation from gas to aqueous solvent (82 × 10-30 to 162 × 10-30 esu), exhibiting notably higher values than those reported for standard compounds such as urea (0.34 × 10-30 esu) and p-nitroaniline (6.42 × 10-30 esu). Furthermore, a two-photon absorption analysis indicates a large cross-section (δ2PA = 77 GM) with superior performance compared to several dyes. These results make the molecule quite interesting for nonlinear optics.

Less is more: surface-lattice-resonance-enhanced aluminum metasurface with giant saturable absorption for a wavelength-tunable Q-switched Yb-doped fiber laser

Resonant metasurfaces provide a promising solution to overcome the limitations of nonlinear materials in nature by enhancing the interaction between light and matter and amplifying optical nonlinearity. In this paper, we design an aluminum (Al) metasurface that supports surface lattice resonance (SLR) with less nanoparticle filling density but more prominent saturable absorption effects, in comparison to a counterpart that supports localized surface plasmon resonance (LSPR). In detail, the SLR metasurface exhibits a narrower resonance linewidth and a greater near-field enhancement, leading to a more significant modulation depth (9.6%) at a low incident fluence of 25 μJ/cm2. As an application example, we have further achieved wavelength-tunable Q-switched pulse generation from 1020 to 1048 nm by incorporating the SLR-based Al metasurface as a passive saturable absorber (SA) in a polarization-maintaining ytterbium-doped fiber laser. Typically, the Q-switched pulse with a repetition rate of 33.7 kHz, pulse width of 2.1 μs, pulse energy of 141.7 nJ, and signal-to-noise ratio (SNR) of greater than 40 dB at the fundamental frequency can be obtained. In addition, we have investigated the effects of pump power and central wavelength of the filter on the repetition rate and pulse width of output pulses, respectively. In spite of demonstration of only using the Al metasurface to achieve a passive Q-switched fiber laser, our work offers an alternative scheme to build planar, lightweight, and broadband SA devices that could find emerging applications from ultrafast optics to neuromorphic photonics, considering the fast dynamics, CMOS-compatible fabrication, and decent nonlinear optical response of Al-material-based nanoplasmonics.

Different Optical Behaviors Revealed by Electroluminescence and Photoluminescence of InGaN/GaN Coupled Quantum Wells.

The optical properties of wurtzite violet InGaN/GaN coupled quantum well (QW) structures are experimentally studied using photoluminescence (PL) and electroluminescence (EL) spectroscopy. Two emission peaks, referred to as Peak H and Peak L, are observed in both PL and EL spectra, due to the ground state splitting induced by the well coupling. Experimental PL and EL results reveal that coupled QWs show different optical responses due to the different variation in the electric field inside the QW structure. Since the direction of the polarization electric field of the as-grown well/barrier layers is different, the external electric field applied by electrodes can change the energy band alignment between the well and the barrier layers, thus adjusting the coupling between the wells. Our results provide relevant information to improve our understanding of the optical properties of InGaN/GaN QWs and to develop novel optoelectronic devices.

Synthesis, crystal structure, spectral analysis and NLO studies of five-coordinate Zn(II) complexes of hydrazochromandione

Using a hydrazochromandione ligand, a straightforward chemical process is used to create zinc(II) complexes (1 and 2) with five coordination. Elemental microanalysis and a range of spectroscopic techniques (FT-IR, 1H NMR and electronic spectroscopy) were used to characterize the ligand and Zn(II) complexes. Single crystal X-ray diffraction was used to identify the crystal structures of HL, complex 1 and 2, and the results showed that ligand has monoclinic system with centrosymmetric space group P21/n. Through ONO donor atoms, Zn(II) metal is coordinated to the ligand in the same way as monoanionic. Two Zn(II) complexes with a deformed square pyramidal geometry surrounding them. Interestingly, relatively strong hydrogen bonds and p-p interactions that result in supramolecular architectures preserve the stabilization of the crystal lattices. Comparing two Zn(II) complexes to hydrazochromandione ligand, they exhibit good non-linear optical response.

Origin of the Nonlinear Optical Response in Organotetrel Molecules, (Hetero)adamantane-Type Clusters with Organic Substituents, and Related Species.

The nonlinear optical response of (hetero)adamantane-type clusters and organotetrel molecules with the general formula [(RT)4E6] and [TR4] (T = group 14, R = organic substituents, E = S, CH2) is investigated from first principles. These clusters have been reported to efficiently convert infrared radiation into white light and are therefore extremely attractive functional materials for a multitude of applications. We demonstrate that the optical nonlinearities of the clusters in the range from 0 to 3 eV have their origin in electronic transitions within the substituents. The cluster core does not directly take part to the generation process; however, it strongly affects the intensity of the linear and nonlinear response. The relationships between optical properties and cluster symmetry, stoichiometry, substituent field, core composition, and further structural characteristics are investigated by systematical variation of R and T. This also demonstrates the possibility to finely tune the intensity as well as the frequency dependence of the optical response. Upon formation of cluster dimers, the intensity of the nonlinearities depends on the overall dimer geometry. In the case of heterogeneous dimers, the optical response strongly resembles that of a dominant cluster. Similarly, upon formation of cluster crystals, the compound inherits the optical characteristics of the parent molecules.

Sequence-Controlled Electrochemical Immobilization of Catalyst-Photosensitizer Oligomers for Tuning Photoelectrochemical Behaviors.

Immobilizing catalysts and photosensitizers on an electrode surface is crucial in interfacial energy conversion. However, their combination for optimizing catalytic performance is an unpredictable challenge. Herein, we report that catalyst and photosensitizer monomers are selectively grafted one-by-one addition onto the electrode surface by interfacial electrosynthesis to achieve composition and sequence-controlled oligomer photoelectrocatalytic monolayers. This electrosynthesis relies on the oxidative coupling reaction of carbazole and the reductive coupling reaction of vinyl on the catalyst and photosensitizer monomers, and it initiates on self-assembled monolayers and propagates with alternating positive and negative potentials. Each addition and completion of the target monomer can be quantitatively identified and monitored by optical and electrical responses and their linear coefficients as a function of reaction steps. The resulting composition and sequence-controlled monolayers exhibit tuning electrocatalytic behaviors including water splitting and CO2 reduction, indicating an efficient way to optimize the electro- and photocatalytic functions and performance of molecular materials.

Yellow-transmissive blue electrochromic polymers based on triphenylamine and ProDOT derivatives

Electrochromic polymer with yellow hue is few relative to those with other two primary colors due to its optical absorption at short wavelength of ≈ 450 nm. Triphenylamine (TPA) and its derivatives (TPAs) as chromogenic groups are frequently used to construct neutral yellow electrochromic polymers, however, those polymers based on TPAs usually exhibit low transmittance at oxidation state due to the residual absorption at short wavelength. Here, three neutral yellow electrochromic polymers (PBBE-1, PBBE-2 and PBBE-3) with different content ratios of ProDOT-10, TPA-4 and benzene were synthesized by Suzuki coupling reaction. With ProDOT-10 content in polymeric chain increasing, the oxidation potentials of polymers decrease gradually. Due to the twisted molecular structure, the absorption peaks of polymers almost remain unchanged when ProDOT-10 content in polymer reaches critical value, which provide an effective method for preparing neutral yellow electrochromic polymers. During oxidation process, PBBE-1 turns to black; PBBE-2 turns to dark blue; PBBE-3 turns to light grey, further to light blue. Through optimizing TBA-4/ProDOT-10 ratio, the electrochromic properties of polymers have been improved, such as optical contrast, response time and coloration efficiency. Especially, PBBE-3 possesses 40 % optical contrast at 435 nm, which is higher than reported TPAs based polymers at short wavelengths.

Optimization of photocurrent and surface wettability of new As10Bi30Se30Te30 thin films through annealing at different temperatures for optoelectronic applications

Group V-VI-based metal-doped double chalcogenides are essential in thermoelectric and suitable optoelectronic devices. The present investigation is based on optimising various optical, structural, and electrical behaviours of quaternary As10Bi30Se30Te30 films through thermal annealing at different temperature scales. The structural study by X-ray diffraction (XRD) exhibited the presence of various Bi2Se3, Bi2SeTe2, and Bi2Te3 phases in the annealed films. The crystallinity gradually enhanced after the annealing process. The microstructural modifications in the material have been confirmed through the Raman spectra. The elemental confirmation was verified from the energy dispersive X-ray (EDX) spectra, whereas the cross-sectional scanning electron microscopy (SEM) view showed the annealing-induced modifications in the films. The granular structure in the films is seen from the surface morphology study. The reduction of the energy gap from 1.36 ± 0.002 eV to 1.26 ± 0.001 eV upon annealing induced the increment in refractive index from 3.08 to 3.15. With annealing, the non-linear refractive index varied from 4.341x10−10 esu to 5.218 x10−10 esu. This indicates the narrowing of the bandgap and enhancement in the non-linear optical response of the material after the annealing process. The 3rd-order nonlinear susceptibility is also increased by annealing, thus making it suitable for nonlinear device applications. Annealing-induced surface change in the material enhances its surface wettability and makes it more hydrophilic. The linear enhancement in photocurrent with the voltage is ohmic and makes it suitable for various optoelectronic applications.

Optical properties of 4H-SiC and 6H-SiC from infrared to vacuum ultraviolet spectral range ellipsometry (0.05–8.5 eV)

Complex dielectric function (ɛ = ɛ1 + iɛ2) spectra are obtained from reflection mode spectroscopic ellipsometry and unpolarized transmittance measurements for 4H and 6H stacking sequence silicon carbide (SiC) nitrogen-doped single crystals from the infrared (IR) to vacuum ultraviolet (VUV) spectral range. A single parametric model describing ɛ predominately for the ordinary directions is developed over the 0.05–8.5 eV spectral range from analysis of (0001)-oriented back side roughened 4H-SiC and 6H-SiC single crystals with some contribution from the extraordinary direction of 6H-SiC in the IR region. Indirect bandgaps for 4H-SiC and 6H-SiC are found to be 3.30 and 3.03 eV, respectively, and the corresponding direct optical gaps are at 4.46 and 4.42 eV. A model describing the optical response in the IR spectral range is created using a Drude expression and either transverse optical (TO) and longitudinal optical (LO) (TOLO) or Lorentz oscillator models. Free carrier concentration (N) is optically measured to be 3.7 × 1018 and 3.3 × 1018 cm−3 using TOLO and Lorentz oscillator models, respectively, and the corresponding carrier mobility (μ) is 34 and 39 cm2/V s for 4H-SiC. Under the same assumption for 6H-SiC, N is measured to 8 × 1018 cm−3 using either TOLO or Lorentz oscillator models and μ is 9 and 10 cm2/V s using the TOLO and Lorentz oscillator models, respectively, in the ordinary direction and 5 cm2/V s in the extraordinary direction using either model. For 4H-SiC, using the TOLO oscillator model, TO and LO phonon modes are measured at 797.7 and 992.1 cm−1, respectively, and corresponding modes are found at same locations using the Lorentz oscillator model. In 6H-SiC, using the TOLO model, TO modes in ordinary and extraordinary directions are found at 797.7 and 789.7 cm−1, and corresponding modes are at 796.9 and 788.9 cm−1 using the Lorentz oscillator model. The LO modes using the TOLO model are found at 992 and 984 cm−1 in the ordinary and extraordinary directions, respectively, and the same modes in the corresponding direction using the Lorentz oscillator model are located at 975.9 and 967.9 cm−1.

Comparative Analysis of Two Different MIM Configurations of a Plasmonic Nanoantenna

AbstractTwo plasmonic nanoantenna configurations—nanodisk and nanostrip arrays—in a metal–insulator-metal (MIM) setup were proposed, optimized, and compared by simulating their optical properties in three-dimensional models using COMSOL Multiphysics software. The optical responses, including electric field enhancement, absorption, reflection, and transmission spectra, were systematically investigated. Optimized geometrical parameters led to a significant enhancement of the electric field within the gap layers and almost perfect light absorptance for both structures. The results showed that the enhancement of the electric field depends on the polarization of the incident light. For both polarizations, the periodic circular nanodisk array showed a stronger field enhancement with an electric field enhancement factor of 6.6 × 106 and TE polarization, and a larger absorptance of 98% at its dipole resonance wavelength, indicating the fundamental plasmonic mode. In addition, weaker resonant modes were observed in the absorptance and reflectance spectra of both nanostructures, with the nanostrips exhibiting sharper and stronger higher-order modes, making them suitable for applications requiring precise wavelength selectivity and narrow-band responses. Despite their different geometric shapes, both structures exhibited similar optimized metal film thickness and nanoparticle height, comparable modes in number and position, and identical optimized light incidence angles. Furthermore, increasing the dielectric gap layer thickness and optimizing it to a specific value revealed its ability to measure the refractive index, making it a promising candidate for sensing applications.

Synthesis, Spectroscopic, SC-XRD/DFT and Nonlinear Optical Response of New Halogenated Schiff Base Ligand and its Square Planar Complexes

This study details the synthesis and characterization analysis of a of new halogenated Schiff base ligand (E)-4-((5‑bromo-2-hydroxybenzyldene) amino) butanoic acid (HL) and its Square Planar trans-L2 Cu(II) complex. Characterization was performed using a suite of spectroscopic techniques, including 1H and 13C NMR, FT-IR, Raman, and UV–Vis spectroscopy, with thorough explanations and discussions of the spectral data. The structure of ligand and its complex CuL2 were elucidated through single-crystal X-ray crystallography. Additionally, the study extended to the computational domain, where the structural optimization, reactivity descriptors, and linear optical properties, as well as the static and dynamic first and second hyperpolarizabilities of HL, Cr(II)L2, Mn(II)L2, Co(II)L2 and Cu(II)L2 were investigated using DFT and TD-DFT calculation. Our results indicate that the second hyperpolarizability escalates as the atomic number of the transition metal increases. Moreover, it is inferred that the ligand examined holds the potential to be a superior material for second-order nonlinear optical applications.

Stretchable Distributed Bragg Reflectors as Strain-Responsive Mechanochromic Sensors.

Mechanochromic materials exhibit color changes upon external mechanical stimuli, finding wide-ranging applications in colorimetric sensing, display technology, and anticounterfeiting measures. Many of these materials rely on fluorescence properties and therefore necessitate external optical or electrical excitation. However, for broader applicability, the detection of color changes by the naked eye only or without complicated detection instrumentation is highly desirable. Photonic crystals offer a promising avenue for attaining such performances. In this work, we present elastomeric distributed Bragg reflectors (DBRs) characterized by a series of photonic bandgaps exhibiting mechanochromic response from the near-infrared to the visible wavelengths. To achieve this, we engineered alternating thin films of a thermoplastic fluoropolymer and a styrene-butadiene copolymer using different elastomeric substrates to attain different behaviors. The reported system demonstrates a reversible and instantaneous shift of the photonic bandgaps in response to 100% strain in multiple deformation cycles. Comparing the DBR stress-strain response with the optical strain response confirms a mechanochromic sensitivity of ∼1.7-6.9 nm/% and ∼80 nm/MPa, with an optical Poisson's ratio in the range 0.3-0.7. All these properties are spectrally dependent, as demonstrated by exploiting the properties of different diffraction order photonic band gaps.

A novel organic fluorescent material: synthesis, structures and optical response properties

A novel organic fluorescent material: synthesis, structures and optical response properties

Shrinking a gradient-index-lens antenna system with a spaceplate

The miniaturization of optical systems is an ongoing challenge across the electromagnetic spectrum. While the thickness of optical elements themselves can be reduced using advances in metamaterials, it is the voids between these elements—which are necessary parts of an optical system—that occupy most of the volume. Recently, a novel optical element coined a “spaceplate” has been proposed, which replaces a region of free space with a thinner optical element that emulates the free-space optical response function—thus having the potential to substantially shrink the volume of optical systems. While there have been a few proof-of-principle demonstrations of spaceplates, they have not yet been deployed in a real-world optical system. In this work, we use a bespoke-designed spaceplate to reduce the length of a gradient-index- (GRIN) lens microwave antenna. Our antenna is designed to operate at 23.5 GHz and the incorporation of a nonlocal metamaterial spaceplate enables the distance between the antenna feed and the GRIN lens to be reduced by almost a factor of 2. We find that the radiation patterns from a conventional and space-squeezed antenna are very similar, with a very low cross-polarization, and only a minor increase in the side-lobe levels when introducing the spaceplate. Our work represents a demonstration of a spaceplate integrated into a real-world optical system operating in microwave spectral region, highlighting the potential for this concept to reduce the physical size of systems in applications including imaging, spectroscopy, radar, and communications. Published by the American Physical Society 2024

Probing inhomogeneous cuprate superconductivity by terahertz Josephson echo spectroscopy

AbstractInhomogeneities crucially influence the properties of quantum materials, yet methods that can measure them remain limited and can access only a fraction of relevant observables. For example, local probes such as scanning tunnelling microscopy have documented that the electronic properties of cuprate superconductors are inhomogeneous over nanometre length scales. However, complementary techniques that can resolve higher-order correlations are needed to elucidate the nature of these inhomogeneities. Furthermore, local tunnelling probes are often effective only far below the critical temperature. Here we develop a two-dimensional terahertz spectroscopy method to measure Josephson plasmon echoes from an interlayer superconducting tunnelling resonance in a near-optimally doped cuprate. The technique allows us to study the multidimensional optical response of the interlayer Josephson coupling in the material and disentangle intrinsic lifetime broadening from extrinsic inhomogeneous broadening for interlayer superconducting tunnelling. We find that inhomogeneous broadening persists up to a substantial fraction of the critical temperature, above which this is overcome by the thermally increased lifetime broadening.

Boosting photocatalytic efficiency and nonlinear optical response of graphitic carbon nitride by infusing carbon nanotubes

Nanostructured materials are widely studied for their light-driven physical and chemical processes, which are key to their potential in photophysical applications. We introduce a one-pot solid-state pyrolysis technique for the synthesis of graphitic carbon nitride/carbon nanotube (g-C3N4/CNT) composites. The formation of the composite was characterized through X-ray diffraction, scanning and transmission electron microscopy, and X-ray photoelectron spectroscopy. Notably, UV-vis diffuse reflectance spectroscopy indicated a reduction in the bandgap of pure g-C3N4 from 2.6 eV to 2.35 eV with the incorporation of 0.5 wt% CNT. The nonlinear optical transmission of the samples was analyzed at 532 nm using the open-aperture Z-scan technique employing 5 ns laser pulses, revealing a twelve-fold increase in the two-photon absorption coefficient (b) for g-C3N4/CNT0.5 compared to pristine g-C3N4. Remarkably, g-C3N4/CNT0.5 showed enhanced photocatalytic efficiency in degrading bisphenol A (BPA), with the kinetic constant (k) being ten times higher than that of pure g-C3N4. The improved photocatalytic performance of g-C3N4/CNT0.5 is attributed to the presence of CNTs, which act as effective electron acceptors and transfer channels, significantly enhancing the separation of photogenerated charge carriers in g-C3N4, as evidenced by the decreased intensity in the photoluminescence spectrum.

Primordial Molecular 1-Bit Magnitude Comparator in consort with Excitation-Guided mouldable Logic Systems: A guided design of Regular Interactions between Molecules.

In addition to designing certain excitation modulated logic systems, we have created the first-ever genuine molecular 1-bit magnitude comparator, using acid and base guided varied absorption responses at separate channels. Designed and manufactured Bifunctional Bis(indolyl)methane Derivative (1) demonstrates distinct optical responses (in UV-visible and fluorescence mode) to a range of chemical stimuli (acid, base, Hg2+, Cu2+, EDTA, GSH, etc.) in aqueous medium. Intriguingly, the compound's excitation-modulated fluorescence responses appeared to change at different detection channels depending on whether the aforementioned analytes were present or not. We have proposed not only an excitation driven logic system with switchable molecular IMPLICATION and XNOR logic gates, but also a molecular 1-bit magnitude comparator in our proposal. A second excitation driven logic system with switchable molecular COMPLEMENT and NOR logic gates was also designed with two different optical channels and used Hg(II) & Cu(II) as chemical inputs.

Ultraviolet-Visible-Near-Infrared Broadband Photodetector Enabled by Cs2AgBiBr6: Sn/Conjugated Polymer Heterojunction.

Broadband photodetectors covering ultraviolet (UV) to near-infrared (NIR) wavelengths play an essential role in communications, imaging, and biosensing. Developing a single photodetector with a broadband optical response operating at room temperature can significantly reduce the complexity and cost of receiver systems for multispectral applications. In this work, utilizing the porous structure characteristics of Cs2AgBiBr6:Sn thin films, a self-powered detector with broad spectral response (UV-vis-NIR) was achieved by constructing an effective Cs2AgBiBr6:Sn/PDPP3T heterojunction. This photodetector possesses a broad response spectrum from 350 to 950 nm with an average detection rate exceeding 1011 Jones and maintains excellent photoelectric performance over two months. Sn2+ doping effectively reduces the bandgap of Cs2AgBiBr6, enhancing its near-infrared absorption and optimizing energy level alignment with conjugated polymer (diketopyrrolopyrrole-terthiophene, PDPP3T). More importantly, the porous structure derived from Sn doping significantly improves carrier extraction and transport under a near-infrared light response at the heterojunction interface. Utilizing its broad spectral response characteristics in the UV-vis-NIR range, a novel information transfer and encryption system employing full optical modulation has been realized within a single perovskite photodetector. This work provides a new approach to fabricating lead-free double perovskite broadband photodetectors with potential applications in photonic devices.

Designing a hollow MoSe2/CuS nanospheres type-II heterojunction photocatalyst with superior UV-vis-NIR absorption for photocatalytic degradation of organic pollutants.

In this work, a hollow MoSe2/CuS type-II heterojunction was fabricated using hollow MoSe2 nanospheres as the basis for structural design. UV-Vis-NIR diffuse absorption tests show that MoSe2/CuS has a broad spectral absorption to extend the optical response range from UV-Vis to NIR. The light source utilization rate and interfacial area are increased by the hollow MoSe2/CuS core-shell structure. The broad absorption ability of MoSe2/CuS can facilitate the photocatalysis process. As the electrochemical impedance of MoSe2/CuS is lower than that of the MoSe2, MoSe2/CuS has a good photogenerated carrier separation efficiency. Benefiting from the synergistic facilitation effect of the multi-level 3D hollow nanosphere and the significant space charge region in type-II heterojunction, the RhB degradation efficiency of MoSe2/CuS reached 96.0% in 120.0minunder Xe (350W) broadband spectrum light irradiation. The photocatalysis mechanism of the hollow MoSe2/CuS core-shell structure was investigated. This work provides an insight into the application of broad spectrum semiconductor heterojunctions to solve environmental problems.

Comparative investigation of structural, electronic, mechanical and optical responses of CsPbI3-PbSe and CsPbI3 with Mg-doped for optoelectronic applications: A first-principles study

A and B-site doping has been viewed as a very effective approach to stabilise the desired perovskite cube phase of pure and doped hetero-structure CsPbI3-Pb1-xMgxSe and the simple system CsPb1-xMgxI3. In this analysis, the effect of (Mg2+) on the crystal structure, electronic, mechanical, and optical responses of hetero-structure CsPbI3-Pb1-xMgxSe and CsPb1-xMgxI3 were thoroughly investigated, by employing first-principles computations. A theoretical study of target responses of the metal-halide CsPbI3 is presented with a plane wave ultra-soft pseudopotential approach as personified in the CASTP code. The computed results show that the band gap of CsPbI3-Pb1-xMgxSe can be changed from '1.809eV' to '1.75eV' when the concentration range (x = 0 to 0.25) is changed. A valuable band gap of '0.48eV' and '1.28eV' of doped CsPbI3-Pb1-xMgxSe can be achieved under concentrations changed from (x = 0.25 to '0.75eV') and as shown in direct (Γ - Γ) nature and become optically active. The density of states shows that Cs-6p, I-4p, and Pb-6p states contribute to the valence band maximum, whereas the main involvement conduction band minimum by Mg-5p and Cs-6p states in the CsPbI3-Pb1-xMgxSe system. Elastic properties designate the flexibility and softness of target materials. The computed elastic parameters further indicate that this hetero-structure material is stable under the doping concentration condition. Replacing the Pb2+ site with Mg2+ has red-shifted the maximum absorption edges and changed the optical characteristics to be anisotropic. Their ability of these two materials with their Mg2+ based mixed halide perovskite nature for optoelectronic applications.