Optical Resonance Research Articles

Einstein–Podolsky–Rosen conditional squeezing for next generation Gravitational-Wave detectors

Frequency-dependent squeezing (FDS) represents a well established way to address quantum noise (QN) in Gravitational-Wave (GW) Earth-based detectors, such as LIGO, Virgo, and KAGRA. This technique is realized with the use of an external detuned optical resonator, the filter cavity. The experiment we present here is a table-top prototype that will probe a cheaper, more compact and more flexible strategy for broadband QN reduction (Ma et al., 2017). This scheme is based on two-mode Einstein–Podolsky–Rosen (EPR) entangled squeezed light, and it works without any filter cavity. The EPR-entangled beams will propagate in a small-scale suspended interferometer with high-finesse arm-cavities. This experiment aims at validating the EPR conditional squeezing at audio frequencies, suited for GW detection, implementing also innovative optical techniques.

Origin of Intersystem Crossing in Red-Light Absorbing Bodipy Derivatives: Time-Resolved Transient Optical and Electron Paramagnetic Resonance Spectral Studies with Twisted and Planar Compounds.

We studied the intersystem crossing (ISC) property of red-light absorbing heavy atom-free dihydronaphtho[b]-fused Bodipy derivatives (with phenyl group attached at the lower rim via ethylene bridge, taking constrained geometry, i.e., BDP-1 and the half-oxidized product BDP-2) and dispiroflourene[b]-fused Bodipy (BDP-3) that have a twisted π-conjugated framework. BDP-1 and BDP-3 show strong and sharp absorption bands (i.e., ε = 2.0 × 105 M-1 cm-1 at 639 nm, fwhm ∼491 cm-1 for BDP-3). BDP-1 is significantly twisted (φ = 21.6°), while upon mono-oxidation, BDP-2 becomes nearly planar on the oxidized side (φ = 3.5°). Interestingly, BDP-2 showed efficient ISC (triplet state quantum yield, ΦT = 40%) due to S1/T2 state energy matching. Long-lived triplet excited state was observed (τT = 212 μs in solution and 2.4 ms in polymer matrix), and ISC takes 4.0 ns. Differently, twisted BDP-1 gives weak ISC only 5%, ISC takes 7.7 ns, and the triplet state is populated only with addition of ethyl iodide. Time-resolved electron paramagnetic resonance spectra of BDP-1 revealed the coexistence of two triplet states, with drastically different zero-field splitting D parameters of -2047 MHz and -1370 MHz, respectively, along with varying sublevel population ratios. We demonstrate that the ISC is not necessarily enhanced by torsion of the π-conjugation framework; instead, S1/Tn state energy matching is more efficient to induce ISC even in compounds that have planar molecular structures.

Rydberg-State Double-Well Potentials of Van der Waals Molecules

Recent progress in studies of Rydberg double-well electronic energy states of MeNg (Me = 12-group atom, Ng = noble gas atom) van der Waals (vdW) molecules is presented and analysed. The presentation covers approaches in experimental studies as well as ab initio-calculations of potential energy curves (PECs). The analysis is shown in a broader context of Rydberg states of hetero- and homo-diatomic molecules with PECs possessing complex ‘exotic’ structure. Laser induced fluorescence (LIF) excitation spectra and dispersed emission spectra employed in the spectroscopical characterization of Rydberg states are presented on the background of the diverse spectroscopic methods for their investigations such as laser vaporization–optical resonance (LV-OR), pump-and-probe methods, and polarization labelling spectroscopy. Important and current state-of-the-art applications of Rydberg states with irregular potentials in photoassociation (PA), vibrational and rotational cooling, molecular clocks, frequency standards, and molecular wave-packet interferometry are highlighted.

Temporal analogs of electromagnetically induced transparency, induced absorption, and Fano resonance.

We describe the occurrence of electromagnetically induced transparency (EIT), electromagnetically induced absorption (EIA), and Fano resonance due to time-controlled discontinuities in the refractive index of a medium, which leads to the formation of a double-cavity system inside a temporal photonic crystal. The temporal resonances partly resemble the optical resonances arising in conventional microcavities, since the amplified temporal EIA displays distinct spectral characteristics. Although an amplified EIT does not occur, a strongly amplified EIA affects the behavior of EIT as well. Besides modifying the temporal resonances via coupled-cavity interactions, we reveal refractive index-controlled temporal resonances. This computational study paves the way to probe the temporally driven coherent phenomena of EIT and EIA with potential applications such as slow-light, amplified fast-light, amplified ultranarrow bandwidth optical filters, and multicavity systems.

Efficient second-harmonic generation in a lithium niobate metasurface governed by high-Q magnetic toroidal dipole resonances.

Lithium niobate (LN) is an excellent nonlinear optical material due to its large nonlinear coefficient, low loss, and broad optical transparency window. So, it is widely used in the generation of nonlinear harmonics. Magnetic toroidal dipole (MTD) resonance is a special optical resonance mode, which can effectively localize the light field inside the device, thus enhancing the nonlinear effects of the materials. In this work, we numerically study the second-harmonic generation (SHG) effect of the LN metasurface based on the MTD mode with a high quality factor (Q-factor). The designed LN nanorod dimer metasurface supports high Q-factor MTD guided mode resonances (GMRs), which are excited by varying the center spacing of the two nanorods, and the Q-factor can be controlled by the offset distance. The excited MTD can effectively confine the electric field within the device, which enables the LN metasurface SHG conversion efficiency to reach 1.15 × 10-2. In addition, by adjusting the structural parameters, it is possible to effectively modulate the wavelength and conversion efficiency of the SHG. Our results provide a new route for high-quality nonlinear light sources.

Thin-film dielectric characterization by bound state in the continuum in high contrast grating

Subwavelength high contrast grating (HCG) is renowned for its remarkable ability to produce sharp optical resonance, known as the bound state in the continuum (BIC). Due to the strong surface field enhancement, the resonant wavelength and quality factor (Q factor) are highly sensitive to the dielectric properties of the surrounding medium. We propose utilizing this extraordinary phenomenon for thin-film dielectric characterization based on a film-substrate-grating configuration. By optimizing the geometrical parameters to control the cross-interference between guided modes in the grating and self-interference of propagating wave in the substrate slab, an accidental BIC with a Q factor reaching 104 is excited. Using this BIC, two retrieval methods based on contour mapping of resonant wavelength and Q factor are proposed to extract the complex permittivity (εf) of the film under test. It has been demonstrated that with a film thickness as thin as 10−5 times the grating period, the error in the retrieved Re[εf] is below 2%, and that of Im[εf] is below 10%. The proposed design is a strong candidate for non-destructive dielectric characterization of thin films with thicknesses below one-thousandth of the operating wavelength. This characterization technique can facilitate the development of high-frequency devices for the 6 G high-speed communication.

Single-photon circulator by spinning optical resonators

A circulator is one of the crucial devices in quantum networks and simulations. We propose a four-port circulator that regulates the flow of single photons at muti-frequency points by studying the coherent transmission of a single photon in a coupled system of two resonators and two waveguides. When both resonators are static or rotate at the same angular velocity, the single-photon transport demonstrates reciprocity; however, when the angular velocities differ, four distinct frequency points emerge where photon circulation can occur. In particular, when the angular velocities of the two resonators are equal and opposite, there are two different frequency points where photon circulation can be achieved, and there is a frequency point where a single photon input from any waveguide can be completely routed to the other waveguide. Interestingly, by rotating the two resonators, the single-photon circulation suppressed by the internal defect-induced backscattering can be restored.

Retraction Note: Application of optical magnetic resonance imaging detection in the safety of direct aspiration thrombectomy for acute intracranial arterial occlusion surgery

Retraction Note: Application of optical magnetic resonance imaging detection in the safety of direct aspiration thrombectomy for acute intracranial arterial occlusion surgery

Genuine non-Gaussian entanglement of light and quantum coherence for an atom from noisy multiphoton spin-boson interactions

Harnessing entanglement and quantum coherence plays a central role in advancing quantum technologies. In quantum optical light-atom platforms, these two fundamental resources are often associated with a Jaynes-Cummings model description describing the coherent exchange of a photon between an optical resonator mode and a two-level spin. In a generic nonlinear spin-boson system, more photons and more modes will take part in the interactions. Here we consider such a generalization: the two-mode multiphoton Jaynes-Cummings (MPJC) model. We demonstrate how entanglement and quantum coherence can be optimally generated and subsequently manipulated in experimentally accessible parameter regimes. A detailed comparative analysis of this model reveals that nonlinearities within the MPJC interactions produce genuinely non-Gaussian entanglement, devoid of Gaussian contributions, from noisy resources. More specifically, strong coherent sources may be replaced by weaker, incoherent ones, significantly reducing the resource overhead, though at the expense of reduced efficiency. At the same time, increasing the multiphoton order of the MPJC interactions expedites the entanglement generation process, thus rendering the whole generation scheme again more efficient and robust. We further explore the use of additional dispersive spin-boson interactions and Kerr nonlinearities in order to create spin coherence solely from incoherent sources and to enhance the quantum correlations, respectively. As for the latter, somewhat unexpectedly, there is not necessarily an increase in quantum correlations due to the augmented nonlinearity. Towards possible applications of the MPJC model, we show how, with appropriately chosen experimental parameters, we can engineer arbitrary NOON states as well as the tripartite W state. Published by the American Physical Society 2024

A comprehensive study of optical resonances in metals, dielectrics, and excitonic materials in double interface structures

From an optical perspective, depending on the relationship between the real (n) and imaginary (k) parts of its refractive index, three broad categories of materials can be distinguished: metals (k ≫ n), dielectrics (n ≫ k), and materials in which n ≈ k (termed here excitonic materials). The modes and optical resonances that appear in a thin film bounded by two dielectrics with similar refractive index, what we call here a double interface structure, have been widely studied in the case of metals, but not for dielectrics, or materials with n ≈ k. In this work, we propose a new approach, based on employing the phase matching condition to correlate the resonances that appear in the wavelength versus incident angle color maps of the reflected power with the modal analysis of the cross section of the structure. This analysis is performed, using an attenuated total reflection (ATR) setup, for thin film materials that belong to each of the mentioned categories: a metal (gold, Au), a dielectric (titanium dioxide, TiO2), and a material with n ≈ k (chromium, Cr). The theoretical analysis is supported with experimental results. It is demonstrated that this method enables to identify any resonance at any wavelength or incident angle, being valid for all three types of materials. Therefore, it is considered the suggested approach will help the research in these materials and in the double interface structure in the optics and photonics field.

Intramolecular Charge Transfer and Spin-Orbit Coupled Intersystem Crossing in Hypervalent Phosphorus(V) and Antimony(V) Porphyrin Black Dyes.

Porphyrin dyes with strong push-pull type intramolecular charge transfer (ICT) character and broad absorption across the visible spectrum are reported. This combination of properties has been achieved by functionalizing the periphery of hypervalent and highly electron-deficient phosphorus(V) and antimony(V) centered porphyrins with electron-rich triphenylamine (TPA) groups. As a result of the large difference in electronegativity between the porphyrin ring and the peripheral groups, their absorption profiles show several strong charge transfer transitions, which in addition to the porphyrin-centered π → π* transitions, make them panchromatic black dyes with high absorption coefficients between 200 and 800 nm. Time-resolved optical and electron paramagnetic resonance (EPR) studies show that the lowest triplet state also has ICT character and is populated by spin-orbit coupled intersystem crossing.

Demonstration of record sensitivity for water vapor detection by means of comb-locked cavity ring-down spectroscopy

We report on the development, characterization, and test of a comb-locked cavity ring-down spectrometer (CL-CRDS) operating in the spectral region around 1.39 µm. The system is based on the use of a hemispherical optical resonator with a finesse as high as ∼507000, which gives an empty-cavity ring-down time of about 285 µs. An Allan-Werle analysis on repeated acquisitions of the ring-down time at a fixed laser frequency suggests a minimum detectable absorption coefficient of 2×10−12cm−1 for the optimum integration time of 45 s. This limit can be exceeded by adopting the strategy of long-term spectral averaging. Taking advantage of the frequency stability guaranteed by the optical frequency comb, the CL-CRDS spectra were averaged over more than two days, thus removing efficiently the effect of mechanical, acoustic, and thermal noises. As a result, we could achieve a minimum detectable absorption coefficient as low as 3.7×10−13cm−1, which corresponds to a limit of detection for H2O in N2 of nine parts per trillion and a H2O partial pressure of 2×10−8 Pa (or 2×10−10 mbar). The potentialities of our approach are demonstrated by recording the absorption features of HD16O and HD18O in flows of ultra-high-purity N2 and ambient air, respectively.

Nonlinear integrated optical resonators for optical fibre data recovery

We apply in simulation a reservoir computer based on evanescently coupled GaAs microrings for real-time compensation of a nonlinear distortion of a 50 Gbaud 16-QAM signal with the launch power up to 14 dBm in a standard single-mode optical fibre. We clearly evidence the crucial role of fast nonlinear response in enabling all-optical signal recovery in real time. With our system we are able to recover from linear and nonlinear distortion caused by a 20 km fibre and 12 dBm launch power below the forward error correction limit.

Purcell Enhancement and Spin Spectroscopy of Silicon Vacancy Centers in Silicon Carbide Using an Ultrasmall Mode-Volume Plasmonic Cavity.

Silicon vacancy (VSi) centers in 4H-silicon carbide have emerged as a strong candidate for quantum networking applications due to their robust electronic and optical properties, including a long spin coherence lifetime and bright, stable emission. Here, we report the integration of VSi centers with a plasmonic nanocavity to Purcell enhance the emission, which is critical for scalable quantum networking. Employing a simple fabrication process, we demonstrate plasmonic cavities that support a nanoscale mode volume and exhibit an increase in the spontaneous emission rate with a measured Purcell factor of up to 48. In addition to investigating the optical resonance modes, we demonstrate an improvement in the optical stability of the spin-preserving resonant optical transitions relative to the radiation-limited value. The results highlight the potential of nanophotonic structures for advancing quantum networking technologies and emphasize the importance of optimizing emitter-cavity interactions for efficient quantum photonic applications.

Gratings for enhanced sensitivity: advancing D-shaped optical fiber surface plasmon resonance sensors with Ag-Fe2O3 structures

This research delves into enhancing biosensing sensitivity by optimizing D-shaped optical fiber surface plasmon resonance (SPR) sensors employing Ag-Fe2O3 structures. By investigating the influence of different grating structures—rectangular, triangular, and elliptical—on sensor performance, a comprehensive analysis was conducted to ascertain the impact of these structural variations on sensitivity and detection precision. The study revealed that while the rectangular structure exhibited a sensitivity of 6.4 µm/RIU, the triangular structure outperformed with an impressive sensitivity of 7.2 µm/RIU. Moreover, the detection accuracy, quantified by the detection angle (DA), reached 15.7(µm)−1 for the triangular grating, surpassing the rectangular grating’s detection angle of 14.8(µm)−1. These results underscore the crucial role of structural design in enhancing sensor performance, with the triangular grating demonstrating superior sensitivity and detection precision in the context of plasmonic resonance. The extended detection range of refractive indices around 1.39 further expands the sensor’s applicability in diverse chemical and biomedical analyses. Notably, the sensor’s capability to detect various chemical solutions and diseases—including plasma, tuberculosis, white blood cells, and breast cancer cells—underscores its versatility and efficacy in dual-parameter detection. Through meticulous simulations and analysis, this study provides valuable insights into optimizing sensor sensitivity, detection accuracy, and application versatility, paving the way for advanced developments in biosensing technology with far-reaching implications for chemical and biomedical research.

Polarization-Controlled Exciton-Polaritons in WS2 Strongly Coupled with Low-Symmetry Photonic Crystal Nanostructures.

Atomically thin transition metal dichalcogenides (TMDs) with ambient stable exciton resonances have emerged as an ideal material platform for exciton-polaritons. In particular, the strong coupling between excitons in TMDs and optical resonances in anisotropic photonic nanostructures can form exciton-polaritons with polarization selectivity, which offers a new degree of freedom for the manipulation of the light-matter interaction. In this work, we present the experimental demonstration of polarization-controlled exciton-polaritons in tungsten disulfide (WS2) strongly coupled with polarization singularities in the momentum space of low-symmetry photonic crystal (PhC) nanostructures. The utilization of polarization singularities can not only effectively modulate the polarization states of exciton-polaritons in the momentum space but also facilitate or suppress their far field coupling capabilities by tuning the in-plane momentum. Our results provide new strategies for creating polarization-selective exciton-polaritons.

Integrated optic microring resonator for various sensing applications: design and analysis

Integrated optic microring resonator for various sensing applications: design and analysis

Fine-Tuning of Optical Resonance Wavelength of Surface-Micromachined Optical Ultrasound Transducer Arrays for Single-Wavelength Light Source Readout.

This article reports the fine-tuning of the optical resonance wavelength (ORW) of surface-micromachined optical ultrasound transducer (SMOUT) arrays to enable ultrasound data readout with non-tunable interrogation light sources for photoacoustic computed tomography (PACT). Permanent ORW tuning is achieved by material deposition onto or subtraction from the top diaphragm of each element with sub-nanometer resolution. For demonstration, a SMOUT array is first fabricated, and its ORW is tuned for readout with an 808 nm laser diode (LD). Experiments are conducted to characterize the optical and acoustic performances of the elements within the center region of the SMOUT array. Two-dimensional and three-dimensional PACT (photoacoustic computed tomography) is also performed to evaluate the imaging performance of the ORW-tuned SMOUT array. The results show that the ORW tuning does not degrade the optical, acoustic, and overall imaging performances of the SMOUT elements. As a result, the fine-tuning method enables new SMOUT-based PACT systems that are low cost, compact, powerful, and even higher speed, with parallel readout capability.

Nanotechnology-Enabled PCR with Tunable Energy Dynamics.

This Perspective elucidates the transformative impacts of advanced nanotechnology and dynamic energy systems on the polymer chain reaction (PCR), a cornerstone technique in biomedical research and diagnostic applications. Since its invention, the optimization of PCR-specifically its efficiency, specificity, cycling rate, and detection sensitivity-has been a focal point of scientific exploration. Our analysis spans the modulation of PCR from both material and energetic perspectives, emphasizing the intricate interplay between PCR components and externally added entities such as molecules, nanoparticles (NPs), and optical microcavities. We begin with a foundational overview of PCR, detailing the basic principles of PCR modulation through molecular additives to highlight material-level interactions. Then, we delve into how NPs, with their diverse material and surface properties, influence PCR through interface interactions and hydrothermal conduction, drawing parallels to molecular behaviors. Additionally, this Perspective ventures into the energetic regulation of PCR, examining the roles of electromagnetic radiation and optical resonators. We underscore the advanced capabilities of optical technologies in PCR regulation, characterized by their ultrafast, residue-free, and noninvasive nature, alongside label-free detection methods. Notably, optical resonators present a pioneering approach to control PCR processes even in the absence of light, targeting the often-overlooked water component in PCR. By integrating discussions on photocaging and vibrational strong coupling, this review presents innovative methods for the precise regulation of PCR processes, envisioning a new era of PCR technology that enhances both research and clinical diagnostics. The synergy between nanotechnological enhancements and energy dynamics not only enriches our understanding of PCR but also opens new avenues for developing rapid, accurate, and efficient PCR systems. We hope that this Perspective will inspire further innovations in PCR technology and guide the development of next-generation clinical detection instruments.

An increased copy number of glycine decarboxylase (GLDC) associated with psychosis reduces extracellular glycine and impairs NMDA receptor function.

Glycine is an obligatory co-agonist at excitatory NMDA receptors in the brain, especially in the dentate gyrus, which has been postulated to be crucial for the development of psychotic associations and memories with psychotic content. Drugs modulating glycine levels are in clinical development for improving cognition in schizophrenia. However, the functional relevance of the regulation of glycine metabolism by endogenous enzymes is unclear. Using a chromosome-engineered allelic series in mice, we report that a triplication of the gene encoding the glycine-catabolizing enzyme glycine decarboxylase (GLDC) - as found on a small supernumerary marker chromosome in patients with psychosis - reduces extracellular glycine levels as determined by optical fluorescence resonance energy transfer (FRET) in dentate gyrus (DG) and suppresses long-term potentiation (LTP) in mPP-DG synapses but not in CA3-CA1 synapses, reduces the activity of biochemical pathways implicated in schizophrenia and mitochondrial bioenergetics, and displays deficits in schizophrenia-like behaviors which are in part known to be dependent on the activity of the dentate gyrus, e.g., prepulse inhibition, startle habituation, latent inhibition, working memory, sociability and social preference. Our results demonstrate that Gldc negatively regulates long-term synaptic plasticity in the dentate gyrus in mice, suggesting that an increase in GLDC copy number possibly contributes to the development of psychosis in humans.