Optical Properties Research Articles

An investigation for optical, photocatalytic, photoluminescence and dielectric properties of Cd0.40Ni0.60ZnO2 annealed nanocomposites

We report here the optical, photoluminescence (PL), and dielectric properties of Cd0.40Ni0.60ZnO2 nanocomposites annealed between 200 and 600oC. An increase in annealing temperature (Tann) up to 600oC correlates with a gradual increase in the crystallite and particle sizes. The surface area, pore radius, and pore volume are increased as Tann increases from 200oC to 300oC, and then decreased, but still higher than of 200oC. Similar behaviors were obtained for the absorbance carrier density, photocatlytic efficiency, degradation rate, PL intensity, dielectric constant, dielectric loss, ac conductivity, F-factor, series resistance, and electronic polarizability. While the energy gap, binding energy, impedance of grains and their boundaries, and effective capacitance show an opposite behavior. The relaxation times at the peak of dielectric parameters are between 11.54 and 159.24ns and between 35.23 and 24273.73ns, respectively. The Cole-Cole plot shows a single semicircle at Tann < 400oC and two successive semicircles at Tann> 500oC. The energy of PL of visible emissions is independent on the chosen Tann. These findings indicated that the nanocomposite annealed at 300oC can be used for water purification, telecommunications, solar cells, supercapacitor, and white light-emitting diodes (LEDs).

Comparative effects of glazing versus polishing on mechanical, optical, and surface properties of zirconia ceramics with different translucencies.

This study compared the effects of glazing versus polishing on mechanical, optical, and surface properties of zirconia ceramics with different translucencies. In this in vitro study, 120 bar-shaped specimens (25 × 4 × 1.2 mm) were fabricated from three different types of zirconia with different translucencies (n = 40, DD Bio ZW, ZX2, and Cube X2). After sintering, each zirconia group was randomly divided into five subgroups of control (glazing), glazing + bur abrasion, glazing + bur abrasion + polishing with EVE Diacera® kit, glazing + bur abrasion + reglazing, and glazing + bur abrasion + polishing with EVE Diacera® kit + reglazing. The specimens underwent surface roughness, hardness, flexural strength, and translucency tests, as well as X-ray diffraction (XRD) and scanning electron microscopy (SEM) for assessment of surface topography. Data were analyzed by one-way analysis of variance, Tukey test, and Pearson test (α = .05). Flexural strength, surface hardness, and translucency were significantly correlated with zirconia type. ZW zirconia had significantly higher flexural strength and surface hardness and significantly lower translucency than Cube X2 and ZX2 (p < .001). Surface roughness had no significant correlation with zirconia type (p = .274). Polishing created the smoothest, and bur abrasion created the roughest surface (p < .001). Flexural strength and hardness in most experimental groups were significantly lower than in the control group (p < .001). Translucency was not significantly different in bur abrasion and polishing groups, compared with the control group; however, reglazing significantly increased the translucency (p < .001). SEM micrographs confirmed the surface roughness results. XRD showed monoclinic phase only in reglazed groups. Of different surface treatments, polishing improved the surface properties and caused the smallest change in mechanical properties of zirconia with different translucencies.

Research and Progress of Inorganic Infrared Electrochromic Materials and Devices.

Electrochromic materials can dynamically change their optical properties (such as transmittance, absorbance, and reflectance under the action of an applied voltage, and their research and application in the visible band have been widely concerned. In recent years, with the continuous development of electrochromic technology, the related research has been gradually extended to the infrared region. This invited review aims to provide an overview of the current status of several inorganic infrared electrochromic materials, to provide some references for future research, and to promote the research and application of electrochromic technology in the infrared region. This review summarizes various research results in the field of infrared electrochromic, which includes a detailed literature review and patent search. Starting from the key performance parameters and device structure characteristics of infrared electrochromic devices (ECDs), the research and progress of several types of inorganic infrared electrochromic materials, including metal oxides, plasma nanocrystals, and carbon nanomaterials, are mainly presented, and feasible optimization directions are also discussed. We believe that the potential of these materials for civilian and military applications, for example, infrared electrochromic smart windows, infrared stealth/disguise, and thermal control of spacecraft, can be fully exploited by optimizing the materials and their devices to improve their performance.

The structural and optical properties of PVA/CMC copolymer cured by UV irradiation for different times

Poly(vinyl alcohol) (PVA)/carboxymethylcellulose (CMC) blend films with equal amounts (0.25 g) of both polymers were prepared through a simple and low-cost comparative casting method. Then, the PVA/CMC blend films were exposed to ultraviolet (UV) radiation for varied time intervals (1, 12, 26, 32, 40 and 48 h). The UV-irradiation effect on the physical properties of as-prepared films, including the structure, morphology, composite and optical properties (transmittance, absorbance and band gap (E g)), was examined. Field-emission scanning electron microscopy images showed that UV irradiation had a strong effect on the shape of PVA/CMC blend films. The X-ray diffraction patterns showed various crystalline qualities in the microstructure of as-synthesized samples. The Fourier transform infrared spectra showed that the UV-irradiation time and CMC film had a positive impact on the blend polymer structure since covalent connections were formed between CMC and PVA. Furthermore, the analysis results of optical inspections showed that the absorbance of the PVA/CMC films improved with an increment in irradiation time from 1 to 40 h. Important tuning of the E g values of blend films was realized. It showed a slight increase from 4.64 to 4.84 eV with increasing irradiation time from 1 to 40 h. The E g value (3.21 eV), however, displayed an inverted behavior due to an increased irradiation time of 48 h. This reduction could be ascribed to the creation of defects inside the blend band gap. Finally, the physical property modification of PVA/CMC blend film using UV irradiation made it an amazing contender in the optoelectronic field.

Enhancement the linear/nonlinear optical and magnetic properties of ZnCo2O4 nanostructures through Ni/Fe dual doping

Nano Zn0.9Ni0.1Co2-xFexO4 samples were prepared using the hydrothermal procedure in order to enhance the functional characteristics of ZnCo2O4 sample. The structural and microstructural parameters of the prepared samples were determined through Rietveld and FTIR analyses. The morphologies and compositions of the samples were examined by SEM and EDS techniques. Upon Ni2+ doping, the bandgap energy of nano ZnCo2O4 decreased from 2.22 eV to 3.61 eV–2.18 eV and 3.51 eV. Doping with Fe caused a slight decrease in bandgap energy for x = 0.05, then an increase for a higher content of Fe. Several empirical equations were used to determine the refractive index from the corresponding obtained optical energy gap values. As the Fe content rose to 5 %, the value of refractive index and nonlinear optical parameters increased; thereafter, it declined with additional Fe doping. The photoluminescence technique was used to analyze defects and processes of charge carrier recombination in the samples. ZnCo2O4 sample exhibits paramagnetic performance. With the addition of Ni to ZnCo2O4, the magnetic characteristics of the sample became superparamagnetic. Samples doped with Ni and various quantities of Fe exhibit a weak ferromagnetic behavior. The effect of doping on the magnetic transition, coercivity, saturation magnetization and remanent magnetization was explored.

Optical, thermal, FTIR, SEM-EDX and 1H NMR analysis of Chenopodium album (Bathua) powder prepared using different drying techniques

Chenopodium album (L.) is an underutilized agricultural crop consumed as a leafy vegetable in Asian countries. Although perishable and cultivated in a specific season, it contains nutrients and phytochemicals in abundance. Preservation by employing drying techniques helps in their utilization in the off-season for better food security. In the present study, Chenopodium album leaves were dried using sun, tray, and freeze drying. The different powder samples were characterized on the basis of their physicochemical, optical, and thermal properties. The water activity of powder samples ranged between 0.29 and 0.56. The highest color retention (L* value 47.21) and lowest particle size (11.5 µm) was observed in freeze dried samples. Fourier-transform infrared spectroscopy and Nuclear magnetic resonance spectra confirmed the presence of several functional groups. Thermal analysis revealed the thermal degradation of powder due heat as depicted by change of state and loss of weight. Surface morphological study indicated that powder samples were flowable and element analysis showed presence of C, O, K, Ca, Mg, P, S element in powders.

A nonlocal photoacoustic effect with variable thermal conductivity of semiconductor material subjected to laser heat source

This study explores the behavior of laser-exposed photo-excited carriers, investigating the propagation of photoacoustic waves in the thermoelastic domain. It also delves into the theoretical generation of surface acoustic waves in semiconductors through photo-thermoelastic processes. The research considers the interaction between thermomechanical and acoustic waves in a nonlocal medium with temperature-dependent thermal conductivity. Unlike relying on electron–phonon or electron-hole thermalization processes, photoacoustic waves here result from thermoelastic stress induced by the laser-induced temperature increase. The investigation accounts for the optical, mechanical, and thermoelastic properties of nanoscale semiconductor materials. Predictions of photoacoustic signals are derived by solving a combined thermal diffusion issue and a thermoelastic problem, using Laplace and Fourier transforms in the mathematical model. Numerical solutions encompass various physical fields within the time domain using the inversion technique of Laplace and Fourier transforms, such as thermal, acoustic, mechanical, and carrier density diffusion. The study evaluates and compares the influences of thermal memory and thermal conductivity presenting visual representations.

Recent Advances in Chemistry, Mechanism, and Applications of Quantum Dots in Photodynamic and Photothermal Therapy.

Semiconductor quantum dots (QD) are a kind of nanoparticle with unique optical properties that have attracted a lot of attention in recent years. In this paper, the characteristics of these nanoparticles and their applications in nanophototherapy have been reviewed. Phototherapy, including photodynamic therapy (PDT) and photothermal therapy (PTT), has gained special importance because of its high accuracy and local treatment due to the activation of the drug at the tumor site. PDT is a new way of cancer treatment that is performed by activating light-sensitive compounds named photosensitizers (PS) by light. PSs cause the destruction of diseased tissue through the production of singlet oxygen. PTT is another non-invasive method that induces cell death through the conversion of near-infrared light (NIR) into heat in the tumor situation by the photothermal agent (PA). Through using energy transfer via the FRET (Förster resonance energy transfer) process, QDs provide light absorption wavelength for both methods and cover the optical weaknesses of phototherapy agents.

Sm-doped ZnO with enhanced photocatalytic performance toward destruction of RhB

In this work, Sm-doped ZnO was prepared by a Sol-Gel method. The structure, morphology, composition and optical properties of the prepared samples were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), surface photovoltage spectrum (SPS) and X-ray photoelectron spectros­copy (XPS). Sm-doping results in high specific surface area and boosted photogenerated carriers separation efficiency, and produces more active free radicals to participate in the photocatalytic reaction. Photocatalytic activities of the samples toward removal of rhodamine B(RhB) were evaluated under UV light irradiation, the results display that Sm-doped ZnO shows higher photocatalytic activity than the reference ZnO.

Manipulating cationic ordering toward highly efficient and zero-thermal-quenching cyan photoluminescence

Developing effective design principle in crystalline materials for superior optical properties remains a critical challenge. Herein, we establish the cationic ordering strategy to build rigid framework and significantly improve phosphor performance. As a proof of concept, the NaHf2-xYx(PO4)3:Eu2+ (x = 0.05–0.2) phosphor series is constructed, which possesses absolutely cationic ordered structure and the linked outstanding photoluminescent properties. Structurally, heterovalent substitution in the lattice maintains the single-site occupancy of Na+ ions in NaHf2-xYx(PO4)3:Eu2+, as confirmed by Rietveld refinements and NMR spectroscopy. This cationic arrangement keeps the cation/vacancy ordered distribution that ensures high structural rigidity, with Debye temperature, as the indicator of rigidity, extracted from low temperature heat capacities exceeding 379 K. The resultant high structural rigidity, coupled with intrinsic defects, induces zero-thermal-quenching luminescence up to 150 °C. Moreover, the substitution of Y3+ at Hf4+ site facilitates effective Eu3+ to Eu2+ reduction, making them excellent cyan emitters with quantum efficiency exceeding 90 % and intense violet absorption. This work provides an impetus for the discovery of the currently state-of-the-art cyan phosphors for practical applications and gives insight into the structural factors influencing luminescent properties.

Comparative studies of GaN, n-GaN and n+-GaN contact layers on GaN/c-Al2O3 virtual substrates synthesized by PA MBE

An approach to create ohmic contacts to GaN layers without using the high-temperature annealing procedure is described in the paper. The results of comparative studies of structural, morphological, optical, and electrical properties of undoped GaN and silicon-doped n-GaN and n+-GaN doped contact layers are presented.The contact layer technology can be successfully realized using a plasma-assisted molecular beam epitaxy (PA MBE) setup of industrial type, where due to characteristic design features, the growth of nitride AIIIN compounds occurs using small streams of activated nitrogen, which significantly limits the possibility of varying the technological parameters.For the first time it is demonstrated that using the proposed technology for the creation of post-grown GaN, n-GaN and n+-GaN contact layers to GaN/c-Al2O3 virtual substrates in Ga-enriched conditions of epitaxial PA MBE growth at relatively low temperatures Ts=700oC an effective filtration of dislocations threading from the buffer GaN layer of the virtual substrate formed by MOCVD can be realized.Calculations of in-plane εxx and out-of-plane εzz deformations, as well as residual biaxial stresses based on X-ray diffraction and Raman microspectroscopy data indicate at high structural quality of the formed contact layer regardless of the silicon doping level. At the same time PA MBE contact layers GaN, n-GaN and n+-GaN demonstrate close optical properties (refractive index and photoluminescence) in a wide range (400-850 nm), as well as minimal influence of defects associated with the formation of silicon clusters at high doping levels.The contact resistance reduced to the pad width determined using the transmission line method for the structure with n+-GaN contact layer was of ∼0.11 Ohm*mm and ∼0.5 Ohm*mm for n-GaN. Note that electrophysical characteristics of n-GaN and n+-GaN contact layers do not degrade under high-dose exposure of high-energy X-ray irradiation.The technique developed in our work to create ohmic contacts to GaN layers, as well as the obtained experimental results, have important implications for understanding the physics of AIIIN nanoheterostructures and will contribute to their potential applications in their fabrication.

Phacoemulsification Plus Intraocular Lens Implantation with Gold Nanoparticles for Complicated Cataract Secondary to Uveitis: Efficacy Analysis

This study analyzes the efficacy of phacoemulsification (PE) plus intraocular lens implantation (IOLI) in patients with complicated cataracts secondary to uveitis. Nanostructured photothermal ring integrated (nano)-intraocular lens (IOLs) were developed to improve the biocompatibility and optical properties of IOLs. However, data on the safety profile and effectiveness of IOLI for patients with complicated cataracts secondary to uveitis are scarce, and studies have questioned the safety of PE in patients undergoing cataract surgery. We used gold nanoparticle (AuNP)-modified commercially available intraocular IOLs combined with PE technology to treat patients with complicated cataracts secondary to uveitis. First, we found that AuNP-modified IOLs were effective in reducing macrophage and bacterial adhesion and were biocompatible with the organism. Then, 64 patients with complicated cataracts secondary to uveitis were totally selected from February 2019 to February 2022, of which 33 cases were treated with PE+IOLI (test group) and 31 with conventional small-incision extracapsular cataract extraction (SIECCE) and IOLI (control group). Intergroup comparisons based on efficacy, safety, visual acuity (VA), aqueous humor protein levels before and after treatment, and quality of life (assessed with the Generic Quality of Life Inventory-74, GQOLI-74) revealed higher overall treatment efficacy and postoperative VA, as well as lower complication rate and postoperative aqueous humor protein levels, in the test group than the control group. Moreover, the test group had higher GQOLI-74 scores in the dimensions of physical function, mental health, psychological health, and social competence than the control group. Thus, PE+IOLI is more suitable for patients with complicated cataracts secondary to uveitis than conventional SIECCE+IOLI. PE+IOLI can improve treatment efficacy and safety, as well as patient VA and quality of life.

Effects of oxygen vacancies on the structural, electronic, and optical properties of the photocatalytic InTaO4 compound

We conducted first-principles calculations based on density functional theory to investigate the impact of the oxygen vacancies on the structural, electronic, and optical properties of the InTaO4 compound. The latter is a famous photocatalytic semiconductor with its optical absorption in the visible range being an object of controversial interpretations. The presence of two types of isolated oxygen vacancies, O1 and O2, occupying 4g(1) and 4g(2) Wyckoff positions respectively, has been simulated within the frame of the supercell approach. Electronic structure and optical absorption (OA) have been calculated using the Becke-Johnson exchange-correlation potential. It is found that the presence of both types of vacancies generates defect states (DS) inside the band gap, primarily involving In-6s and O-2p states. The calculated valence-to-conduction-band band gap (4.25 eV) and DS-to-conduction-band band gap (2.5 eV) closely align with the experimentally determined OA edges for two onsets of InTaO4 absorption. The analysis of the calculated OA spectra leads to the conclusion that only O1 vacancy-induced absorption is consistent with the experimental OA, while O2 vacancy-induced absorption appears absent. This discrepancy probably arises from a higher concentration of O1 vacancies formed during crystal growth, attributed to the fact that the calculated defect formation energy of O1 vacancy is 0.258 eV lower compared to O2 vacancy. Consequently, the photocatalytic activity of InTaO4 is ascribed to intrinsic defects, primarily O1-type vacancies, though the influence of other defects cannot be entirely ruled out.

EXPERIMENTAL AND THEORETICAL INTERPRETATIONS OF STRUCTURAL, OPTICAL, MECHANICAL AND THERMAL PROPERTIES OF 2 AMINOPYRIDINIUM PHTHALATE SINGLE CRYSTALS

Nonlinear optical good quality single crystals of 2-aminopyridinium phthalate single crystals are synthesized by solution growth technique. Structural parameters are elucidated by Single Crystal X-ray diffraction method which reveals that the material crystallizes in non-centrosymmetric crystalline framework. Vibrational assignments are interpreted by Fourier Transform Infrared spectral analysis. The thermal, mechanical and laser stability are explored by TG/DTA, microhardness and Laser Damage threshold analysis. The material has good emission nature in the violet emission region. The linear optical properties are elucidated with the help of UV-visible spectral analysis. The intermolecular charge transfer interactions are analyzed by HOMO-LUMO and MESP maps by using Gaussian ’09 software program. The second harmonic generation efficiency of the synthesized material are predicted by Kurtz Perry powder technique.

Regulation of photoelectric properties of multi-element (Sn, Fe, Ce) co-doped anatase TiO2: The first principles study

The energy band structure, density of states and optical properties of multi-element (Sn, Fe, Ce) co-doped anatase titanium dioxide have been calculated using the first principles method. The results show that two-element (Sn, Fe, Ce) doping affects the energy band structure more than the single doping behaviour. Co-doping of two of the three elements (Sn, Fe, Ce) reduced the energy band gap values of TiO2 compared to pure anatase TiO2.The forbidden bandwidths of Sn and Ce were smaller than those of mono-doped Sn, but the co-doped system had higher bandwidth narrowing than that of the mono-doped system. The co-doping of Sn and Ce is 0.206 eV smaller than the single doping of Sn, and the co-doping of Sn and Fe is 0.56 eV smaller than the single doping of Sn. The utilization of the regional light absorption is increased, and the absorption spectra are red-shifted. It can be seen that the co-doping method is more favourable to the improvement of visible light response and visible photocatalytic activity of TiO2 than the single doping method.

Study on Infrared (IR) Camouflage Using Mylar in the Defense Sector

Abstract: This project investigates the feasibility of utilizing Mylar, a highly reflective polyester film, for infrared (IR) camouflage in the defense sector. Through a comprehensive analysis of Mylar's optical properties, including its reflectivity and reflectance, this study aims to assess the material's potential for reducing thermal signatures and enhancing stealth capabilities of military assets. The research involves theoretical and numerical analysis to evaluate Mylar's performance under various environmental conditions, such as temperature extremes, humidity, and exposure to ultraviolet (UV) radiation. Furthermore, the project explores the integration of Mylar-based IR camouflage into existing defense systems, including vehicle coatings, personnel gear, and tactical equipment. Recommendations for the deployment and optimization of Mylar-based camouflage solutions are provided, addressing factors such as material selection, camouflage design, compatibility with sensor systems, and logistical support. The findings demonstrate Mylar's efficacy in decreasing IR detectability, providing a cost-effective and versatile solution in IR camouflage. This research contributes significantly to the field of defense technology, offering practical insights and paving the way for further advancements in stealth and counter-detection measures in military applications.

Biosynthesis of silver nanoparticles using green tea leaf extract and their structural and optical analysis

In the present study, silver nanoparticles (Ag NPs) were synthesized by biosynthesis method using Green tea leaf extract. Biosynthesis is an easy, economical, and environmentally friendly method to prepare NPs. The synthesized NPs were characterized by using an X-ray diffraction spectrum (XRD), UV-Vis spectra, Tauc plot and Dynamic light scattering spectrum analysis. The XRD results of biosynthesized Ag NPs show that the particles are crystalline and face-cantered cubical in shape, with an average size of 14 nm. UV-visible spectra studies and Tauc plot analysis confirm the excellent optical properties of the Ag NPs. Due to these outstanding qualities, we anticipated that the use of green-produced Ag NPs would result in an exponential increase in various applications. Ag NPs exhibit cytotoxicity and anticancer characteristics, antibacterial, antioxidant, and antifungal activity.

Fabrication of innovative multifunctional dye using MXene nanosheets.

The increasing demand for natural and safer alternatives to traditional hair dyes has led to the investigation of nanomaterials as potential candidates for hair coloring applications. MXene nanosheets have emerged as a promising alternative in this context due to their unique optical and electronic properties. In this study, we aimed to evaluate the potential of Ti3C2Tx (Tx = -O, -OH, -F, etc.) MXene nanosheets as a hair dye. MXene nanosheet-based dyes have been demonstrated to exhibit not only coloring capabilities but also additional properties such as antistatic properties, heat dissipation, and electromagnetic wave shielding. Additionally, surface modification of MXene using collagen reduces the surface roughness of hair and upregulates keratinocyte markers KRT5 and KRT14, demonstrating the potential for tuning its physicochemical and biological properties. This conceptual advancement highlights the potential of MXene nanosheets to go beyond simple cosmetic improvements and provide improved comfort and safety by preventing the presence of hazardous ingredients and solvents while providing versatility.

Recent advances and challenges of the green ZnO-based composites biosynthesized using plant extracts for water treatment.

Recently, there has been a notable rise in the prevalence of persistent pollutants in the environment, posing a significant hazard due to their toxicity and enduring nature. Conventional wastewater treatment methods employed in treatment plants rarely address these persistent pollutants adequately. Meanwhile, the concept of green synthesis has garnered considerable attention, owing to its environmentally friendly approach that utilizes fewer toxic chemicals and solvents. The utilization of materials derived from sustainable sources presents a promising avenue for solving pressing environmental concerns. Among the various sources of biological agents, plants stand out for their accessibility, eco-friendliness, and rich reserves of phytochemicals suitable for material synthesis. The plant extract-mediated synthesis of zinc oxide nanoparticles (ZnONPs) has emerged as a promising solution for applications in wastewater treatment. Thorough investigations into the factors influencing the properties of these green ZnONPs are essential to establish a detailed and reliable synthesis process. Major weaknesses inherent in ZnONPs can be addressed by changing the optical, magnetic, and interface properties through doping with various semiconductor materials. Consequently, research efforts to mitigate water pollution are being driven by both the future prospects and limitations of ZnO-based composites. This review underscores the recent advancements of plant extract-mediated ZnONP composites for water treatment.

Photocatalytic degradation of Rhodamine B dye via Bi2O3 embedded BaO-P2O5-TeO2 glass nanocomposites: An ab initio study of structural, optical, and electrical transport properties

Bismuth incorporated glassy systems with composition xBi2O3-(1-x) [0.3BaO-0.3P2O5-0.4TeO2] (where x = 0.10, 0.15, 0.20, and 0.25) are synthesized by melt quenching technique. The glassy systems are examined for their structural, and surface morphological properties using XRD, SEM, and EDX analysis. A study of photocatalytic activity for the degradation of common organic dyes like Rhodamine B (RhB) dye under visible light is also carried out. From UV-vis absorbance data, the calculated optical band gap energy values declined from (2.99-2.56) eV, whereas the Urbach energy and refractive index values increased from (0.35 -0.52) eV, and (2.39 - 2.52), respectively with the rise of Bi2O3 content(x). Additionally, the fundamental processes of electrical conductivity have been studied within the framework of Jonscher's universal power law and the Almond-West formalism. The Mott and Greaves model asserts that the small polaron hopping model underlies DC conductivity; as Bi2O3 content increases, DC conductivity rises, but hopping distance (Rhop) and hopping energy (Whop) drop dramatically. The electrical conductivity study reveals the semi-conducting nature of the as-prepared samples. In our present study, we are focusing on the structural, optical, and electrical transportation properties, additionally, we investigated this class of glassy materials as a promising candidate for photocatalytic dye degradation. Our study reveals that RhB dye can degrade up to 75% within 340 min of visible light illumination. Moreover, the test demonstrates the production of superoxide radicals by the CB-electrons and hydroxyl radicals by the VB holes enables efficient photocatalytic dye degradation.