Optical Coefficient Research Articles

Ultralow switching threshold optical bistable devices based on epsilon-near-zero Ga<sub>2</sub>O<sub>3</sub>-SiC-Ag multilayer structures

Optical bistability has attracted much attention due to its enormous potential applications in all-optical operation and signal processing. However, the weak nonlinear responses typically require huge pump power to reach the threshold of the optical bistability, thus hindering the real applications. In this study, we propose an efficient optical bistable metamaterial, which is composed of multilayer Ga<sub>2</sub>O<sub>3</sub>-SiC-Ag metal-dielectric nanostructures. We not only use the epsilon-near-zero (ENZ) with SiC-Ag thin layers to enhance the substantial field, but also incorporate the SiC material to increase its significant optical nonlinear coefficient. In the structural design, the introduction of Ga<sub>2</sub>O<sub>3</sub> layer facilitates the light field concentration, contributing to the further reduction in threshold power for optical bistability, and also conducing to the improvement of the physical and chemical stability of the device. The influences of the thickness and length of the ENZ layer on the optical bistability are systematically investigated by using the finite element method. The results demonstrate that optical bistability becomes more pronounced with the increase of the thickness and length of ENZ layer, exhibiting a bistability switching threshold as low as ~10<sup>–6</sup> W/cm<sup>2</sup> in the telecommunication band. Comparing with the previously reported optical bistability based on ENZ mechanism, the threshold shows a significant reduction by 9 orders of magnitude, demonstrating great application potential in the fields of semiconductor devices and photonic integrated circuits.

Long-range underwater wireless optical communication system based on 490 nm vertical-external-cavity surface-emitting laser

The exploration and utilization of marine resources has promoted the rapid development of marine science and technology, and has put forward higher requirements for underwater communication technology. Long distance underwater wireless optical communication (UWOC) requires the selection of light source on the transmitter side. Laser diodes (LDs) have excellent portability and maneuverability, and have been widely used in the UWOC systems. However, their beam quality is not so good and it is difficult to modulate under high power. In recent years, vertical-external-cavity surface-emitting laser (VECSEL) has received much attention due to its high output power and good beam quality. This work is to explore the advantages of using a 490-nm blue VECSEL as a light source in UWOC, and to improve the performance of the UWOC system by the soft-decision pulse-position modulation (PPM). First, the optical power attenuation coefficient of the channel is obtained, and the measured <i>c</i> is about 0.0591 m<sup>–1</sup> in a 96-m-long tap channel. Subsequently, soft-decision and hard-decision are simulated and experimentally verified. Both simulations and measurements show that the bit error rate (BER) can be significantly reduced with soft-decision. Afterwards, we improve the system by using the soft-decision algorithm and investigate the communication performance of 64 PPMs at different bandwidths by adjusting the PPM signal rate. Finally, 50 MHz is chosen as a signal rate in the experiment. Then a UWOC system is demonstrated in this work. The transmitter side consists of a 490-nm VECSEL light source with an acousto-optic modulator (AOM). The pseudo-random binary sequence (PRBS) is loaded into the arbitrary waveform generator (AWG) for digital-to-analog conversion after PPM modulation, and the analog signal is sent to the driver of the AOM for acousto-optic modulation of the incident beam. The laser is focused before entering the AOM and then collimated after having exited to reduce its divergence. The modulated laser beam passes through a distance of 96 m in the tank by using multiple mirrors on both sides of the tank. Then, the beam is focused by a lens to the avalanche photodiode (APD) for photoelectric conversion in the end, and the signal is processed by a mixed signal oscilloscope (MSO) after data acquisition. A soft-decision algorithm is introduced to further optimize the performance of the PPM modulation. When the optical signal passes through a relatively long distance of 96 m, the measured BER is as low as 1.9 × 10<sup>–5</sup>. This indicates that the soft-decision PPM-based 490 nm blue VECSEL UWOC system performs very well.

BCC and Immunocryosurgery scar differentiation through computational resolution-enhanced OCT images and skin optical attenuation: A proof-of-concept study.

Monitoring medical therapy remains a challenging task across all non-surgical skin cancer treatment modalities. In addition, confirmation of residual tumours after treatment is essential for the early detection of potential relapses. Optical coherence tomography (OCT), a non-invasive method for real-time cross-sectional imaging of living tissue, is a promising imaging approach for assessing relatively flat, near-surface skin lesions, such as those that occur in most basal cell carcinomas (BCCs), at the time of diagnosis. However, the skin's inherent property of strong light scattering impedes the implementation of OCT in these cases due to the poor image quality. Furthermore, translating OCT's optical parameters into practical use in routine clinical settings is complicated due to substantial observer subjectivity. In this retrospective pilot study, we developed a workflow based on the upscale of the OCT images resolution using a deep generative adversarial network and the estimation of the skin optical attenuation coefficient. At the site of immunocryosurgery-treated BCC, the proposed methodology can extract optical parameters and discriminate objectively between tumour foci and scar tissue.

O,S-Chelated bis(pentafluorophenyl)boron and diphenylboron-β-thioketonates: synthesis, photophysical, electrochemical and NLO properties.

Boron-β-diketonates are classical emissive materials that have been utilized in various fields, however, boron monothio-β-thioketonates, where one oxygen atom is exchanged for a sulphur atom, have not been explored in detail. To gain a better understanding of this class of materials, we synthesised various aryl substituted monothio-β-diketonate boron complexes with two different aryl substitutions on the boron center and studied their structural, optical and electrochemical properties. Single crystal X-ray analysis revealed that there is considerable deviation in B-O and B-S bond lengths for bis(pentafluorophenyl)boron complexes against diphenyl boron complexes. The bis(pentafluorophenyl)boron complexes have a relatively high absorption coefficient over diphenyl boron complexes. More importantly, a striking difference was observed for the emission behaviour of these compounds. The bis(pentafluorophenyl)boron complexes exhibit weak emission in the solution as well as in the solid state, whereas diphenyl boron complexes do not show any emission in either solution or the solid state. Further, the electrochemical study reveals that diphenyl boron complexes show a reduction potential that is more negative compared to the bis(pentafluorophenyl)boron complexes. The high absorption coefficient of the compounds pointed towards the possibility of high first order hyperpolarizability upon optical excitation, which motivated us to ascertain the nonlinear optical coefficients in the near infrared range, towards applicability of such compounds in optical limiting and switching. The open aperture Z-scan measurements at ultrashort time scales elucidated a few critical features of such compounds towards optical limiting applications.

Nonlinear optical coefficients of Samarium–activated lithium zinc borate glasses in femtosecond and nanosecond regimes

Nonlinear optical coefficients of Samarium–activated lithium zinc borate glasses in femtosecond and nanosecond regimes

The effect of co-substitution of heterovalent ions Ga3+and Sb5+on nonlinear optical properties of phosphate crystals

The nonlinear optical coefficient of the KTP crystal has been significantly improved after co doping with Ga3+and Sb5+ions (1.25 times that of the pure KTP crystal).

Exploring the physical properties of cubic CsGeBr3-nIn (n= 0, 1, 2, 3) compounds: Ab initio calculations of perovskites prospective for the application in solar cells

The cubic perovskites CsGeBr3-nIn (n = 0, 1, 2, 3) were investigated using the density functional theory (DFT) for their structural, electronic, and optical properties. The present DFT calculations are carried out using three models for exchange-correlation potential, namely PBE, mBJ, and YS-PBE0. The bandgap decreases in the above sequence of compounds except CsGeBrI2, which reveals the smallest bandgap. The mBJ approximation has a larger bandgap than the PBE and smaller than the YS-PBE0. Results of calculations within the YS-PBE0 approach for CsGeBr3 and CsGeI3 agree well with QSGW + SO results. The CsGeBr3-nIn compounds are direct bandgap semiconductors and CBM and VBM are positioned at the R point and determined mainly by Ge s-states and Br(I) p-states, respectively. Analysis of optical properties shows that the DFT calculations within the PBE model consistently produce the highest static dielectric function values, while the YS-PBE0 method gives the smallest values. The curves of optical coefficients shift toward lower energies when decreasing the Br atoms in CsGeBr3-nIn. The studied compounds are semitransparent in the infrared and visible regions and show promising potential for photovoltaic applications, including solar cells.

Analysis of the structural, electronic, optical and mechanical properties of CsGeI2Br under tensile and compressive strain for optoelectronic applications: A DFT computational perspective

In this work, the impact of triaxial strain on the structural, optoelectronic and mechanical properties of CsGeI₂Br is thoroughly investigated, with a particular emphasis on its applicability in optical technologies spanning the visible and ultraviolet spectra. This research fills a notable gap in the literature, highlighting the intriguing properties of this material under external strain. First, the unstrained CsGeI₂Br is identified as a direct band gap semiconductor, revealing an energy gap of 0.714 eV. Moreover, the obtained results show a remarkable sensitivity of CsGeI₂Br's band gap to triaxial strain. Under a triaxial deformation ranging from −6% to 6 %, the energy of the bandgap undergoes a remarkable transformation, varying from 1.81 eV under tensile stress to 0.101 eV under compressive strain; The material approaches the metallic state under compressive strain and exhibits increased bandgap energy under tensile stress. Furthermore, the investigation delves into the optical coefficients in both x = y, z directions, revealing that triaxial strain can significantly enhance absorbance, particularly within the visible and ultraviolet energy spectra. Additionally, triaxial strain introduces significant anisotropy and influences the optical band gap. This results in increased absorption capacity and optical conductivity under tensile stress, making it more effective and better suited for various optical applications, including surgical tools, integrated circuits, QLED, OLED, solar cells, waveguides, and materials for solar heat reduction. The mechanical stability of CsGeI₂Br across the entire range of applied strain is validated by the elastic constants, which impeccably adhere to stability criteria. The negative cohesive energy values determined for unconstrained and constrained CsGeI₂Br signify their thermodynamic stability, establishing their experimental feasibility. Compression strain significantly influences the mechanical properties, enhancing the ductility of this compound.

ОПТИЧНА СПЕКТРОСКОПІЯ ДЕТЕКТОРНИХ ВИСОКООМНИХ МОНОКРИСТАЛІВ CdTe (111) ТА ТВЕРДИХ РОЗЧИНІВ Cd 1-x Zn x Te (х= 0,1)

Cadmium telluride is used for the manufacture of uncooled gamma radiation detectors, and solid solutions of Cd 1-x Zn x Te (x=0.1) are used for the manufacture of X-ray and gamma radiation detectors. The study of the effect of doping on the physical properties of semiconductors is relevant both for experimenters and for the theoretical substantiation of physical processes. This paper presents the results of the study of optical reflection spectra in the spectral range (0,2-1,7) . 10 -6 m and transmittance in the region of the fundamental optical transition E 0 of high-resistivity CdTe single crystals of (111) orientation with resistivity ρ = (2÷5)·10 9 Ohm∙cm doped with chlorine, as well as solid solutions of Cd 1-x Zn x Te (x = 0.1) with resistivity ρ = (5 ÷30)∙10 9 Ohm∙cm. Since the optical reflection coefficient R = f (λ) is related to the optical transmittance T = f (λ) and absorption D = f (λ) by the ratio R+T+D=1 (with the light (electromagnetic) wave scattering in the studied samples not taken into account), the absorption spectra D=1-(R+T) versus the light (electromagnetic) wavelength λ were also constructed in this work. It is determined that the energy of the fundamental optical transition E 0 of the studied materials at T = 300 K is as follows: for CdTe - 1.44 eV; and for Cd 1-х Zn х Te (x = 0.1) - 1.5 eV. The energy relaxation time of free charge carriers τ for p-CdTe (111) single crystals and Cd 1-х Zn х Te (x = 0.1) solid solutions was estimated to be 1.343-10 -14 s and 0,878·10 -14 s, respectively. The effective "optical" mobility for single crystals of p-CdTe (111) and solid solutions of Cd 1-х Zn х Te (x = 0.1) is 274 . 10 -4 ; 179,5 . 10 -4 , respectively. It has been shown that the investigated crystals are of high (detector) quality, which is crucial for the manufacture of highly sensitive and high-resolution ionising radiation sensors. The practical value of the obtained results lies in the determination of electronic and physical parameters of technically important semiconductors CdTe and Cd 1-х Zn х Te (x=0.1).

A flexible organic single crystal with room temperature phosphorescent waveguide and piezochromism properties

Flexible crystals with plasticity and elasticity that exhibit phosphorescent emission are quite rare yet highly significant for their potential applications. In our study, we present an example of such flexible (both elastic and plastic) organic crystals based on 1,2-bis(3-bromophenyl)-ethane-1,2-dione (BBPED), which demonstrates a lifetime of 0.504 ms (517 nm) and a quantum efficiency of 26.12 % at room temperature. These crystals exhibit reversible elastic properties in both their original and twisted states, and possess optical waveguide properties with minimal optical loss coefficients in the range of 0.26–0.48 dB/mm. In addition, the above crystals exhibit phosphorescence to phosphorescence blueshift under hydrostatic pressure, whereas mechanical grinding produces a phosphorescence to phosphorescence redshift phenomenon. Theoretical calculations indicate that the alterations in molecular conformation and intermolecular interactions both contribute to the piezochromic phenomenon. In conclusion, this work provides a new approach to the design of multifunctional phosphorescent molecular crystals with flexible characteristics.

Exciton related nonlinear optical properties of a quantum wire

A considerable amount of work is done on nonlinear optical properties in quantum wells and dots. However, relatively fewer work is done on both quantum well wires and the excitonic effects. This work analyzes the excitonic effects on the refractive index change in quantum well wire. Our main effort is to make the effect of the Coulomb interaction more apparent. The density-matrix approach obtains the analytical expressions for the relevant optical coefficients. We have found that the Coulomb interaction plays a key role in the position and the height of the peaks of optical coefficient curves. Our findings show the way to optimize the nonlinear optical coefficients.

Method for quantifying catechin in a strawberry extract by measuring optical absorbance, at high sensitivity, under the effect of wavelength and concentration

Catechin is considered a powerful antioxidant, and its rapid quantification could help urgently prevent inflammatory and coronary heart diseases. Consequently, the UV–Vis absorption spectrophotometry assay technique could serve this need for rapid detection.For this reason, we have carefully studied the possibility of dosing this antioxidant found in strawberry extract with precision, despite its chemical complexity.In the dosage technique used; sometimes the dilution of the solutions could be the way to resolve a specific quantification problem such as catechin in strawberry extract. This is quite particular, when the optical extinction coefficient of the target substance is very low compared to the extinction coefficients of the other chemical compounds in the complex mixture, because at a certain dilution the absorption spectrum of the molecule could appear, specifically, with its total spectral form or at least at one of these wavelengths.In this article, we will study the possibility of rapidly measuring catechin from strawberry extract by spectrophotometry in UV–VIS, while reformulating the Beer-Lambert law in a new form where the extinction coefficient did not depend not only of the chemical nature of the solute and the solvent but also of the excitation wavelength (ε(λ), Eq. (9)).A catechin-methanol solution is taken as a reference to study the spectral variation due to the various dilutions of the solution and the determination of a limiting concentration where the excitation wavelength becomes constant (203 nm), thus the extinction coefficient of the catechin, denoted ε0, but the measurement sensitivity is suddenly reduced.A semi-empirical relationship is determined by linearization of the absorbance function which depended on the concentration (C) and the excitation wavelength (ε(λ)).A separation process will be exposed to recover the strawberry extract, as well as its spectral analysis. Finally, a procedure for analyzing any strawberry extract will be presented at the end of this scientific article.

Long-period fiber grating based on micro-holes-filled PDMS for temperature and pressure measurement

We use femtosecond laser pulses to evenly drill seven micro-holes along the fiber core in a single mode fiber, forming a long period fiber grating (LPFG) with a grating period of 520 μm, and each micro-hole has an aperture of about 15 μm. Then, LPFG is placed in a polydimethylsiloxane (PDMS) solution and fill each micro-holes with the PDMS solution. After filling PDMS, LPFG exhibits three distinct resonance peaks in the range of 1380 nm to 1560 nm, and the corresponding wavelengths are 1405.0 nm, 1469.6 nm, and 1517.8 nm, with intensities of −16.4 dB, −15.4 dB, and −14.6 dB, respectively. Due to the high thermal expansion coefficient, thermal optical coefficient, elastic optical coefficient and good elastic deformation of PDMS, the sensitivity of LPFG filled with PDMS to temperature and air pressure has been greatly improved. The experimental results show that after filling with PDMS, the sensitivity of LPFG to temperature increased from 22.5 pm/°C to −284.9 pm/°C, an increase of 12.7 times. And LPFG has increased its sensitivity to gas pressure from zero to −2.23 nm/MPa. In addition, LPFG also has good repeatability and stability, and a short response time. This method of using micro-holes to prepare LPFG and filling polymer materials in micro-holes to improve the mechanical strength and sensitivity of LPFG has certain novelty, and this sensor design scheme also has certain practical application value.

Thin-core fiber-based Mach-Zehnder interferometer sensor for monitoring temperature, pressure, and humidity

A Mach-Zehnder interferometer (MZI) sensor based on thin-core fiber (TCF) is proposed. Sensitive materials such as polydimethylsiloxane (PDMS) or gelatin are coated on the surfaces of MZIs to achieve temperature, pressure, and humidity measurements. MZI is composed of single mode fiber (SMF), TCF, and multimode fiber (MMF) spliced together to form a “SMF-MMF-TCF-MMF-SMF” structure. The core/cladding diameters of TCF are 3.8 µm and 80 µm respectively. When three types of optical fibers with different core diameters are cascaded together, many cladding modes are excited to form MZI. Firstly, two similar MZI structures were fabricated designated by MZI1 and MZI2. In order to improve the sensitivity and mechanical strength, a layer of PDMS film was coated on the TCF surface of MZI1. Then, a layer of gelatin film is covered on the TCF surface of MZI2. PDMS has the high thermal expansion coefficient, thermal optical coefficient, and elasticity, and gelatin has good humidity sensitivity properties. The experimental results showed that the temperature and pressure sensitivity of MZI1 coated with PDMS reached −340 pm/°C and −14.3 nm/MPa, respectively, while the humidity sensitivity of MZI2 coated with gelatin reached −112.57 pm/% RH. When a fiber Bragg grating is cascaded with the MZI1, the sensor can achieve simultaneous measurement of temperature and pressure, eliminating crosstalk. The proposed sensor has an extremely simple structure and manufacturing method, which only involves the splicing of optical fiber and the coating by the film. In addition, the proposed sensor has a robust structure, good repeatability and stability, and high sensitivity, which has broad application prospects.

Solvent Media on Nonlinear Optical Properties of Triarylmethane Dye via Facile Z-Scan Method.

Solvent environment on third-order nonlinear optical (TNLO) features of triarylmethane dye namely, basic blue 7 in different solvents is reported herein using 650nm diode laser with continuous wave mode. The basic blue 7 dye is dissolved in different solvent media including ethanol, methanol, dimethyl formamide (DMF) and dimethyl sulfoxide (DMSO). The influence of solvent characteristics such as solvent polarizability and dipole moment on solute molecule is discussed. TNLO characteristics such as nonlinear optical index of refraction, nonlinear optical coefficient of absorption, real and imaginary components of the TNLO susceptibility are measured to be the order of 10‒7 cm2/W, 10‒3cm/W, 10‒6 esu and 10‒7 esu, respectively. The dye exhibits large TNLO susceptibility by dissolving in DMSO. The TNLO susceptibility of basic blue 7 dye is measured to be the order of 10‒6 esu. The overall results revealed that the basic blue 7 dye is suitable material for optoelectronics applications.

Effect of ambient argon pressure on the structural, optical and electrical properties of non-crystalline Se85Te3Bi12 nano-thin films

In this research work, we have synthesized non-crystalline Se85Te3Bi12 chalcogenide glasses by conventional melt quenching technique. The differential scanning calorimetry measurement of the synthesized specimen was done to confirm the glassy as well as non-crystalline nature of the bulk Se85Te3Bi12 alloy. The nano-thin films of thickness 30 nm of the synthesized sample at two different ambient argon pressures (1 Torr and 3 Torr) were made using the physical vapor condensation technique at a constant substrate temperature of 77 K using liquid nitrogen. The non-appearance of prominent peaks in the high-resolution x-ray diffractometer profile confirmed the non-crystalline nature of synthesized nano-thin films. The morphological analysis of the prepared nano-thin films using Field emission scanning electron microscopy confirmed the nanochalcogenide having particle size ranges from 30–90 nm. The Fourier transform infrared (FTIR) spectroscopy suggests the presence of moisture and carbon impurities in the prepared nano-thin films. The broad optical transmission shadow observed in the FTIR results is an essential requirement for new-generation IR systems. Based on UV-visible spectroscopy, optical parameters such as optical absorption coefficients, Urbach energy, optical band gaps, Tauc’s parameter and extinction coefficients were measured for synthesized Se85Te3Bi12 nano-thin films. The value of absorption coefficients, Tauc’s parameters, optical band gap and extinction coefficients increases with the increase of ambient argon pressure. The outcome of these studies recommends that these materials can be a preeminent candidate for photovoltaic applications. Photoluminescence spectroscopy results are accredited to the accumulation of non-crystalline nanochalcogenide particles on the substrates. DC conductivity measurements further confirm the semiconducting nature of the nanochalcogenide Se85Te3Bi12 thin films.

Ultrasensitive tunable terahertz lithium niobate metasurface sensing based on bound states in the continuum

Lithium niobate’s substantial nonlinear optical and electro-optic coefficients have recently thrust it into the limelight. This study presents a thorough review of bound states in the continuum (BICs) in lithium niobate metasurfaces, also suggesting their potential for sensing applications. We propose an all-dielectric tunable metasurface that offers high Q factor resonances in the terahertz range, triggered by symmetry-protected BICs. With exceptional sensitivity to changes in the refractive index of the surrounding medium, the metasurface can reach a sensitivity as high as 947 GHz/RIU. This paves the way for ultrasensitive tunable terahertz sensors, offering an exciting path for further research.

Channeling of weak intramode beams in the field of a strong spatial soliton in a thin left-handed film on a right-handed substrate with Kerr effect

The trapping of weak guided modes by a strip waveguide induced by a strong spatial soliton in a planar waveguide based on a thin left-handed film with a right-handed linear cover and a substrate with the Kerr effect at a frequency near the zero group velocity of the TE mode is considered. It is shown that a bright (dark) soliton can induce a strip waveguide not only for a positive (negative) nonlinear optical coefficient of the substrate, but also for a negative (positive) one, which is due to the existence in the original planar waveguide of guided modes with both positive and negative group velocities.

Tensile loading state sensing and estimation of opaque polymer materials using pulsed-terahertz waves

In this study, we used pulsed terahertz (THz) spectroscopy to analyze the THz optical properties of opaque acrylonitrile–butadiene–styrene (ABS). The phenomenon occurring upon the propagation of pulsed THz waves through ABS was analyzed through measurements of the variations in THz optical parameters (absorption constant, complex dielectric properties, and refractive index). When tensile loading of 0.1–1.5 kN was applied to a specimen, large optical coefficient variations were observed at 0.275, 0.471, and 0.686 THz, regardless of the applied tensile loading. The optical parameter variations were analyzed at 0.275 THz. Moreover, the accuracy of a tensile loading state estimation model established using principal component analysis was analyzed; consequently, random loading was confirmed. The input factor was extracted and calculated, with an error of approximately 3%, except for small loading (100 N).

Influence of Te replacement by Bi in In10Se70Te20-xBix films and its structural, optical, morphological, surface wettability and thermal behaviors for optoelectronic applications

The current investigation is based on Bi doping into In–Se–Te alloy and its impact on the surface morphology, structure, and optical behaviors. The transition from In10Se70Te20 to In10Se70Bi20 composition modified its structural phases as observed from X-ray diffraction study. The crystallite size increased from 9.55 nm to 14.04 nm. The lattice strain decreased from 0.0234 to 0.0106 with Bi content. Raman study infers the microstructural and phase formation in the films. The structure change is associated with change in surface morphology as noticed from field emission scanning electron microscopy images. The composition of In10Se70Te20-xBix (x = 0, 5, 10, 15, 20 at %) films were observed from energy dispersive X-ray analysis. The UV–Vis–NIR data showed the decrease in transmittance from 80 % to 10 % at 2100 nm wavelength with Bi%. The decrease in direct bandgap from 1.64 eV to 1.37 eV was discussed by Davis-Mott model for density of defect states. The increase in Urbach energy from 101 meV to 161 meV is based on the transition from In10Se70Te20 to In10Se70Bi20 composition. The optical parameters like optical density, extinction coefficient and absorption coefficient were increased with Bi addition. The calculated static linear refractive index by different model at different Bi% satisfies Moss's relation. The enhanced non-linear susceptibility from 2.96 × 10−10 esu to 3.33 × 10−10 esu and non-linear refractive index from 1.58 × 10−7 esu to 1.86 × 10−7 esu with Te replacement by Bi may be suitable for non-linear optical devices. The change in different theoretically calculated physical parameters were found to be in accordance with the experimental data. The surface wettability study showed the transition from hydrophilic to hydrophobic nature with increase in Bi %. The obtained experimental results for the films may be used for various photonic and optoelectronic device applications.