Opposite Gradient Research Articles

Anomalous birefringence through metasurface-based cavities with linear-to-circular polarization conversion

We propose the metasurface-based cavities for splitting a linearly polarized (LP) electromagnetic wave into two symmetric circularly polarized (CP) beams with opposite helicities. More specifically, periodic strip slits and rectangular C-slits etched on substrate integrated waveguide cavities are shown to be capable of perfectly coupling the LP wave into the cavities from the strip slit array, and then releasing them with specific polarization directions according to the orientations of the C-slits. Such metasurface-based cavities with gradient oriented C-slit array would further create the opposite equivalent phase gradients for the right-hand and left-hand CP transmitting waves that are decomposed from the released LP wave with anomalous birefractions and polarization conversion simultaneously.

Climate change decreases the cooling effect from postfire albedo in boreal North America.

Fire is a primary disturbance in boreal forests and generates both positive and negative climate forcings. The influence of fire on surface albedo is a predominantly negative forcing in boreal forests, and one of the strongest overall, due to increased snow exposure in the winter and spring months. Albedo forcings are spatially and temporally heterogeneous and depend on a variety of factors related to soils, topography, climate, land cover/vegetation type, successional dynamics, time since fire, season, and fire severity. However, how these variables interact to influence albedo is not well understood, and quantifying these relationships and predicting postfire albedo becomes increasingly important as the climate changes and management frameworks evolve to consider climate impacts. Here we developed a MODIS-derived 'blue sky' albedo product and a novel machine learning modeling framework to predict fire-driven changes in albedo under historical and future climate scenarios across boreal North America. Converted to radiative forcing (RF), we estimated that fires generate an annual mean cooling of -1.77±1.35W/m2 from albedo under historical climate conditions (1971-2000) integrated over 70years postfire. Increasing postfire albedo along a south-north climatic gradient was offset by a nearly opposite gradient in solar insolation, such that large-scale spatial patterns in RF were minimal. Our models suggest that climate change will lead to decreases in mean annual postfire albedo, and hence a decreasing strength of the negative RF, a trend dominated by decreased snow cover in spring months. Considering the range of future climate scenarios and model uncertainties, we estimate that for fires burning in the current era (2016) the cooling effect from long-term postfire albedo will be reduced by 15%-28% due to climate change.

Spatial patterns of zooplankton size structure in relation to environmental factors in Jiaozhou Bay, South Yellow Sea.

The spatial variation in size structure of mesozooplankton and its relationship with environmental factors were studied from January 2006 to December 2010 in Jiaozhou Bay. The spatial body-size patterns of zooplankton differed significantly from the inner to the outer bay, and have a significant correlation with environmental variables, especially nutrients, salinity and water depth. The abundance of total zooplankton and small size ranks presented a decreasing gradient from the inner to the outer part, and was positive correlated with nutrients and negative with salinity, while the abundance of large size ranks exhibited an opposite gradient, and was positive correlated with water depth and negative with nutrients. The size spectra slope and size diversity were generally low in the inner part and closely related to body size ranks. Our results suggest that size structure patterns of zooplankton showed a clear spatial pattern and significantly associated with environmental factors in marine ecosystems.

Electrothermally Driven Membrane Distillation for Low-Energy Consumption and Wetting Mitigation.

Membrane distillation (MD) is a promising alternative approach for desalination, especially for high-salinity brines. Its application has been limited by its high operational cost because of the energy consumption required for hydraulic circulation and heating the entire circulating feed. Localized heating of the feed by Joule heating diminishes energy consumption, but the potential charging on the electrothermal material surface causes water splitting and membrane degradation in high-salinity environments. Herein, a novel reverse Joule-heating air gap MD method was designed in which an electrothermal material was placed at the air gap, isolating itself from saline water. Even though the Joule-heating layer was at the air gap side, 90.56% of heat flowed into the saline water for heating the feed. The opposite temperature gradient in the membrane matrix as opposed to conventional MD-mitigated membrane wetting was caused by capillary condensation. This novel electrothermal-driven MD configuration is worthy to be introduced into applications.

ES17.02 Molecular Heterogeneity

ES17.02 Molecular Heterogeneity

Study of Ion Exchangers in Electric Fields Using Resistometric Measurement. Part 2. Methods and Equipment

The experimental technique and equipment used to study the kinetics of ion exchange in weak electric fields in the ion–exchange resins using a computer resistometric measurement method are described. In the course of ion exchange in the NaCl + NaOH model solution–ion exchanger system the chemical composition dynamics of a solution measuring the solution resistance with the help of a resistometer is measured with a flowing sensor; its signal is computer processed. The pattern of interaction between electrical and diffusion ion fields in the solid phase of the ion exchanger is discussed. It is shown that when a weak directional electric field is applied on the spherical ion exchanger particle, the spherical symmetry of the ion displacement rate is distorted, and the balance of the ion flows is changed. Thus, the exchange process is accelerated in the direction of the electric field vector. The test unit for the study of the ion exchange dynamics, which includes a convective reactor, a built-in column with a portion of the exchanger, a temperature control system, a flowing sensor of the electrical resistance of the solution, an electronic resistometer, and a potentiostat–galvanostat, is described. Three experimental methods are described: a nonstationary method with the ion exchange suspension in the enclosed volume, the nonstationary method with filtration through the ion exchanger in the column, and the method of open filtration through the column. It is shown that the speed of the ion flux in the solid phase is constant and does not depend on the saturation value of the exchanger in the suspension mode of exchange in the basic interval time of the process. This effect is caused by the operation of the electroneutrality law on two ion fluxes with the charges of the same sign but with the opposite concentration gradients.

Inferring the population structure of the Maghreb sheep breeds using a medium-density SNP chip.

North Africa has a great diversity of indigenous sheep breeds whose origin is linked to its environmental characteristics and to certain historical events that took place in the region. To date, few genome-wide studies have been conducted to investigate the population structure of North African indigenous sheep. The objective of the present study was to provide a detailed assessment of the genetic structure and admixture patterns of six Maghreb sheep populations using the Illumina 50K Ovine BeadChip and comparisons with 22 global populations of sheep and mouflon. Regardless of the method of analysis used, patterns of multiple hybridization events were observed within all North African populations, leading to a heterogeneous genetic architecture that varies according to the breed. The Barbarine population showed the lowest genetic heterogeneity and major southwest Asian ancestry, providing additional support to the Asian origin of the North African fat-tailed sheep. All other breeds presented substantial Merino introgression ranging from 15% for D'man to 31% for Black Thibar. We highlighted several signals of ancestral introgression between North African and southern European sheep. In addition, we identified two opposite gradients of ancestry, southwest Asian and central European, occurring between North Africa and central Europe. Our results provide further evidence of the weak global population structure of sheep resulting from high levels of gene flow among breeds occurring worldwide. At the regional level, signs of recent admixture among North African populations, resulting in a change of the original genomic architecture of minority breeds, were also detected.

Pore network modelling to enhance liquid water transport through porous transport layers for polymer electrolyte membrane electrolyzers

For the first time, pore network modelling is applied to polymer electrolyte membrane (PEM) electrolyzers. Realistic sintered titanium powder-based porous transport layers (PTLs) are generated via stochastic modelling, and we determine the influence of PTL-catalyst coated membrane (CCM) contact, pore and throat sizes, and porosity on two-phase transport. The PTL-CCM interfaces exhibit large open pore spaces, which are catastrophic for effective reactant transport due to the localized preferential accumulation of oxygen gas. As expected, increasing the sizes of the pores and throats results in higher oxygen gas saturations; however, we concurrently observe a surprisingly dominant mass transport effect whereby liquid water permeability is enhanced. The numerically generated PTLs are further tailored for enhanced mass transport by imposing a porosity gradient. By increasing the porosity from the PTL-CCM interface to the PTL-flow field interface, lower gas saturations and higher liquid water permeabilities are observed. With the opposite porosity gradient, the majority of pores adjacent to the high porosity CCM region become invaded with oxygen gas. We recommend a backing layer (microporous layer) at the CCM-PTL interface that improves the contact and permeation of product oxygen away from the CCM, thereby enhancing the performance of the PEM electrolyzer.

Mechanisms for an Amplified Precipitation Seasonal Cycle in the U.S. West Coast under Global Warming

Abstract The mean precipitation along the U.S. West Coast exhibits a pronounced seasonality change under warming. Here we explore the characteristics of the seasonality change and investigate the underlying mechanisms, with a focus on quantifying the roles of moisture (thermodynamic) versus circulation (dynamic). The multimodel simulations from phase 5 of the Coupled Model Intercomparison Project (CMIP5) show a simple “wet-get-wetter” response over Washington and Oregon but a sharpened seasonal cycle marked by a stronger and narrower wet season over California. Moisture budget analysis shows that changes in both regions are predominantly caused by changes in the mean moisture convergence. The thermodynamic effect due to the mass convergence of increased moisture dominates the wet-get-wetter response over Washington and Oregon. In contrast, mean zonal moisture advection due to seasonally dependent changes in land–sea moisture contrast originating from the nonlinear Clausius–Clapeyron relation dominates the sharpened wet season over California. More specifically, the stronger climatological land–sea thermal contrast in winter with warmer ocean than land results in more moisture increase over ocean than land under warming and hence wet advection to California. However, in fall and spring, the future change of land–sea thermal contrast with larger warming over land than ocean induces an opposite moisture gradient and hence dry advection to California. These results have important implications for projecting changes in the hydrological cycle of the U.S. West Coast.

A new ultrafast 3D gradient echo-based imaging method using quadratic-phase encoding.

To propose a novel 3D ultrafast gradient echo-based MRI method, dubbed RASE, using quadratic-phase encoding. Several characteristics of RASE, including spin behaviors, spatial resolution, SNR, and reduction of susceptibility-induced signal loss, were analytically described. A way of compensating for TE variation was suggested in the quadratic phase-encoding direction. Lemon, in vivo rat and mouse images were demonstrated at 9.4T, including a feasibility study for DCE-MRI as one of promising applications. RASE was successfully demonstrated by lemon and in vivo rat brain imaging, showing a good robustness to field inhomogeneity. Contribution of the quadratic phase to signal enhancement in a range of magnetic susceptibilities was also evaluated by simulation. Taking a geometric mean of 2 phantom data acquired with opposite gradient polarities effectively compensated for the effect of TE variation. Preliminary DCE-MRI results were also presented, showing that RASE could more accurately estimate Gd concentration than FLASH. RASE offers a shorter effective TE, having less sensitivity to field inhomogeneity and T2* effects, much less Nyquist ghosting or chemical-shift artifacts than gradient echo EPI (GE-EPI). We highly anticipate that RASE can be an alternative to GE-EPI in many applications, particularly those requiring high spatial and temporal resolutions in a broad volume coverage.

Double fronts in the Yellow Sea in summertime identified using sea surface temperature data of multi-scale ultra-high resolution analysis

Fronts are ubiquitous phenomena in oceans, and they play a significant role in marine hydrodynamics and ecology. During the stratified season of a shelf sea, the coastal front is usually considered as a single front, i.e., the tidal mixing front. However, using high resolution (~1 km) Multi-scale Ultra-high Resolution (MUR) analysis sea surface temperature (SST) data, this study observes persistent double fronts along the Yellow Sea coast in summertime. The double fronts comprise the well-known offshore tidal mixing front and a nearshore front, and the nearshore front has not been previously reported. The climatological (2002–2017) monthly mean result shows that the double fronts with two SST gradient peaks exceeding ~2 °C/100 km and opposite SST gradient directions basically remain unchanged from June to August, whereas the frontal spacing decreases in September. Analyses based on a two-layer concept model suggest that a topographic slope along with tidal mixing could induce the pattern of double fronts. The frontogenesis of nearshore thermal front could be associated with the different responses of the water column of different water depths to insolation. The offshore movement of the nearshore front in September could be related to the fast cooling of nearshore water and intensified offshore wind, and the topographic slope is important for determining the pattern of double fronts (loose or tight). This study shows a new pattern of coastal fronts in the stratified season, and indicates the significance of high resolution satellite data. The discovery of the double front pattern implies the influence of coastal fronts during the stratified season on marine ecology and environment in a shelf sea might be underestimated.

Ant taxonomic and functional diversity show differential response to plantation age in two contrasting biomes

The increasing global demand for lumber and pulp has led to the conversion of natural habitats into monocultures of fast-growing tree plantations. The environmental filtering model proposes that both environmental characteristics of anthropogenic habitats and biotic interactions act as a filter that can be passed through by some species of the regional pool, driving the formation of local assemblages. Therefore, environmental filtering promotes the selective loss of species and convergence of functional traits, resulting in assemblages of species that are functionally more similar than expected by chance. In Argentina, pine monocultures have expanded in both subtropical forest and grassland biomes. Typically, environmental similarity between plantations and natural habitat decreases in the grassland and increases in the subtropical forest with increasing plantation age (time since pine stands were planted). Then, we predict that changes in biological diversity with plantation age will be opposite when plantations develop in environmentally contrasting biomes. To test the prediction, we studied taxonomic (species richness) and functional (based in morphological functional traits) diversity of epigeal ant assemblages in pine plantations of different ages (from 1 to 12 years old), developing in contrasting biomes that determined different contexts of the main natural (i.e., native) habitat: subtropical forest and grassland. Temperature, humidity and vegetation cover were recorded, and ants were collected using pitfall traps. For plantations and natural habitats of both biomes, we estimated functional diversity in sets of randomized communities and compared them with the observed functional diversity throughout plantation age. As expected, results showed opposite environmental similarity gradients between natural habitats and plantation ages. In the subtropical forest, ant species richness remained similar but functional diversity increased with increasing plantation age, associated with the presence of predatory ants. In the grassland, species richness showed a maximum at intermediate ages, but functional diversity remained similar with increasing plantation age. Null model analyses showed lower functional diversity than expected by chance in young plantations developing in the subtropical forest and at all ages in grassland, indicating convergence of functional traits. Our findings support environmental filtering as the primary mechanism driving the formation of ant assemblages along pine plantation cycle. To our best knowledge, this is the first study analysing patterns of diversity along tree plantation cycles developing in contrasting biomes. Our results show that the biome effect should be taken into consideration to predict diversity responses to commercial forestry and to unify a theory of assemblage formation in monoculture plantations.

Disentangling the hierarchical structure of environmental effects on fish assemblages in tropical coastal ecosystems

Disentangling the hierarchical structure of environmental effects on fish assemblages in tropical coastal ecosystems

Variable jets at the termination of the common envelope evolution

I propose that at the termination of the common envelope evolution (CEE) the companion to the giant star might launch jets that have variable directions and intensities, hence the jets shape the inner zones of the descendant nebula causing it to lose any type of symmetry. This might account for some of the chaotic departures from axisymmetric structures in some planetary nebulae. I base my study on the assumption that at the termination of the CEE the binary interaction forms a circumbinary thick disk that feeds the companion via an accretion disk that launches opposite jets. I consider two processes that might lead to the development of Rayleigh-Taylor instabilities that lead to chaotic accretion flow on to the companion. The chaotic accretion flow leads to a variable accretion disk around the companion, hence to variable jets. In the first process the jets inflate low-density hot bubbles in the inner regions of the envelope. In the second process the inner boundary of the thick circumbinary disk, that faces the center, cools by radiation thus leading to a temperature, and hence also a pressure, increase with radius. The opposite pressure and density gradients lead to Rayleigh-Taylor instabilities. This study further underlines the importance of exploring the termination phase of the CEE to the understanding of the entire CEE and its outcomes.

Possible Counterrotation between the Disk and Protostellar Envelope around the Class I Protostar IRAS 04169+2702

We present results from our SMA observations and data analyses of the SMA archival data of the Class I protostar IRAS 04169+2702. The high-resolution (~0.5") $^{13}$CO (3-2) image cube shows a compact ($r$ ~< 100 au) structure with a northwest (blue) to southeast (red) velocity gradient, centered on the 0.9-mm dust-continuum emission. The direction of the velocity gradient is orthogonal to the axis of the molecular outflow as seen in the SMA $^{12}$CO (2-1) data. A similar gas component is seen in the SO (6$_5$-5$_4$) line. On the other hand, the C$^{18}$O (2-1) emission traces a more extended ($r$ ~400 au) component with the opposite, northwest (red) to southeast (blue) velocity gradient. Such opposite velocity gradients in the different molecular lines are also confirmed from direct fitting to the visibility data. We have constructed models of a forward-rotating and counter-rotating Keplerian disk and a protostellar envelope, including the SMA imaging simulations. The counter-rotating model could better reproduce the observed velocity channel maps, although we could not obtain statistically significant fitting results. The derived model parameters are; Keplerian radius of 200 au, central stellar mass of 0.1 $M_{solar}$, and envelope rotational and infalling velocities of 0.20 km s$^{-1}$ and 0.16 km s$^{-1}$, respectively. One possible interpretation for these results is the effect of the magnetic field in the process of disk formation around protostars, $i.e.$, Hall effect.

A Model for a Filling-in Process Triggered by Edges Predicts "Conflicting" Afterimage Effects.

The goal of our research was to develop a compound computational model that predicts the “opposite” effects of the alternating aftereffects stimuli, such as the “color dove illusion” (Barkan and Spitzer, 2017), and the “filling in the afterimage after the image” (van Lier et al., 2009). The model is based on a filling-in mechanism, through a diffusion equation where the color and intensity of the perceived surface are obtained through a diffusion process of color from the stimulus edges. The model solves the diffusion equation with boundary conditions that takes the locations of the chromatic edges of the chromatic inducer (chromatic stimulus) and the achromatic remaining contours into account. These contours (edges) trigger the diffusion process. The same calculations are done for both types of afterimage effects, with the only difference related to the location of the remaining contour. While a gradient toward the inducing color produces a perception of the complementary color, an opposite gradient yields the perception of the same color as that of the chromatic inducer. Furthermore, we show that the same computational model can also predict new alternating aftereffects stimuli, such as the spiral stimulus, and the averaging of colors in alternating afterimage stimuli described by Anstis et al. (2012). The suggested model is able to predict most of the additional properties related to the “conflicting” phenomena that have been recently described in the literature, and thus supports the idea that a shared visual mechanism is responsible for both the positive and the negative effects.

Ingested microplastic as a two-way transporter for PBDEs in Talitrus saltator

The presence and accumulation of plastic waste into the marine environment are well known environmental issues. Microplastics (MPs) end up in sea waters and, due to their hydrophobicity and high surface/volume ratio, POPs tend to sorb and accumulate to their surface. The supralittoral amphipod Talitrus saltator (T. saltator) was selected to study the role of MPs in the transfer of organic pollutants and to investigate if ingested MPs could either transfer contaminants to biota or clean it adsorbing pollutants taken from the diet. T. saltator is an established POPs (Persistent Organic Pollutants) biomonitor in coastal environments and it is able to swallow microplastics in natural condition.Two laboratory experiments were performed and T. saltator was exposed to a labelled polybrominated diphenyl ether (13C-labelled BDE-47) to investigate the opposite gradient role of MPs. X Ray Micro-CT (Micro-Computed Tomography) analyses were also performed on sandhopper samples to evaluate the uptake of MPs via digestive tract. The results showed that MPs ingestion could whether transfer and remove contaminants from T. saltator, indicating a partial balance among positive and negative effects. This study has underlined MP potential double role demonstrating that MP can act both as a carrier and scavenger for the bioaccumulation of organic pollutants (i.e. PBDEs), suggesting that chemicals leaching from MPs could have a limited impact to biota.

Technical Note: Interleaved bipolar acquisition and low-rank reconstruction for water-fat separation in MRI.

To acquire interleaved bipolar data and reconstruct the full data using low-rank property for water-fat separation. Bipolar acquisition suffers from issues related to gradient switching, the opposite gradient polarities, and other system imperfections, which prevent accurate water-fat separation. In this study, an interleaved bipolar acquisition scheme and a low-rank reconstruction method were proposed to reduce issues from the bipolar gradients while achieving a short imaging time. The proposed interleaved bipolar acquisition scheme collects echo-time signals from both gradient polarities; however, the sequence increases the imaging time. To reduce the imaging time, the signals were subsampled at every dimension of k-space. The low-rank property of the bipolar acquisition was defined and exploited to estimate the full data from the acquired subsampled data. To eliminate the bipolar issues, in the proposed method, the water-fat separation was performed separately for each gradient polarity, and the results for the positive and negative gradient polarities were combined after the water-fat separation. A phantom study and invivo experiments were conducted on a 3T Siemens Verio system. The results for the proposed method were compared with the results of the fully sampled interleaved bipolar acquisition and the Soliman's method, which was the previous water-fat separation approach for reducing the issues of bipolar gradients and accelerating the interleaved bipolar acquisition. The proposed method provided accurate water and fat images without the issues of bipolar gradients and demonstrated a better performance compared with the results of the previous methods. The water-fat separation using the bipolar acquisition has several benefits including a short echo-spacing time. However, it suffers from bipolar-gradient issues such as strong gradient switching, system imperfection, and eddy current effects. This study demonstrated that accurate water-fat separated images can be obtained using the proposed interleaved bipolar acquisition and low-rank reconstruction by using the benefits of the bipolar acquisition while reducing the bipolar-gradient issues with a short imaging time.

Evaluation of Band-Selective HSQC and HMBC: Methodological Validation on the Cyclosporin Cyclic Peptide and Application for Poly(3-hydroxyalkanoate)s Stereoregularity Determination.

Band-selective (bs) HSQC, improving spectral resolution by restriction of the heteronuclear dimension without inducing spectral folding, has been recently used for polymer tacticity determination. Herein is reported an evaluation of various bs-HSQC and bs-HMBC sequences, first from a methodological point of view (selectivity, dependence to INEPT interpulse delay or relaxation delay), using the cyclic peptide cyclosporin selected as a model compound, and then from an applicative approach, comparing tacticity determined from bs-HSQC and bs-HMBC experiments to the one obtained from 1D 13C{1H} on poly(3-hydroxyalkanoate)s samples. For HSQC sequences, the 13C selectivity scheme consisting in substituting a 13C broadband refocalization by a selective one revealed itself problematic, with unwanted aliased signals, whereas the insertion of double pulsed field gradients spin-echo (DPFGSE) or the use of opposite sign gradients bracketing a selective refocalization gave satisfactory results. Determination of the probability of syndiotactic enchainments, Ps, by bs-HSQC is fully consistent and no precision loss was observed when decreasing acquisition time (37 min vs. 106 min for 1D 13C{1H}). Bs-HMBC, although not straightforwardly applicable for tacticity determination, could provide (after a calibration step) an alternative for compounds of which only 13C carbonyl signals are resolved enough for discriminating between syndiotactic and isotactic configurations.

Evaluation of differences between dual salt-pH gradient elution and mono gradient elution using a thermodynamic model: Simultaneous separation of six monoclonal antibody charge and size variants on preparative-scale ion exchange chromatographic resin.

The efficiencies of mono gradient elution and dual salt-pH gradient elution for separation of six mAb charge and size variants on a preparative-scale ion exchange chromatographic resin are compared in this study. Results showed that opposite dual salt-pH gradient elution with increasing pH gradient and simultaneously decreasing salt gradient is best suited for the separation of these mAb charge and size variants on Eshmuno® CPX. Besides giving high binding capacity, this type of opposite dual salt-pH gradient also provides better resolved mAb variant peaks and lower conductivity in the elution pools compared to single pH or salt gradients. To have a mechanistic understanding of the differences in mAb variants retention behaviors of mono pH gradient, parallel dual salt-pH gradient, and opposite dual salt-pH gradient, a linear gradient elution model was used. After determining the model parameters using the linear gradient elution model, 2D plots were used to show the pH and salt dependencies of the reciprocals of distribution coefficient, equilibrium constant, and effective ionic capacity of the mAb variants in these gradient elution systems. Comparison of the 2D plots indicated that the advantage of opposite dual salt-pH gradient system with increasing pH gradient and simultaneously decreasing salt gradient is the noncontinuous increased acceleration of protein migration. Furthermore, the fitted model parameters can be used for the prediction and optimization of mAb variants separation in dual salt-pH gradient and step elution. © 2018 American Institute of Chemical Engineers Biotechnol. Prog., 34:973-986, 2018.