Operating Temperature Research Articles

Improvement of mid-wavelength InAs/InAsSb nBn infrared detectors performance through interface control

We report our study to optimize the growth of mid-wavelength InAs/InAsSb nBn infrared detectors through interface control method with AlSb/AlAs superlattices as electron barrier. The dark current model was employed to investigate the dominant dark current mechanism at various operating temperatures. We extracted the minority carrier lifetime of InAs/InAsSb material grown by different interface growth methods. Electrical and optical characterizations indicated superior performance of the device grown by migration-enhanced epitaxy (MEE) with a 3 s As and Sb soak time. With −0.3 V applied bias and 150 K operating temperature, the optimal device shown a dark current density of 8.95 × 10−6 A/cm2 and peak specific detectivity of 7.12 × 1011 cm Hz1/2/W at 3.8 µm.

Enhanced thermochemical heat storage performance of CaO/CaCO3 via pyroligneous acid impregnation and Co/Mn co-doping

Calcium-based thermochemical heat storage (TCHS) is an economical and environmentally friendly technology for efficient heat storage. It can strengthen the flexibility in power systems of renewable energy and promote the recovery and storage of waste heat in energy-intensive industries. However, CaO/CaCO3 is extremely prone to sintering at operational temperatures. Consequently, a cost-effective approach was proposed to synthesize calcium-based TCHS materials modified by pyroligneous acid (PA) impregnation and co-doping with dual transition metals. The heat storage performance, physicochemical property, and anti-sintering mechanism of synthesized CaO were comparatively examined. The sample prepared with a molar ratio of Ca: Co: Mn = 100:3:7 (PACa-Co3Mn7) exhibited an initial energy storage density of 1.76 MJ/kg, which gradually rose to 1.88 MJ/kg. After 20 cycles, the value decreased by only 4.39 % from its peak, indicating outstanding TCHS performance. Characterization results indicated that the specific surface area and pore volume of PACa-Co3Mn7 were 10.48 m2/g and 0.035 cm3/g, which were 2.34 and 2.69 times those of CaO stemmed from the calcination of limestone, respectively. The fruitful pores provided pathways for CO2 diffusion within the CaO particles or CaCO3 product layer. The uniformly distributed Co and Mn elements combined to form Ca3CoMnO6. Ca3CoMnO6 could serve as the inert carrier that mitigated the grain-growth of CaO, thereby stabilizing the pore structure and resisting the sintering of PACa-Co3Mn7. Furthermore, density functional theory (DFT) calculations demonstrated that the free Mn and Co elements efficiently promoted the electrons transfer between CaO and CO2, which improved the reactivity of PACa-Co3Mn7. Therefore, CaO modified by PA impregnation and co-doping with dual transition metal is a promising candidate for the TCHS system.

Numerical modelling of lead-free perovskite photodetector with GO as ETM and Cz-N as HTM

Photodetectors (PD) are optoelectronic devices that can convert optical signal into electrical signals via the photoelectric effect. A model of CsSn0.5Ge0.5I3 based nip perovskite photodetector (PePd) with graphene oxide (GO) as electron transport material (ETM) and carbazole unit with naphthalene (Cz-N) is used as hole transport material (HTM) are established. The device configuration was analysed using solar cell capacitance simulator-1 dimensional (SCAPS-1D). The effects of absorber thickness, defect density of CsSn0.5Ge0.5I3, metal work function and operating temperature on device architecture have been investigated. For the incident light between 800-820 nm, a maximum responsivity and detectivity 0.65 A/W and 3.6×1013 Jones are obtained respectively. This simulation results will assist in the future research on high-performance lead-free perovskite photodetectors.

Linearity analysis of FE-based graded channel junctionless FET obtaining negative capacitance for low power applications

This paper reports ferroelectric (FE) oxide based graded-channel junctionless FET featuring the negative capacitance effects in nano-scale regime. The linearity nature of its response is analysed on the basis of third order interception point (PIP3), harmonic interception voltages of 2nd and 3rd orders (VIP2, VIP3) and intermodulation distortion (IMD3). Influence of fundamental device’s parameters such as, gate and underlap length, ferroelectric oxide thickness, graded channel doping and operating temperature on its linear behavior is observed and analysed in detail. The subthreshold slope is also found to go below 60mV/dec for optimum features, obtaining the NC characteristics. In its circuit application part, a cascode amplifier is designed using the proposed device showing variations due to the change in the proposed device dimensions. The proposed device is designed and simulated using Silvaco ATLAS device simulator, which is calibrated with the available experimental results. Therefore, the present study is quite relevant in recent days for low power analog applications.

The influence of the elemental valence on the thermophysical properties of high entropy (La0.2Sm0.2Eu0.2Yb0.2Y0.2)2(Ce0.5Zr0.5)2O7 coatings for thermal barrier application

Commercial yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) are no longer sufficient for the stringent demands in the high operating temperature and excellent thermophysical properties of the high-performance gas turbines and aviation engines. High entropy ceramics, distinguished by their superior thermophysical properties, have risen as a potential substitute for TBCs. However, the realm of atmospheric plasma spraying (APS) in the creation of these advanced TBCs remains relatively unexplored. In this work, three distinct high-entropy (La0.2Sm0.2Eu0.2Yb0.2Y0.2)2(Ce0.5Zr0.5)2O7 coatings were developed through the meticulous alteration of spraying power. The effects of spraying power on the microstructure, valence states of constituent elements and thermophysical properties of the coatings were deeply investigated. The results indicated that all the as-sprayed coatings exhibit a defect fluorite structure. Spraying power does have a significant impact on the thermophysical properties of the coatings. With the decrease in spraying power, the thermal conductivity of the coatings shows a progressive reduction, whereas the coefficient of thermal expansion (CTE) exhibits a gradual increase. This trend is closely related to valence states of constituent elements in the coatings. The resulting coating exhibits a low thermal conductivity of 0.54 W⋅m-1⋅K-1, a high CTE of 11.22×10-6·K-1 and a superior phase stability at elevated temperatures.

Research on indoor thermal comfort of traditional dwellings in Northeast Sichuan based on the thermal comfort evaluation model and EnergyPlus

Northeast Sichuan is in the hot summer and cold winter area (HSCW), making its traditional dwellings highly valuable for study. Due to the lack of an appropriate indoor thermal comfort evaluation model, this study developed a suitable model by combining field measurement, questionnaire, and dynamic simulation. The study also investigated the indoor thermal environment of traditional dwellings in the area. The results indicate that in summer, the average indoor air temperature in the bedroom is 25.3°C, and for 81.4% of the summer period, the bedroom operative temperature (top) is below the highest acceptable top of 29.2°C. In contrast, in winter, the average indoor air temperatures in both the bedroom and the hall are below 9.0°C, with only 9.6% of the winter period having bedroom top exceeding the minimum acceptable top of 12.2°C. These findings suggest that there is significant room for improvement in the winter indoor thermal environment. Additionally, the summer neutral top for occupants is 27.0°C, which is higher than the predicted value of 25.4°C, while the winter neutral top is 14.2°C, which is lower than the predicted value of 19.3°C. This indicates that both the traditional dwellings and their occupants have adapted to the local climate to some extent. This study aims to provide a theoretical framework and research basis for optimizing the indoor thermal environment of traditional dwellings in this area.

Incorporating Mixed-Ligand Zeolitic Imidazolate Framework into Polydimethyldiethoxysilane (PDMDES) Membrane for Enhancing Alcohol Pervaporation Recovery.

In the present study, a zeolitic imidazolate framework with mixed ligands, ZIF-8-90, was synthesized and embedded into an ultrathin polydimethyldiethoxysilane (PDMDES) matrix to prepare a ZIF-8-90/PDMDES mixed matrix membrane (MMM) for the enhanced recovery of alcohols from dilute aqueous solutions via pervaporation, using a facile solution coating method. The synthesized ZIF-8-90 particles demonstrated superior hydrophobicity and thermal stability compared to those of both ZIF-8 and ZIF-90 particles. Furthermore, the hydrophobicity, thermal stability, and sorption ability for alcohols of the ZIF-8-90/PDMDES MMM were significantly improved, attributed to the incorporation of mixed-ligand ZIF-8-90. Notably, the MMMs displayed two distinct cross-sectional morphologies: (1) ZIF-8-90 particles enveloped by PDMDES polymer forming filler bulges and (2) an accumulation of ZIF-8-90 particles resembling a brick-wall-like structure. The MMM incorporating 2.5 wt % ZIF-8-90 exhibited the optimal performance among the fabricated MMMs with various ZIF-8-90 loadings, spanning from 0 to 3.2 wt %. The effects of feed concentrations and operation temperatures were systematically investigated. The best pervaporation performance was achieved using the 2.5 wt % ZIF-8-90-filled MMM, effectively separating a 5.0 wt % ethanol/water mixture at 60 °C, yielding a distinguished total flux of 7.70 kg·m-2·h-1, an improved separation factor of 9.96, and an extraordinarily high PSI of 68.99 kg·m-2·h-1. Comparative analyses highlighted the superior pervaporation performance of the ZIF-8-90/PDMDES MMM over ZIF-8/PDMDES MMM, ZIF-90/PDMDES MMM, and other MMMs, underscoring its potential for practical applications in alcohol recovery.

Amorphous Carbon Film as a Corrosion Mitigation Strategy for Stainless Steel in Molten Carbonate Salts for Thermal Energy Storage Applications

Ternary carbonate salts (Li2CO3-Na2CO3-K2CO3) are promising heat transfer fluids to increase the efficiency of the electric power in concentrated solar power (CSP) technology. However, the corrosion produced at high operating temperatures is a key challenge to tackle for employing cost-effective steels as construction materials in CSP. In this work, the use of stainless steels with amorphous carbon was investigated, for the first time, as a surface modification method to mitigate the corrosion of structural CSP materials by molten salts. In doing so, an amorphous carbon (a-C) film of 100 nm in thickness was deposited on the 301LN stainless steel’s surface by the carbon thread evaporation technique. The corrosion behavior of the 301LN was assessed in carbonate salt at 600 °C for 1000 h. This film decomposed forming carbide layers, contributing to corrosion mitigation due to the generation of denser oxide layers, decreasing the Li+ diffusion through the stainless steel.

Dynamic simulation of roll bond PVT solar collector under Simulink/Matlab

Abstract This paper presents an innovative methodology to investigate dynamic roll bond PVT solar systems under real-world operational weather conditions using the Simulink/Matlab environment. The method is based on the MPPT electrical model of the solar cell and the differential energy equations of PVT at each of its layers. The effect of PV operating temperature, mass flow rate, and insulation medium on overall PVT thermal performance are all thoroughly examined. Results reveal that the annual average power delivered, in terms of both heat and electricity, is 352.8 W and 34.08 W, respectively. Furthermore, the addition of an insulating layer could lead to a significant improvement in PVT overall effectiveness. The present work offers a simple and flexible integration tool for roll bond PVT system simulation.

Quantum limits of superconducting-photonic links and their extension to millimeter waves

Photonic addressing of superconducting circuits has been proposed to overcome wiring complexity and heat-load challenges. However, such superconducting-photonic links suffer from an efficiency-noise trade-off that limits scalability. This trade-off arises because increasing power conversion efficiency entails reducing optical power, which makes the converted signal susceptible to shot noise. We analyze this trade-off and find that the laser-driven qubit gate infidelity scales inversely with the number of photons used. While methods such as nonlinear detection or squeezed light could mitigate this effect, we consider generating higher-frequency electrical signals, such as millimeter waves (100 GHz), using laser light. At these higher frequencies, circuits have higher operating temperatures and cooling power budgets and alleviate constraints posed by the trade-off. Therefore, we demonstrate an optically driven cryogenic millimeter-wave source with a maximum power efficiency of 8×10−5 that can generate a maximum of 0.7μW of 80 GHz power, with a 1200-thermal-photon equivalent of added noise at 4K. Using this source, we perform frequency-domain spectroscopy of superconducting NbTiN resonators at 80–90 GHz. Our results show a promising approach to lessen the efficiency-noise constraints on superconducting-photonic links, while leveraging the benefits of photonic signal delivery. Further optimization of power efficiency and noise at high frequencies could make scalable photonic control of superconducting qubits viable at temperatures exceeding 1K. Published by the American Physical Society 2024

Properties of Hydrochar Derived from Arabica Coffee Agro-Industry Residues under Wet Torrefaction Method

This study utilized coffee cherry residues, which is an abundantly available source of biomass in Indonesia. One of the methods to utilize coffee plantation residues effectively is wet torrefaction. This method is well-known as a hydrothermal method, where the biomass conversion process uses liquid as a medium and reactant in the process. The objective of this work was to develop an effective procedure for converting coffee agro-waste into marketable products using hydrothermal technology. The information related to changes in physical and thermal properties were explored in this work. To achieve the research objectives, three main steps were performed, i.e., feedstock preparation, wet torrefaction, and hydrochar characterization. Two types of feedstocks were studied in this work, coffee parchment and coffee pulp. In the wet torrefaction process, each feedstock was treated using two types of solutions, i.e., distilled water and acetic acid, at different concentrations. The reaction was carried out in an autoclave with a pressure of 2 bar (g) and an operating temperature of 130 ℃ for 2 hours. The properties of the hydrochar products were then analyzed using various methods, including bomb calorimetry, SEM, density, TGA-DTG, and hydrophobicity analyses. Overall, the results indicated that the hydrochar produced under acetic acid solution had better characteristics compared to that treated under distilled water. In terms of fixed carbon content and calorific value, the values increased up to 25.3% and 4,603 kcal/kg, respectively. Enhanced hydrophobicity was only observed in the coffee parchment hydrochar, where the average time required to adsorb water was 146.6 s, which can be categorized as strongly hydrophobic.

A study of chemical composition and physical-mechanical properties of rigid polyurethane-polyisocyanurate foams changes under conditions of extreme heating

Polyurethane-polyisocyanurate rigid (PIR) foams are used as thermal insulation materials in a wide range of applications such as construction and pipe insulation. Some of the utilizations require the maximum operating temperature of these materials to reach extremely high temperatures. This work is devoted to the study of changes in the chemical composition and the main physical-mechanical and thermophysical characteristics of PIR foams subjected to prolonged extreme heating in the presence of the material direct contact with air and in its absence. Based on the results obtained, prolonged extreme heating of such materials leads to a significant change in their chemical composition, mainly due to the thermal decomposition of allophanate, urethane and urea linkages, as well as the gradual formation of uretidione, linear carbodiimide polymer and the oxidation of ethers to esters. The relative compressive strength of these materials changes only to a small extent, while the thermal conductivity of these materials increases significantly during heating.

Kinetic Modeling in Temperature-Modulated Semiconductor Gas Sensor Utilizing Eley-Rideal Mechanism and Its Application in Discriminative Detection of VOCs.

This study presents a comprehensive kinetic investigation for describing the dynamic sensing process of semiconductor metal oxide (SMO)-based gas sensors, with a focus on the Eley-Rideal mechanism as a valid pathway. The modeling elucidates the direct interactions between volatile organic compounds (VOCs) and adsorbed oxygen on the material surface, providing insights into the temperature-dependent response characteristics of the sensor and addressing selectivity toward different VOCs fundamentally. By incorporating the effects of thermal modulation, the kinetic model was validated through theoretical fitting of experimental data obtained from a fabricated SnO2 nanoparticle gas sensor exposed to ethanol, n-propanol, toluene, and butanone at systematically varying operating temperatures. The results demonstrated that the model accurately captures response transient values, enabling a general framework for qualitatively discriminating specific gases based on their unique reaction kinetics. Furthermore, a machine learning procedure containing the above model and power laws of quantitative concentrations after identifying compounds was developed for the prediction of target VOCs. The qualitative accuracy was determined to be 99.4%, while quantifying with the mean absolute errors of 5.0, 7.5, 4.0, and 8.9 within the range of 25-200 ppm, respectively. The precise and straightforward strategy facilitates the response modeling of SMO-based gas sensors, offering a valuable platform for the designing model-driven algorithms applicable in gas analysis and monitoring.

Thermochemical energy storage with the solid-gas reaction of SrCO3 improved with CaCO3

Abstract In the context of thermochemical energy storage (TCES) for concentrating solar power (CSP) applications, metal carbonates’ reversible calcination and carbonation are gaining prominence, particularly in the SrCO3/SrO system. This system is notable for its high theoretical energy density of 10.61 GJ/m³ and operational temperatures up to 1,200 °C. However, like the CaCO3/CaO system, SrO experiences a significant drop in reactivity during cycling due to sintering and agglomeration of particles. In this work is proposed that the conversion effective will be improved by mixing the strontium carbonate with calcium carbonate. The best mix found was 80/20 SrCO3/CaCO3 with the operating parameters of calcination-carbonation temperatures of 1,200 °C and 900 °C, respectively. This reaction has a notably better stable conversion rate than pure strontium carbonate. The study was carried out using thermogravimetry analysis. The mixture was subjected to 9 cycles, and for the ninth cycle, there was an effective conversion of 33.14 %, which, compared to pure SrCO3, was 2.33 %; that was improved noticeably during the carbonation process. There was an increase in the percentage effective conversion of 30.81 %. Volumetric energy density was reduced from 6.93 to 2.81 GJ/m3 in the first and after nine cycles. The XRD analysis of the unprocessed mixture after 4 and 9 cycles showed no formation of new or secondary compounds, only the expected compounds: SrO, SrCO3, CaO, and CaCO3. This important change is explained during the carbonation looping because the CaO remains encapsulated in the SrCO3 and does not react completely at 900 °C. As a hypothesis, this encapsulation delays the sintering of the SrCO3. Using a T carb = 850 °C promotes the carbonation of CaO. By promoting CaO to react, the CaO encapsulated is released rapidly, and the material was sintering faster than the T carb = 900 °C. Comparing the seventh cycle at a T carb = 900 and 850 °C, it is observed that the effective conversion decreases from 0.4431 to 0.4202 and, in the same proportion, the volumetric energy density.

On the Thermal Conductivity and Local Lattice Dynamical Properties of NASICON Solid Electrolytes.

The recent development of solid-state batteries brings them closer to commercialization and raises the need for heat management. The NASICON material class (Na1+xZr2PxSi3-xO12 with 0 ≤ x ≤ 3) is one of the most promising families of solid electrolytes for sodium solid-state batteries. While extensive research has been conducted to improve the ionic conductivity of this material class, knowledge of thermal conductivity is scarce. At the same time, the material's ability to dissipate heat is expected to play a pivotal role in determining efficiency and safety, both on a battery pack and local component level. Dissipation of heat, which was, for instance, generated during battery operation, is important to keep the battery at its optimal operating temperature and avoid accelerated degradation of battery materials at interfaces. In this study, the thermal conductivity of NaZr2P3O12 and Na4Zr2Si3O12 is investigated in a wide temperature range from 2 to 773 K accompanied by in-depth lattice dynamical characterizations to understand underlying mechanisms and the striking difference in their low-temperature thermal conductivity. Consistently low thermal conductivities are observed, which can be explained by the strong suppression of propagating phonon transport through the structural complexity and the intrinsic anharmonicity of NASICONs. The associated low-frequency sodium ion vibrations lead to the emergence of local random-walk heat transport contributions via so-called diffusons. In addition, the importance of lattice dynamics in the discussion of ionic transport as well as the relevance of bonding characteristics typical for mobile ions on thermal transport, is highlighted.

Optimizing non-toxic (CH3NH3)3Bi2I9 perovskite solar cells by SCAPS-1D

Abstract Low-dimensional bismuth-based perovskite solar cells (PSCs) have demonstrated some benefits over lead-based PSCs for nontoxicity and remarkable stability. These two factors are now the primary concerns in the photovoltaic community. The power conversion efficiency (PCE) of PSCs using the lead Pb-free chemical methylammonium bismuth iodide (CH3NH3)3Bi2I9 is severely limited due to the poor quality of the photoactive material. Herein, the photovoltaic performance of the (CH3NH3)3Bi2I9 PSCs was investigated. The objective of this study was to investigate the intrinsic impacts of (CH3NH3)3Bi2I9 perovskite by using SCAPS-1D (Solar Cell Capacitance Simulator) to simulate the PSCs and the adjustment of relevant physical parameters to closely match experimental results. Moreover, the cells were optimized based on (CH3NH3)3Bi2I9 film thickness, total defect density of (CH3NH3)3Bi2I9, optical bandgap, and interfacial defects. By conducting a comprehensive analysis of the current-voltage (J-V) plots and quantum efficiency feature, the best values of perovskite thickness, bandgap, and defect density were determined to be 100 nm, 1.6 eV, and 1014 cm-3, respectively. Furthermore, defects in the interfaces between the electron-transporting layer (ETL)/(CH3NH3)3Bi2I9 and hole transport layer (HTL)/(CH3NH3)3Bi2I9 were considered, and their influence on performance was also investigated. Accordingly, the optimized cell has realized a record PCE of 9.043% and a high quantum efficiency exceeding 60%, which is comparable to those of some Pb-free perovskite analogues. The operational temperature calucations showed that all parameters remain relatively constant with increasing temperature. Therefore, the results imply that the simulated Pb-free PSCs can be stable in a thermal environment. The proposed structural layout and optimization approach can encourage more study and actual applications for Pb-free organometallic perovskite solar cells.

Impact of submicron Nb3Sn stoichiometric surface defects on high-field superconducting radiofrequency cavity performance

Nb3Sn film coatings have the potential to drastically improve the accelerating performance of Nb superconducting radiofrequency (SRF) cavities in next-generation linear particle accelerators. Unfortunately, persistent Nb3Sn stoichiometric material defects formed during fabrication limit the cryogenic operating temperature and accelerating gradient by nucleating magnetic vortices that lead to premature cavity quenching. The SRF community currently lacks a predictive model that can explain the impact of chemical and morphological properties of Nb3Sn defects on vortex nucleation and maximum accelerating gradients. Both experimental and theoretical studies of the material and superconducting properties of the first 100 nm of Nb3Sn surfaces are complicated by significant variations in the volume distribution and topography of stoichiometric defects. This work contains a coordinated experimental study with supporting simulations to identify how the observed chemical composition and morphology of certain Sn-rich and Sn-deficient surface defects can impact the SRF performance. Nb3Sn films were prepared with varying degrees of stoichiometric defects, and the film surface morphologies were characterized. Both Sn-rich and Sn-deficient regions were identified in these samples. For Sn-rich defects, we focus on elemental Sn islands that are partially embedded into the Nb3Sn film. Using finite element simulations of the time-dependent Ginzburg-Landau equations, we estimate vortex nucleation field thresholds at Sn islands of varying size, geometry, and embedment. We find that these islands can lead to significant SRF performance degradation that could not have been predicted from the ensemble stoichiometry alone. For Sn-deficient Nb3Sn surfaces, we experimentally identify a periodic nanoscale surface corrugation that likely forms because of extensive Sn loss from the surface. Simulation results show that the surface corrugations contribute to the already substantial drop in the vortex nucleation field of Sn-deficient Nb3Sn surfaces. This work provides a systematic approach for future studies to further detail the relationship between experimental Nb3Sn growth conditions, stoichiometric defects, geometry, and vortex nucleation. These findings have technical implications that will help guide improvements to Nb3Sn fabrication procedures. Our outlined experiment-informed theoretical methods can assist future studies in making additional key insights about Nb3Sn stoichiometric defects that will help build the next generation of SRF cavities and support related superconducting materials development efforts. Published by the American Physical Society 2024

Dynamically Confined Active Silver Nanoclusters with Ultrawide Operating Temperature Window in CO oxidation.

Supported metal nanoclusters are often highly active in many catalytic reactions but less stable particularly under harsh reaction conditions. Here, we demonstrate that this activity-stability trade-off can be efficiently broken through rational design of surrounding microenvironment of the supported nanocatalyst including gas adsorbate overlayer and underneath support surface chemistry. Our studies reveal that chemisorbed oxygen species on Ag surface and surface hydroxyl groups on oxide support, which are dynamically consumed during reaction but sustained by reaction environment (O2 and H2O vapor), drive spontaneous redispersion of Ag particles and stabilization of highly active Ag nanoclusters. Such a dynamic confinement effect from gas-catalyst-support interaction enables the Ag nanoclusters to exhibit complete catalytic oxidation of CO over a wide temperature window of 25 - 500 °C under dry conditions and 200 - 800 °C under wet conditions as well as remarkable stability at 300 °C over 1000 h.

Dynamically Confined Active Silver Nanoclusters with Ultrawide Operating Temperature Window in CO oxidation

AbstractSupported metal nanoclusters are often highly active in many catalytic reactions but less stable particularly under harsh reaction conditions. Here, we demonstrate that this activity‐stability trade‐off can be efficiently broken through rational design of surrounding microenvironment of the supported nanocatalyst including gas adsorbate overlayer and underneath support surface chemistry. Our studies reveal that chemisorbed oxygen species on Ag surface and surface hydroxyl groups on oxide support, which are dynamically consumed during reaction but sustained by reaction environment (O2 and H2O vapor), drive spontaneous redispersion of Ag particles and stabilization of highly active Ag nanoclusters. Such a dynamic confinement effect from gas‐catalyst‐support interaction enables the Ag nanoclusters to exhibit complete catalytic oxidation of CO over a wide temperature window of 25‐500 °C under dry conditions and 200‐800 °C under wet conditions as well as remarkable stability at 300 °C over 1000 h.

Energy Sources and Battery Thermal Energy Management Technologies for Electrical Vehicles: A Technical Comprehensive Review

Electric vehicles are increasingly seen as a viable alternative to conventional combustion-engine vehicles, offering advantages such as lower emissions and enhanced energy efficiency. The critical role of batteries in EVs drives the need for high-performance, cost-effective, and safe solutions, where thermal management is key to ensuring optimal performance and longevity. This study is motivated by the need to address the limitations of current battery thermal management systems (BTMS), particularly the effectiveness of cooling methods in maintaining safe operating temperatures. The hypothesis is that immersion cooling offers superior thermal regulation compared to the widely used indirect liquid cooling approach. Using MATLAB Simulink, this research investigates the dynamic thermal behaviour of three cooling systems, including air cooling, indirect liquid cooling, and immersion cooling, by comparing their performance with an uncooled battery. The results show that immersion cooling outperforms indirect liquid cooling in terms of temperature control and safety, providing a more efficient solution. These findings challenge the existing literature, positioning immersion cooling as the optimal BTMS. The main contribution of this paper lies in its comprehensive evaluation of cooling technologies and its validation of immersion cooling as a superior method for enhancing EV battery performance.