This study presents the development of an advanced operational risk model that leverages Fourth Industrial Revolution (4IR) technologies to optimize carbon dioxide (CO2) storage within deepwater abandoned hydrocarbon reservoirs. The model systematically combines Artificial Neural Networks (ANN) with the optimization capabilities of Genetic Algorithms (GA) and the probabilistic analysis strengths of a Bayesian Network (BN) to perform dynamic and comprehensive risk assessments. By applying the model to a dataset covering a 200-year timeframe, it effectively forecasts CO2 storage capacities while simultaneously evaluating associated risks across different operational scenarios. One of the key innovations of this model is the introduction of a novel loss function designed to precisely manage forecast deviations and enhance the efficiency of operational processes. This function is critical in ensuring that the model remains robust and accurate in real-time risk assessments, allowing for more reliable decision-making in CO2 storage operations. In addition, the study conducts an economic evaluation that underscores the crucial role of 45Q tax credits in bolstering the financial sustainability of carbon sequestration projects. The analysis highlights how these credits significantly reduce the economic barriers to adopting carbon utilization, storage, and sequestration (CUSS) technologies, making large-scale implementation more feasible. The model's performance is underscored by its ability to achieve a 49% CO2 retention rate over two centuries, with an impressively low average error margin of 0.249%. These results highlight the model's impressive efficiency and accuracy, while also demonstrating its capacity to markedly improve the predictability of CO2 storage outcomes. The findings suggest that this model could play a pivotal role in advancing global sustainability efforts by optimizing CO2 storage processes, thereby contributing to the reduction of atmospheric CO2 levels and supporting long-term climate goals.