We present an approach for automatic classification of Arctic sea ice and open water from spaceborne C-band RADARSAT-2 fully polarimetric (HH, HV, VH, VV) synthetic aperture radar (SAR) imagery, based on the random forest (RF) model. The HH- and HV-polarized radar backscatter, incidence angle and optimal polarimetric features are inputs of the RF model. <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">First</i> , we use a physics-based unsupervised scheme to generate well-annotated sea ice and open water samples. This scheme can alleviate labeling errors arising from visual interpretation or temporal-spatial mismatch between SAR images and operational ice charts. <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">Subsequently</i> , we estimate a set of characteristic polarimetric parameters and select the most representative features, using the recursive feature elimination method. <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">Finally</i> , the RF model is trained and validated using more than one million labelled samples. Statistical validation results show that the overall sea ice and water classification accuracy is 99.94% and the Kappa coefficient is 0.999. We find that ice–water discrimination accuracy can be improved by about 4%–10%, when optimal polarimetric features are involved in the RF model input. Moreover, the <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">polarization difference</i> (PD, VV–HH) is found to be the foremost polarimetric parameter for distinguishing sea ice from open water. The proposed approach has capability of yielding satisfactory ice–water classification over the complicated marginal ice zone. High-resolution ice–water classification maps clearly show that sea ice leads and their surroundings are also well separated.
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