The article analyzes the influence of the individual characteristics of lithium-iron-phosphate (LiFePO4) cells on the overall efficiency, stability and duration of operation of battery assemblies. The influence of such parameters as internal resistance, polarization resistance and capacity on the operation of battery assemblies under different load regimes and changes in temperature conditions was studied. It was found that these parameters can vary significantly between cells within the same assembly, which leads to an imbalance during the operation of the battery system. Such an imbalance causes an uneven distribution of charge between the cells, which reduces the overall performance of the system, accelerates the degradation of the cells and shortens their service life. To overcome these problems, the use of active balancing methods based on Unscented Kalman Filter (UKF) algorithms was proposed. The application of UKF allows for dynamic evaluation of the state of charge (SOC) of each cell and adjustment of system parameters in real time, which provides more accurate management of battery assemblies in conditions of variable external factors such as temperature and current loads. Special attention is paid to online identification of battery parameters, such as polarization resistance and capacity, which change over time due to cell aging. The conducted studies confirmed that constant monitoring of temperature regimes is critically important for maintaining stable operation of battery cells, preventing overheating and ensuring uniform load distribution. The performed simulation confirmed the effectiveness of the application of adaptive methods of balancing and temperature control, which allows to increase the reliability and overall performance of battery assemblies.