Real-time and accurate detection of SF6 decomposition products is a crucial approach to diagnosing internal faults of gas-insulated switchgear (GIS). However, the limited sensitivity and selectivity of SnS2 gas sensors have hindered their further development and application. This study employs density functional theory to design the optimal Pd-ZnO/SnS2 monolayer structure and investigate its adsorption behavior toward H2S, SO2, and CS2. The findings indicate that Pd atom doping and ZnO nanoparticle incorporation significantly enhance the conductivity of the SnS2 monolayer, reducing the band gap to 0.54 eV and lowering the work function by 5.019 eV. Regarding gas adsorption and sensing, the Pd-ZnO/SnS2 monolayer outperforms intrinsic SnS2 and ZnO/SnS2, showing the order in which SF6 decomposition products are selected is: CS2 > SO2 > H2S. Additionally, the sensitivity and recovery time of Pd-ZnO/SnS2 as a gas sensor were evaluated, confirming its excellent sensing performance for SO2 and CS2 detection. This study provides theoretical insights to advance the application of gas sensors in online insulation equipment monitoring.
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