The state of charge (SOC) of a lithium-ion battery plays a key role in ensuring the charge and discharge energy control strategy, and SOC estimation is the core part of the battery management system for safe and efficient driving of electric vehicles. In this paper, a model-based SOC estimation strategy based on the Adaptive Cubature Kalman filter (ACKF) is studied for lithium-ion batteries. In the present study, the dual polarization (DP) model is employed for SOC estimation and the vector forgetting factor recursive least squares (VRLS) method is utilized for model parameter online identification. The ACKF is then designed to estimate the battery’s SOC. Finally, the Urban Dynamometer Driving Schedule and Dynamic Stress Test are utilized to evaluate the performance of the proposed method by comparing with results obtained using the extended Kalman filter (EKF) and the cubature Kalman filter (CKF) algorithms. The simulation and experimental results show that the proposed ACKF algorithm combined with VRLS-based model identification is a promising SOC estimation approach. The proposed algorithm is found to provide more accurate SOC estimation with satisfying stability than the extended EKF and CKF algorithms.