Oldoinyo Lengai Volcano Research Articles

Detecting Transient Uplift at the Active Volcano Ol Doinyo Lengai in Tanzania With the TZVOLCANO Network

AbstractOver the last 7 years, geodetic data have detected periods of uplift and subsidence of the active volcano Ol Doinyo Lengai in Tanzania. Although numerous eruptions of the volcano have occurred historically, a systematic investigation of transient deformation using continuous Global Navigation Satellite System (GNSS) data has not been undertaken. We use the Targeted Projection Operator (TPO) to assess 7 years of continuous GNSS data from the TZVOLCANO network for transient signals and find rapid uplift spanning March 2022–December 2022 and then steady‐state uplift through August 2023. We conduct a nonlinear inversion of the GNSS velocities associated with the transient signal using dMODELS and find consistency with an inflating spheroidal source located 2.3 ± 0.6 km beneath the crater. Prior to March 2022, geodetic data indicated quiescence just below Ol Doinyo Lengai, thus detecting transient deformation with TPO allows for tracking changes in the magmatic system over time in the Natron Rift.

Carbonatite research: The African Legacy

Almost all igneous rocks are composed of silicate minerals; carbonatites are the main exception to this rule. They form only a minor proportion of the continental crust but are of fundamental scientific and economic importance. These rocks, originally described as a limestone (Kaiserstuhl, Germany) or magmatic limestone (Alnö, Sweden), were recognized in 1921 by W. C. Brøgger as a distinct magmatic rock type under the name “Karbonatite” in the Fen complex (Norway). Extensive field mapping in Africa, and particularly studies within the Chilwa Alkaline Province (Malawi), have led to the discovery of diverse intrusive and extrusive carbonatites. The latter, including the Fort Portal volcanic field in Uganda, Rufunsa Province in Zambia, and Oldoinyo Lengai volcano in Tanzania (the only volcano ever to have been seen to erupt carbonatites), have been exceptionally important in the recognition of carbonatites as truly magmatic rocks. The possibility of the existence of carbonate melts has been confirmed and shown by experimental studies of diverse carbonate systems with added volatile components (H2O, F) and alkali elements (Na, K). The study of the Oldoinyo Lengai gregoryite-nyerereite carbonatites, which are mineralogically and compositionally different from all known carbonatites worldwide, has led to long-lasting discussions about the origin of carbonatites. This includes composition of primary/parental carbonate melt, derivation of carbonatites by either liquid immiscibility or fractional crystallization, carbonatite evolution, and especially, the possible genetic relationships between alkali-rich and alkali-poor carbonatites. The rapid alteration of Oldoinyo Lengai carbonatites and their transformation to calcite carbonatite-like rocks has been proposed as the explanation for the absence of alkali-rich carbonatites in the geological past. Detailed mineralogical studies have shown that the occurrence of nyerereite is not restricted to Oldoinyo Lengai and that this mineral is now known to occur in other carbonatites (e.g., Guly, Kovdor, Oka, Kerimasi), alkaline rocks, and kimberlites (and even in diamond). This would suggest compositionally different mantle-derived melts enriched in alkali elements. In addition, carbonatite tephra has an important role in the preservation of some key paleontologic and anthropologic localities in East Africa. Despite these important discoveries, several problems related to carbonatite petrogenesis are not yet resolved. Future work is required, and carbonatites within Africa, with its key localities, may help to solve these problems.

Rare earth element transport and mineralization linked to fluids from carbonatite systems

Abstract Rare earth elements are critical constituents for modern technologies, and some of their largest natural resource deposits are related to carbonatite systems. However, the mechanisms leading to rare earth element mineralization and the role of magmatic fluids in carbonatite systems remain poorly understood. Here, we present the first in situ characterization of fluids and their trace-element compositions in natural carbonatite systems by studying secondary quartz-hosted fluid inclusions from Oldoinyo Lengai volcano. By comparing our data to other fluids and melts from various carbonatite systems, we constructed a model for fluid-mediated rare earth element transport and mineralization. We show that carbonatite-related fluids are rich in alkali-carbonate + sulfate + chloride and CO2, but poor in H2O, and they can be significant carriers of rare earth elements (>1600 ppm). We argue that fluid CO2 contents are essential to preclude or slow down the interaction with wall rock during migration and that fluid-mediated rare earth element mineralization occurs when partial pressure of CO2 decreases in the fluid (i.e., during degassing).

Evaluation of geological structures and geothermal resources in the North Tanzania Volcanic area using remote sensing and gravity data analysis

Problems Statement and Purpose. Northern Tanzania Volcanic terrain has been a subject of evaluation for geothermal potential in the last four decades. The region is characterized by Neogene to Recent volcanic and tectonic activities. This preliminary study based on remote sensing, water chemistry, gravity data, geological structures and volcanic centers distribution reports the geothermal manifestations identified and discusses the implications on geothermal fluid pathways. Oxygen-hydrogen isotope data from water samples indicate that there were involved in the hydrothermal system. Tectono-Volcanic Structures. The Northern Tanzania Divergence (NTD) area characterized by Neogene to Recent volcanic and tectonic activities. Recent volcanic and tectonic activities are ash cone and lava dome eruption at the floor of Meru crater a century ago, dyke intrusion and volcanic eruption south of Gelai volcano, and Oldoinyo-Lengai volcano, respectively. Fumarolic activities and hot springs are dominant in a relatively young volcanic area to the north-eastern and northern part of the NTD. Data and Methods. Shuttle Radar Topography Mission (SRTM), Landsat 8 Operational Land Imager (OLI) image, water isotope analysis and gravity data were used to extract and analyze the surface and subsurface geological lineaments and map the hydrothermal alteration zones in the study area. The hydrothermal alteration is used to evaluate and identify the permeable structures. Analysis and interpretation of the length and trends of extracted lineaments were used to investigate the tectonic evolution. Geological map of a study area was digitized from the existing geological maps and the age of rocks to delineate volcanic activity and associated lineaments based on the age of the lithological domain. Digital image processing was applied to enhance the visual interpretation. Gravity data were used to give insight into the subsurface structure in the study area. Results and Discussion. The higher δ 18O values and large deviation from meteoric water lines suggest that is due to the interaction of fluids with host rocks at elevated temperatures. These are consistent with open structures that act as conduits for fluid flow. The potential field gravity data reveal a basin-like structure trending in the NNW direction. The gravity data show that the basement units gradually deepen towards the central part and that it is controlled by two main fault systems that trend N-S and NW-SE respectively. The gravity data presented here provides new constraints on the tectonic evolution and geothermal resources of the study area.

Remote volcano monitoring using crowd-sourced imagery and Structure-from-Motion photogrammetry: A case study of Oldoinyo Lengai's active pit crater since the 2007–08 paroxysm

Active volcanic craters are highly dynamic geological features that undergo morphological changes on a broad range of spatial and temporal scales. Such changes have implications for the stability of the edifice, the eruptive style and the associated hazards. However, monitoring the morphological evolution of active craters at high spatial resolution and over long periods of time can be challenging, especially at remote volcanoes. In this study, we demonstrate the potential of Structure-from-Motion Multi-View Stereo photogrammetry technique based on crowd-sourced data, applied to the case study of Oldoinyo Lengai (OL) volcano in northern Tanzania. Following the 2007–08 paroxysm, OL volcano resumed its characteristic effusive activity and started to fill in with lava the newly-formed 300 m wide and 130 m deep pit crater. Monitoring capability is limited at OL due to its location in a remote non-urbanized area, therefore, the eruptive and morphological evolution is poorly constrained (e.g., lava emission rates, number of vents, location of unstable areas), with hazard implications for tourists visiting the summit area. Here we use crowd-sourced images, including Unoccupied Aircraft System (UAS) images, ground-based videos and pictures collected between October 2014 and June 2022, to reconstruct high-resolution topographic time-series of OL's summit crater. With these data, we have generated 7 Digital Elevation Models (DEMs) of OL's pit crater spanning the past 8 years, and estimated the emitted volume of lava and the corresponding time averaged discharge rates (TADR). From this we characterize the geomorphological evolution of OL pit crater since the 2007–08 paroxysm and perform a preliminary hazard assessment of the crater area. InSAR COSMO-SkyMed and Sentinel-1 data covering the periods 2013–2014 and 2018–2019 were also used in this study to complement our observations. Our results indicate that the main location of lava emission within the crater floor has repeatedly shifted over the years and that the 2008 cone has experienced a subsidence over time. OL's TADR has increased over the years, reaching values one order of magnitude higher in the period 2021–2022 compared to 2014–2018. Assuming similar TADR in the coming years, the crater could be filled in by lava within the next decade, leading to new lava overflows on the flanks of the volcano.

Advective structures of the bottom of lake Natron and its surroundings (Tanzania)

In this study we consider the features of the development of weakly lithified bottom sediments and the general structure of lake Natron against the background of its seasonal drying and watering. This study takes into account the laws of advection and the periodic placement of cellular zonal advective structures in space. The consedimentary structures in the lake sediments demonstrate the conditions for the formation of sodic ores and their positions. Provided space and aerial photographs depict unique genetic information about the evolution of geochemistry and the development of bottom morphology during sedimentation. This includes the presence of two sources that feed the lake - river and mud eruptions of the adjacent Oldoinyo-Lengai volcano, supposedly the only one on Earth that erupts carbonatite lavas. The combination of two sources and two processes leads to the development of an epimagmatic phreatic-hydrothermal recycling system. In it, the masses of the lake penetrate through fissure structures into the suprafocal space of the volcano, providing mud volcanism with solutions of soda masses containing organic matter of sediments. Volcanic soda eruptions are not carbonatite lavas. The morphological similarities and differences of structures are shown - small craters on the bottom of the lake, associated with the advection of thin layers of sedimentary material; large craters located nearby among volcanic strata along the shores of the lake; and both subsidence calderas and explosion calderas associated with magmatic and mud types of volcanism in the setting of strike-slip transtension.

Chronostratigraphic Studies of the Ootun Area Revealing the Late Holocene Plume Volcanism of the Oldoinyo Lengai, Ngorongoro, Tanzania

Oldoinyo Lengai has been a subject of international attention for geoscientists because of its uniqueness. The mountain is the world’s only active natrocarbonatite volcano whose recent activities are well documented. However, little is known about its eruptive history during the Holocene. One way of uncovering past volcanic activities is through chronostratigraphic studies. A rare stratigraphic sequence in the Ootun area containing buried tephra beds and paleosols is presented in this article. The beds suggest that the nearby active Oldoinyo Lengai volcano experienced the main plume volcanism during the late Holocene. This work presents the lithology of the area, estimated deposition period, and elemental and mineralogical compositions of strata, and establishing similarities between ash properties and information from previously reported chemistry and eruptions of the Oldoinyo Lengai volcano. Energy dispersive X-ray fluorescence, X-ray diffractometry, and accelerated mass spectrometry techniques were used for elemental, mineralogical, and radiocarbon dating analyses. A 1.3-m vertical soil profile revealed three major strata: topsoil, tephra bed, and paleosols. The paleosols are presumed to have been topsoil of the Ootun area during the Holocene. Subsurface tephra layers were found to contain similar properties to the volcanic material of the Oldoinyo Lengai. Based on the experimental findings and literature data, the study reports the occurrence of two major plume eruption events from the Oldoinyo Lengai, which happened around the minimum (oldest) age of490±10 BCand 771 AD. This work is essentially important in demonstrating the relevance of the region’s tephra chronostratigraphic studies by revealing the prospect of collecting additional scientific data on past geological processes and paleoenvironmental conditions of northern Tanzania.

The Interconnected Magmatic Plumbing System of the Natron Rift

AbstractUnderstanding the magmatic plumbing system of rift volcanoes is essential when examining the interplay between magmatic and tectonic forces. Recent seismicity, volcanic activity, magma emplacement, and volatile release make the Natron basin the ideal location to study these processes in the East African Rift System. Here, we present the first high‐resolution tomographic imaging of Oldoinyo Lengai volcano and surrounding volcanic systems using attenuation mapping. High scattering and absorption features reveal fluid‐filled fracture networks below regions of magmatic volatile release at the surface and a close spatial association between carbonatite volcanism and deeply penetrating, fluid‐filled faults. High‐absorption features appear sensitive to fluids and thermal gradients, revealing a central sill complex and connected plumbing system down to the mid‐crust, which links volcanoes and rift segments across the developing magmatic rift.

Toward Autonomous Detection of Anomalous GNSS Data Via Applied Unsupervised Artificial Intelligence

Artificial intelligence applications within the geosciences are becoming increasingly common, yet there are still many challenges involved in adapting established techniques to geoscience data sets. Applications in the realm of volcanic hazards assessment show great promise for addressing such challenges. Here, we describe a Jupyter Notebook we developed that ingests real-time Global Navigation Satellite System (GNSS) data streams from the EarthCube CHORDS (Cloud-Hosted Real-time Data Services for the geosciences) portal TZVOLCANO, applies unsupervised learning algorithms to perform automated data quality control (“noise reduction”), and explores autonomous detection of unusual volcanic activity using a neural network. The TZVOLCANO CHORDS portal streams real-time GNSS positioning data in 1[Formula: see text]s intervals from the TZVOLCANO network, which monitors the active volcano Ol Doinyo Lengai in Tanzania, through UNAVCO’s real-time GNSS data services. UNAVCO’s real-time data services provide near-real-time positions processed by the Trimble Pivot system. The positioning data (latitude, longitude and height) are imported into the Jupyter Notebook presented in this paper in user-defined time spans. The positioning data are then collected in sets by the Jupyter Notebook and processed to extract a useful calculated variable in preparation for the machine learning algorithms, of which we choose the vector magnitude for further processing. Unsupervised K-means and Gaussian Mixture machine learning algorithms are then utilized to locate and remove data points (“filter”) that are likely caused by noise and unrelated to volcanic signals. We find that both the K-means and Gaussian Mixture machine learning algorithms perform well at identifying regions of high noise within tested GNSS data sets. The filtered data are then used to train an artificial intelligence neural network that predicts volcanic deformation. Our Jupyter Notebook has promise to be used for detecting potentially hazardous volcanic activity in the form of rapid vertical or horizontal displacement of the Earth’s surface.

Origin of alkali-rich volcanic and alkali-poor intrusive carbonatites from a common parental magma

The discrepancy between Na-rich compositions of modern carbonatitic lavas (Oldoinyo Lengai volcano) and alkali-poor ancient carbonatites remains a topical problem in petrology. Although both are supposedly considered to originate via fractional crystallization of a “common parent” alkali-bearing Ca-carbonatitic magma, there is a significant compositional gap between the Oldoinyo Lengai carbonatites and all other natural compositions reported (including melt inclusions in carbonatitic minerals). In an attempt to resolve this, we investigate the petrogenesis of Ca-carbonatites from two occurrences (Guli, Northern Siberia and Tagna, Southern Siberia), focusing on mineral textures and alkali-rich multiphase primary inclusions hosted within apatite and magnetite. Apatite-hosted inclusions are interpreted as trapped melts at an early magmatic stage, whereas inclusions in magnetite represent proxies for the intercumulus environment. Melts obtained by heating and quenching the inclusions, show a progressive increase in alkali concentrations transitioning from moderately alkaline Ca-carbonatites through to the “calcite CaCO3 + melt = nyerereite (Na,K)2Ca2(CO3)3” peritectic, and finally towards Oldoinyo Lengai lava compositions. These results give novel empirical evidence supporting the view that Na-carbonatitic melts, similar to those of the Oldoinyo Lengai, may form via fractionation of a moderately alkaline Ca-carbonatitic melt, and therefore provide the “missing piece” in the puzzle of the Na-carbonatite’s origin. In addition, we conclude that the compositions of the Guli and Tagna carbonatites had alkali-rich primary magmatic compositions, but were subsequently altered by replacement of alkaline assemblages by calcite and dolomite.

Volcanic hazards assessment of Oldoinyo Lengai in a data scarcity context (Tanzania)

The objective of our study is to establish an assessment of four volcanic hazards in a country threatened by the eruption of the OlDoinyo Lengai volcano. The last major eruption dates back to 2007-2008 but stronger activity in 2019 has revived the memory of volcanic threats to the Maasai and Bantu communities and human activities (agro-pastoral and tourism). The methods chosen have had to be adapted to the scarce and incomplete data. The volcanic hazards and their probability of occurrence were analysed on the basis of data available in the scientific literature and were supplemented by two field missions combining geography and hydro-geomorphology. Our study enabled us to map the hazards of ash fall, lava flows, lahars and avalanches of debris. Each hazard was spatialised by being ascribed an intensity. They are sometimes synchronous with the eruption sometimes they occur several months or years after a volcanic eruption. The results are the first step towards developing a volcanic risk management strategy, especially for the pastoral communities living around Lengai and for the growing tourist activities in this area.

Multi-element isotope study of natrocarbonatites (1993 lava flows) from Oldoinyo Lengai volcano, Tanzania: Implications for core-mantle interactions

We contribute to the debate of core-mantle interactions by providing tungsten (W) isotope (ε182W) data from natrocarbonatite samples collected from the 1993 lava flows at Oldoinyo Lengai (OL) volcano, Tanzania. The 182Hf-182W system (half-life = 8.9 Ma) is well suited to constraining the timing of core formation and monitoring incursions of the core into the mantle. Most mantle-derived rocks are difficult to analyze because of their ultra-low W contents. We consider natrocarbonatites as suitable proxy for quantifying the core-mantle interactions given their unusually high W concentrations (published values range from ~40 to 115 ppm). The ε182W values of 7 natrocarbonatites measured by multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) represent the first dataset obtained for the OL lavas (OLLs). The ε182W values calculated from W isotope ratios range from −0.01 to +0.16 and are indistinguishable within limits of uncertainty, from those of the ambient modern mantle sources (i.e., EM1, HIMU, and HIMU-like). The relatively uniform W isotope compositions associated with the lack of any ε182W anomaly from the natrocarbonatites imply that there may have been no contribution from the core (i.e., ε182W < 0) into the magma source of the OLLs. Alternately, the core signature could have been obscured either by the addition of mantle components that survived since the Earth's early accretion, or by an unknown region formed by an inefficient percolation of metal during core-mantle segregation that left parts of the mantle enriched in W. New C–O isotope data from the same samples (δ13C = −5.9 to −6.9‰; δ18O = 9.5–10.9‰) rule out any involvement of the continental crust into the OL magma and are consistent with other studies that show a mantle signature for most natrocarbonatites. The heavier δ18O values can be attributed to sub-solidus processes. The potential oxygen isotopic shift would not, however, affect the W isotopic compositions of the OLLs.

Insights Into Fault‐Magma Interactions in an Early‐Stage Continental Rift From Source Mechanisms and Correlated Volcano‐Tectonic Earthquakes

AbstractStrain in magmatic rifts is accommodated by both faulting and dike intrusion, but little is known of the frequency of dike intrusions in early‐stage rifts. We use a new earthquake data set from a dense temporary seismic array (2013–2014) in the ~7‐Myr‐old Magadi‐Natron‐Manyara section of the East African Rift, which includes the carbonatitic Oldoinyo Lengai volcano that erupted explosively in 2007–2008. Full moment tensor analyses were performed on M &gt; 3.4 earthquakes (0.03‐ to 0.10‐Hz band) that occurred during the intereruptive cycle. We find two opening crack‐type and various non‐double‐couple earthquake source mechanisms and interpret these as fluid‐involved fault rupture. From waveform analysis on the nearest permanent seismic station, we conclude that similar rupture processes probably occur over eruptive and intereruptive cycles. The repeated and dynamically similar fluid‐involved seismicity, along with intrabasinal localization of active deformation, suggests that significant and persistent strain is accommodated by magmatic processes, modulated by tectonic cycles.

New tephrostratigraphic data from Lake Emakat (northern Tanzania): Implications for the eruptive history of the Oldoinyo Lengai volcano

The northern Tanzanian sector of the Gregory Rift is an area of an active continental rifting, in which sedimentation processes are strongly affected by volcanism. Due to limited stratigraphic exposure, the volcanic record of the region is rather sparse, and assigning volcanic centres for the individual eruptions is difficult. This study presents new data on the tephrostratigraphy of the sedimentary sequence of Lake Emakat, Empakaai Crater, northern Tanzania. Seven volcanic ash layers are identified and described from a 1.1-m core of lake sediments. Geochemical, mineralogical, petrographic and magnetic analyses show that: (1) all ash layers are products of highly explosive eruptions of melilite-bearing magmas; (2) most of the eruptions originate from a complex magmatic system; (3) all ash horizons are very well preserved in the lake environment; and (4) there are significant fluctuations of the bulk magnetic susceptibility of the lacustrine sediments which is related to microtephra from additional eruptions, the result of detritus, washed from the shore during periods of strong lake level fluctuations or periods of high erosion rates, or simply by the contamination by the material from the ash layers. Based on geochemistry and mineralogy of the seven identified ash layers in Lake Emakat, combined with the eruption ages from 14C datings, we can pinpoint Oldoinyo Lengai volcano as the source of these specific layers. The combination of this new data with existing chronological data from Ryner et al. (2007), retrieved from the same core, provides precise ages of the voluminous highly explosive eruptions in this region of East Africa during the Pleistocene-Holocene transition.

Structural controls of CO2 on Y, La and Sr incorporation in sodium-rich silicate - carbonate melts by in-situ high P-T EXAFS

Carbonate-rich silicate and carbonate melts play a crucial role in deep Earth magmatic processes and their melt structure is a key parameter, as it controls physical and transport properties. Carbon-rich melts can be strongly enriched in trace elements, but the structural incorporation mechanisms of these elements are difficult to study because such melts generally cannot be quenched to glasses. In this contribution we investigate the influence of CO2 on the local environments of trace elements contained in silicate glasses with variable CO2 concentrations and in silicate and carbonate melts. The melts were studied in-situ at high pressure and temperature conditions using the Paris-Edinburgh press (2.2 to 2.6GPa and 1200 to 1500°C). The compositions studied include sodium-rich peralkaline silicate melts and glasses and carbonate melts similar to those occurring naturally at Oldoinyo Lengai volcano. The local environments of yttrium (Y), lanthanum (La) and strontium (Sr) were investigated using extended X-ray absorption fine structure (EXAFS) spectroscopy. Main findings of the study suggest: (1) In peralkaline silicate glasses the local structure of Y is unaffected by the CO2 content. Contrary, a slight increase of oxygen bond lengths of Sr and La is inferred with increasing CO2 content in peralkaline glasses, while they remain constant in glasses of even higher peralkalinity independent of the CO2 content. (2) In silicate melts of different CO2 contents Y-O bond lengths are constant, while a slight increase within carbonate melt compositions is deduced. On the other hand, a steady bond lengths increase over the whole compositional range is inferred for La-O and Sr-O. This may well be explained by distinct preferences of these elements for specific local environments. Based on these new data, we suggest potential mechanisms for the structural incorporation of these elements, a key step towards understanding their partitioning behavior in natural magmatic systems.

Thermodynamic Analysis of Secondary Minerals Stability in Altered Carbonatites of the Oldoinyo Lengai Volcano, Northern Tanzania

Carbonatites from the Oldoinyo Lengai volcano, northern Tanzania, are unstable under normal atmospheric conditions. Owing to carbonatite interaction with water, the major minerals—gregoryite Na2(CO3), nyerereite Na2Ca(CO3)2, and sylvite KCl—are dissolved and replaced with secondary low-temperature minerals: thermonatrite Na2(CO3) · H2O, trona Na3(CO3)(HCO3) · 2H2O, nahcolite Na(HCO3), pirssonite Na2Ca(CO3)2 · 2H2O, calcite Ca(CO3), and shortite Na2Ca2(CO3)3. Thermodynamic calculations show that the formation of secondary minerals in Oldoinyo Lengai carbonatites are controlled by the pH of the pore solution, H2O and CO2 fugacity, and the ratio of Ca and Na activity in the Na2O–CaO–CO2–H2O system.

Fault‐magma interactions during early continental rifting: Seismicity of the Magadi‐Natron‐Manyara basins, Africa

AbstractAlthough magmatism may occur during the earliest stages of continental rifting, its role in strain accommodation remains weakly constrained by largely 2‐D studies. We analyze seismicity data from a 13 month, 39‐station broadband seismic array to determine the role of magma intrusion on state‐of‐stress and strain localization, and their along‐strike variations. Precise earthquake locations using cluster analyses and a new 3‐D velocity model reveal lower crustal earthquakes beneath the central basins and along projections of steep border faults that degas CO2. Seismicity forms several disks interpreted as sills at 6–10 km below a monogenetic cone field. The sills overlie a lower crustal magma chamber that may feed eruptions at Oldoinyo Lengai volcano. After determining a new ML scaling relation, we determine a b‐value of 0.87 ± 0.03. Focal mechanisms for 65 earthquakes, and 13 from a catalogue prior to our array reveal an along‐axis stress rotation of ∼60° in the magmatically active zone. New and prior mechanisms show predominantly normal slip along steep nodal planes, with extension directions ∼N90°E north and south of an active volcanic chain consistent with geodetic data, and ∼N150°E in the volcanic chain. The stress rotation facilitates strain transfer from border fault systems, the locus of early‐stage deformation, to the zone of magma intrusion in the central rift. Our seismic, structural, and geochemistry results indicate that frequent lower crustal earthquakes are promoted by elevated pore pressures from volatile degassing along border faults, and hydraulic fracture around the margins of magma bodies. Results indicate that earthquakes are largely driven by stress state around inflating magma bodies.

Tracing helium isotope compositions from mantle source to fumaroles at Oldoinyo Lengai volcano, Tanzania

Abstract Oldoinyo Lengai is the only volcano on Earth currently erupting natrocarbonatites, of which the source and genesis remain controversial. Cognate xenoliths and fumaroles were sampled at the summit of Oldoinyo Lengai, and deep crustal xenoliths from Oltatwa maar, in 2010 and 2014, after the 2007–2008 sub-Plinian eruption. The summit cognate xenoliths provide direct information on the isotopic composition of the mid-crustal magma chamber that was active during the 2007–2008 explosive eruption. Cognate xenolith-hosted pyroxenes from Oldoinyo Lengai have an average 3He/4He = 6.58 ± 0.46 RA, similar to values from nearby silicate volcanoes (4.95–7.30 RA), and reflecting a sub-continental lithospheric mantle (SCLM) signature. This similarity implies that Oldoinyo Lengai carbonatites form from a similar mantle reservoir as the nearby silicate volcanoes. We identify SCLM, metasomatized by fluids/melts derived from the depleted convective mantle, as the common source of magmas in the Arusha volcanic province. Fumarole measurements highlight that fumarolic 3He/4He values have been relatively constant since at least 1988, indicating that dramatic changes to the crater region morphology during the 2007–2008 eruption did not affect the architecture of the hydrothermal system, which is probably connected to the crustal magma chamber(s). Moreover, the similarity between 3He/4He values from the mid-crustal magma chamber (6.58 ± 0.46 RA) and fumaroles (7.31 ± 0.24 RA) of Oldoinyo Lengai attests that helium is not subjected to atmospheric contamination or crustal assimilation during transport to the surface.

High‐pressure Raman study of nyerereite from Oldoinyo Lengai

A rare sodium carbonate nyerereite, (Na,K)2Ca(CO3)2, first found in unique natrocarbonatite lava of Oldoinyo Lengai volcano, also attracted a lot of attention as an inclusion phase in mantle minerals formed in the course of deep carbonatite magmatism. We measured the evolution of nyerereite Raman spectra under quasi‐hydrostatic compression up to 6.4 GPa using a diamond anvil cell. The ν4(CO32−) band (710 cm−1 at ambient pressure) and ν1(CO32−) doublet (1077 and 1086 cm−1 at ambient pressure) demonstrated a positive pressure shift with dν/dP irregularities at 0.5 and 3.0 GPa. The obtained calibration was then used for residual pressure measurements in nyerereite‐bearing inclusions in olivine from the Udachnaya‐East kimberlite. Copyright © 2017 John Wiley &amp; Sons, Ltd.

Leaching of lava and tephra from the Oldoinyo Lengai volcano (Tanzania): Remobilization of fluorine and other potentially toxic elements into surface waters of the Gregory Rift

Volcanic ash leachate studies have been conducted on various volcanoes on Earth, but few have been done on African volcanoes until now. Tephra emissions may affect the environment and the health of people living in this area, and therefore we conducted a first tephra (ash and lapilli sized) leachate study on the Oldoinyo Lengai volcano, situated in northern Tanzania. The recent explosive eruption in 2007-2008 provided us with fresh samples from the first three weeks of the eruption which were used for this study. In addition, we also used a natrocarbonatitic sample from the activity prior to the explosive eruption, as the major activity at Oldoinyo Lengai is natrocarbonatitic. To compare the leaching process affecting the natrocarbonatitic lavas and the tephras from Oldoinyo Lengai, the 2006 natrocarbonatitic lava flow was resampled 5years after the emplacement and compared to the initial, unaltered composition.Special interest was given to the element fluorine (F), since it is potentially toxic to both humans and animals. A daily intake of fluoride (F−) in drinking water of >1.5mg/l can lead to dental fluorosis, and higher concentrations lead to skeletal fluorosis. For this reason, a guideline value for fluoride in drinking water was set by the WHO (2011) to 1.5mg/l. However, surface waters and groundwaters in the Gregory Rift have elevated fluoride levels of up to 9.12mg/l, and as a consequence, an interim guideline value for Tanzania has been set at 8mg/l.The total concentration of fluorine in the samples from the natrocarbonatitic lava flow is high (3.2wt%), whereas we observed a significant decrease of the fluorine concentration (between 1.7 and 0.5wt%) in the samples collected three days and three weeks after the onset of the explosive 2007–08 eruption. However, the total amount of water-extractable fluoride is lower in the natrocarbonatitic lavas (319mg/l) than in the nephelinitic tephra (573–895mg/l). This is due to the solubility of the different F-bearing minerals. In the natrocarbonatites, fluorine exists predominantly in fluorite (CaF2), and in the early tephra as Na-Mg bearing salts such as neighborite (NaMgF3) and sellaite (MgF2). All these three minerals have very low solubility in water (16–130mg/l). The later nephelinitic tephras contain surface coating of villiaumite (NaF), which is highly soluble (42,200mg/l) in water and can thus release the fluoride more readily upon contact with water.Although there is still the need for further data and a more precise study on this topic in Tanzania, we can already draw a first conclusion that the intake of water during or directly following the deposition of the tephra is not advisable and should be avoided, whereas the release of fluoride from the lava flow has less influence on the river waters.