Oil Transportation Research Articles

ИЗУЧЕНИЕ СОРБЦИОННОЙ СПОСОБНОСТИ МОДИФИЦИРОВАННОГО ДИОКСИДА КРЕМНИЯ ПО ОТНОШЕНИЮ К НЕФТИ

Oil production and transportation are associated with the risk of man-made accidents that lead to pollution of soil and water surfaces. Sorbents of various natures, in particular silicates, are widely used t o remove oil pollution. An urgent task is to improve the sorption properties of silicon dioxide by modifying it with metal ions and subsequent hydrophobization with organosilicon compounds. It has been established that modifying the surface of silicon dioxide with metal ions increases its sorption activity in relation to oil. Optimum concentrations of the hydrophobizer that ensure high buoyancy of the sorbents have been determined

Internal Corrosion Control Strategy of Oil Gathering and Transportation Pipeline

Abstract Internal corrosion and perforation of metal pipelines is the main reason for failure of gathering and transportation pipelines in a western oil field. The content of Cl-in the transport medium of the oilfield is between 24910-118051mg/l, the total salinity is between 65404-39363mg/l, the reduced sulfur content is between 6-36mg/l, and the number of SRBS is between 20-300 /ml, which are the main factors leading to corrosion in the pipeline. Through investigation, demonstration and field test, the internal corrosion control technology system of pipeline has been formed, which includes internal extrusion coating, internal penetration, 32MPa high pressure flexible composite pipe, polyethylene lined FRP composite pipe technology. The internal corrosion control strategy has been popularized in oil field, and the effect is good.

Study on the Accumulation Model of the Cretaceous Reservoir in AHDEB Oilfield, Iraq

The Ahdeb oil field is located in the southwestern part of the Zagros fold deformation zone. The study of the model of the formation of the oil reservoir in this field will be helpful to deepen the pattern of hydrocarbon distribution in this zone. In this paper, we use the seismic data of the Ahdeb oil field to recover the tectonic evolution history of the field. Under neotectonic movement, the oil field formed in the early stage, migrated to the high point in the late stage, and finally entered the present formation. From here, for the oil-bearing inclusions within the reservoir, the photometric absorption values of the organic matter groups were measured by infrared spectroscopy. Their ratios were used to evaluate the maturity, thus discovering two phases of oil charging. Finally, using the hydrocarbon generation history and tectonic evolution history, combined with the oil and gas transportation periods in the reservoir, we deduce that the reservoir formation mode in the area is a two-phase gathering and final adjustment formation mode. This understanding of the hydrocarbon formation patterns will promote oil and gas exploration in this zone.

Deformation and Stress Prediction of Tank under Uneven Settlement

Abstract The differential settlement of crude oil tank foundations can lead to deformation and stress concentration, posing significant risks to the safe operation of storage tanks. This study developed a finite element model for a large crude oil storage tank subjected to harmonic settlement to address the issue of non-uniform settlement around the tank. The model systematically varied the tank’s diameter-to-thickness ratio, height-to-diameter ratio, and the wind beam’s relative bending stiffness. The research examined the impact of these three factors on the maximum dimensionless radial displacement at the tank top and the maximum equivalent stress at the tank bottom. A predictive method was proposed for estimating the radial displacement at the tank top and the equivalent stress at the tank bottom under uneven settlement, offering valuable insights for assessing the integrity of large tanks in such conditions.

Research on the evolution and venting characteristics of gasoline–air mixture explosions in confined pipeline trench spaces

In recent years, international energy cooperation has become more extensive, and the safe and reliable transportation of oil and gas resources has become increasingly important. However, storage and transportation sites can have confined spaces in engineering practice, which can lead to safety problems. There is a risk of gasoline–air mixture explosions in confined spaces such as pump rooms, valve operation rooms, and inspection wells, particularly in Class B and Class C pipeline trench areas that utilize non-sand-filled trenches or where the local depth exceeds 2.0 m. These locations are equipped with doors, manholes, or ventilation openings for personnel access within oil storage zones. To investigate the combustion characteristics of gasoline–air mixture explosions in such confined spaces, experimental research was conducted on a simulation platform (L/D = 15, V = 0.015 m3). The findings reveal the following: (1) the most hazardous initial gasoline–air mixture volume fraction for ignition at the upper ignition point is 1.7%; (2) the morphology of the internal flame evolves through four distinct stages, with the post-explosion flame shapes resembling “brush-like” and “mushroom cloud” formations; (3) low YCH = 1.1%, medium YCH = 1.7%, and high YCH = 2.3% volume fractions of hydrocarbons were selected to analyze the progression of the explosion development process; (4) the external overpressure distribution during venting explosions, with varying initial gasoline–air mixture volume fractions, conforms to the function y = ae−bx as the distance L varies, with venting pressure waves exhibiting a trend of exponential decay.

Parameters Analysis of Crude Oil Transport with Pipes

Parameters Analysis of Crude Oil Transport with Pipes

A legal and regulatory compliance framework for maritime operations in Nigerian oil companies

The maritime sector plays a critical role in Nigeria's oil industry, serving as the primary conduit for offshore oil exploration, production, and transportation. As the country remains heavily reliant on its oil revenues, ensuring that maritime operations comply with legal and regulatory standards is crucial for operational safety, environmental sustainability, and economic stability. This review outlines a comprehensive legal and regulatory compliance framework for maritime operations in Nigerian oil companies, focusing on the roles of key regulatory bodies such as the Department of Petroleum Resources (DPR), the Nigerian Maritime Administration and Safety Agency (NIMASA), and the National Environmental Standards and Regulations Enforcement Agency (NESREA). It explores major laws such as the Coastal and Inland Shipping (Cabotage) Act, Petroleum Industry Act (PIA), and Environmental Impact Assessment (EIA) Act, highlighting their implications for offshore drilling, oil transportation, and environmental protection. Additionally, the review discusses the compliance challenges Nigerian oil companies face, including environmental risks, maritime security threats, jurisdictional conflicts, and the technical demands of adhering to safety standards. To address these challenges, the study emphasizes the need for regular audits, technology integration, capacity building, and collaborative engagements between oil companies and regulatory authorities. Through case studies on oil spill response and the enforcement of cabotage laws, the review underscores the importance of robust regulatory enforcement to ensure safety, mitigate environmental damage, and enhance operational efficiency. This framework is essential for the future growth of Nigeria’s oil sector, balancing economic gains with legal compliance and sustainability in maritime operations.

TECHNOLOGICAL SOLUTION FOR COMBATING HYDROGEN SULFIDE AT THE FIELD

One of the urgent problems in the production of hydrogen sulfide-containing oils is the problem of increasing the efficiency of hydrogen sulfide removal. Optimization of costs associated with the production, transportation and preparation of oil is very important at the present time. In order to reduce the costs of oil preparation, the use of a differentiated approach to solving the problem of its purification from hydrogen sulfide at the Kashagan field depends on the volumes of oil preparation, the mass fraction of hydrogen sulfide in the oil, the presence of gas near the high-sulfur oil preparation unit (UPVSN) that does not contain hydrogen sulfide, the presence of a gas collection system and the possibility of transporting increased volumes of hydrogen sulfide-containing gas to the sulfur purification unit. Taking these factors into account, it is necessary to identify the maximum values ​​​​of the volume fractions of methane, ethane, nitrogen and carbon dioxide in the composition of the stripping gas, at which the mass of oil will be preserved, as well as the conditions under which it will be purified from hydrogen sulfide in the conditions of the Kashagan field. Studies have shown that with an increase in the oil heating temperature and a decrease in the pressure in the desorption column, the maximum total volume fraction of methane and nitrogen in the mixture in the composition of the stripping gas decreases. A decrease in the mass fraction of hydrogen sulfide in oil below 100 ppm and maintaining the mass yield of oil depending on the proportion of these components in the composition of the stripping gas is possible if the oil temperature and pressure in the column are optimized. An increase in the total volume fraction of methane and nitrogen in the composition of the stripping gas leads to a decrease in its required consumption to achieve a certain efficiency of oil purification from hydrogen sulfide at specified operating parameters of the column.

Fractal Characterization on Three-Dimensional Tortuosity of Fault Tectonic

Faults, as a kind of fracture tectonics, play a role in reservoir closure or provide oil and gas transportation channels. The accurate understanding of the distribution characteristics of faults is significant for oil and gas exploration. The traditional fractal dimension for fault number (Df3) cannot comprehensively characterize the complexity and heterogeneity of fault network distribution. In this paper, a fractal characterization method on three-dimensional (3D) tortuosity of fault tectonics is proposed based on 3D seismic exploration. The methodology is described in detail to establish the model on the fractal dimension for the 3D tortuosity of fault tectonics. The results show the proposed method of estimation of the DT3 displaying high accuracy and rationality. Compared with the traditional fractal dimension Df3, the proposed DT3 can comprehensively characterize the fractal characteristics of faults network systems in the 3D space. This study achieves a breakthrough in the fractal characterization of the 3D tortuosity of fault tectonics. It is worth further study for establishing an analytical fractal equation based on the DT3 and oil or gas transfer, which can provide the theoretical foundation and technical support for oil and gas exploration.

Asphaltene deposition effects on reservoir rock wettability and modification strategies

Asphaltene deposition, a widespread challenge in the petroleum industry, detrimentally affects oil production, transport, and processing. Our study investigates asphaltene's impact on sandstone and carbonate reservoir rock wettability using ASTM-D6560 extraction and heptol solutions. A significant part of our focus was to examine wettability change due to asphaltene damage and the use of nanoparticles to improve this situation. Qualitatively, advanced techniques reveal altered rock composition, and contact angle measurements, along with zeta potential assessments, highlight significant wettability changes. Quantitatively, asphaltene-infused solutions induce a quantifiable increase in contact angles. Specifically, with gamma alumina nanoparticle addition, contact angles rise from 68° to 87° for sandstone and 110°–142° for carbonate rocks. Temperature variations within our experimental range also induce notable wettability changes. These findings establish a clear link between asphaltene deposition and quantifiable wettability modifications, providing crucial insights for optimizing oil recovery processes and enhancing well performance in the petroleum industry. The study's results suggest that nano-gamma alumina can be an effective solution for improving wettability and mitigating asphaltene deposition issues in carbonate rocks, offering promising prospects for the oil and gas industry.

Research on the Performance of New Microbial Fuel Cell Anodes

In recent years, with the vigorous development of the maritime transportation industry, the resulting problem of ship oil pollution has become increasingly prominent. Efficient and thorough treatment of oily wastewater is the key to solving such problems. Microbial fuel cell (MFC) technology is a promising biological treatment method due to its good degradation effect, no secondary pollution, and energy recovery. In this paper, the discarded corn cob materials in nature were selected for high-temperature carbonization at 350°C, and NaOH was used to modify the modified biochar. Then, the coating technology of Ti3C2 MXene, NbC, WC, TaC and other materials was used to modify the surface of biochar, and the biochar anode material was obtained to construct a double-chamber microbial fuel cell device. The properties of the modified anode biochar materials were studied.

A mathematical model of a liquid-loading vessel at the initial stages of design

To substantiate the main unknowns at the initial stages of design and, above all, during the re-search design, it is necessary to develop a mathematical model as sensitive as possible to changes in variable parameters, which can be any elements of the vessel or its subsystems. The need to ensure seaworthiness, such as buoyancy, stability, unsinkability, strength, seaworthiness and capacity requires the inclusion of these modules in modeling either in the form of calculation functions, such as determining precipitation from the equation of mass and buoyancy, or in the form of restrictions requiring, if not fulfilled, recalculation of the former. The paper describes a similar mathematical model in relation to an oil tanker of mixed (river-sea) navigation of the M-SP class of the Russian Classification Society. Its feature is the use of computer-aided design of the hull shape and the inclusion in the mathematical model of the actual calculation of the elements of buoyancy, initial stability and capacity, rather than using statistical dependencies for them, which significantly increases the adequacy of the final result.

Market of transport and logistics services in the context of global transformation of supply chains

The article examines the market of transport and logistics services in the Russian Federation and provides an analysis of key trends and changes caused by the transformation of supply chains associated with political and economic factors. The analysis examines the quantitative characteristics of the transport and logistics services market and identifies current trends and their impact on the transformation of logistics systems. An analysis of the development of the multimodal transportation segment and the role of cargo containerization in the development of this segment is provided. When discussing the results, the classifications of transport and logistics services proposed by various researchers and their applicability in studying of the market of transport and logistics services in the Russian Federation are analyzed. The impact of supply chain transformation is examined using the example of the oil and gas complex of the Russian Federation. The main problems faced by oil and gas enterprises in the context of changing supply chains and the orientation of the economy are highlighted. The article presents the main ways to solve some of the problems identified by researchers, for example, the reorientation of oil transportation to the Northern Sea Route and the Siberian pipelines, leading material flows to the east and to the countries of the Asia-Pacific region.

Studying the Characteristics of Tank Oil Sludge

Oil sludge is one of the main pollutants generated by the oil industry. Due to serious pollution and increasing oil production, problems arise every year in the effective treatment of oil sludge. The current study examines the composition and physicochemical characteristics of oil sludge, as well as traditional and new methods for processing oil sludge. With the tightening of environmental protection requirements, oil sludge quality reduction, recycling, and harmless treatment technologies will become necessary in the future. The primary task was to determine the composition of tank oil sludge, separate it from mechanical impurities, and study the influence of ultrasonic treatment and subsequent atmospheric distillation on the extract. The separation of the concentrate and the composition of the tank oil sludge, using an extracted mixture of hexane and benzene, are considered. The use of modern SEM methods, elemental analysis, NMR analysis, IR, ultrasound, and GC–mass spectrometry made it possible to characterize the organic part of reservoir oil sludge and its distillation products. First, 300 g of tank oil sludge was preheated and mixed with 300 mL of solvent (hexane:benzene = 1:1). After mixing with the solvent, the result mixture was filtered. Then, it was placed in an ultrasonic bath and exposed to ultrasound at a frequency of 100 kHz for 30 min. After processing, it was extracted in a Soxhlet apparatus at a temperature of 65 °C to isolate the extract. The resulting extract was analyzed on a gas chromatograph with mass detection. The composition of the extract was as follows (in %): hexane—83.99; total hydrocarbon isomers—7.12; n-hydrocarbons—2.52; benzene—6.37%. At a temperature of 85 °C, the benzene yield was 65.85%. It has been established that the fractions obtained through the distillation of oil sludge at temperatures of 65–85 °C have improved dissolving capacity. It has also been shown that the use of these fractions promotes an increase in the content of hydrocarbon isomers by 12–13% in the extract composition.

Adsorption behavior of non-ionic demulsifiers at the oil/water interface stabilized by asphaltenes: Experiments, adsorption kinetics, and mechanisms

Formation of emulsions containing asphaltenes is both undesirable and unavoidable in petroleum production. Chemical demulsifiers, such as non-ionic surfactants, have long been applied as the cheapest and most effective method of breaking emulsions by altering the oil/water interfacial properties. In this study, the association state of the asphaltenes, the dehydration rate, and the interfacial rheology under various demulsifier concentrations were used to analyze the contributions of non-ionic demulsifiers to the breaking of the asphaltene-containing emulsions. Additionally, the dynamic interfacial tension (DIFT) data over time were used to investigate the adsorption kinetics of the asphaltenes and the demulsifier at the oil/water interface. Results indicate that liquid paraffin enhanced the association of the asphaltene molecules, while the non-ionic demulsifier rendered asphaltene aggregate sizes smaller. The addition of the demulsifiers reduced the interfacial strength, leading to an unstable interface. The oil-soluble demulsifiers reduced IFT more effectively than the water-soluble ones, due to their faster migration rate and low interfacial tension gradient to the oil–water interface. The adsorption process of the asphaltenes, influenced by the demulsifier concentration, could be divided into three stages: a short-term diffusion-controlled process, a transition process, and a slow descent process (referred to as Regimes I, II, and III). In Regime I, the diffusion coefficient of asphaltenes increased with the demulsifier concentration, indicating that the demulsifier aided the dispersing of the asphaltenes in the solution. The equilibrium IFT and the maximum surface excess concentration of the asphaltenes in the long-term adsorption process decreased with the demulsifier concentration, indicating that the asphaltene-containing emulsions generally became unstable after adding the demulsifiers. Our results offer valuable insights into the adsorption kinetics and the mechanisms of alterations by the asphaltenes and demulsifiers of the oil/water interface, with implications for various interfacial phenomena (e.g., emulsion stability) involving surfactants in oil production, transportation, and processing.

Pitching Stabilization Control for Super Large Ships Based on Double Nonlinear Positive Feedback under Rough Sea Conditions

Due to the rapid development of a global navigation satellite system and the rapid growth of ships, the traditional control algorithms are not suitable; hence, the longitudinal rocking phenomenon generated by external disturbances is more serious when a ship is sailing. This paper takes a mathematical model of the super large oil tanker “KVLCC2”’s longitudinal motion as the controlled plant, establishing a multi-input multi-output instability control system, using the root trajectory shaping method and a weighting matrix to ensure the stability of its transfer function’s mathematical model. An improved closed-loop gain-shaping algorithm is utilized to design a simple robust controller. And a dual nonlinear positive feedback control algorithm is added to the control system to further improve the controller’s pitching stabilization performance and reduce the controller’s output energy. In order to verify that the controller has a consistently strong robustness, simulation experiments are carried out by adding a level 6, 7 and 8 wind wave model and a perturbation link to the control system, respectively. The results show that when the value of the hysteresis constant is taken as 0.25, the output values of the heave displacement and the pitch angle are greatly reduced, and the longitudinal rocking phenomenon is significantly improved. The dual nonlinear positive feedback control algorithm enhances the ship’s pitching stabilization control capability and further reduces the controller’s output energy, which provides technical support for the smooth and efficient sailing of super large ships under changing sea conditions. Combined with a global navigation satellite system, this algorithm provides a new method for pitching stabilization control of super large ships.

Hydrate Formation and Blockage in Inlet/Outlet and Slope Pipes of Gas–Water–Oil Transportation Pipeline

Hydrate Formation and Blockage in Inlet/Outlet and Slope Pipes of Gas–Water–Oil Transportation Pipeline

Advanced corrosion resistance and mechanistic insights of electroless Ni-P-PTFE coatings on L245NS substrate in H2S-saturated environments

The extraction and transportation of oil and gas pose significant challenges due to corrosive environments, particularly hydrogen sulfide (H2S) exposure. This study investigates the use of polytetrafluoroethylene (PTFE) to enhance the corrosion resistance of nickel‑phosphorus (NiP) coatings in H2S-rich environments. Electroless deposition was employed to prepare Ni-P/PTFE coatings, which were then subjected to simulated H2S corrosion tests. Results indicate that the incorporation of PTFE led to a more uniform NiP coating with reduced porosity, significantly improving corrosion resistance. The coatings exhibited enhanced protective performance by stabilizing corrosion product layers and preventing the formation of corrosion channels. Ni-P-PTFE coatings overcame the existing research challenge of NiP coatings' corrosion in H2S environments, showing no penetration of the corrosive medium into the substrate after 720 h of immersion. The corrosion rate of the coating is only 0.0261 mm/year, only 4.27 % of the corrosion rate of the L245NS substrate in the early stage of corrosion. Moreover, after characterization by SEM, XRD and XPS, it was found that the presence of PTFE altered the corrosion mechanism, promoting the formation of stable nickel sulfide and oxide layers on the surface. This study sheds light on the mechanisms underlying PTFE-enhanced corrosion resistance in NiP coatings, offering promising implications for extending the lifespan of equipment in the oil and gas industry.

On the transition of liquid dispersion states and their physical-thermodynamic nature in the development of gas-condensate reservoirs in depletion mode

This work presents new results of physical and chemical analysis of samples from contaminated areas of the Absheron field. The advantages and disadvantages of the used and traditional methods of cleaning oil waste are shown. Modern methods have been used to determine the characteristics of oil sludge samples from the Balakhany, Ramana, Surakhany, Bibiheybet fields of the Absheron Peninsula: oil sludge composition, viscosity, density, water content, chemical composition, temperature, cutting size, toxicity, volume, pH level, turbidity, BOD (biological oxygen demand), TDS (total dissolved solids). The main properties of oil sludge from the fields of the Absheron Peninsula are analyzed and compared. Chromatographic analysis (Agilent 7820A GC) allowed us to separate the oil waste and mixtures of the studied samples into individual compounds and components. The separation and determination of the components of the waste mixture by gas chromatography consisted of three stages: 1) Introduction of the sample into the chromatograph, 2) Separation of the sample into individual components, 3) Determination of the compounds contained in the sample. An inductively coupled plasma mass spectrometer (Agilent 7500 cs) with reaction cell was used for the efficient determination of trace heavy metals in petroleum waste. The ion lens unit used in the Agilent 7500cs provided high sensitivity measurements. Thus, trace metals were detected in the samples. A vacuum distiller (Retort Oil and Water Kit RROW-50) was used to quantify liquid and solids in drilling mud. Comparison of our oil sludge analysis results with field data demonstrates the effectiveness of these methods in identifying the composition of oil sludge for obtaining target products. From the studied wastes of the oil industry, it is possible to obtain special additives and use them, for example, for asphalt concrete. The dependences of oil sludge evaporation (of the Balakhany, Ramana, Surakhany, Bibieybet deposits) on air temperature and thermal resistance of the waterproofing material of the oil storage facility have been studied. The evaporation of components also depends on the concentration of oil sludge. Based on our sample analyses, it has been shown that the combined use of physicochemical and chemical methods makes it possible to purify oil sludge to acceptable limits. The dependences of oil evaporation on air temperature and the thermal resistance of the waterproofing material of an oil tank on the concentration of oil sludge have been established.

Molecular dynamics simulation of deposition of high waxy crude oil on different pipeline walls

ABSTRACT Wax deposition occurs in the process of waxy crude oil pipeline transportation, which seriously affects the normal operation of crude oil pipeline. At present, non-metallic pipes have been proved to be effective in delaying the occurrence of wax deposition. Therefore, based on the pipeline walls of 20 G steel, glass fiber reinforced plastic (FRP), and polyethylene (PE), the microscopic mechanism of wax deposition during the pipeline transportation of waxy crude oil was studied by molecular dynamics simulation. The simulation results show that the waxy crude oil clusters undergo diffusion, deposition, reverse diffusion processes, and finally a wax deposition layer is formed on the pipeline surface. On the pipe walls of different materials, the surface free energy affects the interface energy of the solid-liquid contact surface between the waxy crude oil and the pipe wall, which is the main factor for the low surface free energy pipe to have the anti-wax effect. At the same time, according to the analysis of the contact angle on different materials in the simulation results, the difference in pipeline materials can only delay the formation speed of the wax deposition layer and cannot completely prevent the occurrence of wax deposition..