Oil Suspension Research Articles

Increasing performance efficiency of reconstructed oil fields

In the oil-gathering stations of most OGPDs, oil water sand clay mixtures that enter the settling equipment after passing through the separators are initially separated and collected in appropriate tanks. Prior to the production of commercial oil, more labor and energy is utilized to separate water and sand-clay mixtures from oil. Tanks are quickly contaminated with bottom sediments consisting of sand-clay and cleaning of them is difficult. Mixtures of sand-clay-water from settler, formation water from oil tanksa are drained into open oil traps, as a result, the environment is polluted with oil wastes and oil losses occur. It is more efficient to use a horizontal oil and gas separator to overcome shortcomings identified in the reconstruction of the tank farm with a capacity of more than 1.500 m3/day. Sand-clay separator should be installed at the inlet of it to protect the separator and tanks from sand-clay mixed sediments. Sand-clay separators should be installed inside the overflow tanks for better separation of formation water and sand-clay mixtures from oil, oil suspensions and sand-clay mixtures from water in formation water storage tanks. In order to reduce evaporation losses in the tanks, an auxiliary palte should be used under the PSV and the gas phase of the technological tanks and commercial oil tanks should be connected via pipes.

Magnetic Resonance Imaging of Multi‐Phase Lava Flow Analogs: Velocity and Rheology

AbstractThe rheology of lavas and magmas exerts a strong control on the dynamics and hazards posed by volcanic eruptions. Magmas and lavas are complex mixtures of silicate melt, suspended crystals, and gas bubbles. To improve the understanding of the dynamics and effective rheology of magmas and lavas, we performed dam‐break flow experiments using suspensions of silicone oil, sesame seeds, and N2O bubbles. Experiments were run inside a magnetic resonance imaging (MRI) scanner to provide imaging of the flow interior. We varied the volume fraction of sesame seeds between 0 and 0.48, and of bubbles between 0 and 0.21. MRI phase‐contrast velocimetry was used to measure liquid velocity. We fit an effective viscosity to the velocity data by approximating the stress using lubrication theory and the imaged shape of the free surface. In experiments with both particles and bubbles (three‐phase suspensions), we observed shear banding in which particle‐poor regions deform with a lower effective viscosity and dominate flow propagation speed. Our observations demonstrate the importance of considering variations in phase distributions within magmatic fluids and their implications on the dynamics of volcanic eruptions.

Investigation of rheological properties of composite suspension fuels

THE PURPOSE. The features of the rheological behavior of composite fuel oil suspensions depending on the shear rate, temperature and composition of the composite fuel are considered.METHODS. Suspensions with a coal content of 30, 40 and 50% (by weight) were prepared. The mixing time varied from 1 to 10 minutes. The samples of fuel oil were examined using a Rheomat RM 100 rotary viscometer to determine the values of dynamic viscosity at different shear rates and temperature.RESULTS. The results of experimental studies of the dynamic viscosity of fuel oil as a function of the shear rate and temperature are obtained. The best values of coal dust content in fuel oil suspensions for fuel transportation have been determined.CONCLUSION. The obtained research results can be used by both energy companies and transport companies to determine the technological viscosity indicators of composite suspension fuels used as boiler fuel and fuel for marine engines.

Bioactivity, Uptake, and Distribution of Prothioconazole Loaded on Fluorescent Double-Hollow Shelled Mesoporous Silica in Soybean Plants.

Prothioconazole (PTC) has been widely utilized for plant fungal disease control, but its metabolite prothioconazole-desthio (PTC-d) exhibits reproductive toxicity. In the present study, carbon quantum dot (CQD)-modified fluorescent double-hollow shelled mesoporous silica nanoparticles (FL-MSNs) loaded with PTC, referred to as PTC@FL-MSNs, were constructed with an average size of 369 nm and a loading capacity of 28.1 wt %, which could increase the antifungal efficiency of PTC. In addition, upright fluorescence microscope and UPLC-MS/MS studies showed that PTC@FL-MSNs could be effectively transported via root uptake and foliar spray in soybean plants. Compared to a 30% PTC dispersible oil suspension agent, the PTC@FL-MSN treatment group showed higher concentrations (leaves: 0.50 > 0.48 mg/kg), longer half-lives for degradation (leaves: 3.62 > 3.21 d; roots: 3.39 > 2.82 d), and fewer metabolites. These findings suggest that sustained pesticide release and toxicity reduction are potential applications for PTC nanofungicide delivery technology.

Chloroplast/thylakoid-rich material: A possible alternative to the chemically synthesised flow enhancer polyglycerol polyricinoleate in oil-based systems

Chloroplasts are abundant organelles in a diverse range of plant materials; they are predominantly composed of multicomponent thylakoid membranes which are lipid and protein rich. Intact or unravelled thylakoid membranes should, in principle, have interfacial activity, but little has been published on their activity in oil-in-water systems, and nothing on their performance on an oil continuous system. In this work different physical methods were used to produce a range of chloroplast/thylakoid suspensions with varying degrees of membrane integrity. Transmission electron microscopy revealed that pressure homogenisation led to the greatest extent of membrane and organelle disruption compared to less energy intensive preparation methods The ability of the derived materials to modulate the flow behaviour of a chocolate model system (65% (w/w) sugar/ sunflower oil (natural amphiphiles removed) suspension) was investigated by acquiring rheological parameters. All chloroplast/thylakoid preparations reduced yield stress, apparent viscosity, tangent flow point and cross over point in a concentration-dependent fashion, although not as significantly as polyglycerol polyricinoleate applied at a commercially relevant concentration in the same chocolate model system. Confocal laser scanning microscopy confirmed presence of the alternative flow enhancer material at the sugar surfaces. This research reveals that low-energy processing methods that do not extensively disrupt thylakoid membranes are applicable to generating materials with marked capacity to affect the flow behaviour of a chocolate model system. In conclusion, chloroplast/thylakoid materials hold strong potential as natural alternatives to synthetic rheology modifiers for lipid-based systems such as PGPR.

Causes and treatment of adhesive damage in polymer flooding injection pipeline

The viscosity of polymer liquid is an important parameter used in oilfield. Understanding the loss rule and regularity of polymer liquid will help to improve the distribution and water injection quality of polymer liquid and ensure the effective distribution of polymer liquid. According to the oil-water viscosity data of the previous polymer flooding fluid, it is found that the oil-water viscosity is within the range of 5%-20%, with an average of 9.8%. The reasons of single well pipeline viscosity are complex and varied, which are closely related to reducing substances, types and quantities of bacteria, fouling oil suspensions on the inner wall of pipeline, pipeline length and running time. Therefore, from the aspects of Fe2+, pipeline running time and so on, the influence factors and prevention methods of single well pipeline viscosity loss were studied, and the corresponding treatment measures were worked out, and good results were obtained.

Electrorheological and dielectric analysis of self-crosslinked poly(ionic liquid)s with different flexible chain spacer

Three kinds of self-crosslinked poly(ionic liquid)s (S-PILs) with different flexible chain spacers, namely P[B2V][TFSI], P[C8DVIM][TFSI] and P[TEGDVIM][TFSI], were prepared. The influence of flexible chain spacer on electrorheological (ER) effect of S-PIL suspension in silicone oil under electric fields was studied by rheological method and dielectric spectroscopy. It is found that as the flexibility of chain spacer increases, the ER effect increases. However, the dielectric spectrum shows that the variation of ER effect is not completely consistent with that of interfacial polarization but is related to the competition between interfacial polarization induced by ion motion and electrode polarization formed by ion leakage. By combining wide-angle X-ray scattering spectra and ion activation energy analysis, we further clarify that the reason for the inconsistence of dielectric property and ER effect is not only related to the flexibility of chain spacer but also related to the interaction between oxygen on chain spacer and counter-anions in the S-PILs. The result provides an insight for the molecular design of S-PIL ER materials.

Insights on macro- and microscopic interactions between Confidor and cyclodextrin-based nanosponges

Imidacloprid is one of the most widely used soluble neonicotinoid insecticide, which is non–volatile and persists in the soil, with hazardous effects on birds, honeybees, and mammals. It is used in both agricultural and veterinary applications, and is found in at least 7% of European topsoils. One of the commercially available formulations is Confidor O–TEQ® that exhibits higher retention, spreading, and penetration capacity being in form of an oil suspension. In this work, porous materials based on cyclodextrin nanosponges (CDNSs) were developed for the efficient removal of imidacloprid. In the synthesis of CDNSs, α– and β–cyclodextrin and two diamine monomers, hexane–1,6–diamine (HDA) and dodecane–1,12–diamine (DDA) were used. It was found that linkers with longer aliphatic chains resulted in CDNSs with higher thermal stability and crosslinking degree. αCD2–HDA and βCD2–HDA showed superior sorption efficiency for Confidor O–TEQ®, as evaluated by kinetic and equilibrium sorption analyses at optimal conditions. To better understand the effects of monomer chain length and type of cyclodextrin, the sorption performance of αCD and βCD, αCD–HDA and βCD–HDA, αCD–DDA and βCD–DDA, dimeric αCD2–HDA and βCD2–HDA, and αCD2–DDA and βCD2–DDA with imidacloprid was also investigated by atomistic molecular dynamics simulations. Relevant contact patterns based on the identification of the stabilizing/destabilizing noncovalent interactions within the CD-based complexes were described in detail. Results suggest that significant modulation of the sorption performance of CDNSs for imidacloprid can be achieved by imposing various features, with direct implications for the rational design of supramolecular materials with high sorption capacity for pesticides.

Study of multilayer flow of a bi-viscous Bingham fluid sandwiched between hybrid nanofluid in a vertical slab with nonlinear Boussinesq approximation

Bi-viscosity Bingham plastic fluids are used to understand the rheological characteristics of pigment–oil suspensions, polymeric gels, emulsions, heavy oil, etc. In many industrial and engineering problems involving high-temperature situation, a linear density-temperature variation is inadequate to describe the convective heat transport. Therefore, the characteristics of the nonlinear convective flow of a bi-viscous Bingham fluid (BVBF) through three layers in a vertical slab are studied. The two outer layers of the oil-based hybrid nanofluid and the intermediate layer of BVBF are considered. The thermal buoyancy force is governed by the nonlinear Boussinesq approximation. Continuity of heat flux, velocity, shear stress, and temperature are imposed on the interfaces. The governing equations are derived from the Navier–Stokes equation, conservation of energy, and conservation of mass for three layers. The nonlinear multi-point (four-point) boundary value problem is solved using the differential transform method (DTM). Converging DTM solutions are obtained, and they are validated. The entropy equation and Bejan number were also derived and analyzed. It is established that the nonlinear density–temperature variation leads to a significant improvement in the magnitude of the velocity and temperature profiles due to the increased buoyancy force, and as a result, the drag force on the walls gets reduced. The drag force on the slab gets reduced by decreasing the volume fraction of nanoparticles. Furthermore, nonlinear convection and mixed convection give rise to an advanced rate of heat transport on the walls and thereby to an enhanced heat transport situation.

Effect of Dispersion Medium on Pharmacokinetic Profile of Rotigotine Crystalline Suspension following Subcutaneous Injection.

Rotigotine (RTG) is prescribed as a once-daily transdermal patch for managing early Parkinson’s disease (PD), which presents issues such as skin irritation and poor patient adherence. Therefore, the aims of the present study were to formulate aqueous and oily vehicle-based RTG crystalline suspensions for prolonged delivery and to compare their pharmacokinetic profiles and the local behaviors of RTG crystals. RTG-loaded aqueous (AS) and oil suspensions (OS) were fabricated using bead-milling technology (100 mg/mL as RTG), employing carboxymethyl cellulose and sesame oil as suspending agent and oily vehicle, respectively. RTG AS and OS exhibited comparable physical properties in terms of particle size (about 800−900 nm), crystallinity, and dissolution profile, despite higher drug solubility in OS than AS (19.6 and 0.07 mg/mL, respectively). However, AS and OS exhibited markedly distinctive local distribution and inflammatory responses at the injection site, which further promoted different pharmacokinetic patterns following subcutaneous injection in rats. With OS, no drug aggregates were observed with prolonged persistence of the Sudan III-stained oily vehicle at the injection site. In contrast, with AS injection, drug clusters > 7 mm were formed, followed by an enclosure with macrophages and a fibroblastic band. Accordingly, AS exhibited a protracted pharmacokinetic profile over 3 weeks, with prolonged elimination half-life. The local inflammatory response caused by AS injection was almost alleviated after 3 weeks post-dosing. Based on these findings, we conclude that RTG AS system can be a platform to design sophisticated long-acting delivery systems with extended dosing intervals to manage PD.

Physical Interpretation of Nanofluid (Copper Oxide and Silver) with Slip and Mixed Convection Effects: Applications of Fractional Derivatives

A fractional model was developed for presenting the thermal assessment of nanoparticles in an inclined moving surface. Water was used as a base fluid, while the nanofluid utilized copper oxide and silver nanoparticles. The modification of the thermal model was further supported by mixed convection, magnetic force, and porous saturated space. Slip effects to the porous surface were also introduced. The fluctuation in temperature at different times was assumed by following the ramped thermal constraints. The fractional computations for the set of flow problems were performed with implementations of the Atangana–Baleanu (AB) and Caputo–Fabrizio (CF) analytical techniques. The integration process for such computations was achieved using the Laplace transformation. The comparative velocity and thermal analysis for the water and kerosene-oil-based nanofluid model is presented. The declining change in the velocity was observed due to the increase in the volume fraction of nanoparticles. It was observed that the increment in the temperature profile was more progressive for the kerosene oil and silver nanoparticle suspension.

Synthesis and study of new nonionic polyether water clarifier for oily wastewater

AbstractIn order to solve the problem of oily wastewater treatment in Shengli Oilfield, tert‐butyl phenol (TP) series nonionic polyether water clarifiers were synthesized by polymerization with p‐tert‐butyl phenol (PTBP) as the initiator. The water clarifiers were characterized by Fourier‐transform infrared spectroscopy (FT‐IR) and the interfacial tension test was carried out. The TP series of water clarifiers effect were evaluated by the oil content and suspension content in the clean water experiments. In addition, the effects of dosage and temperature on the water effect were discussed through the control variable method. The experimental results showed that the oil removal rate of TP6 can reach 95% and the suspension removal rate can reach 92% when the dosage of water clarifier was 40 mg/L, the cleaning water temperature was 55°C, and the cleaning water time was 30 min. The oily wastewater colour after cleaning was clear and transparent with the TP series of water clarifiers, and the effect was better than with commercial water clarifiers.

Preparation and performance evaluation of oil-tolerant and easy-wetting viscoelastic system for enhancing the stability of highly viscous oil-water lubricated flow

Based on the free sliding phenomenon of the monopterus albus in the cave, an oil-tolerant and easy-wetting viscoelastic system (A3B4C3E5F2) was selected and compounded as a possible lubricant to enable the transportation of heavy crude oil. In the viscoelastic system, the final floating equilibrium velocity of LD1 crude oil droplets with a diameter of about 5 mm is 0.01853 mm/s, and the floating resistance coefficient (C D) is 11067862, which shows favorable oil suspension performance. When the shear rate is approximately zero, the viscosity of the viscoelastic system is about 7000 mPa·s. However, when the shear rate is up to100 1/s, the viscosity is only about 32 mPa·s. A high viscoelastic film is formed at shutdown or low flow rates. Conversely, a low viscosity liquid ring formed at high flow rate. After being wet by easy-wetting viscoelastic system, the contact angle between LD1 crude oil and common pipe materials is wider than 160° at 30 min. The incubation time (t 0) and the wettability composite index (WCI) are shorter than 1800 s and higher than 4800, respectively. Upon stability evaluation, the system can maintain good viscoelasticity and wettability in the range of temperature (5 ∼ 90 °C), oil content (0 ∼ 15 wt.%), and shear rate (0 ∼ 1000 1/s), respectively.

New insights on carbon black suspension rheology—Anisotropic thixotropy and antithixotropy

We report a detailed experimental study of peculiar thixotropic dynamics of carbon black (CB, Vulcan XC-72) suspensions in mineral oil, specifically the observation of sequential stress increase then decrease at a fixed shear rate in a step-down test. We verify that such dynamics, though peculiar, come from a true material response rather than experimental artifacts. We also reveal how this long-time stress decay is associated with antithixotropic structural change rather than viscoelastic stress relaxation by using orthogonal superposition (OSP) rheometry to probe viscoelastic moduli during the step-down tests. The orthogonal storage and loss moduli are present, showing this two-timescale recovery then decay response, which demonstrates that this response is antithixotropic, and it involves shear-induced structuring. We further show a mechanical anisotropy in the CB suspension under shear using OSP. Based on the rheological results, a microstructural schematic is proposed, considering qualitatively thixotropic structure build-up, antithixotropic densification, and anisotropic structure evolution. Our observation for these CB suspensions is outside the standard paradigm of thixotropic structure-parameter models, and the elastic response provides us with new insight into the transient dynamics of CB suspensions.

Characterization, stability, digestion and absorption of a nobiletin nanoemulsion using DHA-enriched phosphatidylcholine as an emulsifier in vivo and in vitro

The emulsification ability of phospholipids might be associated with fatty acid composition. However, there is no research regarding the emulsification ability of marine-derived phospholipids rich in docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA). The present study developed a nanoemulsion delivery system using DHA-enriched phosphatidylcholine as an emulsifier to deliver the poorly soluble ingredient nobiletin. The prepared nobiletin-loaded nanoemulsion was stable, with a small particle size of approximately 200 nm, a polydispersity index of 0.082, and a neutral zeta potential. The nobiletin-loaded nanoemulsion exhibited high lipolysis ability in in vitro experiments. Moreover, the nobiletin-encapsulated nanoemulsion was digested quickly and entered the serum faster than the oil suspension. There was a high distribution of nobiletin in organs such as the liver, brain, kidney, and spleen in the emulsion group after oral administration for 2 h. The findings provided a nanoemulsion delivery system to increase the bioavailability of nobiletin in vitro and in vivo.

Lipid based intramuscular long-acting injectables: Current state of the art

Long acting injectables (LAI) have received increased research and commercial interest due to their potential for improving treatment effectiveness and adherence for antipsychotic, antiviral and addiction treatments. A range of materials have been used to formulate LAI products, including lipids and polymers. Classic lipid-based LAI, such as oil solutions of antipsychotic drugs, have been widely prescribed to patients. Clinical evidence has shown significantly improved key therapeutic markers such as reduction of relapses in the case of schizophrenia patients. The commercial LAI products can be given either via subcutaneous or intramuscular injection. The main types of lipid-based LAI formulations include oil solutions, lipid-based nanoparticles and lipid based liquid crystal formulations, which are currently clinically available, and oil suspensions and oleogels and which currently have no commercial products available. This review will discuss all relevant aspects related to the development of lipid-based long acting injectables with a special focus on intramuscular (IM) injectables. It aims to provide useful guidance on effective future LAI product design and development. Lipid-based nanoformulations are not discussed in this review as they are thoroughly reviewed in literature elsewhere.

Entomopathogenic fungi associated with Stomoxys calcitrans in Slovakia and efficacy of local fungal strains against the stable fly

The stable fly, Stomoxys calcitrans, is the most important ectoparasite of livestock throughout the world. Entomopathogenic fungi are natural antagonists of stable flies with the potential to be used as biocontrol agents in integrated management programmes of this pest. The prevalence and species diversity of entomopathogenic fungi in populations of the stable fly were documented on a dairy cattle farm in south-western Slovakia. The prevalence of fungal infection was low and the maximum percentage of infected flies reached 2.72% during the season. Three Beauveria species were identified from infected flies, B. bassiana, B. pseudobassiana and B. brongniartii. Beauveria pseudobassiana and B. brongniartii are reported from S. calcitrans for the first time. In laboratory tests, the pathogenicity of four entomopathogenic fungi B. bassiana, B. pseudobassiana, M. anisopliae and Isaria fumosorosea against adult stable flies was compared. The flies were susceptible to infection by the fungi and the most virulent isolate of B. bassiana (IKEP10) was selected for spore formulation testing and field trials. We tested three types of spore formulations and the aqueous spore suspension was more effective against stable flies than spores formulated in the powder or oil suspension. Repeated treatments of the interior of the stable with B. bassiana spores at fortnightly intervals during June–August resulted in a 10 times higher prevalence of fungal infection in the stable fly population compared with the untreated stable, but the treatments did not effectively reduce the fly population. The selected B. bassiana isolate may represent an interesting tool in the biocontrol of stable fly populations, but further experiments are needed to design an appropriate formulation and enhance its efficacy.

Effect of pine essential oil and rotating magnetic field on antimicrobial performance

This work presents the results ofa study which concerns the influence of rotating magnetic field (RMF) on the antibacterial performance of commercial pine essential oil. A suspension of essential oil in saline solution and Escherichia coli were exposed to the rotating magnetic Afield (the frequency of electrical current supplied by a RMF generator f = 1–50 Hz; the averaged values of magnetic induction in the cross-section of the RMF generator B = 13.13 to − 19.92 mT, time of exposure t = 160 min, temperature of incubation 37 °C). The chemical composition of pine (Pinus sylvestris L.) essential oil was determined by gas chromatography coupled with mass spectrometry (GC–MS). The main constituents were α-pinene (28.58%), β-pinene (17.79%), δ-3-carene (14.17%) and limonene (11.58%). The present study indicates the exposition to the RMF, as compared to the unexposed controls causing an increase in the efficacy of antibacterial properties of pine oil. We have shown that rotating magnetic fields (RMF) at a frequency, f, between 25 Hz to and 50 Hz increased the antimicrobial efficiency of oil a concentration lower than 50%.

Sugar-sugar interactions in oil suspensions containing surfactants and effects on macroscopic phenomena

Surfactants are used in confectionery production to control the viscosity and yield value of molten chocolate. To develop a deeper understanding of the structure–function relationship of surfactants in food-related particle suspensions, the apparent viscosity, yield value, sedimentation, and particle interactions of 10 wt% confectioner’s sugar-in-canola oil suspensions were investigated in the presence of up to 1 wt% commercial soy lecithin, polyglycerol polyricinoleate (PGPR), citric acid esters of monoacylglycerols (CITREM) or ammonium phosphatides (AMP). Atomic force microscopy (AFM) was used to measure attractive forces at the nano-Newton scale between a sugar substrate and a sugar crystal-functionalized AFM cantilever in an oil environment. For all but PGPR, addition of surfactant reduced the adhesion force between sugar surfaces up to a critical concentration above which the force increased, implying the presence of additional interactions. This critical concentration was assumed to be when monolayer coverage of the sugar surfaces by surfactant occurred (0.05 wt% for lecithin, 0.10 wt% for CITREM and AMP). No critical concentration was found for PGPR, with its greatest effect for each analysis occurring at the highest concentrations tested (0.60 and 1.00 wt%). The significance of these interactions on macroscopic phenomena such as apparent viscosity and sedimentation was also assessed. Like with the AFM data, there was an optimal concentration of added surfactant above which viscosity increased. Sedimentation rate greatly decreased with addition of PGPR while being only slightly affected by addition of lecithin, CITREM and AMP. An argument regarding their efficacy was made based on the relative sizes of the polar headgroup and nonpolar tail groups of the molecules, which contributed to how they adsorbed to the sugar surface. Overall, these results suggested that surfactant properties such as molecular weight and head group properties played an important role in modifying the interactions between sugar crystals in an oil-continuous environment.

The size effect of faceted detonation nanodiamond particles on electrorheological behavior of suspensions in mineral oil

Suspensions of hydrogenated detonation nanodiamond (DND) particles in mineral oil are electrorheological fluids: their viscosity and yield stress increase under an electric field. The effect of the initial DND particles size obtained during the explosion on the properties of low-filled (up to 4 wt%) electrorheological fluids was considered. The small-angle X-ray scattering method revealed the differences in the structural organization of DNDs with sizes of 3 and 5 nm in a mineral oil, which affects the sedimentation stability of suspensions and their electrorheological behavior. The sedimentation ratio and the values of the yield stress are lower for 3 nm particles suspensions in the whole studied electric field strength (0–6 kV/mm). The method of impedance dielectric spectroscopy showed the differences in the electrophysical characteristics of suspensions filled with particles of 3 and 5 nm. The activation energies of polarization processes were estimated from the temperature dependences of the dielectric loss modulus. The study shows the key role of filler size for creating high performance electrosensitive materials and hypothesizes the reasons for different properties of electrorheological fluids filled by 3 and 5 nm DND particles.