Oil Production Research Articles

Spatial Analysis of Regional Planning Related to Moratorium Right to Cultivate (Plantation) in Indonesia

Indonesia is a country that is blessed by Allah Swt with a very large expanse of space and territory and is located on the equator surrounded by the sea. This is a natural resource that is very rarely owned by other countries, where the sun shines every year with high humidity. These resources are controlled by the state and used as much as possible for the welfare of the community. One of the related natural resources is plants that can grow well in the area. Oil palm is a plant originating from West Africa that is very suitable for growing in the equatorial area. Currently, Indonesia is the largest producer of palm oil in the world. The greatest utilization of this blessing are for the welfare of the community and based on sustainable Regional Spatial Planning. On its implementation the Regional Spatial Planning has been divided according to its function and sustainability. This condition is contrary to the current government policy, where the government has implemented a moratorium policy on new business use rights for the Plantation sector. The regulation was Presidential Instruction (Inpres) Number 8 of 2018. The purpose of the Moratorium is to control the deforestation of Primary Forests and also improve the Governance of Oil Palm Plantations. In its implementation, there are indeed successes and weaknesses. Successes are mainly in holding back the rate of deforestation or forest encroachment. The weakness is that in terms of Regional Spatial Planning, there should still be many areas that can be used for developing plantation land, especially unproductive and non-forest areas. So that the ideals of improving the welfare of the community can be truly realized.

Chemical Fingerprinting, PAHs Characterization and Ecological Risks of Carcinogenic PAHs in Surficial Sediments of Egi Crude Oil Producing Communities, Niger-Delta, Nigeria

In order to do PAHs rings analysis, its source identification, extent to which cPAHs present and what kind of ecological risk they pose, the surface sediments from various freshwaters in the Egi crude oil producing cities in the Niger Delta, Nigeria were analyzed. Sediments collected from the research areas for PAHs loadings (in mg/kg dry weight) ranged from 0.020 to 1.790, 0.050 to 1.880, and 0.020 to 1.640, respectively for Obite, Obagi, and Ibewa cluster areas, as measured by gas chromatography-mass spectrometer. In these clusters, the respective average concentration of the three dominant carcinogenic PAHs were Indeno(1,2,3-cd)pyrene (1.170.0mg/kg), Dibenz[a,h]anthrancene (0.870.0 mg/kg), and Dibenz[a,h]anthrancene (1.3670 mg/kg) for Ibewa, Obagi and Obite cluster areas. The findings showed that dominant PAHs rings are of high molecular weight (HMW) PAHs in these sediments are, 5 member rings, which are benzo(b)fluoranthene, Benzo(k)fluoranthene, and Benzo(a)pyrène, and 6-member ring which are, Indeno(1,2,3-cd)pyrene, Dibenz[a,h]anthrancene, and Benzo[ghi] perylene, respectively. Their fingerprints points majorly to pyrogenic sources, combustion of coal, biomass, petroleum, and other related anthropogenic petroleum activities as the primary source of PAHs in the environment. Notably, the RQNCs and RQMPCs for single PAHs molecule are both less than 1, it means the contamination it generates is considered of low ecological risk. Again, the research area experiences frequent flooding, it is believed that this contributes to the low ecological risk of PAHs chemical pollution. Consequently, the area is deemed to be quite safe.

Oil and Gas Production, Treatment and Transportation 10th International Conference

Oil and Gas Production, Treatment and Transportation 10th International Conference

Effect of the Composition of the Mediterranean Diet on Body Mass Index, Waist Circumference, Fat Level, and Visceral Fat in Patients with Obesity

Excessive and unhealthy fat storage is known as obesity. Both monounsaturated and polyunsaturated fatty acids are highly encouraged in the Mediterranean diet. Obese patients at a Bandung clinic were studied to examine how the Mediterranean diet affects their BMI, waist size, fat percentage, and visceral fat. Analytical observational methods utilizing prospective cohort observations were employed. A systematic random sample technique was used to carry out the sampling. Participants were 34 overweight individuals who had twelve monthly food pattern assessments and two monthly examinations for body mass index (BMI), waist size, fat percentage, and visceral fat. To compare proportions between the rMED adherence groups and to look for differences in the composition of the Mediterranean diet on BMI, waist circumference, fat content, and visceral fat, we used the ANOVA test and Tuckey’s post-hoc test. In addition, the eight tenets of the Mediterranean diet were assessed using linear regression. The average age of the obese patients who followed the Mediterranean diet was 57.54 years, and 79.41% of them were female. It was found that the components of vegetables, fruits, nuts, seafood, and dairy products had a substantial impact on the body mass index of the participants, while the components of vegetables, fruits, nuts, legumes, seeds, meat, fish, olive oil, and dairy products did not have a significant impact on the waist circumference, fat content, or visceral fat. Keywords: body mass index, fat content Mediterranean diet composition, obesity, visceral fat, waist circumference

Geochemical fingerprinting and statistical variation of 35 elements in produced water and rock material from offshore chalk reservoirs

Trace metals and metalloids occur in small quantities in the subsurface water generated from oil wells, called produced water (PW). While these substances are present in low concentrations, PW volumes are sufficiently large that they are still a potential environmental concern. This study has focused on quantifying 71 trace metals and metalloids present in PW from Danish offshore oil production sites. These metals are often a challenge to measure and are globally underreported. By employing optimized sample treatment combined with ICP-OES and ICP-SFMS methods, the full elemental screening of PW samples collected from various offshore platforms has been carried out with high accuracy. Distinct geochemical signatures involving 35 elements have been discovered and they are associated with significant site-specific variations in the concentrations of key trace metals, including W, Ba, Mo, Cu, and Tl. Utilizing Principal Component Analysis (PCA), the study has effectively distinguished between PW samples from different fields, highlighting the relevance of certain trace metals and elemental ratios as potential geochemical markers. Geochemical analysis of the chalk rock material from the same production wells as the fluid samples has shown a correlation of key elements Tl, W, Cu, Mo, Ba, and As in the chalk with the produced water, potentially indicating the origin of the metals. The study has revealed a high compositional variability of PW and found that elements including Zn, Co, Hg, and Cs occur in concentrations of magnitude higher than previous estimates from reports. In addition, there is high variability in concentrations at different sampling times, underlining the need for environmental monitoring and developing more informed management strategies for the main offshore PW stream. The variability in concentrations in space and time leads to large uncertainties in environmental reporting based on a few samples. The detailed sampling campaign reported here for the first time highlights the need for much more frequent sampling, ideally continuous monitoring. The safety of produced water discharge to sea can be significantly underestimated by limited sampling. This paper provides the first field-specific and time varied screening of heavy metals in real produced water and shows the discrepancy in our understanding of the environmental impact of PW.

Development of a flow diagram for the production of asphalt concrete mixture using polyethylene waste, contaminated with oil products

Large quantities of low-pressure polyethylene containers used for transportation and storage of oil products (motor oils) entail higher environmental risks produced by their utilization or disposal. An urgent scientific task is to search for new ways for utilization of such containers, to involve them in production of new target products without thorough cleaning of waste from contaminants and residues of motor oils. The present study involved crushed containers used for storage and transportation of motor oil in order to explore the possibility of including polyethylene in the production of asphalt concrete mixture. A sample, containing 17.5% of low-pressure polyethylene (contaminated with motor oil by 8% of asphalt mass), and a control sample of asphalt concrete mixture free of polyethylene, were made in order to investigate the change of properties, occurring in the low-pressure polyethylene asphalt concrete. Results. The study assessed main physical and mechanical properties of asphalt concrete samples containing low-pressure polyethylene and motor oil. According to the assessment, a number of properties exceed the values stated in GOST 9128-2013. In addition, the study results included development of technological regulations for producing asphalt concrete mixture with polyethylene as well as the flow diagram for obtaining asphalt concrete mixture. Using polyethylene waste contaminated with motor oil in the production cycle of asphalt concrete mixtures will reduce the consumption of raw materials for asphalt concrete production and the negative impact on the environment.

Investigating concentrations and sources of polycyclic aromatic hydrocarbons in South and Central Texas bays and estuaries along the Gulf of Mexico, USA

Polycyclic aromatic hydrocarbons (PAHs) are among the most widespread organic contaminants in the environment, and anthropogenic activities can produce PAHs through a variety of pyrogenic or petrogenic means. Knowing the concentrations and sources of PAHs helps evaluate ecosystem health and manage natural resources. In this study, 16 US Environmental Protection Agency priority PAHs were analyzed in water and sediment samples collected from September 2021 to September 2023 in four bay systems along the south and central Texas coast, which are a hotpot of crude oil transportation in the United States. Our results indicated that the total concentration of PAHs ranged from 1.9 to 8.3 ng/mL in surface waters (< 0.5 m) and from 520 to 1257 ng/g in surface sediments (top 5 cm). Grain size analysis revealed that the sediment was dominated by silt (4 - 63 μm), followed by clay (< 4 μm) and sand (> 63 μm) fractions. Both organic carbon and clay content were shown to play a significant role in controlling the PAH content in sediments. Diagnostic ratios indicated that PAHs were primarily sourced via pyrolytic processes, such as the combustion of fossil fuels. Additional sampling at Port Bay, a shallow, secondary bay in the Mission-Aransas National Estuarine Research Reserve, implicated a strong role of resuspension in the distribution and composition of PAHs in the bay systems studied. Overall, these data offer insights into the concentration levels and sources of PAHs in this key region housing oil production and transportation in the United States.

Comparative analysis of transcriptome in oil biosynthesis between seeds and non-seed tissues of Symplocos paniculata fruit.

The Symplocos paniculata, a woody oil plant, has garnered attention for its oil-rich fruit, which exhibits potential for both oil production and ecological restoration endeavors, thereby presenting substantial developmental value. However, the comprehension of the distinctive oil biosynthesis and deposition strategies within the fruit's various compartments, coupled with the tissue-specific biosynthetic pathways yielding optimal fatty acid profiles, remains in its infancy. This investigation was designed to delineate the tissue specificity of oil biosynthetic disparities and to elucidate the molecular underpinnings within the fruit mesocarp and seeds of S. paniculata, employing lipidomic and transcriptomic analyses. The results revealed that oil biosynthesis within the fruit mesocarp commences approximately 40 days prior to that within the seeds, with a concomitant higher lipid content observed in the mesocarp, reaching 43% as opposed to 30% in the seeds. The fruit mesocarp was found to be enriched with palmitic acid (C16:0) and exhibited a harmonious ratio of saturated, monounsaturated, to polyunsaturated fatty acids (SFA: MUFA: PUFA=1:1:1), in stark contrast to the seed oil, which is predominantly composed of unsaturated fatty acids, accounting for 90% of its total FA content. Microstructural assessments have unveiled divergent oil deposition modalities; the fruit mesocarp oils are predominantly sequestered within oil cells (OC) and a spectrum of lipid droplets (LD), whereas the seeds predominantly harbor uniformly-sized LD. The expression patterns of pivotal genes implicated in oil biosynthesis were observed to be markedly contingent upon the tissue type and developmental stage. Notably, the light-responsive fatty acid synthase (FAS) gene demonstrated preferential transcription within the fruit mesocarp. In contrast, genes pivotal for carbon chain elongation, such as 3-ketoacyl-ACP synthase II (KASII) and fatty acyl-ACP thioesterase A (FATA), and desaturation, typified by Stearoyl-ACP desaturase (SAD) and Fatty Acid Desaturase (FAD), were noted to be more robustly transcribed within the seeds. Furthermore, isoenzyme gene families integral to the assembly of triacylglycerol (TAG), including long-chain acyl-CoA synthetases (LACSs), glycerol-3-phosphate acyltransferases (GPATs), and lysophosphatidic acid acyltransferases (LPATs), exhibited pronounced tissue specificity. This research endeavors to clarify the molecular regulatory mechanisms that oversee oil biosynthesis within both seed and non-seed tissues of oilseed-bearing plants with entire fruits. Collectively, these findings lay the groundwork and offer technical scaffolding for future targeted cultivation of woody oil plants, with the ultimate aim of augmenting fruit oil yield and refining FA compositions.

Fluorescence visualization dynamics of carbonated water injection processes in homogeneous glass micromodels

Understanding the flow behavior of oil–water phases in porous media is crucial for revealing the kinetic mechanisms underlying oil–water movement. In this study, we designed and constructed a fluorescence visualization experimental platform for carbonated water injection (CWI). We evaluated the effects of nine distinct injection rates on oil production and CO2 sequestration capabilities using three types of homogeneous porous structure micromodels. The microscale oil–water seepage behavior at the pore scale was also explored. The experimental results indicate that optimally increasing the injection rate can improve displacement efficiency, whereas excessively high rates may lead to viscous and capillary fingering. The geometry of the micromodels, particularly the hexagonal matrix, demonstrates potential advantages in enhancing oil displacement due to its uniform flow paths. The capillary number (Ca) significantly influences oil droplet capture behavior within micromodels. For instance, micromodel A captures the largest ganglion area at low Ca values, with a noticeable reduction in average ganglion area as Ca increases. Conversely, micromodels B and C exhibit similar trends in ganglion size variation at high Ca values, suggesting a more uniform impact of pore structure on oil droplet capture behavior. At elevated Ca values, capillary forces exert a more uniform and controlled effect on oil droplet capture and release, minimizing size variability. Additionally, the injection rate plays a critical role in CO2 sequestration, with higher rates promoting convective mixing between CO2 and reservoir fluids, thereby enhancing dissolution and storage efficiency. The complexity of the pore structure, characterized by the presence of micropores and macropores, affects the dissolution kinetics and mobility of CO2, influencing sequestration efficiency. These experimental findings provide valuable insights into the dynamics of oil–water motion and the potential for enhanced oil recovery (EOR) and CO2 storage, offering essential guidance for optimizing CWI strategies in the petroleum industry.

Enhanced oil recovery and carbon sequestration in low-permeability reservoirs: Comparative analysis of CO2 and oil-based CO2 foam

Excessive CO2 emissions contribute to global climate change thus mandating effective methods for CO2 utilization and sequestering. In this study, one-dimensional flow simulation experiments on CO2 flooding, CO2 Huff-n-Puff, oil-based CO2 foam flooding, and oil-based CO2 foam Huff-n-Puff are conducted using low-permeability sandstone cores modeled after the Q131 block in Liaohe Oilfield, characterized by porosity ranging from 15% to 20% and permeability between 25 mD to 35 mD. Low permeability reservoirs are rich in oil resources and may effectively sequester CO2. Parameters pertaining to oil and gas production and carbon storage are collected. Nuclear magnetic resonance (NMR) is employed to determine the spatial variation of oil saturation in the cores. The experimental results show 8.03% and 41.21% increase in oil recovery factor by foam flooding and foam Huff-n-Puff relative to CO2 as the recovery agent. Moreover, NMR analysis confirms lower residual oil saturation in core samples using foam, suggesting better displacement agent. Oil-based CO2 foam recovery contributed to effective carbon sequestration, with carbon storage increasing by 34.24% and 315% relative to CO2 flooding and CO2 Huff-n-Puff, respectively. CO2 storage mechanisms for oil-based CO2 foam recovery method are detailed.

Predicting scale thickness in three-phase flow using neutron activation analysis and deep learning

Calcium carbonate scales occur on the inner walls of the pipes used in oil and gas production, reducing the internal diameter and obstructing fluid flow. This study proposes a method for predicting of scale thickness using a neutron source and gamma radiation analysis with a deep neural network (DNN). The detection system includes a 241Am-Be neutron source and 72 detectors that count particles and record photons. A measurement setup was designed using the MCNP6 code to optimize the detection of scale thickness, utilizing a flat neutron source and strategically positioned detectors. The gamma-ray spectra generated from this setup were used as input data for the DNN to predict scale thickness within a three-phase water–gas-oil annular system. The results indicated that the DNN accurately predicted scale thickness with a mean relative error of 3.01 %, achieving a relative error below 5 % for 92.68 % of the dataset, demonstrating the potential for reliable real-time monitoring in industrial settings.

Determination of Oil Content and Fatty Acid Composition of Tea Plants at Plantations in the Black Sea Region

Aims: The aim of this study was to determine the fatty acid composition and oil content of C. sinensis seeds collected from different locations at the Northern Black Sea region. Study Design: The study based on the collection of tea seed samples from different locations at the the Northern Black Sea Region in Türkiye and comparing their fatty acid composition and oil content of analyzed samples. Place and Duration of Study: Recep Tayyip Erdogan University, Faculty of Agronomy, Field Crops Department, Rize, Türkiye, between 2022 and July 2023. Methodology: A total of 54 samples were taken within the scope of determining oil content and fatty acid composition of Camellia sinensis seeds collected from different locations. The location were choosen from different cities concerning altitude. The number of samples taken from the province of Rize is 37, the number of samples taken from the province of Trabzon is 7, the number of samples taken from the province of Giresun is 5, and the number of samples taken from the province of Artvin is 5. Fatty Acid composition was analyzed using GC-MS and oil content with an automated oil extraction device. Results: Oil ratio and fatty acid composition were determined in these samples. As stated in the literature, oleic acid, which is the criterion of vegetable oil quality, was found to be high in all samples. With Principal Component Analysis, the oil content and fatty acid composition data of the samples were used to reveal the differences in the samples. The obtained data will shed light on future studies. Conclusion: Knowing the fatty acid composition of tea oils will enable production of oils according to their intended use. For this purpose, it will be possible to produce oils suitable for the purpose by growing the desired types in suitable regions. We have to consider, that seeds were obtained after leaf harvest of tea plants. We can assume that the seed yield will increase if the tea plants are grown only for seed production. With governmental support tea seed oil production will be an potential additional income for local farmers.

ANALYSIS OF THE ECONOMIC PERFORMANCE OF PROJECT ADVANCED OIL RECOVERY WITH CO2 INJECTION (EOR/CCUS-CO2) THROUGH FINANCIAL INDICATORS: BRAZILIAN OVERVIEW

Enhanced Oil Recovery (EOR) is a method associated with Carbon Capture, Utilization, and Storage (CCUS) that consists of injecting CO2 into mature oil fields to store CO2 and enhance production. CO2-EOR projects are costly, requiring technical and economic evaluations to determine their viability. This research analyzes various economic parameters in CO2-EOR projects to develop a comprehensive model for assessing their economic viability in Brazil. The model was tested on projects developed by Silva et al. (2010) and included six scenarios of CO2-EOR in mature reservoirs. The results demonstrate the impact on well completion costs. The scenario with the highest oil production had one additional completion and, for this reason, did not show the best Net Present Value (NPV) result. This work also conducts a sensitivity analysis of parameters and reviews their impacts on NPV. Results indicate a significant impact of barrel price and minimum attractiveness rate on the NPV, while finding that the taxation of excess CO2 was not very significant. Low barrel prices (<$9) proved to be unfeasible with negative NPVs.

FOAM ASSISTED GAS LIFT (FAGL) TECHNIQUE: LABORATORY TESTS, FIELD APPLICATION, AND EVENTUAL EFFECTS ON CRUDE OIL PROCESSING

Even though the foam assisted gas-lift (FAGL) technology is not exactly a technical innovation, curiously, it has attracted the attention of the crude oil industry in recent years. Broadly speaking, the FAGL consists in either boosting the well’s crude oil flow rate while maintaining the same gas injection rate, or, conversely, it refers to maintaining the well´s crude oil production at a reduced gas injection rate. The application of the FAGL technology to a crude oil well is simple, just demanding the dosage of a tailored crude oil foamer surfactant (“crude oil foamer”) to the Gas Lift (GL) stream. Preliminary lab tests and the data recovered from the specialized literature together with the ones derived from the still sparse FAGL field applications have shown promising results. The FAGL´s underlying philosophy, its eventual interference on the topside crude oil processing, and some other pivotal FAGL-related questions are also addressed in this technical contribution.

Testing Pellets Fuel Production from Sewage Sludge of Palm Oil Industry

The wastes from the palm oil production process were used in this study, such as wastewater sludge and cake decenter or decanter waste. That moisture was less than 40% and increased density by the cold pelletizing process. The aim is to use pellet fuel for heating. Analysis of pellet fuel consists of physical properties, proximate (moisture, ash, volatile matter and fixed carbon) and heating value. The results showed that cake decenter and wastewater sludge had similar high volatile matter. The decenter cake had a higher heating value than the wastewater sludge at 26.649 and 14.965 MJ/kg, respectively. The ash of decenter cake was lower than wastewater at 11.71% and 22.34%, respectively. Blending both raw materials for pelletization increased the volatile matter that did not mix with another material. Therefore, both materials can be used to produce pellet fuel that has an optimal shape and size. That was hard to break. The results of chemical property testing show that it is within acceptable limits and can be used as pellet fuel.

Texture and surface morphology influence of A106 carbon steel pipe on mechanical properties and corrosion resistance after welding process

The surface morphology influenced the corrosion resistance, which depended on the welding process and its parameters. In this study, we investigated the relevance of the welding process that produces excellent mechanical properties and corrosion resistance, which gives the best working performance for carbon steel pipes that transfer refined oil products in an Iraq oil refinery. AISI 1020-A106 carbon steel pipes are welded using shielded metal arc welding (SMAW) and gas tungsten arc welding (GTAW). Electrochemical corrosion tests were performed in 3.5% NaCl and immersion tests in heavy Naphtha at 50, 75, and 100 °C. The results show that retained austenite, ferrite, pearlite, and martensite phases are produced after the SMAW process. In contrast, ferrite, pearlite, and a small amount of martensite are produced after GTAW. The ultimate tensile strength of the SMAW samples was higher than those of the GTAW samples, but the GTAW samples had higher fracture elongation, and all samples had no cracks in the welding area during the bending test. The electrochemical and immersion corrosion rates of the samples welded with SMAW are higher than those welded with GTAW. The corrosion rate increases when the naphtha temperature increases and has a higher and unacceptable value at 100 °C.

Investigation the Impact of Different Injection Agents on Tight Oil Reservoirs of Recovery Performance

Abstract Objectives/Scope: Due to strong water sensitivity and extremely low permeability, conventional water flooding method is not suitable for the Mahu Conglomerate reservoir. In response to the complex reservoir physical properties, different injection agents such as CO2, N2, water and air huff and puff injection were carried out in order to optimize injection parameters for enhanced oil recovery in tight conglomerate reservoirs. Methods, Procedures, Process: By means of NMR, scanning electron microscopy, energy spectrum, pore fluids state in different media after different agents displacement were studied. Displacement and CT testing on different media and post fracturing state were conducted. Through experiments on on-site cores from two different layers, three different injection media (H2O, N2, CO2 and air with different O2 concentration) were tested for enhanced oil recovery. Then, the injection process was performed under different injection pressures. Finally, multiple cycles of enhanced oil recovery tests were conducted corresponding optimal injection pressures. Results, Observations, Conclusions: The remaining oil in the pores is mainly in free and bound states, with a free state of approximately 58% and a bound state of approximately 42%. Four pressures were selected for this test based on the minimum miscibility pressure of CO2 with crude oil: 15MPa, 20MPa, 23MPa, and 25MPa. The recovery factor under different pressures is 6.44%, 8.14%, 10.31%, and 10.38%, respectively. As the huff and puff pressure increases, the recovery of CO2 huff and puff gradually increases, and the increase of recovery is insignificant when the mixture pressure is reached. The gas flooding process involves oil production from large and submicron pores first. As the displacement pressure difference increases, oil production from large pores decreases, with medium pores becoming the main force of oil production, while oil production from nanoscale micropores shows an increasing trend. The increase in oxygen content results in significant development of sub-micron micron scale pores. The gas breakthrough time is long, the capillary force decreases, and air can undergo low-temperature oxidation with crude oil, resulting in an overall oil displacement efficiency of 65.81%. Novel/Additive Information: At present, there is few research on the pore fluid flow and status of oil displacement in tight conglomerate reservoirs with different injection media. This study provides a good understanding of the submicron to nanoscale pore throat structure characteristics of tight oil reservoirs, revealing the state of pore fluids in gravel after displacement by different injection media, and providing support for on-site application of CO2 enhanced oil recovery in tight conglomerate oil reservoirs.

Enhancing Oil Recovery in Eagle Ford Shale: A Multiscale Simulation Study of Surfactant Huff ’n’ Puff Methodology

In this paper, we present a simulation case study of a surfactant huff ’n’ puff pilot in the black oil window of the Eagle Ford (EF) Shale. The target horizontal well, which had been depleted for nearly 8 years, underwent stimulation via a surfactant huff ’n’ puff treatment. The surfactant was selected through laboratory screening using reservoir rock and fluid samples. After a 17-hour injection and a 1-month shut-in period, the well’s production increased fivefold from the baseline oil rate, sustaining incremental oil production for at least 2 years. The surfactant enhances oil recovery by altering rock wettability toward a more water-wet state and moderating oil/water interfacial tension (IFT). This process is modeled by surfactant adsorption in the simulator, indicating the degree of dynamic changes in relative permeability (krl) and capillary pressure (Pc) curves. We propose a comprehensive workflow comprising three stages: development of core-scale and field-scale models, sequential model calibrations, and multiobjective optimization to integrate laboratory measurements and field data from this pilot into multiscale numerical simulations. By matching oil recoveries from imbibition experiments on the core model and field production histories on the field model, krl and Pc profiles of two extreme states, basic reservoir properties, and additional reservoir properties altered during huff ’n’ puff operations are characterized. The matched core model reproduces a 15.1% incremental oil recovery for surfactant-assisted spontaneous imbibition (SASI) process relative to pure brine imbibition process. The matched reservoir model predicts the surfactant huff ’n’ puff treatment increases the oil production by 21.9% relative to water huff ’n’ puff treatment and by 52.9% relative to primary depletion for a 4-year period. The calibrated reservoir model also serves as a base case for optimizing well operation schedules through the implementation of a multiobjective genetic algorithm. The surfactant injection rate, injection time, and well shut-in time of the base case are varied to achieve higher oil production and reduced surfactant usage. Statistical analysis of eight trade-off cases indicates that optimal well operations, compared with existing practices, frequently involve increased injection rates [16.6–18.9 barrels per minute (bpm)], shorter injection periods (10–11.3 hours), and prolonged shut-indurations (49–65 days). This workflow offers valuable insights into surfactant huff ’n’ puff treatments for unconventional reservoirs, thereby facilitating the optimization of well operations and maximizing tertiary oil recovery.

Case Study: Understanding H2S Occurrence: Bakken Production Using Sulfur Isotopes

_ Souring—or H2S generation—in the Bakken petroleum system (BPS) production is becoming problematic for oil producers and pipeline operators because of the sporadic occurrence and associated economic and HSE impacts. Paradoxically, crude oil produced from the tight Middle Bakken (MB) and underlying Three Forks (TF) reservoirs of the BPS has historically been light (40 °API to 50 °API) with low sulfur content (<0.2 wt.%), typically exhibiting nonexistent to low (<10 parts per million) H2S concentrations. Additionally, neither the MB nor the TF reservoirs have public records indicating the presence of H2S during drillstem tests (DST). However, based on previous work performed by the University of North Dakota Energy & Environmental Research Center (EERC), the frequency of H2S occurrence in BPS wells has increased from 2010 to 2023. Even though the observed H2S increases correlate with larger, multistage well stimulation and completion practices in the BPS, the unclear geographical and temporal trends make the exact mechanisms responsible for souring an open research question. At least five known mechanisms can potentially lead to H2S occurrence in the oil production stream of BPS wells, including: 1. Thermochemical sulfate reduction (TSR) 2. Bacterial sulfate reduction (BSR) 3. Source rock generation 4. Migration from deeper or shallower H2S reservoirs 5. Geochemical mechanisms related to reservoir stimulation work (Table 1). Understanding the mechanisms of H2S generation might reduce the risk of souring in new wells and enable more effective mitigation and management strategies in the wells already producing H2S. Samples Used in the Study This study is focused on oil and gas operations in the North Dakota portion of the Williston Basin and the H2S occurrences in the BPS, which includes two main oil-producing reservoirs: the MB and the TF. In the simplified stratigraphic sequence, the BPS comprises three distinctive lithofacies. From deepest to shallowest, those lithofacies are the Lower Bakken Shale (LBS), the MB reservoir, and the Upper Bakken Shale (UBS). Underlying the BPS is the TF, the upper part of which is the oil-rich TF reservoir, considered part of the BPS. The UBS and LBS are the source rocks for the oil in MB and TF reservoirs and consist of black, organic-rich, siliciclastic mudstones (i.e., shale). Directly overlying the BPS is the Madison Group, a carbonate-dominated Mississippian section that is subdivided into three formations—the Lodgepole (LP), Mission Canyon (MC), and Charles. The Birdbear Formation lies beneath the TF and on top of the Duperow Formation. Both the Duperow and Birdbear Formations produce oil and are dominated by carbonate deposits of shallow marine limestone and dolostones. A sampling program was developed to investigate areas of the BPS with varying levels of souring in the production stream and multiple organic-rich formations representing potential source rocks, including the UBS, LBS, LP, and MC. The samples were collected from locations and formations with different lithologies and maturity levels. Over 70 sour wells were identified for H2S sampling in western North Dakota.

Effect of pre-oxidation on the rate of formation of sulfur-containing aromatic compounds during vacuum gas oil thermal cracking

It was shown that oxidation followed by heat treatment is an effective method for desulfurization of vacuum gas oil. Patterns of changes in the quantitative content of the thiophene series compounds in liquid cracking products of vacuum gas oil and liquid cracking products of pre-oxidized vacuum gas oil are described. A mixture of hydrogen peroxide and formic acid (molar ratio 3:4) was used as the oxidation system. The hypothetical mechanism for the formation of thiophene, benzo- and dibenzothiophene and their homologues from high-molecular weight components of the initial vacuum gas oil and its oxidation products is proposed. Presumably, main path of formation considerate compounds is thermal decomposition of high-molecular weight sulfur-containing components. On the basis of IR spectroscopy and structure-group analysis data, the averaged structures of such components were constructed. The influence of pre-oxidation and its conditions on the value of the rate constants for the formation of thiophene, benzo- and dibenzothiophene and their homologues during thermal cracking of initial and oxidized vacuum gas oils is studied.