Oil Distribution Research Articles

Prediction Method for the Distribution of the Effective Dominant Path of Sand Bodies Transporting Oil and Gas and Its Application

To study the oil and gas distribution law in the slope area of a hydrocarbon-bearing basin, one must first define the dominant hydrocarbon transport paths of sand bodies as the superimposed area of the contiguously distributed area of the sand bodies and the paleotectonic ridges at the top interface of the formation. Then, the oil and gas supply area of the oil source faults must be defined, as the overlapped area of the favorable transport paths of oil source faults and the width of their associated fracture zones. Stacking the two areas, we can delineate the distribution of the effective dominant paths of sand bodies transporting oil and gas. The results from our case study of the Qinan area show that the effective dominant paths of sand bodies transporting oil and gas in the lower sub-member within the first member of the Shahejie Formation (Es1L) in the Qinan area are distributed throughout the region, with better development in the west than in the east. And, the effective dominant paths in the eastern part extend from north to south, while those in the western part extend from northeast to southwest. These are favorable for the convergence of oil and gas generated from source rocks in the third member of the Shahejie Formation (Es3) in the main depression of Qikou Sag in the Es1L in the Qinan area. The results are consistent with the fact that oil and gas discovered in the Es1L in the Qinan area are mainly distributed in the central and western regions, with a small amount in the southeast. Therefore, the suggested method is feasible for predicting the effective dominant paths of sand bodies transporting oil and gas.

Fats and oils contaminants: an analysis of EU RASFF notifications from 1999 to 2023

Between 1999 and 2023, an extensive analysis of 713 notifications from the EU Rapid Alert System for Food and Feed (RASFF) related to fats and oils was conducted. The analysis covered the most frequently reported products, associated hazards, countries of origin, notification classifications, risk decisions, and actions taken in response. The data demonstrate considerable variability in RASFF notifications throughout the studied period, with significant spikes and a recent upward trend. Of all notifications, 44.32 % were categorized as alerts, and 23.42 % as border rejections. In terms of risk decisions, 34.08 % were deemed serious and 60.59 % remained undecided. Palm oil emerged as the most frequently notified product, representing 37.87 % of all notifications, followed by olive oil at 15.71 % and sunflower oil at 11.36 %. The Sudan 4 dye was identified as the most common hazard, constituting 30.01 % of all fats and oils notifications. Other notable hazards included benzo(a)pyrene (26.65 %), glycidyl esters (6.03 %), and chlorpyrifos (3.37 %). The top three countries of origin for RASFF notifications on fats and oils were Ghana (22.30 %), Ukraine (13.18 %), and Italy (9.96 %). These findings could benefit further research and influence decision-making, thereby enhancing food safety protocols in the global production, processing, and distribution of fats and oils.

The Formation Mechanism of Residual Oil and Methods of Enhanced Oil Recovery in a Fractured Low-Permeability Metamorphic Rock Reservoir in Bohai Bay

The oil reservoirs of the metamorphic rocks in Bohai Bay have geological characteristics such as low matrix porosity and permeability, developed natural microfractures, which result in the injection water rapidly advancing along fractures, a fast increase in the water content, and difficulties in extracting the remaining oil. In order to reveal water channeling and the residual oil formation mechanisms in fractured low-permeability reservoirs and solve the water channeling problem, we first analyzed the reservoir development status, then studied the formation mechanism of residual oil using a microfluidic chip device, and formed a method of hierarchical control to effectively control the water channeling problem of fractured reservoirs and maximize the displacement of residual oil. The results show that (1) Due to the low permeability of the reservoir matrix, a large amount of injected water flows along the fracture channel, which leads to the long-term high water cut of some oil wells and the retention of a large amount of crude oil in the matrix. (2) The results of microfluidic experiments show that the distribution of residual oil after water flooding mainly includes five types: blind end of the pore throat, columnar, cluster, flake and film, and residual oil. Among them, sheet-like and clustered residual oil are dominant, accounting for 75~85% and 10~13%, respectively. (3) Based on the characteristics of fracture development in buried-hill reservoirs, a hierarchical control technology of “gel particle + liquid crosslinked gel system” is established. The field application effect predicted that the input–output ratio was 1:3. This study provides a reference for the comprehensive treatment of water channeling in the same type of offshore fractured low-permeability metamorphic rock reservoirs.

Strong effect of often-overlooked initial spilled oil distribution on subsequent soil remediation: A pore-scale perspective

The removal of spilled oil within soil by water injection is essentially an immiscible fluid displacement process. Numerous studies have been conducted to investigate the way to achieve a higher displacement efficiency. However, these studies often assumed that the pore space was initially saturated by oil only, ignoring the effect of initial oil distribution on the remediation, which led to incorrectly computed flow field and biased analysis. This work aimed to reveal the effect of initial oil distribution on flow physics during the remediation. Based on a pore-scale model and the phase-field method, the spilled oil invasion and remediation in a heterogeneous porous media were investigated, and the dynamic evolution of the phase interface was examined in particular. Four different distribution patterns of spilled oil were obtained through various velocities during the oil invasion stage, which were considered as initial states for the subsequent remediation stage. The results showed that ignoring the oil invasion process led to a more than 10% reduction in the ultimate remediation efficiency. However, the maximum interfacial area of fluids was larger and the obtained relative permeability curve was much smoother for the scenario considering the oil invasion. Besides, a higher initial water saturation led to a lower starting pressure. This work provided new pore-scale insights into the often-overlooked roles of initial phase distribution in fluid dynamics behind the remediation of oil-contaminated soil by water injection, which was of fundamental importance to the development of effective response strategy for soil contamination.

Integration of Geological Model and Numerical Simulation Technique to Characterize the Remaining Oil of Fractured Biogenic Limestone Reservoirs

AbstractFine geological modeling leads to accurate reservoirs numerical simulations. Fractured biogenic limestone has abundant storage spaces and flow paths to accumulate oil and gas. The complexity and diversity of fractured biogenic limestone also lead to challenges in accurately characterizing its pore volume and remaining oil. This investigation aimed to enhance the understanding of fractured biotite reservoir properties via geological modeling. Numerical simulations were used to characterize the remaining oil during the late stage of field development. Considering the differences in porosity and permeability between fractures and matrix, a facies-controlled stochastic modeling technique was used to establish a dual-porosity and dual-permeability (DPDP) model for numerical simulation. Core information, logging data, and multiple seismic attributes were combined to guide low-level sequence fault interpretation for tectonic refinement. Based on classified seismic inversion, sedimentary phases were reconstructed. A discrete fracture network (DFN) model was obtained based on fracture occurrences and density models. The optimized discrete adjoint (ODA) algorithm was utilized to calibrate model parameters. The findings revealed that dense tectonic fractures develop in thick biogenic limestone areas. Combined with advanced reservoir simulation technology, these findings suggest that areas of thicker biogenic limestone were consistent with areas of higher fracture matrix conductivity multipliers. The remaining oil distribution patterns were investigated, and to deploy new wells was guided. Therefore, it is essential to better understand the tectonic characteristics of fractured biogenic limestone reservoirs and their remaining oil distribution patterns by integrating multiple sources of information and mastering advanced reservoir simulation technology for oilfield development.

Chemical Composition, Enantiomeric Distribution, and Physical Properties of the Fruit Essential Oil from Zanthoxylum lepidopteriphilum (Reynel) Rutaceae from Ecuador

Chemical Composition, Enantiomeric Distribution, and Physical Properties of the Fruit Essential Oil from Zanthoxylum lepidopteriphilum (Reynel) Rutaceae from Ecuador

A straight-forward fabrication of yuba films with controllable mechanical properties by oil-in-water emulsion model system rather than soymilk

The traditional process of producing yuba films from soybeans strictly limits the development of its industrial production due to the numerous processes and intricate procedures involved. In this study, a straight-forward and effective strategy was proposed to substitute soymilk with an emulsion made from soybean protein isolate and soybean oil for the formation of yuba films. It was found that the mechanical properties of yuba films formed through this method were controlled by the concentrations of proteins and oils. As the protein concentrations increased, a higher ratio of adsorbed proteins adhered to the surface of oil droplets, which in turn facilitated the recombination of proteins and the formation of larger aggregates during heat incubation. The rheological properties and interfacial adsorption behavior suggested that larger protein aggregates exhibited a greater diffusion rate and were more prone to unfolding and re-crosslinking at the interface through heat induction, resulting in the formation of stronger protein networks. Confocal laser scanning microscope images revealed a notable increase in the density of oil distribution within the yuba films as the oil concentrations in the pre-emulsion rose. Combined with the dense protein network formed at high protein concentrations, the elongation of yuba films was significantly increased.

LARGE-SCALE LANDSLIDES DUE TO SALINE WATER PLUME INTRUSION - AN EXAMPLE OF THE OKIMI LANDSLIDE IN NIIGATA PREFECTURE, JAPAN

Large-scale landslides with volumes ranging from tens to hundreds of millions of m3 are scattered throughout Niigata Prefecture, Japan. There is no accepted theory, although many researchers have argued about the mechanism of these landslides. Highly concentrated Na-Cl type groundwater (hereafter called "saline water") has often been found in large-scale landslides in Niigata Prefecture. In addition, the observation wells where saline water occurs are sometimes flowing wells. We also pay special attention to the distribution of landslide-prone areas and oil and gas fields in Niigata Prefecture, which generally overlap, and saline water from landslides is originally fossil seawater such as oil-brine based on geochemical characteristics. On the other hand, anomalous high-pressure reservoirs at depths of more than 1,000 m in oil and gas fields have been known since the 1960s and are possible saline water sources. We believe saline water's behavior is key to better understanding the mechanism of large-scale landslides. The Okimi landslide, this research area, is located in the Kamiya area, Joetsu City, western part of Niigata Prefecture, Japan. The aspect of the active body is about 500 m wide and 1,500 m long, with an area of about 70 ha. The bedrock geology is mainly Neogene unconsolidated mudstone. According to previous studies, saline water has been detected in observation wells at the head of this landslide. Since the geological formation containing saline water has a considerably low resistivity value (≤ 2.0 Ωm), the CSMT method is best suited for electromagnetic exploration to visualize the resistivity up to 1,000 m depth. The survey results confirm the existence of a saline water plume rising from a "saline water chamber" located 100 to 300 m below the western side of this landslide to the bottom of this landslide (at a depth of about 30 m). The presence of the saline water plume suggests that the upwelling of saline water from the anomalous high-pressure reservoir (saline water chamber) is closely related to several large-scale landslides.

Analysis of spatial structure and singularity of microbial biogeochemical anomalies in the Taiwan Strait Basin

The abundance of specific hydrocarbon-oxidizing bacteria (MV value) in surface soil is closely linked to the concentration of thermogenic light hydrocarbons found in the underlying layers. The identification of these bacteria using specific detection techniques offers unique insights into microbiological anomalies associated with oil and gas, underscoring the significance of delineating microbiological geochemical anomalies in the exploration process. Accurate determination of the anomaly range is crucial for forecasting potential oil and gas reservoirs. In this study, a variety of fractal and geological statistical methods were employed to analyze microbiological geochemical data from the Taiwan Strait Basin. The multifractal approach allows for the simultaneous assessment of spatial autocorrelation and singularity in geochemical fields, with the fractal distribution reflecting the localized enrichment and depletion patterns of microbiological geochemical elements in rocks and other substrates. Geological statistical methods, such as the variation function, enable the assessment of spatial autocorrelation in geochemical and geophysical fields. The results indicate that microbiological anomalies in the Jiulongjiang Depression are mainly concentrated in the southwestern part of the study area, with some anomalies also observed in the central region. Conversely, microbiological anomalies in the Jinjiang Depression are predominantly located in the southern portion of the study area. Microbiological anomalies in the study area (Jinjiang Depression and Jiulongjiang Depression) exhibit a northeast-southwest strip distribution, aligning with the trend of the depressions and faults, suggesting that faults could influence the distribution of oil and gas resources in the region. Based on microbiological statistical analyses, the Jiulongjiang Depression shows better potential for oil and gas prospects compared to the Jinjiang Depression, guiding future research efforts in the Jiulongjiang Depression.

Experimental investigation on the oil occurrence and mobility of lacustrine shales in offshore area of China using 1D/2D nuclear magnetic resonance and centrifugal techniques

Shale oil occurrence mechanism and mobility have significant influences on hydrocarbons extraction from shale systems. However, the effects of petrophysical and petroleum geochemical properties on oil mobility are not understood. In this study, shales with different lithofacies were investigated using thin sections, scanning electron microscopy, nuclear magnetic resonance (NMR), and organic geochemical analysis. Shales at original, extracted, oil-saturated, and centrifugal states were systematically scanned using 1D and 2D NMR technologies. The multi-scaled pores were obtained by comparing the T2 spectra of samples at different states. The 2D NMR identification spectra for hydrocarbon-bearing components were established. The free oil, adsorbed oil, mobile oil contents were quantitatively evaluated and the geological controls on oil mobility were discussed.Results show that the siliceous shales have the highest total oil and movable oil contents, while the argillaceous shales have the lowest values due to the limited pore space and poor connectivity. Mobile oil mainly stores in interparticle pores, dissolution-related pores and bedding fractures. Its content increases with the increasing felsic minerals. Oil in siliceous shales are rich in low carbon-chain hydrocarbons and has high mobility. Based on oil distribution in multi-scaled pores, a strategy about the mobile oil distribution were proposed: Ultramicropores region is the immobile oil zone; Micropores region is the oil difficult-to-flow zone; Transition pores region is the oil easy-to-flow zone; Macropores region is the completely mobile oil zone. The mobile oil mainly accommodates in transition pores and macropores (pore size >20 nm and mobile oil saturation exceeds 60 %).

Examining a Conservative Phase-Field Lattice Boltzmann Model for Two-Phase Flows

In this study, a conservative phase-field lattice Boltzmann model is examined for simulating immiscible two-phase flows with large density and viscosity ratios. This model is built upon the Allen–Cahn equation, incorporating a filtered collision operator and high-order corrections in the equilibrium distribution functions. The numerical model is also integrated with the volumetric boundary scheme and the immersed boundary method to achieve various stationary and moving boundary conditions on arbitrary geometries for different application scenarios. A comprehensive evaluation of this phase-field solver is conducted through a range of academic and industrial cases. First, droplet splashing cases at different Reynolds numbers are studied. The phase-field LB model effectively captures the surface wave motion and splashing of the droplet, although some smearing of small structures is observed due to the diffused interface property of the numerical model. Second, a tuned liquid damper is simulated, accurately capturing sloshing forces on solid walls. In the simulation of a dam-breaking case, predicted gauge pressure and free-surface elevation time histories compare well with experimental data. Lastly, a gearbox case under dip lubrication is simulated, with both the gearbox churning loss and oil distribution being well predicted across a range of rotating speeds. The validation studies demonstrate the effectiveness of the present phase-field lattice Boltzmann model in simulating immiscible two-phase flows with large and realistic density and viscosity ratios. The strengths, limitations, and weaknesses of the conservative phase-field LB model are discussed, and suggestions for the development and application of this numerical model are provided.

Characteristics and hydrocarbon accumulation model of Paleogene whole petroleum system in western depression of Qaidam Basin, NW China

Based on the oil and gas exploration in western depression of the Qaidam Basin, NW China, combined with the geochemical, seismic, logging and drilling data, the basic geological conditions, oil and gas distribution characteristics, reservoir-forming dynamics, and hydrocarbon accumulation model of the Paleogene whole petroleum system (WPS) in the western depression of the Qaidam Basin are systematically studied. A globally unique ultra-thick mountain-style WPS is found in the western depression of the Qaidam Basin. Around the source rocks of the upper member of the Paleogene Lower Ganchaigou Formation, the structural reservoir, lithological reservoir, shale oil and shale gas are laterally distributed in an orderly manner and vertically overlapped from the edge to the central part of the lake basin. The Paleogene WPS in the western depression of the Qaidam Basin is believed unique in three aspects. First, the source rocks with low organic matter abundance are characterized by low carbon and rich hydrogen, showing a strong hydrocarbon generating capacity per unit mass of organic carbon. Second, the saline lake basinal deposits are ultra-thick, with mixed deposits dominating the center of the depression, and strong vertical and lateral heterogeneity of lithofacies and storage spaces. Third, the strong transformation induced by strike-slip compression during the Himalayan resulted in the heterogeneous enrichment of oil and gas in the mountain-style WPS. As a result of the coordinated evolution of source-reservoir-caprock assemblage and conducting system, the Paleogene WPS has the characteristics of “whole process” hydrocarbon generation of source rocks which are low-carbon and hydrogen-rich, “whole depression” ultra-thick reservoir sedimentation, “all direction” hydrocarbon adjustment by strike-slip compressional fault, and “whole succession” distribution of conventional and unconventional oil and gas. Due to the severe Himalayan tectonic movement, the western depression of the Qaidam Basin evolved from depression to uplift. Shale oil is widely distributed in the central lacustrine basin. In the sedimentary system deeper than 2 000 m, oil and gas are continuous in the laminated limy-dolomites within the source rocks and the alga limestones neighboring the source kitchen, with intercrystalline pores, lamina fractures in dolomites and fault-dissolution bodies serving as the effective storage space. All these findings are helpful to supplement and expand the WPS theory in the continental lake basins in China, and provide theoretical guidance and technical support for oil and gas exploration in the Qaidam Basin.

Evaluation of source rocks and prediction of oil and gas resources distribution in Baiyun Sag, Pearl River Mouth Basin, China

By conducting organic geochemical analysis of the samples taken from the drilled wells in Baiyun Sag of Pearl River Mouth Basin, China, the development characteristics of hydrocarbon source rocks in the sag are clarified. Reconstruct the current geothermal field of the sag and restore the tectonic-thermal evolution process to predict the type, scale, and distribution of resources in Baiyun Sag through thermal pressure simulation experiments and numerical simulation. The Baiyun Sag is characterized by the development of Paleogene shallow lacustrine source rocks, which are deposited in a slightly oxidizing environment. The source rocks are mainly composed of terrestrial higher plants, with algae making a certain contribution, and are oil and gas source rocks. Current geothermal field of the sag was reconstructed, in which the range of geothermal gradients is (3.5–5.2) °C/100 m, showing an overall increasing trend from northwest to southeast, with significant differences in geothermal gradients across different sub-sags. Baiyun Sag has undergone two distinct periods of extensional process, the Eocene and Miocene, since the Cenozoic era. These two periods of heating and warming events have been identified, accelerating the maturation and evolution of source rocks. The main body of ancient basal heat flow value reached its highest at 13.82 Ma. The basin modelling results show that the maturity of source rocks is significantly higher in Baiyun main sub-sag than that in other sub-sags. The Eocene Wenchang Formation is currently in the stage of high maturity to over maturity, while the Eocene Enping Formation has reached the stage of maturity to high maturity. The rock thermal simulation experiment shows that the shallow lacustrine mudstone of the Wenchang Formation has a good potential of generating gas from kerogen cracking with high gas yield and long period of gas window. Shallow lacustrine mudstone of the Enping Formation has a good ability to generate light oil, and has ability to generate kerogen cracking gas in the late stage. The gas yield of shallow lacustrine mudstone of the Enping Formation is less than that of shallow lacustrine mudstone of the Wenchang Formation and the delta coal-bearing mudstone of the Enping Formation. The numerical simulation results indicate that the source rocks of Baiyun main sub-sag generate hydrocarbons earlier and have significantly higher hydrocarbon generation intensity than other sub-sags, with an average of about 1 200×104 t/km2. Oil and gas resources were mainly distributed in Baiyun main sub-sag and the main source rocks are distributed in the 3rd and 4th members of Wenchang Formation. Four favorable zones are selected for the division and evaluation of migration and aggregation units: No. ▪ Panyu 30 nose-shaped structural belt, No. ▪ Liuhua 29 nose-shaped uplift belt and Liwan 3 nose-shaped uplift belt, No. ▪ gentle slope belt of Baiyun east sag, and No. ▪ Baiyun 1 low-uplift.

Geochemical Characteristics and Significance of Molecular Markers in the Paleogene-Neogene Crude Oils of the Northwest Qaidam Basin.

The western Qaidam Basin is rich in oil and gas resources, constituting over 90% of the total oil and gas resources in the whole basin. However, the regional distribution characteristics of molecular markers of crude oil and the petroleum system elements relevant to the distribution of oil and gas in the northwest Qaidam Basin are still unclear, which restricts further exploration of oil and gas reservoirs. A total of 38 crude oils were collected from the Xiaoliangshan Sag and Mangya Sag in the northwest Qaidam Basin and analyzed by gas chromatography-mass spectrometry (GC-MS). The indicators of sedimentary environment, organic matter source, and thermal maturity show regular changes from the west to the east in the Xiaoliangshan Sag and Mangya Sag. The nC21 -/nC22 +, n(C21 + C22)/n(C28 + C29), and C27-C28-C29 regular sterane distribution characteristics indicate that the input proportion of lower aquatic organisms in source rocks (E3-N1) gradually increases, while the input proportion of terrigenous organic matter gradually decreases. The triaromatic dinosterane index (TDSI) and methyltriaromatic steroid index (MTDSI) indicate that the input proportion of dinoflagellates gradually increases. The gradual increase in the Pr/Ph ratio indicates a decrease in the reducibility of the sedimentary environment of source rocks. The gammacerane index (Ga/C30H) and methylated-2-methyltrimethyltride-cylchromans (MTTCs) indicate that the degree of stratification and salinity of water body gradually decrease. A total of 23 thermal maturity parameters indicate that crude oil is in a mature evolution stage, and the thermal maturity of crude oil increases with depth, indicating that there are the characteristics of hydrocarbon accumulation close to source rocks. The variation features of sedimentary environment, organic matter origin, and thermal maturity indicators from the west to the east in the Xiaoliangshan Sag and Mangya Sag are controlled by the sedimentary structure characteristics of the study area.

Numerical simulation of thermal deformation of oil distribution sleeve based on heat transfer theory

Numerical simulation of thermal deformation of oil distribution sleeve based on heat transfer theory

Perancangan Rute Optimal Distribusi Kargo Bahan Bakar Minyak dengan Metode Brute - Force Untuk Meminimasi Biaya Konsumsi Bahan Bakar Minyak Perusahaan Pelayaran PT XYZ

TSP of fuel oil distribution using tankers, the projected route search often does not contain the most minimal mileage, which can lead to adverse results such as significant additional costs. This research analyzes four different routes using several iterative proposals to reduce travel distance, time, and fuel costs compared to actual conditions. Problem solving is carried out using the Brute-Force method which enumerates all permutation results. The analysis results show that all proposed iterations were able to provide significant reductions in all three aspects. The four research routes achieved optimization results of 21,7% compared to the actual route modeling. This optimization proves that the iterative methods applied can substantially improve operational efficiency. Therefore, the determination of the tanker route must consider all the possibilities required in determining the route. The optimal route created is expected to have a new model with the aim of minimizing fuel costs based on the smallest distance and time calculations.

Study on the Impact of Microscopic Pore Structure Characteristics in Tight Sandstone on Microscopic Remaining Oil after Polymer Flooding.

As a non-renewable resource, oil faces increasing demand, and the remaining oil recovery rates in existing oil fields still require improvement. The primary objective of this study is to investigate the impact of pore structure parameters on the distribution and recovery of residual oil after polymer flooding by constructing a digital pore network model. Using this model, the study visualizes the post-flooding state of the model with 3DMAX-9.0 software and employs a range of simulation methods, including a detailed analysis of the pore size, coordination number, pore-throat ratio, and wettability, to quantitatively assess how these parameters affect the residual oil distribution and recovery. The research shows that the change in the distribution of pore sizes leads to a decrease in cluster-shaped residual oil and an increase in columnar residual oil. An increase in the coordination number increases the core permeability and reduces the residual oil; for example, when the coordination number increases from 4.3 to 6, the polymer flooding recovery rate increases from 24.57% to 30.44%. An increase in the pore-throat ratio reduces the permeability and causes more residual oil to remain in the throat; for example, when the pore-throat ratio increases from 3.2 to 6.3, the total recovery rate decreases from 74.34% to 63.72%. When the wettability changes from oil-wet to water-wet, the type of residual oil gradually changes from the difficult-to-drive-out columnar and film-shaped to the more easily recoverable cluster-shaped; for example, when the proportion of water-wet throats increases from 0.1:0.9 to 0.6:0.4, the water flooding recovery rate increases from 35.63% to 51.35%. Both qualitative and quantitative results suggest that the digital pore network model developed in this study effectively predicts the residual oil distribution under different pore structures and provides a crucial basis for optimizing residual oil recovery strategies.

Variations in Oil Occurrence State and Properties during High-Speed Stirring Treatment of Oily Sludge.

Oily sludge (OS) has long been regarded as a hazardous waste, and improper disposal may lead to serious environmental concerns and human health risks. Despite various methods having been proposed and applied to the treatment of OS, the oil occurrence states and properties in sludge are rarely characterized, which may directly link to the selection and effectiveness of treatment methods. Here, confocal laser scanning microscopy (CLSM), X-ray diffraction (XRD), gas chromatography (GC), and four components (SARA) analysis were utilized to characterize the changes in the oil occurrence states and compositions in OS samples before and after high-speed stirring (HSS) treatment. Our results show a substantial reduction in the oil concentration of OS after HSS treatment (from 32.98% to 1.65%), while SARA analysis reveals a similar oil composition before and after treatment, suggesting the broad applicability of HSS in removing oil and its insignificant selectivity towards various hydrocarbon components. This is further supported by the total petroleum hydrocarbon (TPH) analysis results, which show that the separated oil phase has a hydrocarbon composition similar to that of the original OS sample. The CLSM and fluorescence analysis suggest a homogeneous distribution of oil in the sludge, with relatively light components more concentrated in the pore systems between coarse mineral particles, whereas relatively heavy components tend to coexist with clay minerals. After HSS cleaning, both light and heavy components are removed to varying degrees, but light components are preferentially removed while heavy components tend to be retained in the sludge due to adsorption by clay minerals. This is consistent with TPH analysis, where a significant decrease in n-alkanes with lower carbon numbers (n-C14 to n-C20) was observed in the residual sample. Our findings demonstrate the dynamic response of oil occurrence states and compositions to the OS treatment process and highlight the importance of characterizing these fundamental properties prior to the selection of OS treatment methods.

Effect of α-tocopherol on the oil absorption of French fries based on physicochemical characteristics of frying oil and the morphology of French fries

With the development of oil processing technology, the retention rate of lipid concomitants in oil has increased. The effect of lipid concomitants on the physicochemical characteristics of oil has garnered significant interest; however, the effect of the lipid concomitant α-tocopherol on the physicochemical properties of rice bran oil (RBO) and the oil absorbency of French fries during frying is unclear. Thus, the influence of α-tocopherol on total polar compounds, diacylglycerols content, and viscosity of frying oil as well as oil content and distribution, moisture content, micromorphology, and quality of French fries is studied. The results revealed that RBO with 0%–0.1% α-tocopherol dose-dependently decreased the total polar compounds, diacylglycerols content, and the viscosity of RBO. This primarily affected the adsorption of surface and structural oils in the French fries. Additionally, RBO with 0%–0.1% α-tocopherol decreased the porous structure of the French fries. Compared with other α-tocopherol levels, RBO supplemented with 0.1% α-tocopherol demonstrated a better effect on reducing the oil absorption in French fries. Moreover, α-tocopherol had a minimal effect on French fry quality. Consequently, incorporating α-tocopherol (0.1%) into frying oil because of its inhibitory effect on the oil absorption of French fries is recommended.

Effect of fat replacement in high internal phase emulsions constructed by high temperature saccharification of grafted proteins on gel properties and flavor profiles of sausages

In order to mitigate the risk of cardiovascular diseases associated with excessive saturated fatty acid intake, utilizing high internal phase emulsions (HIPEs) as a substitute for animal fat in producing high-quality fat-substituted meat products is an ideal approach. This study involves the preparation of glycosylation products of egg white protein (EWP) through saccharification at high temperatures in the presence of fructooligosaccharides (FO). The resulting glycation products of EWP were employed to create colloidal particles, forming HIPEs, which were further utilized to induce the formation of HIPEs gels (HIPEs-Gs). The study investigated the effects of substituting different ratios (25%, 50%, 75%, and 100%) of animal fat with HIPEs and HIPEs-Gs on the gel properties and flavor characteristics of sausages. Results showed that, compared to the control group, substituting fat with HIPEs significantly improved the gel properties, cooking yield, and G' of sausages, while excessive HIPEs-Gs substitution yielded negative effects. Low-field nuclear magnetic resonance results also demonstrated that adding HIPEs improved water and oil distribution in the sausage batter, enhancing protein's binding capacity with water. Scanning electron microscope revealed that HIPEs substitution led to a denser gel network with smaller pores, effectively "locking in" more water. Analysis of volatile compounds indicated accelerated release of aromatic compounds, alkanes, sulfides, and lipids when fat was substituted with HIPEs and HIPEs-Gs. Electronic tongue analysis suggested that HIPEs-Gs substitution reduced response values for umami and saltiness. In conclusion, compared to HIPEs-Gs, using HIPEs as a fat substitute improves the quality of sausages.