The Grampian and Appin groups of the southwestern Monadhliath Mountains form the earliest known syn-rift sequences of the Scottish central Highlands. They were likely to have formed in an intracontinental setting and represent deposition of mixed clastic and carbonate shallow and deep marine strata. The Grampian Group of the southern Monadhliath Mountains was deposited during a period of initial basin rifting (NW–SE extension) followed by a phase of thermal subsidence. Syn-rift sediments comprise a 2.5–6 km thick turbidite system. Thermal subsidence brought about the basinward progradation of shallow marine shelf sediments resulting in the infilling of pre-existing basin topography. The overlying Appin Group commenced with deposition of a shallow marine sequence alternating between nearshore tidal sand and offshore mud deposition. This formed in response to renewed rifting and concomitant subsidence. Accelerated rifting resulted in localized footwall uplift and erosion while sedimentation continued in the hanging-wall areas. Resultant subsidence, perhaps partly thermally driven, caused gradual basin widening and produced an onlapping marine sequence. There followed a period of progressive clastic deprivation when carbonates were precipitated, and at the onset of anoxic conditions, deposition of organic muds. The fundamental structural elements responsible for the formation of the Grampian and Appin group basins were also influential in the orogenic evolution of the basin-fill. Half-graben fills were deformed to produce regionally extensive folds such as the Stob Ban–Craig a’ Chail Synform.