Abstract Despite the electrical energy scenarios are quite different between industrialized countries and emerging and developing ones, for both contexts, energy storage systems could play a key role in the next future. Specifically, in emerging and developing countries, energy storage systems may allow a cost-effective exploitation of renewable sources in order to cope with energy security for centralized energy systems, but mainly to become a building block of rural electrification by off-grid power systems. In this paper a short overview of energy storage systems within the emerging and developing countries scenarios is reported. Specifically the paper provides a description of the typical configuration for batteries within off-grid systems and an overview of the typical economic models for batteries applications and the regulatory frameworks when off-grid applications are introduced. Finally the description of an experimental project in rural area of Tanzania points out the peculiar characteristics of batteries application in off-grid applications.