Subduction Of Oceanic Slab Research Articles

Neoarchean granitoid magmatism and geodynamic process in the northeastern North China craton

The composition of Archean granitoid rocks changed from predominantly tonalite-trondhjemite-granodiorite (TTG) gneisses in the early Archean (4−3 Ga) to diversified granitoid rock assemblages in the late Archean (3.0−2.5 Ga), marking a crucial transformation in the geodynamic processes of early Earth. However, the reason for this major transition remains enigmatic because the petrogenetic features of different granitoid assemblages and their crust-mantle interactions during different periods are poorly understood. We use variations in the spatial-temporal distribution, lithological association, chemical composition, and petrogenesis of Neoarchean (2.7−2.5 Ga) granitoids and inferred correlative crust-mantle interactions in the Eastern Liaoning Range (ELR) of the northeastern North China craton to explore this geodynamic transition. The early Neoarchean (ca. 2.7 Ga) ELR granitoids were dominated by TTG gneisses, and the late Neoarchean (2.6−2.5 Ga) ELR granitoid typology and compositions became more complex, changing into TTGs and more K2O-rich granitoid rocks. The TTGs can be subdivided into a high-Ca group and a low-Ca group: The 2.71−2.68 Ga high-Ca group TTG magma originated from partial melting of subducted juvenile oceanic crust, and the low-Ca group TTG magma was derived from fractionation crystallization of the high-Ca group TTG magma. The chemical composition of the magmatic sources played a dominant role on the 2.60−2.50 Ga TTG magmatism: the high-Ca and low-Ca group TTG magmas came from low-K mafic rocks and tonalites, respectively. The 2.58−2.49 Ga K2O-rich granitoids can be divided into three petrogenetic series: (1) The high-Ca-Mg group K2O-rich granitoid magma originated from partial melting of high-K mafic rocks, (2) the low-Ca-Mg group K2O-rich granitoid magma was derived from partial melting of sedimentary rocks, and (3) the transition group K2O-rich granitoid magma was sourced from metagreywackes. The 2.71−2.68 Ga TTGs were generated in an island arc belt, and subducted slab melting and subsequent magmatic differentiation were the dominant mechanisms of the TTG magmatism. The 2.60−2.50 Ga diversified granitoids were formed in the oceanic-continental subduction process under the active continental margin; the complicated oceanic slab subduction and arc-arc and arc-continent collisions contributed to the diversity of late Neoarchean granitoid magmatism.

Fluid-metasomatized rocks with extremely low δ26Mg values in subducted oceanic lithosphere: Implications for mantle Mg isotope heterogeneity and the origin of low-δ26Mg magmas

The subduction of oceanic slabs with diverse lithologies greatly contributes to the geochemical heterogeneity of the mantle. Oceanic metasomatism leads to the formation of rocks with heterogeneous geochemical characteristics, which can be further modified by fluid–rock interactions during subduction zone processing. Investigations of exhumed high-pressure oceanic rocks not only shed light on the compositional variations that occur during oceanic metasomatism and subduction processes but also help in understanding mantle heterogeneity and magma genesis. Here, we present a comprehensive Mg–O–Sr–Nd isotope study on eclogite-facies Mg- and Ca-metasomatized rocks (Ti-clinohumite dikelets and metarodingites, respectively) and their host meta-serpentinites from the Voltri Massif (Ligurian Western Alps). Compared to their Fe–Ti gabbroic protoliths, the Ti-clinohumite (Ticl) dikelet and metarodingite are characterized by high MgO contents (∼32–38 wt%) and CaO contents (∼17–25 wt%), respectively. These Mg- and Ca-enriched rocks both display low δ26Mg values of −0.54 ‰ to −0.43 ‰ and −1.49 ‰ to −0.82 ‰, respectively, while the serpentinite hosts have mantle-like δ26Mg values of −0.26 ‰ to −0.20 ‰. The Ticl-chlorite rind rimming the metarodingite has a low δ26Mg value of −1.00 ‰. No carbonate minerals were found for metasomatized rocks that have low δ18O values ranging from +2.0 ‰ to +3.4 ‰, demonstrating that their low δ26Mg signature cannot be attributed to metasomatism by fluids involved with carbonate components. The increase in MgO content and decrease in δ26Mg in the Ticl dikelets are ascribed to fluid-induced mass transfer through low-δ26Mg fluids buffered by serpentinization of the host ultramafic rocks. The metarodingite has comparable MgO but extremely low δ26Mg values compared to those of the gabbroic protolith. By integrating reported Mg isotope data for low-grade rodingites, we propose that the low δ26Mg values of metarodingites are ascribed to isotopic exchange with serpentinizing fluids during progressive rodingitization reactions at the seafloor. However, the extremely low δ26Mg value of the Voltri metarodingite (as low as −1.49 ‰) may be attributed to further metasomatic modification in the subduction zone. High pressure metamorphic recrystallization of these metasomatized rocks play a limited role in their Mg isotope compositions. Therefore, our results show that the oceanic metasomatized metarodingite and Ticl-bearing dikes hosted in serpentinite display systematically low-δ26Mg features. Such isotopically light Mg compositions can be preserved during subduction to eclogite-facies conditions. Hence, subduction of these metasomatized rocks may lead to the transfer of a low-δ26Mg component into the deep mantle, which was overlooked thus far and may further contribute to the origin of low-δ26Mg magmas.

Light oxygen isotopic composition in deep mantle reveals oceanic crust subduction before 3.3 billion years ago

Compositional heterogeneity exists in Earth’s deep mantle, which can be caused by the subduction of oceanic slabs. How early this process started on Earth remains highly debated due to the scarcity of early Archean materials with pristine mantle compositional signatures. Here, using the oxygen isotope and elemental compositions of fresh olivine grains in the 3.27-Ga komatiites of the Weltevreden Formation in the Barberton Greenstone Belt in Southern Africa, we discovered two groups of samples with primitive olivine grains. Group I exhibits normal mantle-like δ18O values and high Fo contents (δ18O = 4.9–5.4‰; Fo = 93–95); Group II is characterized by lower δ18O values with slightly lower Fo contents (δ18O = 3.6–4.7‰; Fo = 91–93). These δ18O values correlate with other geochemical proxies of olivine-poor iron-rich pyroxenite sources, indicating that the Weltevreden komatiites were derived from two distinct mantle sources. The existence of the low-δ18O magmas can be best explained by recycling of the altered oceanic crust into deep mantle arguably by subduction, which started 3.3 billion years ago and is responsible for the deep mantle heterogeneity in early Earth.

Comparison of Sn-related granitoids in subduction and collision settings by accessory mineral geochemistry: A case study in the Tengchong-Lianghe tin belt, SW China

Magmatic-hydrothermal Sn deposits can develop in both subduction and collision settings. However, a systematic comparison of the geochemical fingerprints and petrogenetic evolution of Sn-related granitoids from both settings is still lacking. The Tengchong-Lianghe tin belt hosts numerous Sn deposits but of different metallogenic ages, such as the Xiaolonghe and Lailishan Sn deposits, which provide an ideal study area for addressing this issue. Zircon U–Pb dating suggests that the Xiaolonghe and Lailishan Sn-related granitoids were emplaced at 74.2–75.5 and 50.0–51.1 Ma, respectively. Given the initial India-Asia collision commenced at ca. 65–60 Ma, these ages, consistent with available Sn metallogenic ages, suggest the formation of the Xiaolonghe and Lailishan Sn deposits in subduction and collisional settings, respectively. New zircon and apatite compositions, and apatite Sr isotopic data, combined with previously reported whole-rock geochemical results, all indicate that the Xiaolonghe and Lailishan Sn-related granitoids share similar magma sources, evolution processes, redox states, and volatile contents. The presence of hornblende, high apatite NdN/NdN* (mostly > 1), and whole-rock evolutionary trends, together indicate that they represent fractionated I-type granites. Distinctly elevated apatite 87Sr/86Sr ratios (0.70988–0.71430) suggest that they originated from an ancient lower crust. Subsequently, they underwent an extensive fractional crystallization dominated by feldspar, as revealed by whole-rock, apatite, and zircon elemental variation trends. The low zircon CeN/CeN* (mainly < 200) and ΔFMQ (–1.9 to 1.7), together with elevated apatite F content (2.30–3.69 wt%), reveal that they crystallized from reduced and F-rich magmas. The relatively high whole-rock zircon saturation temperatures (mainly > 800 ℃) and Ba/Pb ratios imply that they were produced at a higher temperature by biotite-dehydration melting, which requires additional heat from the mantle. The specific mechanism that triggers mantle upwelling (oceanic slab subduction or break-off) could be the most significant difference between Sn-related granitoids formed during subduction and collision processes.

Munabulake ophiolitic mélange: Implication for the evolution history of the north branch of the Proto-Tethys ocean

One of the ophiolites that record the Proto-Tethys Ocean’s episodic closure is the Munabulake ophiolitic mélange, which is situated in the middle of the Kunlun–Qaidam and Altun–Qilian blocks. Detailed field mapping revealed that the Munabulake ophiolitic mélange comprises local (ultramafic rocks, basalts, andesites, gabbros, diorites, and plagiogranites) and exotic (marble, gneiss, schist, and amphibolite) blocks, many of which are in the schist matrix (Qimantage Group). Based on geochronological, geochemical, and petrological observations, the mafic rocks in the Munabulake ophiolitic mélange can be categorized into three categories: 498-Ma OIB-like gabbros, 468-Ma Hawaiian alkaline basalt-like dolerite and pillow basaltic slices, and 428 Ma massive SSZ-like ultramafic rocks. The 501–452 Ma I-type granites exhibit arc affinities due to the oceanic crust subduction. These findings, along with spatial relationships, suggest that the Early Paleozoic ophiolite complex, island arc rocks, and accretionary complex generated as an intra-oceanic arc system as a result of obduction of the south Altun Ocean’s onto the Central Altun block within a north-directed subduction event. A dextral strike–slip was evident throughout the Early Paleozoic oceanic crust subduction based on the whole set of planar and linear structural data, and the subduction polarity was likely to the north. According to the ophiolitic mélange’s youngest rocks and the existence of 413 Ma granite dykes that are widely exposed in the Munabulake ophiolitic mélange, the Munabulake ophiolitic mélange was most likely emplaced during the Middle Silurian. This Munabulake ophiolitic mélange is similar in age and petrochemical characteristics to the other ophiolites in the South Altun subduction–collision belt, indicating that the Manabulak ophiolite mélange is a westward extension of the Apa–Mangya subduction–collision belt, which formed during the northward subduction of the South Altun Ocean slab during the Early Paleozoic. Thus, the final closing time of the South Altun Ocean is between 413 and 428 Ma.

Neoproterozoic slab window in the western Yangtze Block, South China: Evidence from adakitic granodiorites, gabbro-diorites and high-K granites in the Panxi arc belt

Neoproterozoic igneous rocks are widespread along the margins of the Yangtze Block and record key information on the tectonic evolution of the South China Craton. In this paper, we present a comprehensive study of zircon U-Pb ages, whole-rock geochemistry and Sr-Nd-Hf isotopes on the Neoproterozoic granodiorites, gabbro-diorites, and high-K granites in the western Yangtze Block. The granodiorites, gabbro-diorites and high-K granites were dated at 848 ± 5.3 Ma, 824 ± 5.1 Ma and 819 ± 1.5 Ma, respectively. The granodiorites have high Sr (567 ∼ 607 ppm) contents and Sr/Y (84.4 ∼ 88.0) ratios and low alkalis (Na2O + K2O = 4.3 ∼ 4.9 wt%) and Y (6.6 ∼ 7.1 ppm) and Yb (0.7 ∼ 0.9 ppm) contents, similar to typical adakitic rocks. They show low MgO (0.9 ∼ 1.3 wt%), Cr (15.2 ∼ 26.7 ppm) and Ni (3.6 ∼ 4.4 ppm) contents and positive εNd(t) (+1.7 to + 4.2) and εHf(t) (+3.0 to + 8.2) values. The parental magmas for granodiorites were generated by partial melting of thickened juvenile mafic lower crust. The gabbro-diorites are characterized by the enrichment in LREEs, significantly negative Nb, Ta and Ti anomalies, and positive εNd(t) (+2.2 to + 4.2) and εHf(t) (+5.8 to + 10.4) values. They are inferred to be derived from partial melting of lithospheric mantle modified by subduction-related fluids. The high-K granites display high Zr + Nb + Ce + Y (208 ∼ 366 ppm) and alkali (Na2O + K2O = 7.6 ∼ 8.4 wt%) contents, high 10000*Ga/Al (2.31 ∼ 2.64) ratios and zircon saturation temperatures, similar to A-type granites. We suggest that these granites were formed by the partial melting of felsic crustal materials under low pressure and high temperature conditions. The association of granodiorites, gabbro-diorites and high-K granites indicates Neoproterozoic oceanic slab subduction in the western Yangtze Block. We suggest that a subducting oceanic slab window can account for Neoproterozoic magmatism in the western Yangtze Block.

Zircon Hf-O and apatite Sr-O isotopes jointly reveal the origin and mineralization of the Miocene adakitic porphyries in the Gangdese belt

The Gangdese belt is a significant belt for exploring the dynamic processes of continental collision orogeny and mineralization. The impact of petrogenesis and chemical heterogeneity of the E-trending Miocene adakitic rocks in Gangdese porphyry deposit belt on mineralization mechanisms has always been controversial. New whole-rock Sr-Nd isotope, zircon U-Pb dating and Hf-O isotope data, especially integrating apatite volatile (Cl and S) and Sr-O isotope compositions, of the Miocene mineralized porphyries from Lakange deposit can provide the development of metallogenic system origin, as well as magmatic and volatile process. The Lakange granites show adakitic geochemical composition affinity with high potassic calc-alkaline. They have high SiO2 content, low MgO and Ni contents, positive εNd(t) value (0.1 ∼ 0.8), and high (87Sr/86Sr)i ratios (0.705088 ∼ 0.705269), positive zircon εHf(t) (7.6 ∼ 11.2), medium δ18O (4.33‰∼7.27‰) values, combining with apatite Sr-O isotopes (87Sr/86Sr = 0.7040 ∼ 0.7169; δ18O = 7.0‰∼8.2‰), implying that the granites are originated from the partial melting of the juvenile lower crust beneath the southern Lhasa subterrane. The Miocene adakitic rocks of the Gangdese metallogenic belt exhibit spatially isotopically heterogeneity in a west to east direction (87°E-93°E). These variations are attributed to the lower crust modification by the oxidized mantle-derived melts/fluids from metasomatic subcontinental lithospheric mantle in Miocene, resulting in the formation of juvenile lower crust, that thickened the crust and shortened the lithospheric mantle. In-situ Sr-O isotope of apatites identified the oceanic components in the volatile sources, indicating that volatiles existed beneath the Lhasa terrane during Neo-Tethyan oceanic slab subduction prior to the Miocene partial melting of the lower crust. The high volatile concentrations (Cl and S) aid in the transport of metals that produce the Gangdese Miocene porphyry deposits.

Genesis and exhumation of the Kongur-Muztaghata and Maeryang gneiss domes in NE Pamir since the Mesozoic

The Kongur-Muztaghata-Maeryang terrane in NE Pamir is considered to be the western extension of the Songpan-Ganze terrane located in the northern Tibetan Plateau. The Kongur-Muztaghata gneiss dome (KMGD) is situated in the north while the Maeryang gneiss dome (MYGD) is in the south. The KMGD comprises Triassic granites and granitic gneiss in the core and Early Paleozoic-Triassic sediments in the mantle that underwent Barrovian-type and Buchan-type metamorphisms. Based on geochemical and geochronological data, the Kongur-Muztaghata magmatic arc was formed around ∼252–204 Ma due to northward subduction of the Paleo-Tethys Jinsha oceanic slab. The collision of the Kongur-Muztaghata magmatic arc and the Qiangtang terrane occurred subsequently. Previous research suggested that the KMGD was formed in the Miocene (21–8 Ma). However, our new in-situ monazite U–Pb data for the mantled metasediment shows that the KMGD was initially formed at ∼198 Ma.The MYGD is comprised of an Early Paleozoic-Triassic metasediment mantle and a Cambrian anatexis complex core that underwent Barrovian-Buchan metamorphisms. Our new structural, geochemical, and geochronological data suggest that the protolith of the Maeryang orthogneiss was formed around ∼519-513 Ma, with the surrounding Early Paleozoic metavolcanic rocks erupted at ∼519-508 Ma. Together, they formed the Early Cambrian magmatic complex. In-situ U–Pb dating of monazites and zircon metamorphic rims for the Triassic metamorphic rocks in the mantle indicate that the Barrovian-Buchan metamorphism in the MYGD occurred around ∼206-187 Ma, likely caused by anatexis in the deep crust of the gneiss dome core. Thus, we propose that the KMGD and MYGD underwent a two-stage exhumation: the initial uplift during the Late Triassic-Early Jurassic thermo-tectonic event associated with the Cimmerian orogeny and the late rapid exhumation since the Miocene driven by the collision between the Eurasian and Indian plates.

Early Paleozoic oceanic slab subduction in South China: Evidence from adakite‐like granodiorite and high‐Mg diorite from Puyang pluton in the Wuyi orogenic belt

AbstractThe mechanism of Caledonian orogeny in South China is still controversial. The main argument focuses on the issue that whether there existed oceanic subduction. To answer this question, the complex Puyang pluton in the central part of Wuyi orogenic belt was selected for zircon U–Pb dating, in‐situ Lu–Hf isotopic analysis and geochemical testing. The Puyang pluton is mainly composed of granodiorite and diorite. The results of geochronology indicate that the granodiorite and diorite emplaced at 450 ± 3.9 Ma and 443 ± 4.0 Ma. Their emplacement time were well corresponding to the subduction stage of the Yunkai orogeny in the southwestern part of Cathaysia block during the Early Paleozoic (460–440 Ma). The Puyang adakite‐like granodiorite shows enrichments in Sr, but depletions in Y and Yb contents, high in Na2O, K2O and Al2O3, with εHf(t) values range from −10.5 to −7.4 (mean of −9.0) and two‐stage Hf model ages range from 1.91 to 2.10 Ga. These characteristics indicate that the magmas were generated by partial melting of subducted oceanic crust mixed with melts from the above wedgy mantle peridotite. The Puyang high‐Mg diorite shows enrichments in Sr and Ba, depletions in Rb, Y and Yb contents, and strongly high in MgO and Al2O3 contents, with εHf(t) values of −2.9 to 0 (mean of −1.4) and two‐stage Hf model ages of 1.43 to 1.61 Ga. These indicate that the magmas were mainly generated by partial melting of the wedgy mantle peridotite, mixed by adakitic melts from subducted oceanic slab. Comprehensive analysis shows that Puyang adakite‐like granodiorite and high‐Mg diorite were formed in fore‐arc setting, where the mantle and crustal magmas mixed during the oceanic subduction initiation period. By extension, this study offered important evidences to support the point that the Caledonian orogeny in South China was related to oceanic subduction which initiated prior to ~450 Ma.

Post-subduction porphyry Cu magmas in the Sanjiang region of southwestern China formed by fractionation of lithospheric mantle–derived mafic magmas

Abstract For porphyry Cu deposits that formed during oceanic slab subduction, there is a general consensus that the ore-forming magmas evolved through fractionation of mafic magmas that were generated by slab fluid (± melt)–fluxed melting of the asthenospheric mantle wedge. This model, however, is not applicable to post-subduction porphyry Cu deposits because they formed distinctly after cessation of oceanic slab subduction. A popular model proposes that post-subduction porphyry Cu magmas were produced by partial melting of lower-crustal, sulfide-rich arc cumulates, with or without minor contributions from potassic mafic magmas. To reappraise the crustal melting model, we focused on one of the largest post-subduction porphyry Cu belts on Earth, which formed during the India-Asia collision in the Sanjiang region of southwestern China. Detailed petrographic studies and new Nd-Sr isotopic data from non-metasomatized versus metasomatized lower-crustal xenoliths suggest that previous models based on crustal melting rest upon wrong radiogenic isotope constraints due to pervasive metasomatism of the xenoliths. Based on traceelement quantitative modeling and regional-scale geochemical trends of magmatic rocks, we demonstrate that the Sanjiang post-subduction porphyry Cu magmas were produced by fractionation of potassic mafic magmas derived from lithospheric mantle. This study highlights that post-subduction porphyry Cu magmas attain their K-rich composition, and all the ore-forming ingredients, from subduction-modified lithospheric mantle, the existence of which may be a prerequisite for the formation of porphyry Cu deposits in post-subduction settings.

Jurassic Paleomagnetism of the Lhasa Terrane—Implications for Tethys Evolution and True Polar Wander

AbstractThe drift history of the Lhasa terrane from Gondwana to Asia plays a crucial role in understanding the Tethys evolution and true polar wander (TPW). However, few reliable paleomagnetic results from Jurassic strata are currently available for reconstructing its northward journey. We performed a combined paleomagnetic and geochronological study on Bima Formation strata in the Xigaze area. Combined with previous results from the Sangri area, our results reveal a paleolatitude of 8 ± 4°S at ∼180 Ma for the reference point (29.3°N, 90.3°E). Along with other paleomagnetic results from the Triassic to Cretaceous, our new results suggest that the Lhasa terrane motion accelerated from ∼2 cm/yr during ∼220–180 Ma to ∼17 cm/yr during ∼180–170 Ma. Paleolatitude information of the North Qiangtang terrane and Tethyan Himalaya is calculated from paleopoles that meet five criteria, which include (a) structural control, (b) well‐determined rock age, (c) stepwise demagnetizations, (d) a minimum of 25 specimens or 8 sites are contained, and (e) robust field or reversal tests are provided. Both terranes also show significant acceleration during their northward motion, which may be related to oceanic slab subduction. Thus, all Gondwana‐derived microcontinents seem to share a significant acceleration during their northward motion. In addition, recent paleomagnetic results from volcanic rocks dated at ∼155 Ma subdivide the overall northward motion during ∼170–130 Ma into two stages, which include a southward drift during ∼170–155 Ma followed by northward motion during ∼155–130 Ma. These results support the fast Late Jurassic TPW during a ∼10 Myr time span.

Featured Neoarchean granitoid association in the central North China Craton: An indicator of warm plate subduction

Abstract Diverse Neoarchean granitoid assemblages, which generally include tonalites–trondhjemites–granodiorites (TTGs) and various K-rich granitoids, are prevalent in most basement terranes of the North China Craton. However, the Hengshan terrane is an exceptional case in the North China Craton; it is dominated by late Neoarchean sodic diorite-TTGs (DTTGs) and sanukitoids. These sanukitoids are the only high-K granitoids and show Mg-rich chemical features. The late Neoarchean DTTGs and sanukitoids were generated at ca. 2486–2537 Ma and show an intimate spatial association. The granitoid assemblages of the DTTGs and sanukitoids are characterized by high Mg# [100 × Mg/ (Mg + Fetotal)] values (43–65) and enriched in light rare earth elements, large ion lithophile elements, heterogeneous zircon Lu–Hf (εHf = −1.6 to +7.4), and whole-rock Sm–Nd (εNd = +0.9 to +4.2) isotopic components, which indicates that they may be derived from varying degrees of interactions between mantle peridotite and subduction-related materials. Combined with the relatively high apparent geothermal gradient (∼17 ± 2 °C/km) and the relatively low basal heat flow of continental crust (∼25 ± 5 mW m−2), the crustmantle interaction process indicates that the occurrence of late Neoarchean high-Mg magmatism was closely related to warm oceanic slab subduction in the Hengshan terrane, and the featured lithological association of DTTGs and sanukitoids most likely developed in the active continental margin at the end of the Archean.

Geochronology and geochemistry of 2.3 Ga mafic intrusions in the Dengfeng area: Evidence for early Paleoproterozoic subduction in the southern North China Craton

The time of 2.45–2.2 Ga in the early Paleoproterozoic era is called as ‘Quiet Interval’ because of the decreased magmatic activity worldwide. However, tectonic evolution of old continents during this time interval is still in dispute due to the rare geological records, especially for magmatism. In the southern North China Craton (NCC), the Jingwan mafic intrusions intruded into the Songshan Group and its zircon U-Pb dating yielded a weighted mean 207Pb/206Pb age of 2301 ± 16 Ma, and thus they are the only ca. 2.3 Ga mafic magmatic records founded in this region. These diabases belong to low-K tholeiitic series with relatively low K2O (0.1–0.7 wt%) and total alkalis (Na2O + K2O) (2.4–4.7 wt%). They have low SiO2 (44.8–54.1 wt%), slightly variable Fe2O3T (10.1–14.4 wt%), Al2O3 (14.8–17.0 wt%), CaO (5.5–10.6 wt%), and medium to high MgO (6.1–10.8 wt%) and Mg# values (58–65). The rocks display LREE enrichment ((La/Yb)N = 3.02–3.58) without obvious Eu anomaly (Eu/Eu* = 0.87–1.18). They are characterized by obvious depletion in Nb, Zr and Ti, and enrichment of Sr, Ba and Pb, indicative of geochemical features of island arc magmas. The rocks have experienced crystallization from clinopyroxene to orthopyroxene, then plagioclase, suggesting the hydrous fractionation order. They also exhibit variable εNd(t) values ranging from − 0.2 to + 0.8 and zircon εHf(t) values from − 3.0 to + 6.6. These features suggest that the mafic intrusions are formed by partial melting of a garnet-spinel lherzolite and derived from an enriched mantle source metasomatized by slab-derived fluids at a shallow depth. Combined with the previous reported magmatic records, the ca. 2.3 Ga magmatic activity may be a result of the oceanic slab subduction beneath the Eastern Block of the NCC, and the subduction probably continue throughout the early Paleoproterozoic from ca. 2.5 Ga to ca. 2.3 Ga, at least 200 Ma. Therefore, the prevalence of early Paleoproterozoic magmatic activities in the southern NCC indicate that the tectonic activity did not shutdown globally during the interval of the ‘tectono-magmatic lull’.

Contrasting fates of subducting carbon related to different oceanic slabs in East Asia

Subduction transfers surface carbon into the Earth’s interior in a main form of carbonates that influences the global carbon cycles and surface climate through geologic time. Nevertheless, whether the fate of downgoing carbonates significantly varies in past subduction zones is rarely constrained by natural observations. Marine carbonates have remarkably higher zinc isotopic ratios (expressed as δ66ZnJMC-Lyon) relative to the mantle (0.99 ± 0.24‰ vs. 0.18 ± 0.05‰), making zinc isotopes a sensitive tracer for subducting carbonates. Here we examine this issue through a comparative zinc isotope study on basalts across the North-South Gravity Lineament (NSGL) in East Asia that were genetically related to two different oceanic slabs. Together with existing data, we show that all basalts in the east of the NSGL have high δ66Zn (∼0.3–0.6‰; n = 134) that do not vary with distances to the trench and are spatially coupled with the horizontally stagnated slab in the transition zone (410–660 km). This indicates that subducting carbonates survived shallow dissolution and were deeply buried during westward subduction of the Paleo-Pacific slab. By contrast, basalts in the west of the NSGL display a gradual decline of δ66Zn from 0.50 ± 0.04‰ to 0.28 ± 0.03‰ (n = 35) with increasing distances to the trench. No known magmatic processes (e.g., partial melting, crystal-melt differentiation, melt-peridotite interaction, and degassing) can account for the spatial Zn isotopic variation. The role of slab-derived sulfate rich fluids is also excluded because of the mantle-like Cu isotopic compositions of these basalts. Instead, the gradual decrease of δ66Zn, together with the coupled decline of CaO/Al2O3, are best explained as the diminished amounts of dissolved carbonates in their mantle sources. Thus, substantial carbonate dissolution must have occurred during southeastward subduction of the Paleo-Asian slab, which prevents deep burial of subducting carbon. The main differences between the two large slabs include: (i) the Paleo-Asian slab has an extended longevity (∼1.1 Ga) and slow spreading rate in comparison with the Paleo-Pacific slab, leading to the main incorporation of carbonate minerals into the altered oceanic crust, and (ii) the younger Paleo-Pacific slab contains abundant deep-sea Mg-rich carbonates that were not sufficiently dissolved at shallow depths. These differences demonstrate that subduction of different oceanic slabs can lead to contrasting fates of subducting carbon in ancient subduction zones, depending on the contents and species of carbonate sediments in the oceanic crust.

Early Cretaceous back‐arc basin basalt‐type gabbros in the southeastern Tibetan Plateau: Implications for Neo‐Tethyan oceanic slab subduction

Although progress has been made in defining and explaining the temporal and spatial distributions of Neo‐Tethyan magmatism in the Tibet–Himalaya region, the correlation of magmatic suites in the SE Tibetan Plateau remains poorly constrained. This paper reports zircon U–Pb dating, geochemistry, and Sr–Nd isotope compositions of a concealed gabbroic unit (coverage area of &gt;6.0 km2) in the southern Lancangjiang tectonic zone, western Yunnan, SW China. Zircon 206Pb/238U ages of 143–133 Ma indicate that the unit formed during the Early Cretaceous (ca. 139.7 Ma). The gabbro samples have variable MgO (7.88–16.1 wt%; Mg# = 58–74) and relatively low TiO2 (0.76–1.24 wt%) and total‐alkali (K2O + Na2O = 2.61–4.06 wt%) contents. The samples exhibit weakly fractionated rare earth element (REE) patterns with slight depletion in light REEs and negligible Eu anomalies. In a primitive‐mantle‐normalized element‐variation diagram, the gabbros, display variable enrichment in large‐ion lithophile elements and relatively flat patterns of high‐field‐strength elements. Initial 87Sr/86Sr ratios of 0.7079 to 0.7142 and relatively depleted εNd(t) values of +3.96 to +4.84 are similar to those of the mantle source of back‐arc basin basalts (BABBs) in the central Lhasa Block and mid‐ocean ridge basalt in the Indus–Tsangpo Suture Zone. These various characteristics suggest that the gabbroic unit was derived from a shallow and depleted mantle source by relatively high‐degree partial melting in the spinel stability field. The parental magma underwent slight crustal contamination, as well as fractional crystallization of clinopyroxene. The studied gabbros have distinct BABB‐type geochemical affinities similar to those of the Okinawa BABB. Combining our data with the coeval occurrence of a continental rift basin (the Simao–Lanping Basin) leads us to suggest the existence of a back‐arc rifting setting in the SE Tibetan Plateau during the Jurassic–Cretaceous. This setting can also be geochronologically and genetically correlated to the back‐arc basin developed within the Lhasa Block. These settings and constituent characteristics formed as a result of Neo‐Tethyan oceanic slab subduction during the late Mesozoic.

Petrogenesis and tectonic significance of the Mengjiaping beschtauite in the southern Taihang mountains

Abstract The evolution process of the North China Craton has been discussed by many scholars; however, the frame for the timing of the Trans-North China Block has not been fully agreed upon. Related research has mostly focused on the northern and southern sections of the Trans-North China Block, and in-depth studies on intrusive rocks in the central region are lacking. In this study, we conduct a systematic study of the petrography, the whole-rock geochemistry, and the zircon U–Pb dating for the beschtauite intrusion, located in the Mengjiaping area of the Southern Taihang Mountains. Our results demonstrate that the dyke intrusion is mainly composed of beschtauite. Laser ablation inductively coupled plasma mass spectrometry zircon U–Pb dating shows that the beschtauite intrusion occurred at ∼1,880 ± 69 Ma. The beschtauite belongs to I-type granite, Arc tholeiite series, and Cale-alkaline series, with low total alkali, low potassium, and high aluminum. They are also enriched in large-ion lithophile elements, relatively depleted in high-field strength elements, and low total rare-earth elements. Based on the abovementioned data, it is suggested that the magmas for the beschtauite intrusion were metasomatized by oceanic slab subduction in the Late Paleoproterozoic. The formation time of the North China Craton basement should be set to after 1,880 Ma.

Tracing carbonate dissolution in subducting sediments by zinc and magnesium isotopes

Carbonate dissolution in subduction zones transfers surface carbon to the mantle and plays an important role in regulating global carbon cycles through geologic time. Petrological observations and thermodynamic models predict substantial dissolution of subducting carbonates induced by slab-derived fluids at arc mantle depths, but this dissolution process has rarely been verified by existing geochemical tracers. In this paper we show that zinc and magnesium isotopes can serve as such tracers through a comparative study on carbonate-bearing and carbonate-free sediments from the South China Sea and the Philippine Sea that are going to be subducted. Leaching experiments are further performed to characterize the isotopic difference between dissolved carbonates and silicate components in sediments. Bulk carbonate-bearing sediments and carbonate-free sediments surprisingly have indistinguishable δ66Zn (0.26 ± 0.04‰ versus 0.25 ± 0.04‰), but the former display systematically lower δ26Mg (−0.85‰ to −0.17‰, n = 10) than the latter (−0.26‰ to +0.13‰, n = 13). Leaching experiments show that dissolved carbonates have much higher δ66Zn (0.82 ± 0.26‰) and lower δ26Mg (−2.70 ± 0.35‰) compared with the silicate residues (δ66Zn = 0.21 ± 0.06‰; δ26Mg = −0.06 ± 0.14‰). These results indicate that the presence of carbonate components has insignificant influence on Zn isotopic compositions of bulk sediments but prominent influence on their Mg isotopic compositions. In this respect, the final fate of carbonates in subducting sediments can be tracked by a combined Mg and Zn isotope analysis on mantle-derived magmas. For instance, bulk carbonate-bearing sediment addition (i.e., no carbonate dissolution) during subduction would produce low δ26Mg but normal δ66Zn values (i.e., Mg-Zn isotopic “decoupling”) in mantle-derived magmas. By contrast, if carbonate dissolution occurs during subduction, the high δ66Zn and low δ26Mg (i.e., Mg-Zn isotopic “coupling”) signals of dissolved carbonates will be transferred to the sources of mantle-derived magmas. We test this application for a Cenozoic subduction-related, arc-like volcanic exposure from Tengchong, Southwestern China and find significant Mg-Zn isotopic coupling, which demonstrates carbonate dissolution during Indian Oceanic slab subduction. Our results also shed constraints on the amount of dissolved carbonates in the sub-arc mantle. Available data reveal the absence of high δ66Zn and low δ26Mg in global arc lavas, for which we suggest to be the result of a relatively low proportion (<20%) of dissolved calcium carbonates in the sub-arc mantle.

A Fossil Paleozoic Subduction-Dominated Trench-Arc-Basin System Revealed by Airborne Magnetic-Gravity Imaging in West Junggar, NW China

A Carboniferous trench-arc-basin system related to oceanic slab subduction has been thoroughly imaged by various geophysical probing approaches and proposed for the formation of West Junggar, Northwest China, located in the southwest of the Central Asian Orogenic Belt. However, debate on the origin of West Junggar still continues. Here, we present an integrated aeronautic magnetic–gravity observation to further identify the trench-arc-basin system and constrain the subduction mode. By deploying an integrated aerial magnetic–gravity survey consisting of 66,000 survey-line kilometers from August 3, 2015 to April 22, 2016, we determine the magnetic and gravitational anomaly across the study region by using geophysical potential-field processing. Our results reveal curial crust-scale variations in magnetic and gravitational structures beneath West Junggar and that a prominent Bouguer gravity high is located between the Darbut and Karamay–Urho faults, likely corresponding to a trapped oceanic slab. Notably, the Tacheng Basin is characterized by high-frequency magnetic signal and gravity highs, as well as the Carboniferous rifting–related sedimentary cover, which could be reasonably interpreted to be a back-arc basin. Integrated with these comprehensive geological and geophysical observations across West Junggar, the previous model of West Junggar trench-arc-basin system related to a fossil intra-oceanic subduction during the Late Paleozoic is further renewed.

Zircon xenocryst Hf-O isotopic compositions in the Qiyugou Au orefield: A record of Paleoproterozoic oceanic slab subduction in the Trans-North China Orogen

The Trans-North China Orogen (TNCO) is suggested to form under a transition from subduction to collision from 2500 Ma to ∼ 1850 Ma, and the Taihua TTG gneiss in the Xiong’ershan district is thought to have formed in an Andean-type continental arc setting or island arc setting during this geological event. However, to date, the geochemical record of the subducted oceanic slab is still lacking. This study focuses on Hf-O isotopic analyses of zircon xenocrysts from the Qi189 hornblende monzogranite, Qiyugou Au orefield, TNCO. The results reveal that zircon xenocrysts with ages from 2304 Ma to 1934 Ma generally have low-δ18O values from 2.66‰ to 3.83‰ and high-εHf(t) values from 2.7 to 7.8. These zircon grains were generated from remelting of high-temperature altered gabbroic rocks of the subducted oceanic slab during the transition from compression to extension. In this paper, we present new evidence for Paleoproterozoic oceanic slab subduction in the TNCO.

Revisiting Phanerozoic evolution of the Qinling Orogen (East Tethys) with perspectives of detrital zircon

This paper presents 5383 detrital zircon U–Pb and 2079 Lu–Hf isotopic data, shedding new light on the Phanerozoic tectonic evolution of the Qinling Orogen. The Silurian rocks are characterized by negative εHf(t) values of early Paleozoic and Neoproterozoic zircon, which in the Devonian to Carboniferous samples show both positive and negative εHf(t) values. Late Paleozoic zircon peak with negative εHf(t) values occurs in the upper Carboniferous to Cretaceous strata. The Permian to Cretaceous strata show peaks at 1.9 Ga and 2.5 Ga. Early Paleozoic and Neoproterozoic peaks are back in Upper Triassic to Cretaceous rocks. A Mesozoic peak with negative εHf(t) values occurs in Cretaceous rocks. In terms of the sources of detrital zircon, the South Qinling Belt and Yangtze Block are major contributors for Silurian strata; South Qinling and North Qinling belts are major sources for Lower Devonian to upper Carboniferous rocks; early Carboniferous detrital zircon related to subduction of Mianlue oceanic slab emerges in upper Carboniferous rocks; North China Block is an important source for Lower Permian to Upper Triassic rocks; Lower Cretaceous strata exhibit diverse provenance, including North Qinling Belt, North China Block, and South Qinling Belt. Provenance changes suggest that the initial spreading of the Mianlue Ocean occurred in the Early Silurian during which the South Qinling Terrane and Yangtze Block had not completely separated. The Mianlue Ocean evolved into a mature stage of spreading in the Early Devonian. Meanwhile, the closure of the Shangdan Ocean took place. The Mianlue Ocean started to subduct in the early Carboniferous. Its final closure occurred in the Late Triassic, leading to uplift and exhumation of Qinling Orogen and cutting off detritus transport from North China Block in the Jurassic. The Qinling Orogen underwent collapse in the late Early Cretaceous.