This study conducts a detailed examination of the characteristics of impact loads in complex triangular areas within liquid tanks via the volume of fluids (VOF) method, with a general understanding of impact loads. By comparing the numerical results with previous experimental data of oblique wedge impacts on water surfaces, the effectiveness of the VOF method was confirmed. Complex dynamic phenomena such as fluid climbing, jet impact, and air cavity effects in corner areas were analyzed through 3D flow characteristics. By examining two types of impacts (a structure impacting fluid and a fluid impacting structure), the equivalence between them is verified. An in-depth exploration of the load characteristics in different areas is conducted by combining the free surface evolution. The multipeak characteristics of the load and synchronicity of the peak loads at different parts are closely related to the phenomenon of the climbing fluid being obstructed. Bubble flow also plays a crucial role in affecting the load characteristics. Further exploration of the effects of structural motion on load characteristics reveals complex load variability. These findings provide a valuable reference for understanding the impact loads in complex corner areas of liquid tanks.