Number Of Hydroxyl Groups Research Articles

Flexible chitosan-graphene oxide-based biomacroporous cryogel via grafting cryopolymerization for selective recovery of myricetin from food sample.

Myricetin has a significant role in pharmacology, specifically in traditional Chinese medicine. The most intriguing pharmacological action of myricetin consists of its multi-pathway anticancer effects. Therefore, rapid and selective isolation of myricetin from garlic and apple juices has notable pharmacological benefits. Chitosan-graphene oxide-based biomacroporous cryogel are highly efficient and environmentally friendly materials for adsorption. The current study involved the synthesis of chitosan-graphene oxide-based biomacroporous cryogel sorbent for the selective recovery of myricetin. The characterization investigation utilizing SEM, XRD, EDS and FTIR demonstrated the successful synthesis of a chitosan-graphene oxide-based biomacroporous cryogel. Additionally, XPS effectively revealed the interaction of functional groups on the biomacroporous cryogel sorbent with myricetin. The maximum adsorption capacity for myricetin, under optimized conditions, was 167 mg g-1 in 60 min. The equilibrium adsorption capacity was achieved at neutral pH with optimal parameters, and the Freundlich isotherm model was followed. The pseudo-second-order model presented better descriptions of the adsorption process. In addition, the chitosan-graphene oxide-based biomacroporous cryogel exhibited remarkable selectivity: due to involvement of two primary factors: the number of hydroxyl-groups and the fact that the extra hydroxyl group at position 5' in ring B allows for a more noticeable transfer of the unshared electron pair from oxygen to the π system of the B ring. The adsorption of myricetin decreases to 2 % after three consecutive cycles, indicating the significant reusability of chitosan-graphene oxide-based biomacroporous cryogel. Additionally, the chitosan-graphene oxide based-biomacroporous cryogel that was produced has been utilized after one month and shown a comprehensive shelf-life. Typical adsorption mechanisms include hydrogen bonding and demonstrates significant potential for the efficient and specific isolation of myricetin in complex mixtures. Furthermore, the chitosan-graphene oxide-based biomacroporous cryogel demonstrated a significant rise in recovery of myricetin flavonoid in real samples of garlic and apple juices, rising from 99.66 % to 114.29 %.

Phenolic Resin-type Microporous Organic Polymers for High-Performance Carbon Capture.

Three new types of Si-centered porous organic polymer (Si-POPs) were successfully prepared using phenolic resin-type chemistry to form C-C bonds. This new family of microporous Si-POPs manifests as uniform, microporous, spherical particles with a high specific surface area. Notably, Si-POPs were engineered to possess varying numbers of hydroxyl (-OH) groups by altering the monomer in the synthetic process. Among these materials, the variant with the highest number of hydroxyl groups exhibited ultra-high CO2 adsorption capacity, reaching up to 4.3 mmol g-1 at 273 K and 1.0 bar, which surpasses the performance of most porous polymers. Furthermore, Si-POPs also demonstrated remarkable selectivity adsorption for carbon dioxide over nitrogen (17-50, IAST at 273 K and 1.0 bar). This study not only highlighted the superior CO2 adsorption properties of Si-POPs but also explored their potential application in selective CO2 adsorption.

Toward sustainable bioproducts from lignocellulosic biomass: Influence of chemical pretreatments on liquefied walnut shells

Abstract The depletion of resources and the generation of significant waste pose considerable environmental challenges. Post-utilization of walnut kernels leaves behind substantial amounts of shells as the unused residue. Walnut shells find application in various production processes, offering an opportunity to mitigate environmental impacts through resource utilization. This study investigates the influence of chemical pretreatment on the properties of liquefied lignocellulosic biomass, specifically focusing on walnut shells as a prominent lignocellulosic material. The results reveal that samples subjected to alcohol pretreatment exhibited the lowest degree of liquefaction (85.00% at 120°C for 45 min), while the highest degree of liquefaction was observed in samples after alkaline pretreatment (90.76% at 90°C for 15 min). Analyzing functional groups in liquefied walnut shell biomass, formed during the addition of polyhydric alcohols, glycols, and organic acids, underscores its potential for diverse bioproducts. Pretreatment significantly increases the hydroxyl (OH) number, irrespective of the type, temperature, and duration of chemical pretreatment. Compared to the untreated sample, alkali pretreatment produces the highest OH number (1288.03 KOH/g), surpassing mean values after acid and alcohol pretreatment. The results highlight the efficacy of chemical pretreatment in tailoring the properties of liquefied walnut shell biomass, addressing the challenges associated with resource depletion and waste accumulation.

Hybrid in-situ and ex-situ hydrolysis of catalytic epoxidation neem oil via a peracid mechanism

The depletion of oil reserves and their price and availability volatility raise researchers’ concerns about renewable resources for epoxidized material. This study aims to produce in situ and ex-situ hydrolyzed dihydroxy stearic acid via the epoxidation of neem oil. Epoxidized neem oil was synthesized using in situ-generated performic acid. The Taguchi method was employed to optimize hydrolysis, aiming for maximum production of dihydroxystearic acid. The Taguchi method’s signal-to-noise (S/N) ratio analysis identified optimal conditions for producing dihydroxy stearic acid with a maximum hydroxyl value of 129.4 mg KOH/g: (1) water/neem oil molar ratio of 2:1, (2) water addition time of 90 min, and (3) reaction stop time of 120 min. ANOVA revealed the significant order of parameters as reaction stop time > water addition time > water/neem oil molar ratio. Lastly, a mathematical model was developed using MATLAB, applying the fourth-order Runge–Kutta method and simulated annealing optimization to determine the best-fitting kinetic model. This research aids in transforming neem oil into a value-added product, reduces petroleum dependence, and provides key insights into reaction kinetics for industrial applications.

Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement.

In recent years, hydroxyborates with excellent properties have attracted much attention. Through dedicated efforts, three new hydroxyborates-K2B5O8(OH), CsB5O6(OH)4, and CsB5O7(OH)2-have been successfully synthesized in a closed system. The ultraviolet (UV) cut-off edges of both K2B5O8(OH) and CsB5O7(OH)2 are below 200 nm, indicating their potential as candidates for deep-ultraviolet (DUV) materials. Furthermore, K2B5O8(OH) exhibits nonlinear optical (NLO) activity and demonstrates significant second harmonic generation (SHG) effects, approximately 2 × KH2PO4 (KDP). Interestingly, although all three compounds are alkali metal borates containing five boron atoms, the calculated birefringence is 0.025 at 1064 nm for K2B5O8(OH), whereas it is 0.067 and 0.070 at 1064 nm for CsB5O6(OH)4 and CsB5O7(OH)2, respectively, which are about three times that of K2B5O8(OH). The reason for the nearly threefold difference in birefringence is analyzed from the view of the structure-property relationship. Furthermore, the effect of the number of hydroxyl groups and shared oxygen atoms on the structural dimensions, birefringence, and band gaps in all alkali and alkaline-earth metal hydroxyborates with five boron atoms has been studied and analyzed. A solid foundation for the use of hydroxyl groups to tune and design structures has been provided.

INFLUENCE OF THE COMPOSITION AND STRUCTURE OF HYDROXYLCONTAINING SURFACTANTS ON THE PROCESS OF ELECTROCHEMICAL TIN‒ BISMUTH ALLOY DEPOSITION

The possibility of electrochemical deposition of tin‒bismuth alloy with an increased tin quota which is in demand for microassembly in electronics was revealed. Modification of the acid EDTA electrolyte with hydroxyl-containing surfactants differing in the length of hydrocarbon chain and the number of hydroxyl groups provided the deposition of Sn–Bi alloys with tin content 36.0–63.0 wt.%. in the presence of 1,4-butyndiol (BD), and up to 80.0 wt.% using polyvinyl alcohol (PVA-10) or a product of processing a mixture of alkylphenols with ethylene oxide (OP-10). The reasons for different surfactants action were found. PVA-10 and OP-10, unlike BD, slow down the diffusion of Bi(III) ions by 3‒4 times. All surfactants accelerate the diffusion of Sn(II) ions, which is especially noticeable in the case of BD. This effect of BD is due to its complexation with Sn(II) ions instead of EDTA, as a result of which the diffusion of positively charged particles to the cathode is accelerated.

Research Progress on the Application of Nanocellulose in Glucose Sensing.

Nanocellulose is not only a biocompatible and environmentally friendly material but also has excellent mechanical properties, biodegradability, and a large number of hydroxyl groups that have a strong affinity for water. These characteristics have attracted significant attention from researchers in the field of glucose sensing. This review provides a brief overview of the current research status of traditional materials used in glucose sensors. The sensing performance, chemical stability, and environ-mental properties of nanocellulose-based glucose sensors are compared and summarized based on the three sensing methods: electrochemical sensing, colorimetric sensing, and fluo-rescence sensing. The article focuses on recent strategies for glucose sensing using nanocel-lulose as a matrix. The development prospects of nanocellulose-based glucose sensors are also discussed. Nanocellulose has outstanding structural characteristics that contribute signifi-cantly to the sensing performance of glucose sensors in different detection modes. However, the preparation process for high-quality nanocellulose is complicated and has a low yield. Furthermore, the sensitivity and selectivity of nanocellulose-based glucose sensors require further improvement.

Linear and branched alkyl chain modification of PF resin: Synthesis, pyrolysis and ablative performance at high heat flux

Alkyl modified phenolic resins were synthesized by acid catalyzed etherification of Phenol formaldehyde resin (PF) using linear (n-propyl-NPA and n-butyl-NBA) and branched (iso-propyl-IPA and t-butyl-TBA) chain alcohols and characterized. Spectroscopic characterization (FTIR and 1H NMR) and hydroxyl value revealed the extent of etherification to be ca. 10-13%. Enthalpy of curing was not significantly varied with etherification from the control PF resin. Mechanical property evaluation indicated an increase in elongation by 60-80 %. Glass transition temperature was about 135-144 °C vis- a- vis 148 °C for the unmodified PF resin. Thermal stability of the synthesized PF resins was not significantly altered and a marginal improvement in char residue (PF- 49 % and alkyl modified PF- 54 -57 %) was observed at 900 °C. Low density carbon composites (0.70 g/cc) were processed using these PF resins as matrix resins and porous graphitic felt as reinforcement and evaluated their thermal and ablative characteristics. Alkyl modification improved the wettability of the graphitic felt and a reduction in backwall temperature was observed when the cured composites were subjected to Plasma arc jet at 220 W/cm2 at the end of 500 seconds.

Effects of Polyol Types on Underwater Curing Properties of Polyurethane.

This study aims to develop castable polyurethane suitable for applications on wet substrates or underwater construction. Polyurethanes were synthesized using various polyols with similar hydroxyl values, including poly(tetrahydrofuran) polyol, polyester polyol, castor oil-modified polyol, soybean oil-modified polyol, and cashew nut shell oil-modified polyol. The corresponding polyurethane curing products were evaluated for their underwater curing characteristics by volume expansion ratios and adhesion strength on dry and wet substrates, combined with analyses of reaction exothermic behavior, wetting properties on dry and wet substrates, interfacial tension, and microstructure characterization from the perspectives of reaction activity and water solubility. The results indicate that polyols with higher hydrophobicity and reactivity to isocyanates lead to reduced side reactions during underwater curing, making them more suitable for underwater applications. Soybean oil-based and cashew nut shell oil-based polyurethanes exhibited fast curing (gel times of 1.15 and 1.35 min, respectively), minimal volume change (within 2.5% after 7 days underwater), and strong wet adhesion (1.95 MPa and 2.38 MPa with minimal loss, respectively). The two polyols showed different mechanical properties, providing tailored options for specific underwater engineering applications.

Solvent-Responsive Glass Transition Behavior of Polyelectrolyte Complexes.

Polyelectrolyte complexes (PECs) have attracted considerable attention owing to their unique physicochemical properties and potential applications as smart materials. Herein, the glass transitions of PECs solvated with varying alcohols are investigated in poly(diallyldimethylammonium)/poly(acrylic acid) (PDADMA/PAA) complexes by using modulated differential scanning calorimetry (MDSC). Solvents with one or two hydroxyl groups are selected to examine the effect of PAA-solvent interactions on the glass transition temperature (T g). Except for glycerol, all alcohol solvents yield PECs with detectable T g's and plasticization behavior. Furthermore, a linear relationship for 1/T g and the natural logarithm of the number of hydroxyl groups to intrinsic ion pair ratio [ln(n hydroxyl/n intrinsic-ion-pair)] is found. This result is significant because prior work demonstrated the relationship only for water and no other solvents. All-atom molecular dynamics (MD) simulations analyze the ability of the solvent to form hydrogen bonds via the solvent's OH groups to the PAA, revealing that the solvent molecule size and available hydroxyl groups govern the change in the glass transition. Overall, the clear dependence of a PEC's glass transition on the solvent's chemical structure provides a simple guideline for predicting their relationship.

The Catalytic Degradation of Waste PU and the Preparation of Recycled Materials.

In this paper, we investigated the efficient metal-free phosphorus-nitrogen (PN) catalyst and used the PN catalyst to degrade waste PU with two-component binary mixed alcohols as the alcohol solvent. We examined the effects of reaction temperature, time, and other factors on the hydroxyl value and viscosity of the degradation products; focused on the changing rules of the hydroxyl value, viscosity, and molecular weight of polyols recovered from degradation products with different dosages of the metal-free PN catalyst; and determined the optimal experimental conditions of reaction temperature 180 °C, reaction time 3 h, and PN dosage 0.08%. The optimal experimental conditions were 180 °C, 3 h reaction time, and 0.08% PN dosage, the obtained polyol viscosity was 3716 mPa·s, the hydroxyl value was 409.2 mgKOH/g, and the number average molecular weight was 2616. The FTIR, 1H, NMR, and other tests showed that the waste urethanes were degraded into oligomers successfully, the recycled polyether polyols were obtained, and a series of recycled polyurethanes with different substitution ratios were then prepared. A series of recycled polyurethane materials with different substitution rates were then prepared and characterized by FTIR, SEM, compression strength, and thermal conductivity tests, which showed that the recycled polyurethane foams had good physical properties such as compression strength and apparent density, and the SEM test at a 20% substitution rate showed that the recycled polyol helped to improve the structure of the blisters.

Effect of Chemical Structure and Apparent Density of Rigid Polyurethane Foams on the Properties of Their Chemical Recycling Products.

The aim of this work was to synthesize polyurethane foams based on petrochemical polyols and biopolyols with specific apparent densities (40, 60, 80, 100, and 120 kg/m3), test their properties, glycolyze them, and finally analyze each glycolyzed product. The petroleum-based foams, used as reference foams, and the bio-based foams underwent a series of standard tests to define their properties (the content of closed cells 20-95%, compressive strength 73-1323 kPa, thermal conductivity 24-42 mW/m∙K, brittleness 4.6-82.9%, changes in linear dimensions < 1%, and water absorption < 1%). Taking into account the need for recycling, the foams were shredded and then glycolyzed by diethylene glycol, with the addition of a catalyst in the form of potassium hydroxide. The chemolysis products were analyzed through determination, i.e., the amine and the hydroxyl values, viscosity, and molecular weight. The obtained rebiopolyols had hydroxyl numbers ranging from 476 to 511 mg KOH/g. The type of biopolyol used in the PUR foam systems had a significant impact on the amine number and the viscosity of the obtained rebiopolyol.

Relationship between wettability of cotton and dyeing properties of reactive dyes in a non‐aqueous medium system

AbstractHerein, we initially used sodium hydroxide to pretreat cotton fabric to obtain different wettability. Then the non‐aqueous dyeing system was applied to the eco‐friendly dyeing and washing process of cotton fibre. Meanwhile, Fourier‐transform infrared (FTIR) spectrometry and zeta potential analysis were performed to analyse the difference of cotton fibres before and after pretreatment. Furthermore, the effect of pretreatment on the adsorption behaviour was investigated by molecular dynamic (MD) simulations. Compared with control cotton, an approximate increase of 23.0% in the colour strength (K/S) value was achieved. Findings from FTIR and zeta potential showed that the number of available hydroxyl groups of cotton involved in the dyeing increased after pretreatment. MD simulations demonstrated reactive dye molecules showed a faster adsorption behaviour on the fibre surface with good wettability. It was attributed to the increased interaction energy between dye molecules and cotton fibres. Therefore, improving the cotton fabric's wettability is an effective way to improve the utilisation rate of reactive dyes in a non‐aqueous medium dyeing system.

Recycling of rigid polyurethane foams via acidolysis

The primary objective of this research is to advance our understanding of the recycling of polyurethane foams (PUF) through the process of acidolysis, with the specific focus on evaluating the potential of recovering rigid PUF waste. Drawing from the prior investigations on acidolysis of flexible PUF waste, we extended our research to the depolymerization of rigid PUF using succinic acid. The resulting recycled polyol (RP) exhibited comparable characteristics to the RP derived from flexible PUF. This similarity was confirmed by Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) analyses, as well as by examining the hydroxyl number (OHnumber) and acid value (AV) of the ensuing RP. Subsequently, rigid foams were produced using the RP as a partial replacement of the conventional polyol. The assessments of the PUF obtained revealed that this substitution did not compromise the morphology nor the physical properties of the foams. This was verified by scanning electron microscope (SEM) analyses, mechanical tests, and thermogravimetric analyses (TGA). In summary, our findings indicate that acidolysis is a viable method for recycling both flexible and rigid PUF, underscoring the growing significance of this recycling technique for the development of more sustainable materials.

Multifunctional Conjugated Polyphenol "Bridge" Capped the Upper Interface of Highly Efficient and Stable Inorganic Perovskite Solar Cells Fabricated in Air.

Carbon-based all-inorganic perovskite solar cells (C-PSCs) are promising alternatives compared with conventional organic-inorganic halide PSCs because of their good thermal stability. However, low carrier transport efficiency and energy level mismatch of the upper interface of the device limit the further improvement of power conversion efficiency (PCE), and all-inorganic perovskites are extremely sensitive to oxygen and humidity, which seriously damages the long-term stability of the device. Upper interface modification is an effective solution to improve the PCE and the stability of devices. Unfortunately, many traditional interface modifiers exhibit insulated and hygroscopic characteristics, which may be harmful to the performance of the device. Herein, a multifunctional conjugated polyphenol "bridge" strategy was adopted on the upper interface of the device fabricated in air, that is, stilbene and polyhydroxy stilbene were capped on perovskite. The results demonstrate that they can effectively enhance the energy level alignment, improve charge transport, passivate defects, suppress nonradiative recombination of interface, and resist oxygen and moisture in air, and the positive effects of modification become more and more pronounced with the increment of the number of hydroxyl groups. The PCE of PSCs was improved from 11.10 to 13.10% after modification. In addition, the unencapsulated modified devices exhibited better stability than the control devices under different environmental conditions.

Relationship Between the Structure of the Flavone C-Glycosides of Linseed (Linum usitatissimum L.) and Their Antioxidant Activity.

Flavonoids have been documented to have good antioxidant activities in vitro. In recent years, reports on the antioxidant activities of flavone C-glycosides, a subclass of flavonoids, have attracted great attention. Despite the wealth of information on this subject, the correlation between structure and function is not well understood. In this work, the relationship between the structure and the antioxidant activity of 12 flavone C-glycosides extracted from the aerial part of winter linseed (Linum usitatissimum L.) was studied to fill the current gaps. Orientin, isoorientin, vitexin, isovitexin, swertisin, swertiajaponin, carlinoside, schaftoside, lucenin-1, lucenin-2, vicenin-1, and vicenin-2 were purified by preparative HPLC and by the drowning-out crystallization method. Then, the control of the purity and the confirmation of the chemical structures were assessed by LC-MS and NMR analyses. The antioxidant activity was evaluated using ABTS, CUPRAC, FRAP, and iron chelating activity in vitro assays. Luteolin and its flavone C-glycoside derivatives exhibited higher antioxidant activity than apigenin and its flavone C-glycosides derivatives. This could be attributed to the ortho-dihydroxyl groups at C-3' and C-4' of the B ring in the flavonoid skeleton, which seemed to play an important role in antioxidant behavior. These results indicate that the antioxidant activity of these compounds, derived from apigenin and luteolin, can be closely related to their structural characteristics, including the position and nature of the sugars, the number of hydroxyl groups, and the presence of methyl group.

Environmentally friendly shape memory biofoams

AbstractSearching for renewable raw materials that would comply with the requirements of Green Chemistry and the assumptions of sustainable development is an ongoing and important problem. In the present article, an attempt was made to obtain biopolyols from selected solid plant fats, i.e., babassu, cocoa, coconut, mango, palm, or shea oil. In the research performed, modification of plant oil was provided by a one-step and solvent-free transesterification method, to obtain biopolyols characterized by hydroxyl numbers from 360 to 460 mgKOH/g. Biopolyols from plant oils were subsequently used to obtain polyurethane viscoelastic foams (PUVFs). Biopolyols were applied in the amount of 10%, 20%, and 30% relative to the total weight of the polyols used to prepare PUVFs. The obtained materials were characterized by an apparent density of about 100 kg/m3, a hardness of about 2–3 kPa, a comfort factor of about 2.5, and a resilience of less than 10%, which may be interesting to the industrial sector for applications such foams as the materials able to energy absorbing. The study analyzed the effect of the chemical structure of the oils on the physicochemical properties of the obtained biopolyols, as well as the physical and mechanical properties of PUVFs.

Interlaced Composite Membranes by Charge-Induced Alternating Assembly of Monolayer Cationic COF and GO.

The efficient preparation of two-dimensional large-sized monolayer covalent organic framework (COF) nanosheets for highly permeable membranes has posed a long-standing challenge in the COF field. While the self-exfoliation of charged COFs represents a promising method for nanosheet production, its efficiency requires further enhancement. In this study, we present a novel finding that the presence of hydroxyl groups on the monomer significantly influences the self-exfoliation efficiency of charged COFs. Through precise regulation of hydroxyl group numbers on the monomers, we successfully achieved the efficient fabrication of large monolayer cationic COF nanosheets with impressive solubilities in common organic solvents. By virtue of their positive charge, COF monolayer nanosheets rapidly interacted with negatively charged monolayer graphene oxide (GO) in solution, facilitating their assembly into interlaced composite membranes through electrostatic interactions. The composite membranes benefited from the strong Coulombic attraction between the COF and GO nanosheets, leading to enhanced membrane stability, while the shielding effect of GO on the COF pores contributed to improved size sieving efficiency. This innovative strategy enabled the composite membranes to achieve highly selective separation of ReO4- and MoO42-, with a remarkable 100% interception rate for MoO42-.

High-performance bio-based foam from agricultural waste luffa seed oil polyols

The present study aimed to develop eco-friendly polyurethane viscoelastic foam (PVF) with enhanced tear strength while preserving softness, comfort, and safety by utilizing bio-based polyols derived from luffa seed oil (LSO). Two types of bio-based polyols (PLSO-D and PLSO-M) were synthesized through the epoxidation process using diethylene glycol (DEG) and methanol (MeOH), respectively, for the production of LSO-based polyurethane viscoelastic foams (LSO-PVFs). The analyses revealed that these polyols exhibited high dispersion, appropriate hydroxyl values, and contained by-products such as oligomeric esters of fatty acids that facilitated physical and chemical crosslinking. LSO-PVFs demonstrated a uniform and fine cell structure with abundant open-cells, thick cell walls (55.5–76.6µm), and high apparent density (48.7–50.7kg/m3). Moreover, they exhibited enhanced tensile and tear strength (increasing up to 200% compared to petroleum-based PVFs), lower water absorption, excellent mildew resistance at 10% PLSO substitution. Additionally, these factors endowed LSO-PVFs with low indentation hardness and good bottom support performance, characterized by a compressive deflection coefficient of 2.30–3.54. This approach presents a sustainable alternative for foam production that offers comfort, durability while promoting the value-added utilization of agricultural waste.

A New Strategy for the Preparation of High‐Strength Hydrophobic Aldehyde‐Free Starch Adhesive

ABSTRACTStarch adhesives are often used in the plywood sector. They are sustainable, formaldehyde‐free, and biodegradable. However, the problems of poor gluing strength and hydrophobicity need to be overcome. In this study, natural starch was oxidized by sodium persulfate to obtain oxidized starch. Oxidized starch adhesive (SSA‐15%) was crosslinked with PVA. The results show that the dry and wet shear strength of the prepared oxidized starch adhesive (SSA‐15%) can reach 2.95 MPa and 1.31 MPa, which is 163% and 120% higher than that of the natural starch adhesive. Sodium persulfate causes the large number of hydrophilic hydroxyl groups in starch to oxidize directly to carboxyl groups, improving the hydrophobicity of starch. The hydroxyl group present in oxidized starch interacts with the secondary hydroxyl group in PVA to form a hydrogen bond. This interaction enhances the adhesive bonding performance, resulting in improved mechanical properties and increased bonding strength of the final products, while also contributing to the formation of a more robust network structure. The study showed that the oxidized adhesive has good hydrophobicity and storage thermal stability. It is a simple and green biomass wood adhesive, which provides theoretical support for the promotion and application of aldehyde‐free adhesives.