Nucleation Stage Research Articles

The effects of precursory velocity changes on earthquake nucleation and stress evolution in dynamic earthquake cycle simulations

Seismic velocity changes in earthquake cycles have been observed over a wide range of timescales and may be a good indicator of the onset of future earthquakes. Understanding the effects of precursory velocity changes right before seismic and slow-slip events could potentially elucidate the onset and timing of fault failure. We use numerical models to simulate fully dynamic earthquake cycles in 2D strike-slip fault systems with antiplane geometry, surrounded by a narrow fault-parallel damage zone. By imposing S-wave velocity changes inside fault damage zones, we investigate the effects of these precursors on multiple stages of the seismic cycle, including nucleation, coseismic, postseismic, and interseismic stages. Our modeling results show a wide spectrum of fault slip behaviors including fast earthquakes, slow-slip events, and variable creep. One primary effect of the imposed velocity precursor is on the earthquake nucleation phase, and earlier onset of precursors causes earthquakes to nucleate sooner with a smaller nucleation size that is not predicted by theoretical equations. Furthermore, such precursors affect the nucleation of dynamic earthquakes and slow-slip events. Our results highlight the importance of short- and long-term monitoring of fault zone structures for better assessment of regional seismic hazard.

Insights into Early Phases of Phycocyanin Crystal Formation via SONICC Spectroscopy

This research delves into the early nucleation stages of phycocyanin, a protein pivotal for its fluorescent properties and crystalline stability and holding considerable potential for biotechnological applications. The paper contrasts traditional crystallization methods with the innovative Langmuir–Blodgett nanotemplate approach, aiming to enhance molecular assembly and nucleation processes. The study employs Langmuir–Blodgett nanotemplates alongside second-order nonlinear imaging of chiral crystal (SONICC) spectroscopy. This combination is designed to orderly organize phycocyanin molecules and provide a sensitive visualization of early-stage crystal formation, capturing the intricate dynamics of protein crystallization. The experiments were conducted under controlled conditions, where surface pressure was maintained at 26 mN/m and barrier speed at 70 cm/min to optimize the monolayer formation at the air–water interface. The Langmuir–Blodgett method, compared to traditional vapor diffusion techniques, shows improvements in the uniformity and efficiency of nucleation. The sensitivity of SONICC spectroscopy significantly enhances the visualization of the nucleation process, revealing a more structured and uniform crystalline assembly in the early stages of formation. This method demonstrates a substantial improvement in nucleation dynamics, leading to a more orderly growth process and potentially larger, well-ordered crystals. Integrating Langmuir–Blodgett nanotemplates with SONICC spectroscopy offers a significant step in understanding protein crystallization processes with insights into the nucleation and growth of protein crystals and broad implications for refining crystallography methodologies of protein-based biomaterials, contributing to the advancement of structural biology and materials science.

Mechanisms of grain boundary α precipitation in the metastable β-titanium Ti-5Al-5Mo-5V-3Cr

In this study, we investigated the early nucleation and growth of grain boundary α during the aging heat treatment of Ti-5553. Through a correlative approach using scanning electron microscopy, electron backscatter diffraction, transmission Kikuchi diffraction, transmission electron microscopy, and atom probe tomography, high-angle β-grain boundaries were investigated in detail to understand the evolution of the precipitation of grain boundary α through nucleation and subsequent growth. It is found that at grain boundaries there is a pronounced nucleation of α precipitates with similar orientations. Growth of these similarly orientated α precipitates, in the later stages, leads to their agglomeration and the formation of grain boundary α. This investigation provides insights into the formation of grain boundary α in its early stages of nucleation and growth.

Calcium ions promote migrasome formation via Synaptotagmin-1.

Migrasomes, organelles crucial for cell communication, undergo distinct stages of nucleation, maturation, and expansion. The regulatory mechanisms of migrasome formation, particularly through biological cues, remain largely unexplored. This study reveals that calcium is essential for migrasome formation. Furthermore, we identify that Synaptotagmin-1 (Syt1), a well-known calcium sensor, is not only enriched in migrasomes but also indispensable for their formation. The calcium-binding ability of Syt1 is key to initiating migrasome formation. The recruitment of Syt1 to migrasome formation sites (MFS) triggers the swelling of MFS into unstable precursors, which are subsequently stabilized through the sequential recruitment of tetraspanins. Our findings reveal how calcium regulates migrasome formation and propose a sequential interaction model involving Syt1 and Tetraspanins in the formation and stabilization of migrasomes.

Formation of a zirconium oxide crystal nucleus in the initial nucleation stage in aluminosilicate glass investigated by X-ray multiscale analysis

Understanding the nucleation mechanism in glass is crucial for the development of new glass-ceramic materials. Herein, we report the structure of a commercially important glass-ceramic ZrO2-doped lithium aluminosilicate system during its initial nucleation stage. We conducted an X-ray multiscale analysis, and this analysis was used to observe the structure from the atomic to the nanometer scale by using diffraction, small-angle scattering, absorption, and anomalous scattering techniques. The inherent phase separation between the Zr-rich and Zr-poor regions in the pristine glass was enhanced by thermal treatment without changing the spatial geometry at the nanoscale. Element-specific pair distribution function analysis using anomalous X-ray scattering data showed the formation of a liquid ZrO2-like local structural motif and edge sharing between the ZrOx polyhedra and (Si/Al)O4 tetrahedra during the initial nucleation stage. Furthermore, the local structure of the Zr4+ ions resembled a cubic or tetragonal ZrO2 crystalline phase and formed after 2 h of annealing the pristine glass. Therefore, the Zr-centric periodic structure formed in the early stage of nucleation was potentially the initial crystal nucleus for the Zr-doped lithium aluminosilicate glass-ceramic.

Phase-Centric MOCVD Enabled Synthetic Approaches for Wafer-Scale 2D Tin Selenides.

Following an initial nucleation stage at the flake level, atomically thin film growth of a van der Waals material is promoted by ultrafast lateral growth and prohibited vertical growth. To produce these highly anisotropic films, synthetic or post-synthetic modifications are required, or even a combination of both, to ensure large-area, pure-phase, and low-temperature deposition. A set of synthetic strategies is hereby presented to selectively produce wafer-scale tin selenides, SnSex (both x=1 and 2), in the 2D forms. The 2D-SnSe2 films with tuneable thicknesses are directly grown via metal-organic chemical vapor deposition (MOCVD) at 200°C, and they exhibit outstanding crystallinities and phase homogeneities and consistent film thickness across the entire wafer. This is enabled by excellent control of the volatile metal-organic precursors and decoupled dual-temperature regimes for high-temperature ligand cracking and low-temperature growth. In contrast, SnSe, which intrinsically inhibited from 2D growth, is indirectly prepared by a thermally driven phase transition of an as-grown 2D-SnSe2 film with all the benefits of the MOCVD technique. It is accompanied by the electronic n-type to p-type crossover at the wafer scale. These tailor-made synthetic routes will accelerate the low-thermal-budget production of multiphase 2D materials in a reliable and scalable fashion.

Misoriented Lamellar Microstructures in Mo‐Si‐Ti Alloy Due to Asymmetrical Nucleation Distance and Interfacial Energies: A Phase‐Field Analysis

The material properties are crucially affected by the microstructure formed during solidification, which is typically divided into three stages: (I) Early stage of nucleation in molecule scale, which is beyond the scope of the mean‐field model; (II) Middle stage of nucleation, where the dispersed nuclei have formed; (III) Late stage of nucleation, where the nuclei contact with each other. In previous studies, the formation of the stable eutectic lamellae is mostly based on the assumption that a stable solid–solid interface has already been established, corresponding to the stage (III), and the growth stage (II) is often overlooked. In the current work, by varying the nucleation density and distance, an alternative mechanism for the misoriented microstructure formation in Mo‐Si‐Ti alloy is proposed, which considers nucleation stage (II). Furthermore, the misoriention angle as a function of the nucleation density, distance, and the interfacial energies is quantified by systematic phase‐field simulations. The simulated composition distribution reveals the mechanism for the misorientation of eutectic lamellar pairs, which becomes more pronounced when the solids‐fluid interfacial energies are unequal. It is expected that the present work provides a potential perspective for the fundamental understanding of misoriented microstructures in solidification.

Bubbles Management for Enhanced Catalytic Water Splitting Performance

Water splitting is widely acknowledged as an efficient method for hydrogen production. In recent years, significant research efforts have been directed towards developing cost-effective electrocatalysts. However, the management of bubbles formed on the electrode surface during electrolysis has been largely overlooked. These bubbles can impede the active sites, resulting in decreased catalytic performance and stability, especially at high current densities. Consequently, this impediment affects the energy conversion efficiency of water splitting. To address these challenges, this review offers a comprehensive overview of advanced strategies aimed at improving catalytic performance and mitigating the obstructive effects of bubbles in water splitting. These strategies primarily involve the utilization of experimental apparatus to observe bubble-growth behavior, encompassing nucleation, growth, and detachment stages. Moreover, the review examines factors influencing bubble formation, considering both mechanical behaviors and internal factors. Additionally, the design of efficient water-splitting catalysts is discussed, focusing on modifying electrode-surface characteristics. Finally, the review concludes by summarizing the potential of bubble management in large-scale industrial hydrogen production and identifying future directions for achieving efficient hydrogen production.

In-situ formation of AlN nanoparticles in NiAl-strengthened ferritic alloy with enhanced high-temperature mechanical properties via SLM fabrication

A ferritic alloy strengthened by in-situ formed AlN and B2–Ni(Al, Mn) nanoparticles was designed using thermodynamic computational and formed via selective laser melting (SLM) fabrication. Uniformly dispersed B2–Ni (Al, Mn) and hexagonal wurtzite AlN nanoparticles in the ferritic alloy were observed by transmission electron microscopy (TEM). The incorporation of AlN nanoparticles significantly improved high-temperature performance of the alloy. The crystallographic orientation relationship (101‾0)Wurtzite//(101)α−Fe and [0001]Wurtzite//[1‾11]α−Fe between hexagonal wurtzite AlN and α-Fe was identified. Furthermore, Fe/AlN interfaces were analyzed by first-principles calculations. The results suggested that hexagonal AlN is more stable, while cubic AlN tends to precipitate in the early stages of nucleation due to its low strain energy and transforms into hexagonal AlN during prolonged heat treatment. As a result, this integrated approach provides insights into achieving superior high-temperature performance in the ferritic alloy.

Mechanism underlying effects of CaO-MgO combined expansive agent on hydration kinetics of cement-based systems

With the order of better understanding the early hydration process and reaction mechanism of CaO-MgO combined expansion agent-involved cement-based systems (CMEA-CBS), CMEA dosage, CaO to MgO ratio (Ca/Mg), MgO activity, hydration temperature, and water-binder ratios (w/b) were chosen as the influencing factor. Accordingly, isothermal calorimetry was implemented to analyze the hydration heat release law, and the Krstulovic–Dabic model was applied to investigate the hydration kinetic. Moreover, the activation energy of CMEA-CBS was calculated. The findings of this study are as follows. The incorporation of CMEA can accelerate the hydration of cementitious systems. Hydration temperature increase markedly promote the hydration reaction of CMEA-CBS. The hydration reaction of CMEA-CBS is a complex associated reaction process dominated by multiple reaction mechanisms in sequence. At both 20 °C and 45 °C, the hydration process of CMEA-involved cement-based systems experienced three stages of crystallization nucleation and crystal growth (NG), phase boundary reaction (I), and diffusion (D), and the hydration mechanism was NG → I → D. However, the hydration of CMEA-CBS at 65 °C switched from the NG stage to the D stage directly. The hydration promotion effect of increasing temperature on I and D process of CMEA-CBS is less than I and D process of pure cement. Compared to the other groups, the temperature increase had the least effect on the early hydration process of 10%-C1M1-M-0.4 with the lowest apparent activation energy.

The beneficial effect of lauric acid addition in nucleation stage on the soot catalytic combustion performance of cerium-manganese catalyst

For cerium-manganese catalyst system, increasing the threshold of the amount of Mnx+ entering into the CeO2 lattice can generate more oxygen vacancies and adsorb more active oxygen species, thus promoting its soot catalytic combustion. However, this is difficult to achieve under the premise of fixed cerium-manganese ratio of the catalyst. Fortunately, the results of this study show that the addition of lauric acid at the nucleation stage of the cerium-manganese catalyst can effectively improve its activity and high temperature aging resistance. Combined with a series of characterization results, the addition of lauric acid can increase the threshold of Mnx+ content in CeO2 lattice, improve the structural performance of the catalyst, increase the specific surface area and pore volume of the catalyst, inhibit the secondary aggregation of catalyst particles, increase the content of surface Ce3+, increase the low temperature reduction performance and the content of surface chemical desorbed oxygen of the catalyst. In addition, it can also prevent the phase separation of cerium-manganese solid solution, the growth of grains, the increase of reduction peak temperature and the decrease of H2 consumption during high temperature aging. Moreover, the addition of lauric acid also greatly improves the release performance of active oxygen in cerium-manganese catalyst. Therefore, this study plays a positive role in promoting the commercial application of highly active cerium-manganese catalyst.

Synthesis of layered double hydroxides: Investigating the impact of stirring conditions and reactor design parameters

The synthesis by coprecipitation of Layered Double Hydroxides (LDHs) is governed by the stages of nucleation and crystal growth associated with the efficiency of the mixing and dispersion process of the reagents. Mixing efficiency is related to process variables, such as agitation speed, type of impeller and baffles presence, among others. In this context, this work proposes an analysis of these variables in a batch reactor, using a 23 factorial design employing the factors: acceleration speed (200 and 1000 rpm), mixing time (2 and 18 h) and presence or absence of baffles. The results were evaluated quantitatively (amount of LDH produced, time and amount of base for the formation of LDHs to begin) and qualitatively (mixing aspects, sedimentation ad grinding). The significant factors affecting the amount of LDH produced (51.94–80.81 g) were agitation speed and aging time. These factors were also correlated with the structural characteristics of the materials produced, such as crystallinity, crystallite size (70.99–174.79 nm), surface area (69.81–97.62 m2/g), pore volume (0.28–0.59 cm3/g), and pore diameter (11.40–34.66 nm). LDHs produced at higher agitation rates (1000 rpm) and longer aging times (18 h) yielded higher quantities of materials (80.81 g) with improved structural characteristics. The study highlights the importance of systematically exploring the synergistic effect between process variables, emphasizing the research potential in this area.

Ultrasonic cavitation-modulated nanocrystal facets growth of zinc-based oxide

In this study, in situ detection of the transient cavitation intensity during the sonochemical synthesis of Zinc-based Oxide (ZBO) is realized. At a fixed ethanol/water ratio of 25%, the transient cavitation intensity initially increases to a certain level during the nucleation stage of ZBO since the growth units of ZBO serve as supplementary induction sites for transient cavitation bubbles. Once the process surpasses the critical supersaturation point of ZBO growth units, a decrease of transient cavitation intensity is observed because the formation of massive ZBO nanocrystals may cause ultrasonic scattering attention. As a result, high-aspect-ratio ZBO nanorods are formed due to the preferential growth along the [001] direction. In addition, by increasing the ethanol/water ratio, a similar but decreasing trend in the time-dependent transient cavitation intensity during the ZBO synthesis process is obtained. This results in fewer ethanol molecules detaching from the ZBO (001) crystal surface, due to reduced cavitation bubble explosions, thereby inhibiting ZBO growth along the [001] direction. At an ethanol/water ratio of 75%, a morphological transition from slender nanorods to ultra-thin Zn5(NO3)2(OH)8·2H2O nanoflakes is facilitated. These ultra-thin nanoflakes demonstrate promising photocatalytic performance. This work provides a rational sonochemical approach for synthesizing facet-controlled growth of nanocrystals.

Determination of the process effect on cocoa butter crystallization by rheometer: Kinetic modeling by Gompertz equation.

In this study, the effects of temperature (22, 24, 26, 28, and 30°C) and strain (0.1%, 1%, and 5%) on cocoa butter (CB) crystallization were investigated by oscillatory test, and the four-parameter Gompertz model was used to interpret the effect of parameters on pre-crystallization, nucleation, and crystal growth stages of CB. Lag time and growth rate were calculated using the Gompertz model using time-dependent storage modulus (G') data. According to the results, CB crystallization at 26°C with a 1% strain value had the highest growth rate value, the shortest lag time, and the formation of βv polymorph type. Followingly, polymorphic types of the CB crystals were determined based on the melting points of polymorphs via the temperature ramp step, and the results obtained were correlated with a polarized light microscope. In conclusion, using a rheometer in both the observation of the pre-crystallization process and the determination of polymorph types is very important for research and development studies in the chocolate industry for process and formulation optimization. PRACTICAL APPLICATION: This study demonstrates the feasibility of a novel approach for investigating crystallization and oscillatory shear of CB using a rheometer, both for observing crystallization kinetics and determining polymorph type, accompanied by the Gompertz equation to model the crystallization kinetics. According to the results, the effect of process parameters (temperature and shear) on the crystallization behavior of CB can be observed by rheometer, which can provide a detailed perspective for chocolate manufacturers and researchers in research and development studies.

Co-solvent strategy for highly efficient perovskite solar cells by spray coating

The ultrasonic spray coating has been shown to be an effective technique for scaling up production. The nucleation and crystallization process of the perovskite film prepared by the ultrasonic spraying approach is more complicated than that by the spin coating, but they are essential to gaining efficient perovskite solar cells (PSCs). At the same time, the green solvent is the primary problem that must be solved in the process of PSCs commercialization. In this paper, the low boiling point and green solvent isopropyl alcohol (IPA) is introduced into the perovskite precursor solution to prepare FAPbI3 perovskite by ultrasonic spraying. The addition of IPA enhanced the saturated vapor pressure of the precursor solution, which can create the local chemical microenvironment on the film surface and subsequently retard the nucleation rate from 8.31 s to 8.54 s at nucleation stage. The local chemical improves the initial homogeneity of the sol–gel phase and then leads to improved structural and optoelectronic properties within the FAPbI3 film via sufficient crystallization from the sol–gel phase to α-FAPbI3. Ultimately, IPA-based PSCs exhibit the champion device efficiency of 22.43 %. The good long-term stability of PSCs (maintain more than 90 % of the initial efficiency after 1000 h, and keep 80 % after 400 h) in ambient conditions.

Effect of initial pore water content and salinity on the resistivity of methane hydrate-bearing fine sediments

Methane hydrates are widely distributed in the soft silty-clayey soils of continental margin sediments. The resistivity method is generally used to detect their distribution state and monitor their kinetic reaction process. However, there are some major details to be elaborated on as to the occurrence state and the evolution of key characteristic parameters. Based on the kinetic reaction experiment under different lithological conditions (initial water content and pore water salinity), this research records the changing resistance of natural sand porous medium system during the cooling formation of hydrates by in-situ measurement. The Archie formula is further used to study the influencing factors of the resistance of hydrate-bearing sediments and how the resistance changes during hydrate formation. The results demonstrate that these two lithological parameters can significantly affect the resistivity of the hydrate-bearing natural sand porous media system. It is found that within a certain range, NaCl in pore water will inhibit the formation reaction of hydrates, while an increase of initial water content will enhance the hydrate production amount in the system. With the hydrate formation in the pores, the porosity and skeleton composition of the natural sand porous medium change as well, coupled with the salt-removing effect, which further changes the system resistivity. During hydrate formation, the system resistivity changes regularly in the cooling stage, hydrate nucleation stage, and hydrate formation stage. Our study systematically considers the influence of these geological parameters on resistivity characterization at different reaction stages during the formation of natural hydrates. Thus, it can serve as a technical reference for hydrate reservoir logging and other related issues.

Influence of grain size on twinning behavior of WE43 magnesium alloy during room-temperature compression deformation

In the present study, room-temperature compression experiments and characterization experiments via optical microstructure (OM), X-ray diffractometer (XRD) and electron backscattered diffraction (EBSD) techniques were conducted on WE43 magnesium (Mg) alloy samples to investigate the grain size effect on twinning behavior. Three couples of solution treatments (823 K for 0.5 h, 798 K for 8 h, 823 K for 16 h, followed by water-quenching at ⁓333 K) were adopted and these solutionized samples are with different grain sizes of 48.5, 72.0 and 120.2 μm, respectively. Results show that {10-12} extension twin (ET) and {11-21} ET serve as major twinning modes during plastic deformation. For all 7.7%-deformed samples, although the volume fractions of {10-12} ETs and {11-21} ETs increase with the increasing grain size. {10-12} ETs are in growth stage, while {11-21} ETs are mainly in nucleation stage and they still maintain narrow and parallel to each other. Besides, {10-12} ETs mainly contribute to the rotation of c-axes of grains towards compression direction, while {11-21} ETs mainly contribute to the formation of a nearly ring-shaped texture component in (0002) pole figure. Twin variants analysis with the assistance of Schmid factor (SF) demonstrates that the activation of twin variants mainly obeys Schmid law. When only {10-12} ETs occur in individual grains, the maximum number of twin variants shows some positive relationship with the increasing grain size. By comparison, when both {10-12} ETs and {11-21} ETs occur in individual grains, the maximum numbers of twin variants are rarely influenced by the increasing grain size.

Insights into the Dead Sea Transform Activity through the study of fracture-induced electromagnetic radiation (FEMR) signals before the Syrian-Turkey earthquake (Mw-6.3) on 20.2.2023

Observations of fracture-induced electromagnetic radiation (FEMR) were conducted along the Dead Sea Transform (DST) from Sodom to Jericho, coinciding with a magnitude (Mw) 6.3 aftershock earthquake (EQ) in the Turkey-Syrian region on February 20, 2023. The FEMR parameters (“hits,” Benioff strain release, frequency, rise-time, energy) and associated crack dimensions were analyzed, focusing on trends leading up to the EQ. This study investigated the Benioff Strain plot and other parameters in three consecutive earthquake nucleation stages leading to the catastrophe. The first stage showed increased FEMR hits and frequency, decreased rise time (T′), and crack dimensions. In the second stage, FEMR hits and crack width decreased while other parameters continued to rise, accumulating the second-highest energy, likely due to high-stress drop. The third stage exhibited steadily increasing FEMR hits and energy and a notable increase in crack dimensions, suggesting an imminent macro failure event. The cyclic trend in FEMR hits indicates alternating periods of high activity and silence, potentially linked to stress changes during crack propagation. Taken shortly before the earthquake, these measurements offer valuable insights into how FEMR parameters vary before seismic events, bridging the gap between lab-scale studies of rock collapses under stress and large-scale failure phenomena.

Study on the sintering behavior of the ceramic precursor Daqiuni clay

Daqiuni clay is an aluminosilicate clay with unique properties that make it a promising ceramic precursor. Understanding its sintering behavior is crucial for quality control in manufacturing. This study aimed to investigate the phase evolution, densification process, and reaction kinetics during sintering of Daqiuni clay. A combination of X-ray diffraction (XRD), simultaneous thermogravimetric-differential scanning calorimetry (TG-DSC), scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR) techniques were employed to comprehensively analyse the phase transformations. The densification behavior, apparent activation energies, and reaction mechanisms were elucidated through thermodilatometric analysis conducted at varying heating rates. Four stages were identified during sintering including dehydration, dehydroxylation, mullite formation, and partial melting. The maximum shrinkages at each stage were measured. Kissinger analysis yielded apparent activation energies of 122.90, 258.40, 361.98 and 348.69 kJ/mol for the dehydroxylation, mullite nucleation, mullite growth, and partial melting stages, respectively. The dehydroxylation and partial melting processes followed the mechanisms of 3rd order reaction and 3D diffusion. Mullite formation was a two-step nucleation and growth process following the JMA model. This study clarified the phase evolution of Daqiuni clay during sintering.

Controlling Nucleation and Crystallization of CsPbI3 Perovskites for Efficient Inverted Solar Cells.

The unfavorable morphology and high crystallization temperature (Tc) of inorganic perovskites pose a significant challenge to their widespread application in photovoltaics. In this study, an effective approach is proposed to enhance the morphology of cesium lead triiodide (CsPbI3) while lowering its Tc. By introducing dimethylammonium acetate into the perovskite precursor solution, a rapid nucleation stage is facilitated, and significantly enhances the crystal growth of the intermediate phase at low annealing temperatures, followed by a slow crystal growth stage at higher annealing temperatures. This results in a uniform and dense morphology in CsPbI3 perovskite films with enhanced crystallinity, simultaneously reducing the Tc from 200 to 150°C. Applying this approach in positive-intrinsic-negative (p-i-n) inverted cells yields a high power conversion efficiency of 19.23%. Importantly, these cells exhibit significantly enhanced stability, even under stress at 85°C.