To achieve low‐stress and small‐deformation welding of thin‐walled structures for the fourth‐generation nuclear power plants, GH3535 superalloy is welded to itself using electron beam welding (EBW). The microstructure and mechanical properties of the GH3535 superalloy joints are characterized by scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), hardness, and tensile tests. A macro‐defect‐free GH3535 superalloy joint could be obtained using 22 mA welding beam current under 65 kV welding voltage with 300 mm min−1 welding speed. Different sub‐grain solidification morphologies are observed at the weld zone because of the influence of composition undercooling on the solidification process of the weld pool. The M6C type carbides formed in the weld zone and heat‐affected zone (HAZ) take place eutectic transformation under the action of thermal cycles. The eutectic transformation of M6C has no significant effect on the strength of HAZ, whereas this phenomenon is beneficial to hinder the dislocation movement in the weld zone, thereby promoting the tensile strength of the joint. The Vickers hardness of weld zone and HAZ are 250.6 and 252 HV0.5, remarkably lower than that of the base metal (261.2 HV0.5), due to the grain coarsening in those zones. The tensile strength of the GH3535 superalloy joint reached 791 MPa, ≈93.5% that of the base metal, with the fracture occurred in the weld zone.
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