The numerous coal-fired grate furnaces in China, which were designed to partition primary air on the grate and arrange secondary air in the freeboard for air-staging combustion, suffered from poor burnout and high NOx. However, secondary air was conventionally closed or set at marginal openings in real operations and no investigation was reported to explain why. Upon these off-design secondary-air circumstances, industrial-scale tests and modeling investigations were performed for a 75 t/h coal-fired reversal grate furnace at secondary-air ratios of 0 %, 3 %, 6 %, 10 %, and 16 %, respectively. The primary aims were to (i) uncover its combustion and NOx formation characteristics with varying secondary air and (ii) confirm whether secondary air acted on a real air-staging function in reducing NOx. Flow-field deflection and asymmetric combustion were found in the furnace, with the upward gas entirely deflecting towards the rear side. The front-half furnace was filled with a large but weak recirculation zone without effective combustion, acting on a huge dead zone to waste the furnace-space utilization. With increasing the secondary-air ratio, the upward gas deflection deteriorated continuously. Layer combustion worsened while suspension combustion first strengthened and then weakened. NOx emissions displayed an ascent-to-descent trend. Carbon in slag raised while carbon in fly ash decreased. Among the five case setups, the 0 % setting (i.e., fully closing secondary air) exhibited the lowest NOx emissions and burnout loss. Compared with the habitual 6 % setup, fully closing secondary air not only reduced NOx emissions by 22 % but also improved a little burnout. These trends meant that opening secondary air only strengthened suspension combustion for burning well fly ash while raised both NOx and total burnout loss. Secondary air thus failed to role as an air-staging function in reducing NOx.
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