The notch sensitivity of additively manufactured IN 625 superalloy produces by laser powder bed fusion (LPBF) has been investigated by tensile testing of cylindrical test pieces. Smooth and V-notched test pieces with four different radii were tested both in as-built state and after a stress relief heat treatment for 1 h at 900 °C. Regardless of the notch root radius, the investigated alloy exhibits notch strength ratios higher than unity in both as-built and in stress-relieved states, showing that the additive manufactured IN 625 alloy is not prone to brittleness induced by the presence of V-notches. Higher values of notch strength ratios were recorded for the as-built material as a result of the higher internal stress level induced by the manufacturing process. Due to the higher triaxiality of stresses induced by notches, for both as-built and stress-relieved states, the proof strength of the notched test pieces is even higher than the tensile strength of the smooth test pieces tested in the same conditions. SEM fractographic analysis revealed a mixed mode of ductile and brittle fracture morphology of the V-notched specimens regardless the notch root radius. A more dominant ductile mode of fracture was encountered for stress-relieved test pieces than in the case of the as-built state. However, future research is needed to better understand the influence of notches on additive manufactured IN 625 alloy behaviour under more complex stresses.