Atmospheric aerosol characteristics from the Western Ghats (WG), a region that plays a prominent role in modulating the Indian monsoon, was evaluated to study the impacts of long-range transport, local sources, and cloud processing on their chemical properties. Size-segregated aerosols collected from Ponmudi (8.8°N, 77.1°E), a tropical high altitude location (960 m a.s.l.) in the southern part of the WG, during the continental to marine air-mass transition phase (January–April 2020–2021) were analysed for major chemical components, including carbonaceous species, water-soluble ionic species, metallic elements and aerosol liquid water (ALW). The major aerosol components during the north-east monsoon period were identified as (NH4)2SO4, organic matter, and ALW derived from long-range transported biomass emission plumes undergoing cloud processing and aqueous-phase reactions with SO2. Positive Matrix Factorization (PMF) analysis revealed the presence of aged and mixed aerosol types, with influence from local anthropogenic emissions and secondary formation processes. The source profiles for different air-masses indicate that the IGP air-mass is dominated by anthropogenic continental sources rich in sulphates, while the East Asian air-mass comprises highly aged continental emissions rich in organics and mixed with marine emissions from the Bay of Bengal. Fine mode aerosol mass was reconstructed, and organic matter to organic carbon conversion factor was estimated after mass closure, which revealed relatively high values for East-Asian air-mass, providing evidence for their oxidation during long-range transport. The hill station was also influenced by local urban valley emissions transported to the site via daytime convection and sea-breeze circulation. Consequently, the aerosol system over this region exhibited a complex mixture, with elemental carbon particles coexisting with sea-salt, sulphate, and secondary water-soluble organics. The findings highlight the need for further studies to understand the role of chemically processed and mixed aerosol system in modifying regional climate dynamics and air quality over such sensitive ecosystems.
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