North Atlantic Igneous Province Research Articles

Enhanced continental chemical weathering during the multiple early Eocene hyperthermals: New constraints from the southern Indian Ocean

Multiple short-term (<105 years) global warming events (“hyperthermals”) occurred throughout the early Eocene. Chemical weathering of continental silicate rocks is considered to have played a key role in recovery from these transient global warming events via consumption of excess atmospheric CO2. However, although evidence of this negative feedback has been reported for the Paleocene–Eocene Thermal Maximum (PETM), the effectiveness of chemical weathering during other transient hyperthermals remains poorly constrained. Here, we newly report early Eocene marine Os isotope records including Eocene Thermal Maximum 2 (ETM2), the I1 event, and ETM3 at Ocean Drilling Program Site 752 in the southern Indian Ocean. We demonstrate that marine 187Os/188Os increased during the hyperthermal events that were less severe than the PETM. The intensity of continental silicate weathering increased by 18%–22%, 17%–21%, and 13%–16% during ETM2, the I1 event, and ETM3, respectively, compared to the background conditions. Based on a reconsidered formulation of an Os mass-balance model, the intensity of continental silicate weathering during the PETM was reassessed to be a 34%–42% increase relative to the pre-PETM level. Thus, the continental chemical weathering flux during the Eocene hyperthermals may have been up to half as large as that of the PETM. It is noteworthy that the ordering of the changes in continental silicate weathering did not agree with the ordering of the seawater temperature rise among these events. This weathering–warming inconsistency might be attributable to (1) potential underestimation of continental silicate weathering due to the emplacement of Large Igneous Provinces (LIPs) and related basalt weathering, such as the North Atlantic Igneous Province and Siletzia in western North America, (2) changes in the background level of weathering intensity, and/or (3) a secular decrease in continental weatherability through the long-lasting early Eocene warming trend.

Mercury enrichments of the Pyrenean foreland basins sediments support enhanced volcanism during the Paleocene-Eocene thermal maximum (PETM)

The Paleogene records the most prominent global climate change of the Cenozoic Era with a shift from a greenhouse to an icehouse world. Several transient hyperthermal events punctuated this long-term evolution. The most pronounced and the best known of these is the Paleocene-Eocene Thermal Maximum (PETM-56 Ma). This event is associated with global warming, a worldwide perturbation of the carbon cycle, and significant biotic changes. The PETM is primarily recorded by a sharp negative carbon isotope excursion (NCIE) in both carbonates and organic matter of sedimentary successions. The source of the 13C-depleted carbon for the NCIE and whether it was released in one or numerous events is still debated. Several carbon sources have been proposed to explain the PETM-NCIE and the mechanisms that triggered this abrupt climate upheaval. These include, among others, the magmatic and thermogenic release of carbon associated with the emplacement of Large Igneous Provinces (LIP). One proxy for tracking past volcanic emissions in the geological record and testing hypothetical links between volcanism and hyperthermals is the use of mercury (Hg) anomalies found in marine and continental sedimentary successions. Here, we present new high-resolution mercury and stable isotopic records from a continental-marine transect in Pyrenean peripheral basins during the PETM. Compared to deeper marine settings, the significant sedimentation rate that characterizes these high-accommodation and high sediment-supply environments allows the preservation of expanded successions, providing reliable information about the fluctuations of Hg concentration in deposits across the PETM. Our data reveal two large negative carbon excursions across the studied successions. Based on biostratigraphy and the similarity of shape and amplitude of the isotopic excursions with global records, we interpret the largest NCIE as the PETM. This main excursion is preceded by another that we interpret as the Pre-Onset Excursion (POE), found in other profiles worldwide. We find that the POE and the PETM are, in our studied sections, systematically associated with significant Hg anomalies regardless of the depositional environment. These results suggest that large pulses of volcanism, possibly related to the North Atlantic Igneous Province's emplacement, contributed to the onset and possibly also to the long duration of the PETM. Furthermore, the record of higher Hg anomalies in nearshore than offshore settings suggests a massive collapse of terrestrial ecosystems linked to volcanism-driven environmental change triggered significant Hg loading in shallow marine ecosystems. If this is correct, these findings confirm the primary role of the solid Earth in determining past terrestrial climates.

Methodology for Evaluating the North Atlantic Igneous Province Reveals Multiple Hotspots at Breakup

AbstractThe North Atlantic Igneous Province (NAIP) has been the focus of numerous studies. However, a systematic integrated methodology to assess the NAIP, has so far been lacking. For this purpose, a synclinal oceanic rift approach is developed from the stratigraphic record. Mechanisms are addressed combining trace element and seismic velocity data as a proxy for excess mantle potential temperature (ΔTp), using simple mantle melting models. Unconformities play a major role in this assessment, providing evidence for a drop in ΔTp to ambient levels (≤50°C). Three phases can be delineated in the stratigraphic record: a (a) Pre‐; (b) Syn‐; and (c) Post‐breakup phase. The Syn‐breakup phase is bound at the base by the Breakup Unconformity and at the top by the Magmatic Unconformity. At breakup, magmatic crustal thickness (H) can be estimated from addition of basalt‐ and Lower Igneous Crust isopachs. These seismic estimations can be further constrained by observations on volcanic transport directions. This allows differentiation between hotspots and Volcanic Passive Margins (VPMs), where hotspots are characterized by continuous ΔTp amplitude variations, whereas VPMs only display declining or absent fluctuations post breakup. On Iceland and the Greenland‐Iceland‐Faroe Ridge, H is primary controlled by ΔTp fluctuations promoting ridge jumps and second, associated fluctuating active upwelling ratio (χ ∼ 2–4). Results suggest that there were at least three hotspots active at breakup. The West Greenland and proto‐Jan Mayen hotspots lost importance in the Oligocene, while Iceland remained and is currently the main hotspot in the North Atlantic.

Interaction between volcanic and non-volcanic systems and its implication for prospectivity in the Faroe–Shetland Basin, NE Atlantic continental margin

Exploration in the Faroe–Shetland Basin on the Faroese Continental Shelf has revealed thick and complex volcanic successions and discovery of inter-volcanic oil-bearing siliciclastic sandstone fan deposits in the central parts of the basin. The possibility for such play types at the fringe of the North Atlantic Igneous Province requires a better understanding of the interaction between competing sedimentary and volcanic depositional transport systems. We have re-examined volcanic units in cuttings from exploration wells in the greater Judd Sub-basin area for evaluation of facies and geochemical affinity. This allows for chemostratigraphical correlation of wells to the absolute radiometrically age-constrained Faroe Islands Basalt Group. The collective well data were subsequently tied to a regional interpretation of 2D seismic data which facilitated a detailed interpretation of temporal development of the volcanic successions in the Judd Sub-basin area in terms of geometry, volcanic facies, depositional environment, and interdigitation with non-volcanic sedimentary units. The Judd Sub-basin was influenced by major volcanic phases during pre-breakup and syn-breakup. The influence was both direct, in the form of volcanic deposits, and indirect, in the form of obstructing established sedimentary transport systems and creating new provenance areas. The volcanic transport systems reached different areas of the Judd Sub-basin at different times during pre-breakup volcanism. The earliest incursion in the west was during late Mid Paleocene (T-sequence T31/T32). With at least three stratigraphically discrete incursions of volcanic material into the Judd Sub-basin, possibilities arise for sub- and inter-volcanic stratigraphic and structural traps for each incursion.

Reservoir Properties and Reactivity of the Faroe Islands Basalt Group: Investigating the Potential for Co2 Storage in the North Atlantic Igneous Province

Reservoir Properties and Reactivity of the Faroe Islands Basalt Group: Investigating the Potential for Co2 Storage in the North Atlantic Igneous Province

From Continent to Ocean: Investigating the Multi-Element and Precious Metal Geochemistry of the Paraná-Etendeka Large Igneous Province Using Machine Learning Tools

Large Igneous Provinces, and by extension the mantle plumes that generate them, are frequently associated with platinum-group element (PGE) ore deposits, yet the processes controlling the metal budget in plume-derived magmas remains debated. In this paper, we present a new whole-rock geochemical data set from the 135 Ma Paraná-Etendeka Large Igneous Province (PELIP) in the South Atlantic, which includes major and trace elements, PGE, and Au concentrations for onshore and offshore lavas from different developmental stages in the province, which underwent significant syn-magmatic continental rifting from 134 Ma onwards. The PELIP presents an opportunity to observe magma geochemistry as the continent and sub-continental lithospheric mantle (SCLM) are progressively removed from a melting environment. Here, we use an unsupervised machine learning approach (featuring the PCA, t-SNE andk-means clustering algorithms) to investigate the geochemistry of a set of (primarily basaltic) onshore and offshore PELIP lavas. We test the hypothesis that plume-derived magmas can scavenge precious metals including PGE from the SCLM and explore how metal concentrations might change the metal content in intraplate magmas throughout rifting. Onshore lavas on the Etendeka side of the PELIP are classified as the products of deep partial melts of the mantle below the African craton but without significant PGE enrichment. Offshore lavas on both continents exhibit similarities through the multi-element space to their onshore equivalents, but they again lack PGE enrichment. Of the four onshore lava types on the Paraná side of the PELIP, the Type 1 (Southern) and Type 1 (Central-Northern) localities exhibit separate PGE-enriched assemblages (Ir-Ru-Rh and Pd-Au-Cu, respectively). It follows that there is a significant asymmetry to the metallogenic character of the PELIP, with enrichment focused specifically on lavas from the South American continent edge in Paraná. This asymmetry contrasts with the North Atlantic Igneous Province (NAIP), a similar geodynamic environment in which continent-edge lavas are also PGE-enriched, albeit on both sides of the plume-rift system. We conclude that, given the similarities in PGE studies of plume-rift environments, SCLM incorporation under progressively shallowing (i.e., rifting) asthenospheric conditions promotes the acquisition of metasomatic and residual PGE-bearing minerals, boosting the magma metal budget.

Rapid and sustained environmental responses to global warming: the Paleocene–Eocene Thermal Maximum in the eastern North Sea

Abstract. The Paleocene–Eocene Thermal Maximum (PETM; ∼ 55.9 Ma) was a period of rapid and sustained global warming associated with significant carbon emissions. It coincided with the North Atlantic opening and emplacement of the North Atlantic Igneous Province (NAIP), suggesting a possible causal relationship. Only a very limited number of PETM studies exist from the North Sea, despite its ideal position for tracking the impact of both changing climate and NAIP activity. Here we present sedimentological, mineralogical, and geochemical proxy data from Denmark in the eastern North Sea, exploring the environmental response to the PETM. An increase in the chemical index of alteration and a kaolinite content up to 50 % of the clay fraction indicate an influx of terrestrial input shortly after the PETM onset and during the recovery, likely due to an intensified hydrological cycle. The volcanically derived zeolite and smectite minerals comprise up to 36 % and 90 % of the bulk and clay mineralogy respectively, highlighting the NAIP's importance as a sediment source for the North Sea and in increasing the rate of silicate weathering during the PETM. X-Ray fluorescence element core scans also reveal possible hitherto unknown NAIP ash deposition both prior to and during the PETM. Geochemical proxies show that an anoxic to sulfidic environment persisted during the PETM, particularly in the upper half of the PETM body with high concentrations of molybdenum (MoEF &gt; 30), uranium (UEF up to 5), sulfur (∼ 4 wt %), and pyrite (∼ 7 % of bulk). At the same time, export productivity and organic-matter burial reached its maximum intensity. These new records reveal that negative feedback mechanisms including silicate weathering and organic carbon sequestration rapidly began to counteract the carbon cycle perturbations and temperature increase and remained active throughout the PETM. This study highlights the importance of shelf sections in tracking the environmental response to the PETM climatic changes and as carbon sinks driving the PETM recovery.

Paleocene/Eocene carbon feedbacks triggered by volcanic activity

The Paleocene–Eocene Thermal Maximum (PETM) was a period of geologically-rapid carbon release and global warming ~56 million years ago. Although modelling, outcrop and proxy records suggest volcanic carbon release occurred, it has not yet been possible to identify the PETM trigger, or if multiple reservoirs of carbon were involved. Here we report elevated levels of mercury relative to organic carbon—a proxy for volcanism—directly preceding and within the early PETM from two North Sea sedimentary cores, signifying pulsed volcanism from the North Atlantic Igneous Province likely provided the trigger and subsequently sustained elevated CO2. However, the PETM onset coincides with a mercury low, suggesting at least one other carbon reservoir released significant greenhouse gases in response to initial warming. Our results support the existence of ‘tipping points’ in the Earth system, which can trigger release of additional carbon reservoirs and drive Earth’s climate into a hotter state.

Marine diagenesis of tephra aided the Palaeocene-Eocene Thermal Maximum termination

The Palaeocene-Eocene Thermal Maximum (PETM) was a period of intense global warming that began ∼55.9 million years ago and lasted about 170,000 yrs. Various mechanisms have been proposed to cause this warming, including the emplacement of the North Atlantic Igneous Province (NAIP). Equally, many mechanisms have been invoked to explain sequestration of carbon from the ocean-atmosphere system necessary to promote the recovery to more temperate conditions. Here we propose that an important path for carbon sequestration was tied to NAIP volcanism through the precipitation of calcium carbonate (CaCO3) cements within the tephra layers. These cements formed after the deposition and burial of tephra over a wide area of the North Atlantic Ocean during the late Palaeocene and early Eocene. We find strong evidence that authigenic CaCO3 cements formed shortly after tephra deposition. Monte Carlo simulations suggest that this process may have been responsible for a quarter of the carbon sequestered during the PETM recovery phase, providing a major, but previously unconsidered sink of isotopically-light carbon, and one which may have persisted into the Eocene.

The spatial distribution of igneous centres along the Norwegian Atlantic Margin (Møre and Vøring) and their relationship to magmatic plumbing systems

A series of offshore intra-basinal igneous centres have been documented across the North Atlantic Igneous Province including the UK, Ireland and Greenland. However, inconsistent cross-border terminology implies that similar features are not present in the Norwegian offshore, which, in turns, leads to misperceptions of cross-border geological differences. This paper presents evidence for a series of Norwegian igneous centres and suggests a consistent non-genetic cross-border terminology. In the Møre Basin, several igneous centres sit close to the continent–ocean boundary (COB), which have previously been identified as seamounts and/or ‘outer highs’. To provide cross-border consistency these features are consolidated under umbrella terms: igneous centres or volcanic fissures. Further centres are probably present within the Møre Basin (east of the COB) where 3D seismic data were not available. In the Vøring Basin two new igneous centres, one intrusive and one extrusive, are identified within the continental domain. Additionally, a possible deep magmatic upwelling associated with the regionally significant T-Reflector is identified. These igneous centre end-members represent the complexity of the magmatic plumbing across the Norwegian margin. With further data it is likely that further igneous centres will be identified offshore mid-Norway.

Temporally variable crustal contributions to primitive mantle-derived Columbia River Basalt Group magmas

The Steens Formation is one of the earliest and most primitive (>7 wt. MgO) eruptive products of the Columbia River Basalt Group (CRBG) and the CRBG-Yellowstone-Snake River large igneous province. New major-, trace-, and highly siderophile-element abundance and 87Sr/86Sr, 143Nd/144Nd and 187Os/188Os data are reported for the lower and upper Steens Formation to examine likely mantle sources and the nature of magmatic differentiation and crustal contamination acting on lavas. Examined Steens Formation basalts are relatively mafic (7–9 wt% MgO), incompatible trace element enriched, and have weaker Nb and Ta anomalies compared to other CRBG lavas. The most primitive basalts have isotopic compositions at the time of crystallization consistent with originating from a mantle source that was relatively depleted (87Sr/86Sr = ~0.7033; εNdi = ~ + 6.5; γOsi = ~ + 1). Primary magma compositions for the Steens Formation do not provide compelling evidence for a subducted slab component, instead suggesting derivation from primitive mantle sources more similar to those of other Mesozoic continental flood basalts (CFB; e.g., Deccan, North Atlantic Igneous Province). Onset of sulfide saturation in the CRBG occured at lower MgO (<7 wt%) than in other CFB (~ 8 wt%) leading to the high Os contents in the Steens Formation. Collectively, the Steens Formation exhibits decreasing Os contents, εNdi values and increasing 187Os/188Os with decreasing MgO. These geochemical signatures are consistent with increasing crustal contamination to parent melts with time, a feature that is also shared for the CRBG as a whole. Calculations based on Os and Nd isotopes of likely mantle and crust components to different formations of the CRBG indicates a progressive increase in the quantities of crustal contamination from ~1 to 2% from Steens Formation magmatism to more than 6% during Grande Ronde and Wanapum eruptions. These results would indicate increasing crustal contamination and enhanced potential cryptic degassing of CO2 in the later, more voluminous stages of CRBG magmatism, after ~16.5 Ma. Unless mantle-derived melts can produce sufficient greenhouse gas emission, there is likely an offset between the inception of the mid-Miocene Climatic Optimum at 17 Ma and maximum CO2 release, indicating that CRBG eruption was a contributing factor to climate change at that time, but was not the trigger for it.

Discovery of Two Sub‐Volcanic Basins Below the North Atlantic Igneous Province (NAIP), Faroe Platform, NE Atlantic Ocean

AbstractThe Faroe Platform lies on the outer continental margin of NW Europe. Its pre‐breakup structural configuration has long been debated as it is entirely buried beneath a thick cover of lower Palaeogene volcanic rocks. Here we present the results of an integrated geological and geophysical study designed to test whether low‐gravity areas on the Faroe Platform are basins inverted during the Neogene, and high‐gravity areas are basement blocks. Based on a series of profiles constructed from forward gravity modeling, our results identify two new sedimentary basins—the Beinta and Kerstin basins—bounded by four basement highs—the West Suðuroy High, East Suðuroy High, Borðoy High, and the Sandoy High. The Beinta and Kerstin basins extend to depths of 8–10 km and 8–9 km, respectively, whereas the tops of the structural highs are located between 3–6 km below the present‐day surface of the platform. Deformation of the A‐horizon, which marks the boundary between pre‐and syn‐breakup volcanism, is consistent with a phase of Miocene‐Pliocene basin inversion, also evident in the adjacent Faroe‐Shetland Basin. Our study also gives indications of cross‐cutting intrusive networks that likely represent part of the magmatic plumbing system in the central part of the Faroe Platform.

Calcium isotope composition ofMorozovellaover the late Paleocene–early Eocene

AbstractOcean acidification (OA) during the Paleocene-Eocene thermal maximum (PETM) likely caused a biocalcification crisis. The calcium isotope composition (δ44/40Ca) of primary carbonate producers may be sensitive to OA. To test this hypothesis, we constructed the first high-resolution, high-precision planktic foraminiferal δ44/40Ca records before and across the PETM. The records employ specimens of Morozovella spp. collected from Ocean Drilling Program Sites 1209 (Shatsky Rise, Pacific Ocean) and 1263 (Walvis Ridge, Atlantic Ocean). At Site 1209, δ44/40Ca values start at −1.33‰ during the Upper Paleocene and increase to a peak of −1.15‰ immediately before the negative carbon isotope excursion (CIE) that marks the PETM onset. Values remain elevated through the PETM interval and decrease into the earliest Eocene. A shorter-term record for Site 1263 shows a similar trend, although δ44/40Ca values are on average 0.22‰ lower and decrease shortly after the CIE onset. The trends support neither diagenetic overprinting, authigenic carbonate additions, nor changes in the δ44/40Ca value of seawater. Rather, they are consistent with a kinetic isotope effect, whereby calcite δ44/40Ca values inversely correlate with precipitation rate. Geologically rapid Ca isotope shifts appear to reflect the response of Morozovella to globally forced changes in the local carbonate geochemistry of seawater. All data combined suggest that the PETM-OA event occurred near the peak of a gradual reduction in seawater carbonate ion concentrations during a time of elevated atmospheric pCO2, potentially driven by North Atlantic igneous province emplacement.

Planktic foraminiferal response to an early Paleocene transient warming event and biostratigraphic implications

The Latest Danian Event (LDE, ~ 62.2 Ma) is characterized by global changes in the carbon cycle as indicated by two negative δ13C excursions of up to ~ 1‰. These δ13C shifts are accompanied by a 2–3 °C warming of both surface and deep waters based on benthic and planktic foraminiferal δ18O measurements, and the LDE has, thus, been considered as a so-called hyperthermal event. The event lasted for 200 kyr and has been identified in various ocean basins and shallow marine settings. Here, we present a compilation of data from three deep-sea cores covering the Pacific, North and South Atlantic oceans as well as a southern Tethyan shelf section to document the response of planktic foraminifera assemblages to ocean warming. In all studied successions, we observe the disappearance of the planktic foraminifer genus Praemurica on a global scale that took place close to the onset of the LDE. Moreover, on the long run, praemuricids were contemporaneously replaced by morozovellids. Both the decline of Praemurica and a temperature increase started between 200 and 260 kyr before the LDE onset and were punctuated by the LDE itself. In this paper, we propose two mechanisms that have controlled the environmental changes associated with this event, (1) increased activity of the North Atlantic Igneous Province acting on long time-scales, and (2) changes of orbital parameters resulting in insolation changes on shorter time-scales.In contrast to a proposed muted benthic foraminiferal response, the planktic community has been substantially impacted by the LDE as indicated by changes in planktic foraminifera faunas and calcareous nannofossils. Finally, our quantitative and conventional approaches identifying stratigraphically important planktic foraminifera datum levels justify a revision of the upper Danian to lower Selandian planktic foraminifera biozonation.

A machine learning approach for regional geochemical data: Platinum-group element geochemistry vs geodynamic settings of the North Atlantic Igneous Province

Whilst traditional approaches to geochemistry provide valuable insights into magmatic processes such as melting and element fractionation, by considering entire regional data sets on an objective basis using machine learning algorithms (MLAs), we can highlight new facets within the broader data structure and significantly enhance previous geochemical interpretations. The platinum-group element (PGE) budget of lavas in the North Atlantic Igneous Province (NAIP) has been shown to vary systematically according to age, geographic location and geodynamic environment. Given the large multi-element geochemical data set available for the region, MLAs were employed to explore the magmatic controls on these shifting concentrations. The key advantage of using machine learning in analysis is its ability to cluster samples across multi-dimensional (i.e., multi-element) space. The NAIP data set is manipulated using Principal Component Analysis (PCA) and t-Distributed Stochastic Neighbour Embedding (t-SNE) techniques to increase separability in the data alongside clustering using the k-means MLA. The new multi-element classification is compared to the original geographic classification to assess the performance of both approaches. The workflow provides a means for creating an objective high-dimensional investigation on a geochemical data set and particularly enhances the identification of metallogenic anomalies across the region. The techniques used highlight three distinct multi-element end-members which successfully capture the variability of the majority of elements included as input variables. These end-members are seen to fluctuate in prominence throughout the NAIP, which we propose reflects the changing geodynamic environment and melting source. Crucially, the variability of Pt and Pd are not reflected in MLA-based clustering trends, suggesting that they vary independently through controls not readily demonstrated by the NAIP major or trace element data structure (i.e., other proxies for magmatic differentiation). This data science approach thus highlights that PGE (here signalled by Pt/Pd ratio) may be used to identify otherwise localised or cryptic geochemical inputs from the subcontinental lithospheric mantle (SCLM) during the ascent of plume-derived magma, and thereby impact upon the resulting metallogenic basket.

Evidence of explosive hydromagmatic eruptions during the emplacement of the North Atlantic Igneous Province

Early Eocene sediments in northwest Denmark contain over 180 well-preserved volcanic ash layers, likely sourced from the North Atlantic Igneous Province (NAIP) between 56.0 and 54.6 Ma. Most of these ashes are basaltic, widespread, and represent a phase of unusually large and explosive eruptions that is coincident with the opening of the northeast Atlantic Ocean. Explosive basaltic eruptions of this magnitude are unheard of in historical times and in the current geological record. Here, we combine analyses of glass sulfur concentrations and variations in morphology and vesicularity of pristine volcanic glass grains to explore the possible eruptive processes promoting such widespread basaltic ash dispersal. We suggest that these ashes formed in shallow subaqueous environments (&lt;200 m water depth) where they fragmented and rapidly quenched during explosive hydromagmatic activity. We speculate that magma-water interaction during the opening of the northeast Atlantic was the main cause of this unusual explosive basaltic activity.

The importance of in situ crystallisation and loss of interstitial melt during formation of the Kærven Syenite Complex, Kangerlussuaq, East Greenland

The Kærven Syenite Complex (KSC) is one of the oldest felsic intrusions in the Tertiary East Greenland province. Here we update our previous description of the KSC and supply a greatly expanded and comprehensive geochemical dataset. New data allow us to present a more detailed petrogenetic model for the evolution of the KSC and to investigate the geochemical characteristics of igneous cumulates subjected to loss and, occasionally, replacement of residual liquid. The KSC comprises eleven mappable units that generally young westwards. Rock types range from quartz syenite to quartz alkali feldspar syenite and alkali feldspar granite. Individual intrusive units are relatively narrow and steep-sided and are collectively suggested to represent a ring dyke complex. Basement gneiss and gabbro host rocks have locally contaminated the oldest quartz syenite KSC unit, but most of the main part of the complex escaped significant influence from host rocks. A late suite of E–W to NE–SW striking peralkaline dykes of trachytic to phonolitic compositions intrude the KSC. Compositions of the KSC rocks span a considerable range in SiO2, 59–73 wt%. Concentrations of several elements vary widely for a given SiO2 (especially at SiO2 &lt; 66 wt%), and variation diagrams do not suggest a single model for the evolution of the units of the complex. A cumulative origin is envisaged for several KSC units. Geochemical modelling suggests that KSC magmas were derived from more than one primary magma, and that the complex evolved through a four-stage process: fractional crystallisation in precursory magma chambers was followed by final emplacement of each unit, establishment of a crystal/melt mush, expulsion of part of the residual melt and, finally, crystallisation of the remaining melt. Trace element disequilibria between alkali feldspar and host rocks in two closely associated quartz alkali feldspar syenite units indicate that highly evolved residual melt was replaced by a less evolved melt phase. Modelling of potential parent melt compositions to the Kærven magmas suggests an origin not in the Iceland plume asthenosphere, but rather in a moderately enriched source, possibly in the continental lithosphere. The course of melt evolution by fractional crystallisation is indicated to have taken place in magma chambers at depth, and repeated rise of magma into the upper crustal magma chambers and crystallisation there formed the KSC. Based on our survey of published geochemical data, the inferred parental magmas seem to have few equivalents in the North Atlantic Igneous Province and may have been generated mainly from melting of enriched dry lithospheric mantle of possibly Archaean age.

Cold spells in the Nordic Seas during the early Eocene Greenhouse

The early Eocene (c. 56 - 48 million years ago) experienced some of the highest global temperatures in Earth’s history since the Mesozoic, with no polar ice. Reports of contradictory ice-rafted erratics and cold water glendonites in the higher latitudes have been largely dismissed due to ambiguity of the significance of these purported cold-climate indicators. Here we apply clumped isotope paleothermometry to a traditionally qualitative abiotic proxy, glendonite calcite, to generate quantitative temperature estimates for northern mid-latitude bottom waters. Our data show that the glendonites of the Danish Basin formed in waters below 5 °C, at water depths of <300 m. Such near-freezing temperatures have not previously been reconstructed from proxy data for anywhere on the early Eocene Earth, and these data therefore suggest that regionalised cool episodes punctuated the background warmth of the early Eocene, likely linked to eruptive phases of the North Atlantic Igneous Province.

Transient mantle cooling linked to regional volcanic shut-down and early rifting in the North Atlantic Igneous Province

The Paleocene to Early Eocene Faroe Islands Basalt Group (FIBG) comprises a c. 6.5-km-thick lava flow–dominated sequence located within the centre of the North Atlantic Igneous Province (NAIP). The currently defined pre-breakup and syn-breakup sequences of the FIBG are separated by a significant volcanic hiatus, during which time the coal-bearing Prestfjall Formation was deposited. This major volcanic hiatus is identified across large parts of the NAIP and was preceded on the Faroe Islands by a reduction in eruption rate evidenced by an increased number and thickness of inter-lava sedimentary beds between the simple lava flows of the pre-breakup Beinisvørd Formation. High tempo eruptions resumed after this hiatus with the development of the compound lava flow fields of the Malinstindur Formation which reveal limited evidence for inter-lava breaks. In order to investigate this key transition, flow by flow geochemical sampling of a composite c.1.1-km-thick lava flow sequence spanning this transition were collected and analysed. Three chemically distinct groups are defined based on rare earth elements (REEs) and incompatible trace element signatures. Two high-Ti groups (TiO2 > 2 wt%), B2 and B3, dominate the sampled Beinisvørd Formation and display light REE-enriched signatures (La/YbN c. 2.9–5.9) and evidence for garnet in the source melting region (Dy/YbN c. 1.5–1.6). At the very top of the Beinisvørd Formation, a distinct group of lava flows, B1, displaying lower TiO2 for a given MgO wt% (TiO2 c. 1–2 wt%), weakly light REE-enriched profiles (La/YbN c. 1.7–2.4) and a spinel-dominated mantle melting signature (Dy/YbN c. 1.1–1.2) is identified. Sr, Nd and Pb isotopic signatures for the three groups overlap, revealing limited evidence of crustal contamination, and therefore supporting a mantle melting origin for inter-group variations, rather than source composition or contamination. The group B1 lava flows form a unique stratigraphic occurrence on the islands and provide clear evidence for both a reduction in the initial pressure of melting, alongside an increase in the overall degree of partial melting relative to groups B2 and B3. Increased partial melting is interpreted as evidence for the early onset of rifting and lithospheric thinning to the north of the Faroe Islands. The accompanying reduction in initial pressure of melting provides the first petrological evidence that a transient reduction in mantle temperature leads to the province-wide volcanic hiatus. Our study demonstrates an intimate linkage between rifting history and fluctuations in mantle temperature highlighting that any over-arching model for the evolution of the NAIP must take both into equal account.

Temperature changes across the Paleocene-Eocene Thermal Maximum – a new high-resolution TEX86 temperature record from the Eastern North Sea Basin

The Paleocene-Eocene Thermal Maximum (PETM; ∼55.9 Ma) was a hyperthermal event associated with large carbon cycle perturbations, sustained global warming, and marine and terrestrial environmental changes. One possible trigger and/or source of the carbon release that initiated the PETM is the emplacement of the North Atlantic Igneous Province (NAIP). This study focuses on an expanded section of marine clays and diatomite on Fur Island in northern Denmark, where the entire PETM sequence has been identified by a negative ∼4.5‰ δ13CTOC excursion. This remarkably well-preserved section also contains >180 interbedded ash layers sourced from the NAIP, making it an ideal site for investigating the correlations between large-scale volcanism and environmental changes. This study provides a new and complete high-resolution TEX86-derived sea-surface temperature (SST) reconstruction over the entire PETM and the post-PETM section (up to about 54.6 Ma). The palaeothermometry record indicates an apparent short-lived cooling episode in the late Paleocene, followed by a pronounced temperature response to the PETM carbon cycle perturbations with a ∼10°C SST increase during the PETM onset (up to ∼33°C). Extreme SSTs fall shortly after the PETM onset, and continue to decrease during the PETM body and recovery, down to anomalously cool SSTs post-PETM (∼11–23°C). Both phases of potential cooling coincide with proxies of active NAIP volcanism, suggesting a causal connection, although several overprinting non-thermal factors complicate interpretations of the TEX86 values. Indices of effusive and explosive NAIP volcanism are largely absent from the Danish stratigraphy during the PETM body, though a re-emergence toward the end of the PETM suggest NAIP volcanism might have played a role in the PETM termination in the North Sea. This new SST record completes the previous fragmented view of climate changes at this globally important PETM site, and indicates large temperature variations in the North Sea during the earliest Eocene that are possibly linked to NAIP volcanism.