The deposition of magnesium on tris(8-hydroxyquinolato) aluminum (Alq3) precovered with thin silver was investigated with high resolution synchrotron radiation photoemission. The noble-metal deposit first occupies the vicinity of the pyridyl ring. The appearance of a Fermi level suggests that the incorporated Ag behaves as a metallic cluster, consistent with the results of the Ag 3d cores, which show a nonzero Doniach-Sunjic singularity index of 0.061. Upon Mg adsorption on the Ag∕Alq3 surface, a MgAg mixture begins to develop such that the Ag 4d valence band becomes narrowed and its centroid shifts towards higher binding energy. A phase transformation is thus observed at the interface, from a Ag-rich phase to a Mg-rich phase. The product of the MgAg mixture prevents subsequent Mg atoms from penetrating into the Alq3 film, which grows as a metal on top of the MgAg∕Alq3 interface.
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