Non-trivial Topological Order Research Articles

Spontaneous Atomic-Scale Polar Skyrmions and Merons on a SrTiO3 (001) Surface: Defect Engineering for Emerging Topological Orders.

The emergence of nontrivial topological order in condensed matter has been attracting a great deal of attention owing to its promising technological applications in novel functional nanodevices. In ferroelectrics, the realization of polar topological order at an ultimately small scale is extremely challenging due to the lack of chiral interaction and the critical size of the ferroelectricity. Here, we break through these limitations and demonstrate that the ultimate atomic-scale polar skyrmion and meron (∼2 nm) can be induced by engineering oxygen vacancies on the SrTiO3 (001) surface based on first-principles calculations. The paraelectric-to-antiferrodistortive phase transition leads to a novel topological transition from skyrmion to meron, indicating phase-topology correlations. We also discuss accumulating and driving polar skyrmions based on the oxygen divacancy model; these results and the recent discovery of defect engineering techniques suggest the possibility of arithmetic operations on topological numbers through the natural self-organization and diffusion features of oxygen vacancies.

Terahertz linear/non-linear anomalous Hall conductivity of moiré TMD hetero-nanoribbons as topological valleytronics materials

Twisted moiré van der Waals heterostructures hold promise to provide a robust quantum simulation platform for strongly correlated materials and realize elusive states of matter such as topological states in the laboratory. We demonstrated that the moiré bands of twisted transition metal dichalcogenide (TMD) hetero-nanoribbons exhibit non-trivial topological order due to the tendency of valence and conduction band states in K valleys to form giant band gaps when spin-orbit coupling (SOC) is taken into account. Among the features of twisted WS2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}/MoS2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} and WSe2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}/MoSe2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}, we found that the heavy fermions associated with the topological flat bands and the presence of strongly correlated states, enhance anomalous Hall conductivity (AHC) away from the magic angle. By band analysis, we showed that the topmost conduction bands from the ± K-valleys are perfectly flat and carry a spin/valley Chern number. Moreover, we showed that the non-linear anomalous Hall effect in moiré TMD hetero-nanoribbons can be used to manipulate terahertz (THz) radiation. Our findings establish twisted heterostructures of group-VI TMD nanoribbons as a tunable platform for engineering topological valley quantum phases and THz non-linear Hall conductivity.

Electronic and Optical Properties of Mn-Doped HgSe Topological Insulator for Spintronic Devices

HgSe is a Mercury chalcogenide material of the HgX family (where X = S, Se, Te) which crystallises in the zincblende crystal phase. The electronic band structure of HgSe is indicative of a new state of matter in the condensed phase that is of great interest for fundamental physics and possibly new applications. This paper reports ab-initio calculations of the structural, electronic, magnetic, and optical properties of zincblende Mercury selenide (HgSe) doped with manganese (Mn) in the inter sites HgMnxSe, with x = 0, 0.058, and 0.117, using the framework of spin-polarized density functional theory (SP-DFT). The aim of our investigation is to discuss the different properties of this doped material in order to improve the promising new domain of spintronics with topological systems. Both the GGA + U + mBJ approach and spin–orbit coupling (SOC) are used for band structure calculations and density of states. The results show a nontrivial topological semimetal order for HgSe and a ferromagnetic topological and metallic behaviour for HgMnxSe. The frequency response of optical properties shows interesting characteristics. Furthermore, the variation with concentration x of the critical point for each of the optical parameters is similar to that of the inverted band gap.

Ultrasmall Polar Skyrmions and Merons in SrTiO3 Heterostructures by Polaron Engineering.

Topological objects with skyrmionic textures in ferroelectrics, i.e., polar skyrmions, are promising technological paradigms in next-generation electronic devices. While breakthrough discoveries of stable polar skyrmions approximately ten nanometers in size have been very recently witnessed in complex systems, such a nontrivial topological order in ferroelectrics inevitably disappears below the ferroelectric critical size of several nanometers. Herein, we propose a strategy to overcome this limitation and achieve ultrasmall and isolated polar skyrmions by engineering excess-electron polarons in otherwise nonferroelectric SrTiO3 heterostructures. Our first-principle calculations demonstrate that a polaron localized at a SrTiO3 surface induces a Neel-type polar skyrmion as small as 1.8 nanometers attributed to the effect of atomic-scale surface roughness. Furthermore, we show that this polar topological structure is tunable by the choice of heterostructures and by the mechanical approach, which undergoes a phase transition to a meron state in the twisted boundary and to an antiskyrmion state in the surface with external shear strain, respectively. Such ultraminiaturization of skyrmions and their transitions unexpectedly unravels the formula of ultrasmall topological orders originating from the interplay between an electron polaron and structural symmetry breaking, which is completely different from the common mechanism of geometric confinement for larger-scale skyrmions. Our results not only provide a mechanism for the exploration of polar skyrmions and their rich topological transitions but also hold potential for ultrahigh-density memories.

Chiral edge dynamics and quantum Hall physics in synthetic dimensions with an atomic erbium Bose-Einstein condensate

Quantum Hall physics is at the heart of research on both matter and artificial systems, such as cold atomic gases, with nontrivial topological order. We report on the observation of a chiral edge current by transferring atomic wave packets simultaneously to opposite edges of a synthetic Hall system realized in the two-dimensional state space formed by one spatial and one synthetic dimension encoded in the $J=6$ electronic spin of erbium atoms. To characterize the system, the Hall drift of the employed atomic Bose-Einstein condensate in the lowest Landau-like level is determined. The topological properties are verified by determining the local Chern marker, and upon performing low-lying excitations both cyclotron and skipping orbits are observed in the bulk and edges, respectively. Future prospects include studies of novel topological phases in cold-atom systems.

Topological Magnetic Materials of the (MnSb2Te4)·(Sb2Te3)n van der Waals Compounds Family.

Using density functional theory, we propose the (MnSb2Te4)·(Sb2Te3)n family of stoichiometric van der Waals compounds that harbor multiple topologically nontrivial magnetic phases. In the ground state, the first three members of the family (n = 0, 1, 2) are 3D antiferromagnetic topological insulators, while for n ≥ 3 a special phase is formed, in which a nontrivial topological order coexists with a partial magnetic disorder in the system of the decoupled 2D ferromagnets, whose magnetizations point randomly along the third direction. Furthermore, due to a weak interlayer exchange coupling, these materials can be field-driven into the FM Weyl semimetal (n = 0) or FM axion insulator states (n ≥ 1). Finally, in two dimensions, we reveal these systems to show intrinsic quantum anomalous Hall and AFM axion insulator states, as well as quantum Hall state, achieved under external magnetic field. Our results demonstrate that MnSb2Te4 is not topologically trivial as was previously believed that opens possibilities of realization of a wealth of topologically nontrivial states in the (MnSb2Te4)·(Sb2Te3)n family.

Numerical identification and gapped boundaries of Abelian fermionic topological order

In this work we consider general fermion systems in two spatial dimensions, both with and without charge conservation symmetry, which realize a non-trivial fermionic topological order with only Abelian anyons. We address the question of precisely how these quantum phases differ from their bosonic counterparts, both in terms of their edge physics and in the way one would identify them in numerics. As in previous works, we answer these questions by studying the theory obtained after gauging the global fermion parity symmetry, which turns out to have a special and simple structure. Using this structure, a minimal scheme is outlined for how to numerically identify a general Abelian fermionic topological order, without making use of fermion number conservation. Along the way, some subtleties of the momentum polarization technique are discussed. Regarding the edge physics, it is shown that the gauged theory can have a (bosonic) gapped boundary to the vacuum if and only if the ungauged fermion theory has a gapped boundary as well.

Topological order on the Bloch sphere

A Bloch sphere is the geometrical representation of an arbitrary two-dimensional Hilbert space. Possible classes of entanglement and separability for the pure and mixed states on the Bloch sphere were suggested by [Boyer et al 2017 PRA 95 032 308]. Here we construct a Bloch sphere for the Hilbert space spanned by one of the ground states of Kitaev’s toric code model and one of its closest product states. We prove that this sphere contains only one separable state, thus belonging to the fourth class suggested by the said paper. We furthermore study the topological order of the pure states on its surface and conclude that, according to conventional definitions, only one state (the toric code ground state) seems to present non-trivial topological order. We conjecture that most of the states on this Bloch sphere are neither ‘trivial’ states (namely, they cannot be generated from a product state using a trivial circuit) nor topologically ordered. In addition, we show that the whole setting can be understood in terms of Grover rotations with gauge symmetry, akin to the quantum search algorithm.

Heterogeneous catalysis at the surface of topological materials

Intriguing properties are frequently reported in various topologically non-trivial materials. They include robust metallic surface states, high carrier mobility, chiral fermions, and ultralong Fermi arcs. An exciting recent finding is that these properties are strongly related to adsorption and electron transfer in various heterogeneous catalysis reactions, such as hydrogen evolution, oxygen evolution, oxygen reduction, enantiospecific adsorption, and hydrometallation. Thus, we expect that the introduction of non-trivial symmetry-protected topological order will offer important freedom for designing high-performance heterogeneous catalysts. To uncover the contribution of the topologically non-trivial electronic structure to the heterogeneous reactions, in situ techniques are urgently needed to detect the interaction between surface states, topological electrons, and reaction intermediates.

Emergent anomalous higher symmetries from topological order and from dynamical electromagnetic field in condensed matter systems

Global symmetry (0-symmetry) acts on the whole space while higher $k$-symmetry acts on all the codimension-$k$ closed subspaces. The usual condensed matter lattice theories do not include dynamical electromagnetic (EM) field and do not have higher symmetries (unless we engineer fine-tuned toy models). However, for gapped systems, (anomalous) higher symmetries can emerge from the usual condensed matter theories at low energies (usually in a spontaneously broken form). We pointed out that the emergent spontaneously broken higher symmetries are nothing but a kind of topological order. Thus the study of emergent spontaneously broken higher symmetries is a study of topological order. The emergent (anomalous) higher symmetries can be used to constrain possible phase transitions and possible phases induced by certain types of excitations in topological orders. (Anomalous) higher symmetry can also emerge in gapless systems if the gapless excitations contain gapless gauge fields. In particular, EM condensed matter systems that include the dynamical EM field have an emergent anomalous $U(1)$-1-symmetry below the energy gap of the magnetic monopoles. So EM condensed matter systems can realize some physical phenomena of anomalous higher symmetry. In particular, any gapped liquid phase of an EM condensed matter system (induced by arbitrary fluctuations and condensations of electric charges and photons) must have a nontrivial bosonic topological order.

Imaging topology of Hofstadter ribbons

Physical systems with non-trivial topological order find direct applications in metrology (Klitzing et al 1980 Phys. Rev. Lett. 45 494–7) and promise future applications in quantum computing (Freedman 2001 Found. Comput. Math. 1 183–204; Kitaev 2003 Ann. Phys. 303 2–30). The quantum Hall effect derives from transverse conductance, quantized to unprecedented precision in accordance with the system’s topology (Laughlin 1981 Phys. Rev. B 23 5632–33). At magnetic fields beyond the reach of current condensed matter experiment, around T, this conductance remains precisely quantized with values based on the topological order (Thouless et al 1982 Phys. Rev. Lett. 49 405–8). Hitherto, quantized conductance has only been measured in extended 2D systems. Here, we experimentally studied narrow 2D ribbons, just 3 or 5 sites wide along one direction, using ultracold neutral atoms where such large magnetic fields can be engineered (Jaksch and Zoller 2003 New J. Phys. 5 56; Miyake et al 2013 Phys. Rev. Lett. 111 185302; Aidelsburger et al 2013 Phys. Rev. Lett. 111 185301; Celi et al 2014 Phys. Rev. Lett. 112 043001; Stuhl et al 2015 Science 349 1514; Mancini et al 2015 Science 349 1510; An et al 2017 Sci. Adv. 3). We microscopically imaged the transverse spatial motion underlying the quantized Hall effect. Our measurements identify the topological Chern numbers with typical uncertainty of , and show that although band topology is only properly defined in infinite systems, its signatures are striking even in nearly vanishingly thin systems.

New families of large band gap 2D topological insulators in ethynyl-derivative functionalized compounds

The search for large band gap systems with dissipationless edge states is essential to developing materials that function under a wide range of temperatures. Two-dimensional (2D) topological insulators (TIs) have recently attracted significant attention due to their dissipationless transport, robust properties and excellent compatibility with device integration. However, a major barrier of 2D TIs is their small bulk band gap, which allows for applications only in extremely low temperatures. In this work, first principle calculations were used to analyze the geometric, electronic, and topological properties of PbC2X and BiC2X (X = H, Cl, F, Br, I) compounds. The band gap values are remarkably large, ranging from 0.79 eV to 0.99 eV. The nanoribbons of these compounds exhibited nontrivial topological order in the simulation, thus proving ethynyl-derivative functionalized Pb and Bi films to be new classes of giant band gap 2D TIs. In addition, these findings indicate that chemical functionalization with ethynyl-derivatives is an effective method to tune the band gap and preserve the nontrivial topological order. These novel materials that are applicable at both room temperature and high temperatures open the door to a new generation of electronics.

Experimental observation of classical analogy of topological entanglement entropy

Long-range entanglement is an important aspect of the topological orders, so efficient methods to characterize the long-range entanglement are often needed. In this regard, topological entanglement entropy (TEE) is often used for such a purpose but the experimental observation of TEE in a topological order remains a challenge. Here, we propose a scheme to observe TEE in the topological order by constructing specific minimum entropy states (MESs). We then experimentally construct the classical microwave analogs of the MESs and simulate the nontrivial topological order with the TEE in Kitaev toric code, which is in agreement with theoretical predictions. We also experimentally simulate the transition from Z2 topologically ordered state to topologically trivial state.

Interaction-Induced Fractionalization and Topological Superconductivity in the Polar Molecules Anisotropic t-J Model.

We show that the interplay between antiferromagnetic interaction and hole motion gives rise to a topological superconducting phase. This is captured by the one dimensional anisotropic t-J model which can be experimentally achieved with ultracold polar molecules trapped onto an optical lattice. As a function of the anisotropy strength we find that different quantum phases appear, ranging from a gapless Luttinger liquid to spin gapped conducting and superconducting regimes. In the presence of appropriate z anisotropy, we also prove that a phase characterized by nontrivial topological order takes place. The latter is described uniquely by a finite nonlocal string parameter and presents robust edge spin fractionalization. These results allow us to explore quantum phases of matter where topological superconductivity is induced by the interaction.

Coupled wire models of interacting Dirac nodal superconductors

Topological nodal superconductors possess gapless low energy excitations that are characterized by point or line nodal Fermi surfaces. In this work, using a coupled wire construction, we study topological nodal superconductors that have protected Dirac nodal points. In this construction, the low-energy electronic degrees of freedom are confined in a three dimensional array of wires, which emerge as pairing vortices of a microscopic superconducting system. The vortex array harbors an antiferromagnetic time-reversal and a mirror glide symmetry that protect the massless Dirac fermion in the single-body non-interacting limit. Within this model, we demonstrate exact-solvable many-body interactions that preserve the underlying symmetries and introduce a finite excitation energy gap. These gapping interactions support fractionalization and generically lead to non-trivial topological order. We also construct a special case of $N=16$ Dirac fermions where corresponding the gapping interaction leads to a trivial $E_8$ topological order that is closely related to the cancellation of the large gravitational anomaly.

Electromagnetic response of quantum Hall systems in dimensions five and six and beyond

Quantum Hall (QH) states are arguably the most ubiquitous examples of nontrivial topological order, requiring no special symmetry and elegantly characterized by the first Chern number. Their higher dimension generalizations are particularly interesting from both mathematical and phenomenological perspectives, and have attracted recent attention due to a few high profile experimental realizations. In this work, we derive from first principles the electromagnetic response of QH systems in arbitrary number of dimensions, and elaborate on the crucial roles played by their modified phase space density of states under the simultaneous presence of magnetic field and Berry curvature. We provide new mathematical results relating this phase space modification to the non-commutativity of phase space, and show how they are manifested as a Hall conductivity quantized by a higher Chern number. When a Fermi surface is present, additional response currents unrelated to these Chern numbers also appear. This unconventional response can be directly investigated through a few minimal models with specially chosen fluxes. These models, together with more generic 6D QH systems, can be realized in realistic 3D experimental setups like cold atom systems through possibly entangled synthetic dimensions.

Classification of (3+1)D Bosonic Topological Orders: The Case When Pointlike Excitations Are All Bosons

Topological orders are new phases of matter beyond Landau symmetry breaking. They correspond to patterns of long-range entanglement. In recent years, it was shown that in 1+1D bosonic systems there is no nontrivial topological order, while in 2+1D bosonic systems the topological orders are classified by a pair: a modular tensor category and a chiral central charge. In this paper, we propose a partial classification of topological orders for 3+1D bosonic systems: If all the point-like excitations are bosons, then such topological orders are classified by unitary pointed fusion 2-categories, which are one-to-one labeled by a finite group $G$ and its group 4-cocycle $\omega_4 \in \mathcal H^4[G;U(1)]$ up to group automorphisms. Furthermore, all such 3+1D topological orders can be realized by Dijkgraaf-Witten gauge theories.

Qudit quantum computation on matrix product states with global symmetry

Resource states that contain nontrivial symmetry-protected topological order are identified for universal single-qudit measurement-based quantum computation. Our resource states fall into two classes: one as the qudit generalizations of the 1D qubit cluster state, and the other as the higher-symmetry generalizations of the spin-1 Affleck-Kennedy-Lieb-Tasaki (AKLT) state, namely, with unitary, orthogonal, or symplectic symmetry. The symmetry in cluster states protects information propagation (identity gate), while the higher symmetry in AKLT-type states enables nontrivial gate computation. This work demonstrates a close connection between measurement-based quantum computation and symmetry-protected topological order.

Coupled wire model of symmetric Majorana surfaces of topological superconductors

Time reversal symmetric topological superconductors in three spatial dimensions carry gapless surface Majorana fermions. They are robust against any time reversal symmetric single-body perturbation weaker than the bulk energy gap. We mimic the massless surface Majorana's by coupled wire models in two spatial dimensions. We introduce explicit many-body interwire interactions that preserve time reversal symmetry and give energy gaps to all low energy degrees of freedom. We show the gapped models generically carry non-trivial topological order and support anyonic excitations.

Symmetry-protected topologically ordered states for universal quantum computation

Measurement-based quantum computation is a model for quantum information processing utilizing local measurements on suitably entangled resource states for the implementation of quantum gates. A complete characterization for universal resource states is still missing. It has been shown that symmetry-protected topological order in one dimension can be exploited for the protection of certain quantum gates in measurement-based quantum computation. In this paper we show that the two-dimensional plaquette states on arbitrary lattices exhibit nontrivial symmetry-protected topological order in terms of symmetry fractionalization and that they are universal resource states for quantum computation. Our results of the nontrivial symmetry-protected topological order on arbitrary 2D lattices are based on an extension of the recent construction by Chen, Gu, Liu and Wen [Phys. Rev. B \textbf{87}, 155114 (2013)] on the square lattice.