This paper studies the estimation of high-dimensional, discrete, possibly sparse, mixture models in the context of topic models. The data consists of observed multinomial counts of p words across n independent documents. In topic models, the p×n expected word frequency matrix is assumed to be factorized as a p×K word-topic matrix A and a K×n topic-document matrix T. Since columns of both matrices represent conditional probabilities belonging to probability simplices, columns of A are viewed as p-dimensional mixture components that are common to all documents while columns of T are viewed as the K-dimensional mixture weights that are document specific and are allowed to be sparse. The main interest is to provide sharp, finite sample, ℓ1-norm convergence rates for estimators of the mixture weights T when A is either known or unknown. For known A, we suggest MLE estimation of T. Our nonstandard analysis of the MLE not only establishes its ℓ1 convergence rate, but also reveals a remarkable property: the MLE, with no extra regularization, can be exactly sparse and contain the true zero pattern of T. We further show that the MLE is both minimax optimal and adaptive to the unknown sparsity in a large class of sparse topic distributions. When A is unknown, we estimate T by optimizing the likelihood function corresponding to a plug in, generic, estimator Aˆ of A. For any estimator Aˆ that satisfies carefully detailed conditions for proximity to A, we show that the resulting estimator of T retains the properties established for the MLE. Our theoretical results allow the ambient dimensions K and p to grow with the sample sizes. Our main application is to the estimation of 1-Wasserstein distances between document generating distributions. We propose, estimate and analyze new 1-Wasserstein distances between alternative probabilistic document representations, at the word and topic level, respectively. We derive finite sample bounds on the estimated proposed 1-Wasserstein distances. For word level document-distances, we provide contrast with existing rates on the 1-Wasserstein distance between standard empirical frequency estimates. The effectiveness of the proposed 1-Wasserstein distances is illustrated by an analysis of an IMDB movie reviews data set. Finally, our theoretical results are supported by extensive simulation studies.