Nonionic Surfactant Triton X-100 Research Articles

Synthesis of copolymer of aniline-o-phenylenediamine using nonionic surfactant Triton X-100: analysis of electrical conductivities and supercapacitor properties

Synthesis of copolymer of aniline-o-phenylenediamine using nonionic surfactant Triton X-100: analysis of electrical conductivities and supercapacitor properties

Synthesis of copolymer of aniline-o-phenylenediamine using nonionic surfactant Triton X-100: analysis of electrical conductivities and supercapacitor properties

Synthesis of copolymer of aniline-o-phenylenediamine using nonionic surfactant Triton X-100: analysis of electrical conductivities and supercapacitor properties

Effects of promoter and dedoping process on electrorheological response of polyaniline-graft-chitosan copolymer

In this study, electrorheological (ER) properties of biodegradable and conducting polyaniline-graft-chitosan (PAni-g-CS) copolymer particles were investigated. For this purpose, PAni and PAni-g-CS particles were synthesized by using in situ oxidative radicalic polymerization method. At first, PAni and PAni-g-CS/silicone oil (SO) ER suspensions (15% V/V) were subjected to external electric field and they exhibited low ER activity. When the external electric field strengths ([Formula: see text] were increased, both the suspensions showed electrical breakdown. Therefore, virgin PAni and PAni-g-CS were first subjected to dedoping process by treating with 1.0 M NaOH(aq) and non-ionic surfactant Triton X-100 (T-X) surfactant to enhance the expected ER activity and prevent the electrical breakdown. But we observed that the addition of T-X as promoter had no significant effect on the ER activity. On the other hand, electric filed-induced viscosities of both the suspensions were observed to enhance after the dedoping (DD) process and electrical breakdown prohibited. After the DD process, DD PAni-g-CS/SO ER system exhibited the highest electric field-induced viscosity by reaching 400[Formula: see text]Pa[Formula: see text]⋅[Formula: see text]s at [Formula: see text][Formula: see text]kV/mm. The highest ER efficiency was also obtained for DD PAni-g-CS/SO system at 15% (V/V) as 79. Additionally, typical shear thinning non-Newtonian viscoelastic behavior was observed under externally applied E. The conduction model of DD PAni-g-CS/SO system was determined to well fit the conduction model by showing a slope of [Formula: see text] calculated from the E vb. yield stress graph. In conclusion, conducting and biodegradable-dedoped PAni-g-CS particles would be a good candidate for potential ER applications as dry-based ER materials having high colloidal stability of 76%.

Enhanced crystalline cellulose degradation by a novel metagenome-derived cellulase enzyme

Metagenomics has revolutionized access to genomic information of microorganisms inhabiting the gut of herbivorous animals, circumventing the need for their isolation and cultivation. Exploring these microorganisms for novel hydrolytic enzymes becomes unattainable without utilizing metagenome sequencing. In this study, we harnessed a suite of bioinformatic analyses to discover a novel cellulase-degrading enzyme from the camel rumen metagenome. Among the protein-coding sequences containing cellulase-encoding domains, we identified and subsequently cloned and purified a promising candidate cellulase enzyme, Celcm05-2, to a state of homogeneity. The enzyme belonged to GH5 subfamily 4 and exhibited robust enzymatic activity under acidic pH conditions. It maintained hydrolytic activity under various environmental conditions, including the presence of metal ions, non-ionic surfactant Triton X-100, organic solvents, and varying temperatures. With an optimal temperature of 40 °C, Celcm05-2 showcased remarkable efficiency when deployed on crystalline cellulose (> 3.6 IU/mL), specifically Avicel, thereby positioning it as an attractive candidate for a myriad of biotechnological applications spanning biofuel production, paper and pulp processing, and textile manufacturing. Efficient biodegradation of waste paper pulp residues and the evidence of biopolishing suggested that Celcm05-2 can be used in the bioprocessing of cellulosic craft fabrics in the textile industry. Our findings suggest that the camel rumen microbiome can be mined for novel cellulase enzymes that can find potential applications across diverse biotechnological processes.

Enhanced washing of polycyclic aromatic hydrocarbons from contaminated soils by the empowered surfactant properties of de novo O-alkylated humic matter

Aqueous solutions of humic acid (HA) derivatized by a catalyzed O-alkylation reaction with methyl, pentyl, and benzyl groups at 40, 60, and 80% of total HA acidity were used to wash off polycyclic aromatic hydrocarbons (PAHs) from two contaminated soils. The enhanced surfactant properties enabled the alkylated HA to remove phenanthrene, anthracene, fluoranthene, and pyrene from both soils more extensively than the original unmodified HA, the 60% benzylation generally showing the greatest soil washing efficiency. For both soils, all alkylated HA revealed greater PAH removals than Triton X-100 nonionic surfactant, while the benzylated and methylated HA nearly and fully matched pollutants release by the anionic SDS in the coarse- and fine-textured soils, respectively. A consecutive second washing with 60% benzylated HA removed additional PAHs, in respect to the first washing, from the coarser-textured soil, except for fluoranthene, while removal from the finer-textured soil incremented even more for all PAHs. These findings indicate that the enhanced hydrophobicity obtained by a simple and unexpensive chemical derivatization of a natural humic surfactant can be usefully exploited in the washing of polluted soils, without being toxic to the soil biota and by potentially promoting the subsequent bio-attenuation of organic pollutants.

Enhanced charge capacity and stability of Germanium(IV) Sulfide-Based anodes through Triton X100-Assisted synthesis and polysulfide shuttle mitigation

Highly soluble germanium oxide,an amorphous macroreticular form of germanium oxide, was used as a precursor for the deposition of GeS2on reduced graphene oxide (rGO) through a low-temperature, wet-chemistry process. Thermal treatment of the solid provided an ultrathin rGO – supported amorphous GeS2coating. The GeS2@rGO composite was tested as a lithium ion battery (LIB) anode. Leveraging the versatility of wet chemistry processing, we employed strategies initially developed for mitigating polysulfide shuttle effects in lithium-sulfur batteries to enhance anode performance. The anode exhibited exceptional stability, surpassing 1000 cycles, with charge capacities exceeding 1220 and 870 mAh.g−1 at rates of 2 and 5 A.g−1, respectively. Performance improvements were achieved by minimizing GeS2 grain size using the non-ionic surfactant Triton X-100 during synthesis and preventing polysulfide shuttle effects through a negatively charged thick glass fiber separator, fluoroethylene carbonate additive (FEC) in EC:DEC (ethylene carbonate: diethyl carbonate) solvent, and a polyacrylic acid (PAA) binder. These cumulative modifications more than tripled the charge capacity of the germanium sulfide LIB anode. Feasibility was further demonstrated through full cell studies using a LiCoO2 counter electrode.

A novel approach to mixed micelles formation: study the interactions between bis-quaternary ammonium salts and nonionic surfactant Triton X-100

Abstract This article focuses on the description of novel mixed system formulations of bis-quaternary ammonium salts (bis-QASs) and the nonionic surfactant Triton X-100 (TX-100). Measurements of surface tension (γ), foam stability, contact angle (CA) and cloud point (CP) were investigated at different ratios of the given compounds. The results indicated that changes in the structure of the bis-QASs amphiphilic cation, including the length of the alkyl spacer and the presence or absence of –OH groups, affected the adsorption and micellization. Furthermore, the elongation of the alkyl spacer in the bis-QASs structure affects the increase in the CP temperature. The research carried out shows the future potential of mixed combinations (bis-QASs and TX-100) to be used in industrial applications.

Photocatalytic Destruction of Non-Ionic Surfactant Triton X-100 with Hydrogen Peroxide in Water in the Reactors with Immobilized TiO2

Photocatalytic Destruction of Non-Ionic Surfactant Triton X-100 with Hydrogen Peroxide in Water in the Reactors with Immobilized TiO2

Phase partitioning nature, interaction forces and thermodynamic parameters of triton X-100 and bovine serum albumin mixture: impacts of the composition of Na-salt

Herein, the assessment of interactions between a non-ionic surfactant (NIS) triton X-100 (TNX-100) and a globular protein bovine serum albumin (BSA) was explored through the determination of clouding nature in aqueous solution of sodium salts (Na-salts). Sodium chloride (NaCl), sodium acetate (NaOAc), sodium carbonate (Na2CO3), sodium oxalate (Na2Oxal), sodium sulphate (Na2SO4), and sodium phosphate (Na3PO4) have been chosen to assess their impacts on the clouding nature of TNX-100 + BSA mixture. The estimated cloud point (CP) values were noticed to be lowered with the enhancement of [Na-salts]. The lessening of CP values has been explained by the salting out effect of anions. The calculated standard Gibbs free energy change ( Δ G c o ) was positive at all examined conditions which illustrates the nonspontaneity of phase change. The standard enthalpy ( Δ H c o ) and entropy ( Δ S c o ) changes exhibited negative values at low contents of aq. Na-salts and positive values at high aq. Na-salts content. These consequences illustrate the presence of electrostatic interactions at low Na-salts concentration and hydrophobic interactions at high Na-salts concentration. Furthermore, enthalpy-entropy parameters were successfully computed and explained with proper clarification.

A sparse-dense hierarchical structured conductive elastomer composites for highly sensitive and stretchable strain sensor

Flexible strain sensor using conductive elastomer (CE) have fostered hope for the development of healthcare, human–machine interfaces, and soft robotics technologies. However, it is still challenging to obtain CE based strain sensor with excellent stretchability, wide strain range, high sensitivity coupled with outstanding stability via facile preparation process. Herein, combining the advantages of sparse and dense conductive network, a sparse-dense hierarchical structured conductive elastomer composites (CECs) based on natural rubber (NR) and modified MWCNTs (m-MWCNTs) is developed through facile one-pot synthesis. By means of the low cloud point of nonionic surfactant Triton x-100, the thick-sparse and thin-dense conductive layers as well as the excellent interface between hierarchical structure are formed by controlling the content of Triton x-100 and dispersed temperature. The severe slippage of sparse conductive network at small deformation and the avulsion of dense conductive network at large strain could synergistically enhance mechanical property and sensing performance of NR/m-MWCNTs CECs. Consequently, the designed stain sensor can achieve high sensitivity and linearity at a strain range of 0–200 % and 200–423 %, which are superior to most other state-of-the-art CECs strain sensors. Meanwhile, a wide range of detection (1 %-423 %), a fast response time (0.23 s), excellent repeatability, and stability are also obtained. Besides, our developed strain sensor was successfully applied in elbow pad and knee pad for monitoring human motion. In addition, NR/m-MWCNTs CECs exhibit the superior electric heating performance. The above satisfactory results reveal that our developed sparse-dense hierarchical CECs has the potential for applications in smart wearable electronics.

Extraction of chrysin from propolis and its selective encapsulation in synthetic/natural surfactant-based micelles

The encapsulation characteristics of chrysin (important flavonoid with potential food, pharmaceutical, and biomedical applications) was studied with nonionic surfactants Triton X-114 (TX) and Quillaja Saponin (QS), individually. The factors influencing the encapsulation efficiency (EE) of standard chrysin that is surfactant concentration, pH, NaCl concentration, and chrysin concentration were analyzed. The maximum EE of standard chrysin was found to be 98.23 ± 1.63% with TX micelles and 83 ± 2.31% with QS micelles under the following conditions: 0.02 mg/mL standard chrysin, 5% NaCl, pH 7, and 4% w/w TX 6% w/w QS. Selective extraction of chrysin from propolis was tried using three extraction techniques namely Maceration, Microwave-assisted Extraction (MAE), and Maceration with Microwave-assisted Extraction (MMAE). MAE, which gave a chrysin yield of 3 mg/g, was deemed the most suitable method for chrysin extraction from propolis. This MAE crude extract was subjected to encapsulation under the conditions previously optimized for standard chrysin. Specific encapsulation of chrysin from the propolis crude extract was achieved, with an EE of 92 ± 0.86% with TX and 84.97 ± 1.34% with QS. The encapsulated chrysin was characterized using particle size analysis and antioxidant activity. TX system was found to be the most suitable for the encapsulation, as it was able to selectively encapsulate chrysin from propolis, despite the presence of other interfering flavonoids in the crude extract. The microwave-assisted extraction combined with surfactant-based micellar encapsulation can be said to be an effective process for the extraction and encapsulation of chrysin from propolis.

Synthesis, Photophysical Properties, and Toxicity of o-Xylene-Bridged Porphyrin Dimers

In this work, a number of new porphyrin dimers coupled with spacers based on α,α’-dibromo-o-xylene were synthesized and characterized by 1H, 13C NMR, 1H-1H COSY NMR, UV-vis-spectroscopy, and MALDI-TOF mass spectrometry. The initial A3B-type hydroxy-substituted porphyrins form dimer structures with high yields of 80–85%, while the use of amino-substituted porphyrins as starting compounds leads to the heterocyclization and formation of N-heterocycle fused porphyrins. For porphyrin dimers, photophysical properties and quantum yields of singlet oxygen were investigated. The peripheral alkoxy-substituents increase fluorescence quantum yield in comparison with the unsubstituted compounds. Also, it was found that dimers are characterized by lower singlet oxygen quantum yields compared to the corresponding monomers. Model aggregation experiments in micellar systems demonstrate stabilization of the photoactive monomolecular form of all the porphyrins, using nonionic surfactant Triton X-100. Cytotoxicity of received dimers shows high inhibition against HEK293T cells in the absence of light.

Photocatalytic degradation efficiency of Rhodamine-B for CuO/CdO nanosheets attained through simple co-precipitation method

In the present investigation, the growth of CuO/CdO nanosheets by simple coprecipitation method and characterized by XRD, SEM with EDX, TEM, UV–visible and PL. The incorporation of the non-ionic surfactant Triton X-100 blend with CuO/CdO resulted in hexagonal shaped grains with a nanoporous structure. The pristine CuO and CdO display monoclinic and cubic phases, respectively, whereas the CuO/CdO exhibits a combination of two phases, as proven by XRD analysis. According to TEM analysis the CuO/CdO composite particle size was reduced in the range between 20 and 50 nm resulting, the bandgap value is decreased around 1.26 eV due to size effect. The photocatalytic activity against Rhodamine-B (RhB) showed a 94 % degradation efficiency as compared to pristine CuO (71.42 %) and CdO (77.83 %). Furthermore, the CuO/CdO nanocomposite catalyst dosage increasing the degradation efficiency was found to be 97.62 %. Although the nitration process is more efficient at pH 6, the degradation efficiency for CuO, CdO, and CuO/CdO was found to be 75.74, 85.96 %, and 99.88 % at pH 6. In acidic solution, the reusability of CuO/CdO was outstanding with a 95.80 % degradation efficiency after five successive cycles.

Modified locally derived graphene nanoplatelets for enhanced rheological, filtration and lubricity characteristics of water-based drilling fluids

Drilling fluid rheology, filtration, and lubricity are fundamental parameters that influence the efficiency and ease of drilling operations. The drilling industry is constantly exploring different research areas for stabilizing and improving these parameters at high temperatures. The use of drilling fluid additives, especially synthetic polymers, poses a threat to the environment. Herein, rice husk char (RHC) was used to synthesize graphene Nanoplatelets (GNP) whose surface is modified with triton-X100 nonionic surfactant. Field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR), Particle size distribution (PSD), Energy Dispersive X-Ray Analysis (EDX), and Zeta potential analysis are performed on the synthesized nanomaterials to verify their morphology, functional groups, particle size, elemental composition, and material stability. Synthesized GNP from RHC (GNP-RHC) along with surface-modified GNP-RHC (GNP-TXT) were examined critically and their properties compared using a water-based mud (WBM) formulation. The rheological and lubricity characteristics of all the mud samples were determined before and after hot rolling (AHR), and the filtration properties were determined under API and high pressure high temperature (HPHT) conditions. The TGA results indicate that GNP-TXT nanomaterial resists thermal degradation with 10% weight loss at 300 °C, while the zeta potential analysis indicates the materials are stable. Since the GNP-TXT particles are so well dispersed, the GNP-TXT-based muds worked better than the GNP-RHC-based muds and was more stable at controlling filtration and improving rheological properties. For example, at 1.5 g AHR, the plastic viscosity of GNP-TXT-based mud decreased by 22.2% from 9 to 7 cP, while that of GNP-RHC-based mud decreased from 17 to 7 cP by 59%. Also, the API and HPHT FL of WBM of 11 and 24.8 mL, respectively, were reduced by GNP-TXT-based muds to the range of 8.6 and 9.8 mL for API and 18.6 and 22.3 mL for HPHT. However, GNP-RHC-based drilling muds showed a lower fluid loss control of the WBM between 9.6 and 10.2 mL for API and between 19.6 and 23.6 mL for HPHT. Furthermore, the coefficient of friction of the WBM of 0.45 was decreased with GNP-RHC concentrations between 0.47 and 0.32, while GNP-TXT demonstrated a higher decrease between 0.26 and 0.20.

Микроэкстракционное концентрирование неионными ПАВ и цветометрическое определение фенола

The extraction of the tungsten blue complex formed by the reaction of phenol with Folin-Ciocalteu reagent (FCR) in the presence of a nonionic surfactant Triton X-100 in alkaline medium using the methodology of micellar extraction based on «clouding point» has been studied for the first time. Aqueous solutions of sodium carbonate and sodium sulfate were used to create pH and as a desalting agent. The latter, having a desalting effect, promotes phase separation in the system under study into a micellar phase saturated with surfactant (Triton X-100) and an aqueous phase depleted in surfactant without additional heating at room temperature. Optimal conditions for micellar phenol extraction were determined: FCR (0,2 n.) – Na2CO3 (6%) – Triton X-100 (2%) – Na2SO4 (3,2%). It is shown that micellar-saturated phases of Triton X-100 effectively extract the analytical form (tungsten blue complex), can be proposed for extraction-spectrophotometric and colorimetric determination of phenol. So, for the spectrophotometric determination of phenol (λmax= 760 nm), the Beer-Bouguer-Lambert law obeys an equation of the form: y = 0,0007x – 0,0079, R2 = 0,997. The range of defined contents is in the interval 7·10-7 – 6·10-5 M. A technique for the colorimetric determination of phenol in aqueous media (channel R) has been developed. The intensity of the chromaticity channel R (IR) linearly depends on pc(phenol) in accordance with the equation: y = 95,0x – 455; R2 = 0,997. The range of defined contents is in the interval 7·10-7 – 1·10-5 M. The profiles of the petal diagrams in the RGB CMYK color coordinates are constructed, the dependences of their area are obtained (S) and perimeter (P) from -lgc : (perimeter (P) y = 150x – 284; R2 = 0,994; area (S) y = 17710x – 66930; R2 = 0,994).

Application of curcumin in mixed properties of quaternary N-alkyl tropine-based ionic liquid surfactant with nonionic, anionic and zwitterionic surfactants

Curcumin has been found to be sensitive to the solution environment and has aroused great interest. Based on this, UV spectrophotometry with curcumin as a probe was employed to investigate the solution properties of surfactants. The reliability of UV spectrophotometry using curcumin as a probe was confirmed by comparing the outcomes with those obtained by surface tension method. The micellization behaviors of surfactant mixtures of tropine-based ionic liquid surfactant (TILS) with anionic surfactant sodium dodecyl sulfate (SDS), nonionic surfactant Triton X-100 (TX-100), and zwitterionic surfactant N-dodecyl-N,N-dimethylglycine (BS-12) were investigated, respectively. Based on the theory of regular solutions, the interaction parameters between the two surfactants and their corresponding thermodynamic parameters were analyzed. The negative βm and |βm| > |ln(CMC1/CMC2)| suggest intense attraction between two different surfactants. Thermodynamic parameters indicate that micelle formation is an exothermic and entropy-increasing process. Comparing the interaction parameters of the three systems, it is evident that TILS exhibits stronger synergistic effects in the formation of mixed micelles with SDS as compared to TX-100 and BS-12. These results demonstrate the feasibility of using curcumin for the study of surfactant compounding properties and broaden the application range of curcumin.

Two Spectrophotometric Methods Based on Diazotization Coupling Reaction for Determination of Genistein in Pure and Supplement

Genistein (GEN) is one of the predominant dietary isoflavones found in legumes such as soybeans. Genistein has been recommended as an osteoporosis treatment for postmenopausal women and elderly men, with the intention of reducing cardiovascular disease and hormone-dependent malignancies. Therefore, two sensitive and simple methods for quantifying it in the supplements preparation were developed.The first method (A) comprised employing the surfactant Triton X-114 to extract the result of the diazotization reaction with 4-Aminoacetophenone(4AMA) utilizing a cloud point extraction technique. The product was extracted using micelles of a non-ionic surfactant (TritonX-114) and then spectrophotometrically detected at a specified wavelength of 437nm. The linearity of the calibration curve was in the range of 0.25 -2.75 µg/mL of GEN(r = 0.9978) under optimal conditions. The average sample recovery was determined to be between 96 and 101 %. For 2 µg/mL of GEN, the relative standard deviation (RSD) was (0.27%). The second method (B) involved using the spectrophotometric-flow injection methodology for the same diazotization coupling reaction described above, and the orange colored dyewas measured at a wave length of 437 nm.Calibration curve were linear at different concentration range of GEN 10 to 100 µg/mL , relative standard deviation RSD% were 0.23 to 1.21. The proposed methods were applied to determine the presence of GEN in Supplements.

Magnetron sputtering onto nonionic surfactant for 1-step preparation of metal nanoparticles without additional chemical reagents

Plasma-based sputtering onto liquids (SoL) is a straightforward approach for synthesizing small metal nanoparticles (NPs) without additional stabilizing reagents. In this work, nonionic surfactant Triton X-100 was used for the first time as a host liquid for the SoL process and the production of colloidal solutions of gold, silver and copper NPs was demonstrated. The average diameter of spherical Au NPs lies in the range from 2.6 to 5.5 nm depending on the conditions. The approach presented here opens the pathway to the production of concentrated dispersions of metal NPs of high purity that can be dispersed in water for future usage, therefore extending further the reach of this synthesis pathway.

Deep Destruction of the Triton X-100 Nonionic Surfactant in Water by Advanced Oxidation Processes Involving Ozone

Deep Destruction of the Triton X-100 Nonionic Surfactant in Water by Advanced Oxidation Processes Involving Ozone

Physico-chemical study of the effects of electrolytes and hydrotropes on the clouding development of TX-100 and ceftriaxone sodium drug mixture

The potential interactions between third-generation broad-spectrum cephalosporin antibiotic ceftriaxone sodium (CTS) and nonionic surfactant triton X-100 (TX-100) in the absence and existence of various sodium based electrolytes (sodium chloride (NaCl), sodium acetate (NaAc), sodium sulphate (Na2SO4)) /hydrotropic salts (sodium benzoate (NaBenz) and sodium salicylate (NaSal)) were investigated. The CTS drug is widely used to treat bacterial infections and it showed remarkable reactivity towards Gram-positive and Gram-negative bacteria. The assessments of CP in the TX-100 + CTS system with NaSal demonstrated the hydrophilic interaction which was not found significant when NaBenz solutions were used. The CP values observed for TX-100 + CTS system in aq. electrolytes and hydrotropic salts media demonstrated the order: CPaq.NaSal>CPaq.NaBenz>CPaq.NaCl>CPaq.NaAc>CPaq.Na2SO4. Different thermodynamic variables such as Gibbs free energy (ΔGco), enthalpy (ΔHco), and entropy (ΔSco) changes of clouding were computed to evaluate the nature of interactions between CTS and TX-100 in various electrolytes and hydrotropes medium. The ΔGco was found to be positive in every case indicating the non-spontaneity of the phase separation process. The enthalpy–entropy compensation was analyzed in the respective mixtures and the plot of ΔHc0 vs ΔSc0 showed a linear relationship between them. The findings of this study may be highly useful in different pharmaceutical formulations. These interesting results can also be utilized as significant tools to understand the behaviors of drugs-surfactants interactions in various systems used in different pharmaceutical industries as well as in medical science.