The electron-phonon contribution ${\ensuremath{\rho}}_{\mathrm{ep}}(T,c)$ to the resistivity of an impure metal, or dilute metal alloy, can be drastically different from that of the ideally pure metal, ${\ensuremath{\rho}}_{\mathrm{ep}}^{0}(T)$, if, in the region of the Fermi energy, the conduction-electron relaxation time ${\ensuremath{\tau}}_{0}(\ensuremath{\epsilon})$ for impurity scattering varies with energy $\ensuremath{\epsilon}$ on a scale comparable to or less than the Debye energy $\ensuremath{\hbar}{\ensuremath{\omega}}_{D}$ of the metal. This effect is a consequence of the sensitivity of the (inelastic) electron-phonon resistivity to any energy-dependent component in the nonequilibrium electron-distribution function. We present a working formula for the effect and indicate several important consequences for nontransitional metals containing magnetic or nonmagnetic transitional impurities. In the limit of small impurity concentrations $c$, the alloy and host electron-phonon resistivities are connected to the electron-diffusion thermopower $S(T,c)$ of the alloy via the simple relation ${\ensuremath{\rho}}_{\mathrm{ep}}(T,c)\ensuremath{\simeq}{\ensuremath{\rho}}_{\mathrm{ep}}^{0}(T) {1+{(\frac{\ensuremath{\hbar}{\ensuremath{\omega}}_{D}}{{\ensuremath{\epsilon}}_{F}})}^{2}{[\frac{S(T,c)}{{S}_{0}(T)}]}^{2}}$, where ${S}_{0}$ denotes the "free-electron" thermopower. More generally, ${\ensuremath{\rho}}_{\mathrm{ep}}(T,c)$, and also ${\ensuremath{\rho}}_{\mathrm{imp}}(T,c)$, the resistivity resulting from impurity scattering, are expressed in terms of the first and second derivatives of ${\ensuremath{\tau}}_{0}$ at the Fermi energy ${\ensuremath{\epsilon}}_{F}$. The anomalous electron-phonon resistivity will cause sharp peaks to appear in the atomic-resistivity temperature curves of very dilute magnetic-impurity systems (e.g., $\mathrm{Cu}\mathrm{Fe}$, $\mathrm{Au}\mathrm{Fe}$, $\mathrm{Au}\mathrm{Mn}$). Experimentally, measurements of deviations from Matthiessen's rule should furnish useful information on the energy dependence of the electron-impurity scattering.
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