Non-edible Oil Research Articles

Sustainable synthesis of bio-diesel and jet-fuel range hydrocarbons from poisonous Abrus Precatorius seed oil over MoO3-HPW/Ga-KIT-6

Energy problems and environmental deterioration can be combated by renewable biodiesel production from poisonous, waste, and non-edible oil seeds. Molybdenum oxide and phosphotungstic acid were impregnated into gallium-incorporated KIT-6 mesoporous silica employing a hydrothermal technique, to construct MoO3-HPW/Ga-KIT-6 catalyst. Abrus precatorius (Rosary Pea) seeds were utilized to extract non-edible oil, which was then submitted to a catalytic reaction with freshly prepared MoO3-HPW/Ga-KIT-6 for the synthesis of eco-friendly bio-diesel. An optimal biodiesel yield of 100% was reached from Abrus precatorius oil using MoO3(5)-HPW(10)/Ga (20)-KIT-6 catalyst at 6:1 methanol to oil molar ratio, 100 °C and 3 h reaction time. Oleic, linolenic, eicosapentaenoic, arachidic, and behenic acids were esterified under ideal conditions, and the 1H NMR spectroscopy revealed the result was an isolated methyl ester. Additionally, MoO3(5)-HPW(10)/Ga(20)-KIT-6 catalyst have been effectively produced C16–C18 range jet fuels from Abrus precatorius seed oil (APSO) and Abrus oil methyl ester (AOME) through the hydrodeoxygenation route at 400 °C, WHSV 2.7 h−1, 40 bar H2 pressure (62% of C18H38) and 400 °C, WHSV 1.8 h−1, 30 bar H2 pressure (67% of C18H38) respectively. The high dispersion of molybdenum and HPW on the Ga/KIT-6 catalyst and the more acidic centers, which promote the selectivity of the biodiesel and jet-fuel range hydrocarbons (JFRH), are credited with the good catalytic performance; this was demonstrated by HR-TEM and NH3-TPD (341 μmol/g) analyses.

Novel concepts for the biocatalytic synthesis of second-generation biodiesel

Biodiesel is synthesized by the transesterification of triglycerides of oils with short-chain alcohols, such as methanol and ethanol. According to the Renewable Energy Directive guidelines (RED II 2018/2001/EU) the contribution of advanced biofuels, which do not include edible oils, towards the overall EU target, is at 1% in 2025 and at least 3.5% in 2030. Bioprocesses that valorize non-edible oils for the production of second-generation biodiesel could play a critical role in achieving this goal. Immobilized lipases, as well as other enzyme classes, such as cutinases and acyltransferases, are utilized as biocatalysts for this process. For the sustainability of the process, renewable materials can be used as immobilization matrices, or even enzymes anchored on the cells as whole-cell biocatalysts. Membrane reactors can also be employed to facilitate the enzymatic transesterification by conducting a continuous enzymatic reaction and simultaneously separate the products in a single operation. The advances on the aforementioned fast-pacing fields are presented in this work.

Yield optimization of nonedible vegetable oil-based bio-lubricant using design of experiments

In recent years, there has been a focused effort to reduce the harmful effects of synthetic and mineral-based lubricants by emphasizing the use of biodegradable-based lubricants. These lubricants play a crucial role in minimizing friction, ensuring smooth operation of machines, and reducing the likelihood of frequent failures. With petroleum-based reserves depleting worldwide, prices are rising, and environmental damage is increasing. However, biolubricants derived from nonedible vegetable oils offer environmental benefits as they are nontoxic, emit minimal greenhouse gases, and are biodegradable. In this study, biolubricants are synthesized from jatropha and jojoba oil using sulphuric acid (H2SO4) and hydrochloric acid (HCl) as catalysts through the transesterification and epoxidation processes. The optimization of influencing parameters is achieved using Taguchi’s orthogonal array, a statistical methodology. By employing design of experiments (DOE), the number of experimental trials is minimized while providing comprehensive details on the impact of control factors such as molar ratio, catalyst concentrations, and temperature. The results obtained from DOE reveal that the best optimized yield for jatropha biolubricant with H2SO4 and HCl catalysts is achieved with a molar ratio of 0.5:1.5, a temperature of 70 °C, and a catalyst concentration of 1.2 ml. The experimental yield for jatropha biolubricant with H2SO4 and HCl catalysts was measured at 226 ml and 238 ml, respectively, while the model predicted yield was 221 ml and 231 ml, respectively. The experimental yield for jojoba biolubricant with H2SO4 and HCl catalysts was recorded at 232 ml and 248 ml respectively, whereas the model predicted yield was 226 ml and 245 ml, respectively. Based on the analysis of variance (ANOVA) results, it is evident that among the three control factors, the molar ratio significantly influences the yield of both jatropha and jojoba biolubricants, as indicated by a p-value of less than 5%. The percentage contribution of the molar ratio in jatropha biolubricant with H2SO4 and HCl catalysts is found to be 98.99% and 97.2%, respectively. Furthermore, the R2 value, which exceeds 90%, signifies a strong relationship between the independent and dependent variables. The deviation between the experimental and regression-predicted equations for the yield remains within 2.5% for all combinations of jatropha and jojoba biolubricants. In conclusion, the study successfully prepared biolubricants from jatropha and jojoba-based non-edible vegetable oils and determined the optimal conditions for their production.Graphical abstract

Open-cell bio-based polyurethane foams modified with biopolyols from non-edible oilseed radish oil

Open-cell bio-based polyurethane foams modified with biopolyols from non-edible oilseed radish oil

Review on Performance and Emissions Characteristics of Compression Ignition Engine Fueling Non-Edible Vegetable Oil

The tremendous exhaustion of resources, a surprising price increase of petroleum fuel and worldwide ecological issues implement to find renewable fuel for compression ignition engine. Non-edible vegetable oils have proven consensus to opt as a replacement for diesel fuel due to comparable properties and less-pollutant characteristics. Using Unmixed Untreated Non-edible Vegetable Oil (UUNVO) in the CI engine matches the needs of a sustainable future and restricts the intensifying cost involved in biodiesel production. This paper aims to review the influence of various UUNVO (Karanja, Jatropha, Neem, Linseed, Mahua and Rubber Seed etc.) on the important performance parameters and emission level of diesel engine. UUNVO can be fuelled to the unmodified CI engine. However, the viscosity of UUNVO is reasonably higher compare to diesel fuel at room temperature, which deteriorates the engine performance and exhaust emission. Minor changes in the injection line for preheating the UUNVO and operating parameters are the way to improve it. It can clearly understand here that preheated UUNVOs typically increase NOx emissions and decrease PM, HC, and CO emissions level compared to standard diesel. UUNVO can substitute diesel fuel completely for short-duration operation. With the long-duration operation, UUNVO produces problems like poor engine performance, injector chocking, and erosion of piston crown, rings, cylinder liner, and other internal parts, and degradation of the lubricant. Problems raised due to durability can be minimized by controlling operational parameters.

Performance analysis and emission characteristics of VCR diesel engine using palm stearin oil biodiesel as fuel

Abstract The increasing depletion of fossil fuels has prompted international efforts to search for diesel substitutes. One way to considerably reduce fuel shortages would be to use bio-derived fuels as replacements. Transesterification of edible or nonedible vegetable oils yields biodiesel, which is one example of a bio-origin fuel and a workable solution. Biodiesel’s characteristics are often more advantageous than those of diesel. One well-known example of a nonedible vegetable oil is palm stearin. In this work, we investigate the potential use of transesterified palm stearin methyl esters (PSME) as a substitute fuel. A rated compression ratio (CR) of 17.5 and 210 bar of fuel injection pressure were employed in the experimental investigations, which were carried out at a constant speed of 1500 rpm. Our main goals were to reduce emissions and improve engine performance. The evaluation parameters encompassed brake thermal efficiency (BTE), brake-specific fuel consumption (BSFC), and emission indices. It was observed that using PSME led to better performance and fewer emissions when compared to using conventional diesel, especially when the CR was 17.5. Increased BTE, decreased BSFC, lower air–fuel ratios, and decreased volumetric efficiencies were all correlated with higher CR. As a byproduct of palm oil, PSME shows promise as a seasonally and geographically specific feedstock for biodiesel production, providing benefits over conventional diesel fuels in terms of performance and the environment.

Utilizing Manilkara zapota seed oil for biodiesel production and conducting an investigation into its properties and characteristics

<p>Biodiesel can be derived from the oils of fruit seeds for powering diesel engines, and this study focuses on extracting biodiesel from Manilkara Zapota seeds, which are readily available and not intended for human consumption. The primary aim is to underscore the use of non-edible oils as a cost-effective raw material for biodiesel production. The research indicates a successful production yield of 92.45% using a 0.76% catalyst, an excess of 6 methanol equivalents in comparison to the oil, a temperature of 62°C, and a reaction time of 90 minutes. The biodiesel obtained from Manilkara Zapota seed oil predominantly comprises methyl esters of oleic, stearic, and palmitic acids, presenting a viable alternative to fossil diesel for unmodified diesel engines. Optimal performance variables for maximum conversion efficiency were determined as a 40°C reaction temperature, 6:1 alcohol-to-oil ratio, 120 minutes of experimental duration, and a 0.5wt.% NaOH catalyst. Among these variables, the alcohol-to-oil ratio was identified as the most influential, contributing 84.34% to the overall performance. The thermal profile of Manilkara Zapota Seeds biomass exhibited multistage decomposition behavior. The synthesized Manilkara Zapota Methyl Ester (MZME) derived from seed oil, using the optimized performance variables, complies with the ASME D 6751 and EN14214 Biodiesel Standards.</p>

Microwave-assisted transesterification of Litchi chinensis seed oil using extracted KOH from potato waste for sustainable development

The fast depletion of conventional fuel supplies has forced the world to find suitable substitutes to overcome the expected energy crisis. Fossil fuels also contribute to global warming because of their harmful emissions. Biofuels are sustainable and environment friendly. Biodiesel can be sourced from both edible and non-edible oils to replace fossil fuels. To avoid a shortage of food supply, it is preferred to produce biodiesel from non-edible oils. In this research, Litchi chinensis seed oil (LSO) is used as a feedstock to synthesize biodiesel employing transesterification using a microwave oven. The catalyst, potassium hydroxide (KOH), used in this research was extracted from potato waste. Sun-dried potato waste was converted into ash. The produced ash is then dissolved in distilled water, leading to a 34% yield of KOH. The transesterification achieves a 92.9% conversion rate under the conditions: 30% microwave power utilization, a catalyst loading of 15% (W/W), a stirring speed of 700 RPM, and a methanol concentration of 70% (V/V) with an 8-min reaction time. Response surface methodology (RSM), in comparison with artificial neural networks (ANNs), has been utilized for the optimization of biodiesel yield, giving efficient results with errors of 0.003% for RSM and 0.005% for ANN. Consequently, the study reports optimized biodiesel yields of 92.9% (experimental), 93.27% (RSM), and 92.40% (ANN). Physicochemical properties such as kinematic viscosity (4.4 mm2/s) at 40°C, density (875 kg/m3) at 15°C, cetane number (53.2), calorific value (38.8 MJ/kg), flash point (175°C), oxidative stability (6.1 h), and cold flow properties were determined with respect to the ASTM and EN standards. The findings reveal that biofuels primarily support Sustainable Development Goals (SDGs) 7 and 13, with the prime focus on “affordable and clean energy” and “climate action,” respectively.

Optimization and modeling of the performance of compression ignition engine fired on biofuel from non-edible vegetable oils

Compression ignition CI engine are versatile engines required for both industrial and domestic purposes. CI finds application in household mill, transportation and as components in energy plants. Operating the CI engine with biodiesel and its combination with fossil-based diesel is being encouraged to combat environmental menace of using only fossil diesel. This current work seeks to probe into comparison between the use of biodiesel and its emulsion to improve the performance CI engine. Methyl esters was synthesized from blends of three nonedible oils; Tevetia Peruviana, Honne and Neem (THN) using catalyst made from three bio wastes mixture. The production process was optimized using Taguchi tool. The THN methyl esters (THNME) obtained was assessed for fuel properties. Box Behnken tool was adopted to generate 17 investigational steps to explore the effect of THNME 100 and parts containing 20% and 60% of THNME on the fuel efficiency and safety of the CI engine. These fuel mixes were used as fuel in an unmodified single cylinder CI engine. The engine was operated on three engine loads (EL) 25%, 50% and 75% as well as engine speeds (ES) 1500, 2500 and 3500 rpm (rpm). The result obtained showed that blend of THNME with fossil diesel has the minimum exhaust gas temperature EGT. ANOVA of the performance result shows that the model developed is suitable to predict the behaviour of brake power and exhaust gas temperature only. This work conclude that B20 is moderately fuel efficient and safer for the unmodified engine in terms of EGT and BSFC.Novelty: Emulsion of THNME B20 is a preferred fuel for the safety of the unmodified CI engine because of low EGT

Comparative analysis of compression ignition engines performance and emission characteristics devouring edible and nonedible oil biodiesel

AbstractThe globe is in search for an upgraded and compatible alternative of diesel to triumph over pollution and its limited availability issues. Researchers are using biodiesel from various edible and non‐edible oil sources to reduce environmental footprint of diesel. This article compares the performance and emission characteristics of diesel engines fueled by edible and non‐edible oil biodiesel. In this work, five biodiesels (methyl esters of microalgae, jatropha, karanja, soybean, and sunflower) are tested and transesterification is used to produce methyl esters to optimize their physiochemical properties. It is observed that all the properties lie in tolerance limits. To examine the compatibility of the proposed methyl esters two performance characteristics, brake thermal efficiency and brake specific fuel consumption are examined. Further, the emission characteristics such as nitrogen oxides, carbon monoxide, hydrocarbons, and carbon dioxides are investigated. To validate results the blend characteristics are compared to diesel. The relative analysis revels that the brake thermal efficiency is declined by 8.87% as compared to diesel whereas the brake specific fuel consumption is increased by 4.28%. The carbon monoxide and hydrocarbon levels are decreased by 7.32% and 20.56% whereas nitrogen oxides and carbon dioxide levels are increased by 7.47% and 4.80%, respectively. The analysis infers that microalgae biodiesel gives adequately better characteristics.

Biodiesel production from hempseed (Cannabis sativa L.) oil: Providing optimum conditions by response surface methodology

This study focuses on the optimization of biodiesel synthesis using non-edible hempseed oil as the feedstock. The response surface method was used to find the best methanol: oil molar ratio, catalyst concentration, reaction temperature, and reaction duration for the transesterification process. The center composite design experimental design was used to make the design. A total of 30 cycles were conducted to adjust the four parameters at five different levels in order to optimize the biodiesel production process. It was found that the best conditions for transesterification of hempseed oil were a KOH catalyst concentration of 0.80 wt.%, a molar ratio of 7.41:1, a reaction time of 62.83 min, and a reaction temperature of 61.92 °C. Under these optimized reaction conditions, the predicted biodiesel yield was 95.57%, while the experimental yield was 95.24%. The biodiesel produced using the optimized parameters was analyzed for its properties, and the findings demonstrated that it met the requirements of EN 14214, a standard for biodiesel quality. The optimization of the biodiesel synthesis process using non-edible hempseed oil contributes to the exploration of alternative and sustainable feedstocks for biodiesel production. The values of the produced biodiesel within the standard range demonstrate its suitability for commercial applications and strengthen the potential of hemp seed oil as a suitable raw material for biodiesel production.

Novel solid catalyst sulfonic acid functionalized carbonaceous material for biodiesel production

A one-pot hydrothermal carbonization-sulfonation procedure was employed to develop robust, carbon-based solid catalyst sulfonic acid functionalized carbonaceous material (SAFACAM) possessing acidic functions up to 5.31 mmol g−1 for the first time at 80 °C. With its atom-efficient, one-pot preparation from a plentiful natural biomass derivative (glucose), the current catalyst benefits the environment and has the potential to lower the overall cost of producing biodiesel by converting cheap raw materials. The diminishing supply of fossil fuels coupled with the polluting effects of their use is driving the quest for more sustainable sources of energy. The pursuit of producing biodiesel from affordable, non-edible oil has become progressively significant due to its dual benefits of sustainability and cost-efficiency. In this context, Jatropha curcas oil (JCO) has gained attention in the energy sector, as it holds promise as a viable feedstock for biodiesel manufacturing and a renewable energy solution for numerous nations. Additionally, the catalyst exhibited exceptional physical stability and reactivity throughout 5 consecutive cycles, establishing its potential as a highly promising catalyst for sustainable biodiesel manufacture.

Synthesis and Characterization of Nanoparticle Enhanced Biodiesel using Azadirachta Indica (Neem) leaf extract

Diesel fuel demand is rising globally but its direct combustion possesses many adverse health and environmental impacts. Biodiesel production has emerged as a promising substitute for commercial diesel. Biodiesel is usually prepared from edible or non-edible vegetable oils. Using edible oils for biodiesel production raises many issues such as availability, food security and cost. While in case of non-edible oils, main issues arise in terms of land use change. Fortunately, waste vegetable oils (WVO) are excellent options to solve all these problems, except for trivial costs associated with their collection and recycling. Despite several scientific breakthroughs, the biofuel production process is a slow process and there are various side reactions which inhibit the transesterification reaction. In the recent decade, nanotechnology has vastly expanded. The unique characteristics of nanoparticles such as high chemical stability, adsorption capacity and catalytic activity makes it attractive for enhancing the biofuel production process. In the present work, silver and copper oxide nanoparticles (Ag-NP and CuO-NP) were prepared using a green synthesis method. Three samples of biodiesel were prepared from WVO, one using Ag-NP catalyst, one using CuO-NP catalyst and one without nanoparticles. Prepared biofuel showed a remarkable yield of 72.9% and 64.6%, for Ag-NP biodiesel and CuO-NP biodiesel respectively. Acid values of both the prepared samples of NP biodiesels were decreased by over 7% ensuring a better quality.

Sustainable biofuel synthesis from non-edible oils: a mesoporous ZSM-5/Ni/Pt catalyst approach.

This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst. The HDO activity was thoroughly examined and contrasted using the high surface area catalyst Ni/Pt-ZSM-5 as well as other supports like MCM-48 and H-beta. Ni/Pt bimetals supported on mesoporous ZSM-5 were created via reverse order impregnation to facilitate HDO of non-edible oils. Techniques such as XRD, FT-IR, BET, HR-TEM, HR-SEM, TPD, and TGA were used to characterize the produced catalysts. The synthesized catalysts considerably influenced the hydrodeoxygenation activities for the synthesis of lengthy chain hydrocarbons in a stainless-steel reactor with a high-pressure fixed bed between 300 and 375 °C under 10-40 bar hydrogen pressure. High levels of Ni/Pt-ZSM-5 acidity, textural, and H2 consumption qualities were discovered. Distributions of the products were also reviewed, along with comparisons of the structure-activity connections.

Influence of Mango Seed Oil on Surface Roughness and Cutting Temperature During Sustainable Turning of AISI 1525 Steel Under Minimum Quantity Lubrication Environment

Mineral oil-based cutting fluids have several mechanical advantages. The use of mineral oil has been questioned due to its adverse effect on machinists and the environment. There is need for a sustainable and biodegradable cutting fluid that can perform the task of problematic mineral oil. This study considered a non-edible vegetable oil, mango oil, as a lubricant in the turning operation of AISI 1525 steel using an MQL mode of fluid application. The performance of mango oil was compared with commercial mineral oil using SR and CT as performance metrics. Experiments were conducted under three levels of SS (355, 500, and 710 rev/min), FR (0.10, 0.15, and 0.20 mm/rev), and DOC (0.75, 1.00, and 1.25 mm). Taguchi L9 orthogonal array was adopted for the experimental settings. Afterward, TOPSIS, a multi-optimization tool was employed to determine the best cutting parameters for machining the workpiece with the tungsten carbide tool. The finding showed that mineral oil outperformed mango oil lubricant in terms of both SR and CT. The optimum CT and SR can be achieved using an SS of 355 rev/min, FR of 0.15 mm/rev, and DOC of 1.00 mm for both mango and mineral oil lubricants.

Experimental investigations on spray characteristics of non-edible oils using phase doppler particle analyser

Experimental investigations on spray characteristics of non-edible oils using phase doppler particle analyser

Biodiesel production feedstocks: current state in Algeria

Research and development of affordable, sustainable, and low-carbon energy sources capable of reducing dependence on fossil fuels, contributing to social and economic development, and improving environmental and health skills have become a global priority. In recent decades, biodiesel produced from oilseeds has received significant attention as an alternative biofuel. However, the use of first-generation oilseed crops has sparked controversy, and the use of local non-edible feedstocks is considered a promising alternative. The motivation behind this review is to provide an alternative and enlightening perspective on the use of non-edible vegetable oils for biodiesel production, with a particular focus on the current state of biodiesel production in Algeria. The objective is to assess the conditions under which this production could be sustainable and environmentally friendly while maintaining a balance between energy needs, economic stability, and environmental impact.

Application of Modified Seed Oils of Selected Fruits in the Synthesis of Polyurethane Thermal Insulating Materials.

The use of alternative raw material sources in polyurethane chemistry is necessary given the limited supply of fossil fuels, their rising prices and the concern for sustainability. The production of biopolyols from edible vegetable oils such as rapeseed oil, soybean oil or sunflower oil is often proposed. In order to avoid conflict with the global food economy, non-edible or waste oils are hoped to find application in chemical synthesis. The possibility of using oils from selected fruit seeds to obtain biopolyols is analyzed in this manuscript. Five biopolyols were obtained from watermelon, cherry, black currant, grape and pomegranate fruit seeds using the transesterification reaction of the oils with triethanolamine. Thermal insulating polyurethane foams were then obtained by replacing 75% of petrochemical polyol with the biopolyols in polyurethane systems. Based on an analysis of the foaming process, it was found that the incorporation of triethanolamine molecules into the biopolyols causes a catalytic effect. The use of such biopolyols allows eliminating the catalyst from a polyurethane foam formulation. The polyurethane biofoams obtained with the pomegranate-seed-based biopolyol were characterized by the highest content of closed cells (45 vol.%). The lowest content was found for the foams containing the currant-seed-based biopolyol (9%). The foams were characterized by thermal conductivity coefficients between 32 and 35 kW/m·K and densities of approximately 40 kg/m3. Good dimensional stability and compressive strength between 100 and 250 kPa make them suitable for use in construction.

Experimental Investigations on Thermophysical, Tribological and Rheological Properties of MoS2 and WS2 Based Nanolubricants with Castor Oil as Base Lubricant

Molybdenum disulfide (MoS2) and Tungsten disulfide (WS2) nanoparticles addition to castor oil produce nano lubricants of novel properties. These nanomaterial additives are dispersed thoroughly in the liquid phase and are intended to boost the base fluid's thermo-physical, rheological, and tribological properties. All these properties have been studied by varying concentrations of nanoparticles from 0.05 to 2.5%. The size of both nanoparticles are in the range of <20nm. The density of nano lubricants was found to change with respect to nanoparticle concentration and temperature. The density increases from 0.06 to 0.6% with respect to the increase in concentration and decreases by 4%, for increasing temperature from 25 to 100 o C. A significant (15 %) increase in thermal conductivity with MoS2 nanoparticles in lubricants could be observed while with WS2 nanoparticles only 8 % enhancement was observed. The rheological study suggests that nano lubricants have better dynamic viscosity and shear stress than neat castor oil. A tribology study showed improved lubrication properties of the nanolubricants as compared with base castor oil. The addition of MoS2 and WS2 nanoparticles in castor oil decreased the friction coefficient by 53 % and 42 %, respectively, and reduced the wear scar diameter by 24% and 20 %, respectively, as compared to base castor oil. This study was done to develop nonedible vegetable oil based nanolubricants exploring their potential as emerging lubricants.

Seasonal occurrence of major defoliators of castor in Tamil Nadu

Castor is a non-edible oil bearing crop adapted to dry lands of tropics and semi-arid tropics. The seasonal occurrence of major defoliators viz., semilooper, Spodoptera and hairy caterpillars in castor was recorded continuously for last ten years (2012-2022) at Tapioca and Castor Research Station, Yethapur. The results revealed that Spodoptera litura was the major defoliator with a mean population of 4.3 larva/plant /year followed by semilooper and hairy caterpillar with 1.74 larva/plant/year and 1.44 larva/plant/year respectively. The maximum population of defoliators was recorded every year during 43rd to 49th standard weeks (October, November).