We report the detection of SO2 emission from Io in Jupiter’s shadow, peaking near 26 Rayleigh/Å around 3150Å, and emission from its associated excitation–dissociation products, SO in the 2550Å band and S I in the 1800 and 1900Å multiplets. In addition, an unidentified emission spectrum was discovered between ∼4100Å and ∼5700Å, which appears to be a vibronic band. Its spectral lines are listed in neither the GEISA nor HITRAN database. The line spacing and wavelength regime are characteristic of molecular bending modes, which would imply a molecule with three or more atoms; e.g., SO2 or S2O. Alternative candidates for this species are positive or negative ions of SO2 and its daughter species. The wavelength-averaged intensity of this unidentified species is bracketed by intensities imaged through Galileo and Cassini filters when Io was in eclipse. Both the unidentified and SO2 emission are brighter on Io’s NE half (in the Jovian system), which is the side closer to Jupiter, but the unidentified emission is more asymmetric, suggesting a connection with Io’s wake emission or with volcanic activity. Weakening of the emission intensity between the early eclipse-resolved spectra indicate partial atmospheric collapse due to freezeout of the atmospheric column and the decay of energetic photoelectrons. Specific plume activity is not well constrained through examination of the disk-averaged mid-ultraviolet (MUV) emission spectrum. Simulating the observations using laboratory data published for the electron impact cross sections of SO2 indicates that this emission is consistent with dissociative excitation of SO2 by thermal electrons in the Jovian plasma torus plus a minor non-thermal electron component. Owing to uncertainty in the density and mean energy of non-thermal electrons, the observations are insufficiently constrained to extract the temperature of the upstream electrons. Without any non-thermal electrons, the best fit upstream electron temperature is ∼10eV; however, prior observations found the Jovian torus thermal electron temperature near Io to be 4–6eV and thus a non-thermal component is required to reduce the best-fit simulated electron temperature. The upstream temperature of electrons mixed with a non-thermal component that produced agreement between the simulated and observed absolute peak intensities (at 2550Å and 3150Å) and their ratio, is Te=5–6eV with an accompanying non-thermal component of electrons that is 5% of the thermal density and has a mean electron energy of35eV.
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