Nonradiative Decay Research Articles

Enhanced Spontaneous Emission Rate and Luminescence Intensity of CsPbBr3 Quantum Dots Using a High-Q Microdisk Cavity.

Perovskite quantum dots (QDs) are high-efficiency optoelectronic materials attracting great interest, but further improvement in the luminescence efficiency is crucial for their application. In this work, we enhance both the spontaneous emission rate and the photoluminescence (PL) intensity of CsPbBr3 QDs by coupling them to a high quality (Q) factor SiO2 microdisk cavity. Compared to conventional metal plasmonic cavities, the dielectric cavity structure suppresses the effects of quenching and energy transfer, which could introduce complex fluctuations and nonradiative decays. As such, we obtain a 5.9-fold enhancement of the PL intensity and a 5.6-fold enhancement of the emission rate. Moreover, the different enhancement behaviors for phonon sidebands allow us to further explore the different components in the broad emission peak of ensembled QDs. These results demonstrate the great potential of microdisk cavities in enhancing the luminescence in optoelectronic devices and exploring the exciton-photophysics of perovskite QDs.

Delayed Fluorescence in Dual-Doped Perovskite Nanocrystals: Insight into the Role of Dopants.

This study investigates the photophysical behaviour of Mn/Fe and Mn/Sn co-doped CsPbCl3 perovskite nanocrystals (NCs) to explore carrier dynamics and dopant interactions. Using gated photoluminescence (PL) and temperature-dependent measurements, we elucidate the impact of dopant chemistry on exciton behaviour, focusing on vibrationally assisted delayed fluorescence (VADF) and energy transfer mechanisms. The efficiency of VADF is influenced by factors such as the bandgap, temperature, quantum confinement, and host composition. In Mn/Fe co-doped NCs, Fe-induced trap states introduce additional radiative pathways, resulting in a unique emission around 515 nm. In contrast, in Mn/Sn co-doped NCs, Sn captures photoexcited carriers, preventing the VADF process and leading to non-radiative decay. The findings provide key insights into dopant-dopant interactions and the mechanisms governing carrier transfer, enhancing our understanding of these materials for future optoelectronic applications.

Room-temperature phosphorescent transparent wood

Transparent wood with high transmittance and versatility has attracted great attention as an energy-saving building material. Many studies have focused on luminescent transparent wood, while the research on organic afterglow transparent wood is an interesting combination. Here, we use luminescent difluoroboron β-diketonate (BF2bdk) compounds, methyl methacrylate (MMA), delignified wood, and initiators to prepare room-temperature phosphorescent transparent wood by thermal initiation polymerization. The resultant PMMA has been found to interact with BF2bdk via dipole-dipole interactions and consequently enhance the intersystem crossing of BF2bdk excited states. The transparent wood matrix can provide a rigid environment for BF2bdk triplets and serve as oxygen barrier to suppress non-radiative decay and oxygen quenching. The prepared afterglow material has the characteristics of diverse composition, long afterglow emission lifetimes, and high photoluminescence quantum yield. This afterglow transparent wood also demonstrates potential application value in areas such as high mechanical strength, good hydrophobicity, and high cost-effectiveness.

Precise Manipulation on the Structural Defects of Poly (Triazine Imide) Single Crystals for Efficient Photocatalytic Overall Water Splitting

AbstractConjugated polymers, represented by polymeric carbon nitrides (PCNs), have risen to prominence as new‐generation photocatalysts for overall water splitting (OWS). Despite considerable efforts, achieving highly crystalline PCNs with minimal structural defects remains a great challenge, and it is also difficult to examine the exact impact of complex defect states on OWS process, which largely limits their quantum efficiency. Herein, we devise a ‘in‐situ salt flux’ assisted copolymerization protocol by using nitrogen‐rich and nitrogen‐deficient monomers to precisely manipulate the structural defects of poly (triazine imide) (PTI) single crystals. Stoichiometric control between two comonomers enables continuous tunning of carbon‐ and nitrogen‐vacancies within PTI, allowing the construction of a series of PTI crystals with different defect states. Theoretical and experimental results unveil the carbon vacancies are related with the radiative decay of excitons, while the nonradiative decay is mainly derived from the nitrogen vacancies. Owing to the effective suppression of both radiative and nonradiative losses, the as‐synthesized PTI achieves a record apparent quantum efficiency of 37.8 % by one‐step‐excitation OWS. This work highlights the significance of rational control of the structural defects and describes clear structure‐property‐activity relationships in PTI photocatalyst, offering guidance for the development of polymer photocatalysts for solar fuel production.

Impact of the Acceptor Group on the Properties of Triphenylamine-Donor-Acceptor Dyes: An Experimental and Computational Study.

Three triphenylamine-Indane donor-acceptor dyes with different functional groups on the acceptor were studied to investigate how substitution would affect the optical properties. The dyes studied were IndCN, containing two malononitrile groups; InO, with two ketone groups; and InOCN, which features mixed functional groups. A combination of Raman spectroscopy, UV-vis absorption and emission spectroscopy, and density functional theory (DFT) calculations were employed for characterization. The dyes exhibited intramolecular charge transfer transitions with relatively high molar absorptivity (εabs) of ∼50 mM-1 cm-1 at 491-591 nm within the visible spectrum and emissions at 690-840 nm in dichloromethane. The malononitrile-containing dyes showed lower-energy absorption and emissions due to a reduced band gap compared to ketone-containing dyes. The bulkiness of the malononitrile group led to a bent geometry, increasing nonradiative decay and reducing the fluorescence quantum yield. The dyes exhibited fluorescence quantum yields less than 0.25 and lifetimes of ∼5 ns. Resonance Raman spectra and DFT calculations showed that the longer linker group (propen-1-ylidene linker) in these systems reduced the charge-transfer character of the optical transition. The emission intensities of the three dyes were temperature-sensitive, with ketone-containing dyes showing shifts in emission bands as well. This could be due to molecular stacking and intermolecular π-interactions.

Photophysical Properties, Fluorescence Quenching of Metformin Hydrochloride by Caffeine, and its Docking with the AMP-activated protein kinase receptor.

In this research, the photophysical properties of metformin hydrochloride (MF-HCl) were studied using spectroscopic and molecular docking techniques. The interaction between metformin hydrochloride and caffeine is essential for understanding the pharmacokinetics of metformin, particularly in populations with high caffeine consumption. Metformin is a first-line medication for managing type 2 diabetes, while caffeine is a widely consumed dietary stimulant. Knowing how caffeine may affect the action of metformin is crucial for effective diabetes management. The spectroscopic techniques results showed that the photophysical properties (fluorescence quantum yields, lifetime, radiative, and non-radiative decay) of the drug are influenced by solvent polarity and drug concentration. The binding mechanism of metformin hydrochloride-caffeine (MF-HCl-CAF) was identified through the fluorescence quenching method. The quenching of drugs induced by caffeine is due to ground state complex formation. The binding occurs due to hydrogen bonds and Van der Waals forces in the reaction. The förster resonance energy transfer (FRET) between metformin hydrochloride and caffeine was also calculated using flourtools.com software. The threshold distance (R0), for 50% energy transfer from metformin hydrochloride to caffeine is 1.81nm and the binding distance (r), between caffeine and the amino acid residue in metformin hydrochloride is 1.55nm. Dynamic light scattering (DLS), Zeta potential, and Fourier transform infrared (FTIR) spectroscopy confirm the conformational change of the drugs, as the caffeine molecule binds to metformin hydrochloride molecules. The molecular docking of metformin hydrochloride with the amp-activated protein kinase receptor (PDB Id: 1z0n) is analyzed. Again the docking of both metformin hydrochloride and caffeine (two ligands) with the protein receptor (PDB Id: 1z0n) was also analyzed and the results agreed with the fluorescence quenching techniques.

Deciphering the Photophysical Properties of Nonplanar Heterocyclic Compounds in Different Polarity Environments.

Nonplanar (butterfly-shaped) phenothiazine (PTZ) and its derivative's (M-PTZ) photophysical and spectral properties have been tuned by varying the solvents and their polarity and investigated employing spectroscopic techniques such as UV-Vis, steady-state and time-resolved fluorescence, and TDDFT calculations. The UV-Vis absorption studies and TDDFT calculations reveal two distinct bands for both compounds: a strong π-π* transition at shorter wavelengths and a weaker n-π* transition, which displays a little bathochromic shift in polar solvents. The detailed emission studies reveal that such dual emission is a result of the photoinduced excited-state conjugation enhancement (ESCE) process. The band at a shorter wavelength corresponds to the locally excited (LE) state, while the longer wavelength band arises from the planarized excited state resulting from ESCE. With the increase in solvent polarity, the LE band is less affected, whereas strong positive solvatochromism is observed for the ESCE band. As the solvent polarity increases, the ESCE band demonstrates significant positive solvatochromism, while emission intensity decreases with higher solvent polarity, suggesting stabilization of the excited state. The biexponential decay of fluorescence lifetimes further corroborates the dual emission behavior of PTZ and M-PTZ. PTZ exhibits a higher photoluminescence quantum yield (PLQY) than that observed for M-PTZ, and the solvent viscosity influences the PLQY, indicating that nonradiative decay is activated during the planarization of the excited state, also known as excited-state conjugation enhancement. Furthermore, the (time-dependent) density functional theory (TD) DFT calculations performed to understand the geometrical parameters and the electronic transitions of these model molecules further corroborate experimental findings. These findings underscore the significant influence of solvent polarity and molecular structure on the dual emission and excited-state dynamics of PTZ and M-PTZ, which eventually hold substantial implications for advanced photophysical applications.

Near-Infrared Photothermal Conversion by Isocorrole and Phlorin Derivatives.

Photothermal therapy is a promising strategy for treating tumors and bacterial infections by using light irradiation to locally heat tissues. Metalloisoporphyrinoid materials have been investigated for their use as singlet oxygen photosensitizers for photodynamic therapy but remain underexplored as photothermal agents. Recently, two metallophlorin and two metalloisocorrole materials were found to have strong near-infrared absorbance, with low photoluminescent quantum yields, suggesting high rates of nonradiative decay. Here we demonstrate that when encapsulated into aggregated organic nanoparticles (a-Odots), these materials show high photothermal conversion efficiencies between 67.3 ± 8.4 and 75.7 ± 4.1%. When considered alongside their ability to generate singlet oxygen, these materials may show promise as agents for dual photothermal and photodynamic therapy.

A computational study on the effect of structural isomerism on the excited state lifetime and redox energetics of archetype iridium photoredox catalyst platforms [Ir(ppy)2(bpy)]+ and Ir(ppy)3.

This study investigates the impact of structural isomerism on the excited state lifetime and redox energetics of heteroleptic [Ir(ppy)2(bpy)]+ and homoleptic Ir(ppy)3 photoredox catalysts using ground-state and time-dependent density functional theory methods. While the ground- and excited-state reduction potentials differ only slightly among the isomers of these complexes, our findings reveal significant variations in the radiative and non-radiative decay rates of the reactivity-controlling triplet 3MLCT states of these closely related species. The observed differences in radiative decay rates could be traced back to variations in the transition dipole moment, vertical energy gaps, and spin-orbit coupling of the isomers. In [Ir(ppy)2(bpy)]+, transition dipole moment differences play a significant role in controlling the relative lifetime of the triplet states, which we rationalized by a vectorial analysis of permanent dipole moments of the ground and excited states. Regarding the two isomers of Ir(ppy)3, changes in radiative decay rates were primarily attributed to variations in vertical energy gaps and intensity borrowing from other singlet-singlet transitions driven by spin-orbit coupling. Non-radiative decay variations were assessed in terms of differences in reorganization energies, adiabatic energy gap, and spin-orbit coupling. For both complexes, reorganization energies associated with low-energy molecular vibrations and metal-ligand bond length changes following the de-excitation process were major contributors. These insights provide a deeper understanding of how molecular design can be leveraged to optimize the performance of iridium-based photoredox catalysts, potentially guiding the development of more efficient catalytic systems for future applications.

Low Temperature Emissive Cyclometalated Cobalt(III) Complexes.

A series of CoIII complexes [Co(RImP)2][PF6], with HMeImP = 1,1'-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene)) and R = Me, Et, iPr, nBu, is presented in this work. The influence of the strong donor ligand on the ground and excited-state photophysical properties was investigated in the context of different alkyl substituents at the imidazole nitrogen. X-ray diffraction revealed no significant alterations of the structures and all differences in the series emerge from the electronic structures. These were probed via cyclic voltammetry and UV-vis spectroscopy, detailing the influence of the different alkyl substituents on the ground-state properties. All complexes are emissive at 77 K from a 3MC state, which exhibits lifetimes in the range of 1-5 ns at room temperature, depending on the alkyl substituent. Therefore, it is clearly shown that even small differences in the electronic structure have a large impact on the details of the excited state landscape. The observed behavior was rationalized by a detailed DFT analysis, which shows that the minimum-energy crossing point to the ground-state is located only slightly above the MC energy: Consequently, nonradiative decay to the ground state at room temperature is enabled, while at 77 K this path is prohibited, leading to low-temperature 3MC emission.

Suppression of Nonradiative Decay in TADF Emitters via a Macrocyclic Strategy: An Experimental Study.

To experimentally investigate the impact of macrocyclic structures on the nonradiative decay rate constants (knrs) of thermally activated delayed fluorescence (TADF), a macrocyclic molecule L-ring and its analogue NL-ring were designed and synthesized. The photophysical measurements reveal their TADF characteristics, and the knrs of the L-ring (4.19 × 106 s-1) is slower than that of the NL-ring (1.96 × 107 s-1), endowing the L-ring with a photoluminescence quantum yield of 92.00%. Therefore, the L-ring device exhibited a high external quantum efficiency of 25.61%.

Theoretical Study on the Internal Conversion Decay Pathways of Bithiophene-Fused Isoquinolines.

In this study, the radiative and nonradiative decay pathways from the first singlet excited states (denoted as S1) of three bithiophene-fused isoquinolines were investigated by using the mixed-reference spin-flip time-dependent density functional theory approach. These isoquinolines, which are prepared via [2 + 2 + 2] cycloaddition reactions between three types of bithiophene-linked diynes and nitriles, exhibit different fluorescence quantum yields in response to the positions of their sulfur atoms. The decay processes, including the fluorescence emission and internal conversion, were considered. In the internal conversion pathway, the minimum energy conical intersection structures between the ground and first singlet excited states (denoted as S0/S1 MECI) of the ring strain for the isoquinoline skeleton and the ring opening of the thiophene skeleton were systematically explored. Dewar-type ring strain resulted in the smallest energy barrier from the equilibrium geometries of the ground state (denoted as S0) to the MECI structures between the S0 and S1 states. The energy difference between the three types of bithiophene-fused isoquinolines at the transition state geometries of the S1 state varies owing to the steric effects between the methyl groups and the hydrogen atom of the thiophene ring, and the excitation energy increases owing to a decrease in aromaticity. In addition, the oscillator strengths of the S0 and S1 states were evaluated at the equilibrium geometries of the S1 state to determine the contribution of the fluorescence process. The obtained theoretical results are consistent with the experimental results.

Precise Manipulation on the Structural Defects of Poly (Triazine Imide) Single Crystals for Efficient Photocatalytic Overall Water Splitting.

Conjugated polymers, represented by polymeric carbon nitrides (PCNs), have risen to prominence as new-generation photocatalysts for overall water splitting (OWS). Despite considerable efforts, achieving highly crystalline PCNs with minimal structural defects remains a great challenge, and it is also difficult to examine the exact impact of complex defect states on OWS process, which largely limits their quantum efficiency. Herein, we devise a 'in-situ salt flux' assisted copolymerization protocol by using nitrogen-rich and nitrogen-deficient monomers to precisely manipulate the structural defects of poly (triazine imide) (PTI) single crystals. Stoichiometric control between two comonomers enables continuous tunning of carbon- and nitrogen-vacancies within PTI, allowing the construction of a series of PTI crystals with different defect states. Theoretical and experimental results unveil the carbon vacancies are related with the radiative decay of excitons, while the nonradiative decay is mainly derived from the nitrogen vacancies. Owing to the effective suppression of both radiative and nonradiative losses, the as-synthesized PTI achieves a record apparent quantum efficiency of 37.8% by one-step-excitation OWS. This work highlights the significance of rational control of the structural defects and describes clear structure-property-activity relationships in PTI photocatalyst, offering guidance for the development of polymer photocatalysts for solar fuel production.

How Structure and Hydrostatic Pressure Impact Excited-State Properties of Organic Room-Temperature Phosphorescence Molecules: A Theoretical Perspective.

Organic room-temperature phosphorescence (RTP) emitters with long lifetimes, high exciton utilizations, and tunable emission properties show promising applications in organic light-emitting diodes (OLEDs) and biomedical fields. Their excited-state properties are highly related to single molecular structure, aggregation morphology, and external stimulus (such as hydrostatic pressure effect). To gain a deeper understanding and effectively regulate the key factors of luminescent efficiency and lifetime for RTP emitters, we employ the thermal vibration correlation function (TVCF) theory coupled with quantum mechanics/molecular mechanics (QM/MM) calculations to investigate the photophysical properties of three reported RTP crystals (Bp-OEt, Xan-OEt, and Xan-OMe) with elastic/plastic deformation. By analyzing the geometric structures and stacking modes of these crystals, we observe that the geometric structure variations influence the electronic structures, subsequently modifying the transition properties and the energy consumption processes. Specifically, the presence of strong π-π interactions and hydrogen bonds in the Xan-OEt crystal inhibits a nonradiative decay process, thereby realizing long-lived emission. Additionally, the hybridized local and charge-transfer (HLCT) excited-state feature with the largest charge transfer excitation contributions (57.74%) for Xan-OEt stabilizes the triplet excitons and facilitates the radiative decay process, ultimately achieving high efficiency and long lifetime emissions. Furthermore, by applying high hydrostatic pressure for the Bp-OEt crystal, the RTP emission efficiencies and lifetimes are enhanced and blue-shifted. All of these results demonstrate the crucial role of molecular structure and stacking modes as well as the hydrostatic pressure effect in regulating RTP properties. Thus, our findings reveal the structure-packing-property relationship and highlight the control of molecular packing and the related tunable approaches, which could provide prospective strategies for constructing stimuli-responsive RTP emitters in practical applications.

Ultrafast Dynamics of Diketopyrrolopyrrole Dimers.

Diketopyrrolopyrroles (DPPs) have attracted attention for their potential applications in organic photovoltaics due to their tunable optical properties and charge-carrier mobilities. In this study, we investigate the excited-state dynamics of a DPP dimer using time-dependent density functional theory (TDDFT) and nonadiabatic molecular dynamics simulations. Our results reveal a near-barrierless hydrogen migration state intersection that facilitates ultrafast internal conversion with a lifetime of about 400 fs, leading to fluorescence quenching. Electronic density analysis along the relaxation pathway confirms a hydrogen atom transfer mechanism. These findings highlight the critical role of state intersections in the photophysical properties of DPP dimers, providing new insights for the design of functionalized DPP systems aimed at suppressing nonradiative decay for enhanced performance in photovoltaic applications.

Precise photorelease in living cells by high-viscosity activatable coumarin-based photocages.

Intracellular viscosity is a critical microenvironmental factor in various biological systems, and its abnormal increase is closely linked to the progression of many diseases. Therefore, precisely controlling the release of bioactive molecules in high-viscosity regions is vital for understanding disease mechanisms and advancing their diagnosis and treatment. However, viscosity alone cannot directly trigger chemical reactions. Inspired by molecular rotor fluorophores, we have developed a series of high-viscosity activated photocages by modifying the C3 position of the coumarin scaffold with electron-withdrawing groups. In low-viscosity environments, both fluorescence and photocleavage of the photocages are inhibited by nonradiative decay caused by intramolecular free rotation. In contrast, in high-viscosity environments, the restriction of this intramolecular rotation restores fluorescence and photocleavage. These unique photolysis properties enable the selective photorelease of these photocages in high-viscosity conditions. As a proof of concept, we have developed a drug delivery system that targets abnormal mitochondria with high viscosity. This system demonstrates enhanced photolysis efficiency in abnormal mitochondria compared to normal ones, allowing for precise drug release in diseased mitochondria while ensuring excellent biological safety in healthy mitochondria. We anticipate that these photocages will serve as convenient and efficient tools for the precise release of active molecules in high-viscosity environments.

Unusual high fluorescence of a 7,7'-diazaisoindigo derivative: A photophysical study.

7,7'-Diazaisoindigos are π-conjugated compounds but with poor luminescence properties. Their poor luminescence is generally attributed to the twisting around the central C7-C7' bond in the excited state which favors non-radiative decay. We have found an unusual high fluorescence quantum yield (ΦF ≈ 15%) in a N,N‑Octyl-7,7'-diazaisoindigo derivative incorporating two triphenylamine (TPA) subunits at 5,5'-positions (called compound 12). There are very few examples of fluorescent 7,7'-diazaisoindigos have been reported and the emission mechanism is generally associated by the hindering of the rotation around the central C7-C7' bond. Unexpectedly, 12 also experiences a twisting around the central C7-C7' bond in the excited state but is highly emissive. The intense fluorescence emission of 12 was attributed to the coexistence of two TPA-7-azaoxindole subunits acting as two fluorophores into a single molecule. The fluorescence emission of 12 is also sensitive to the polarity of the solvent. The intramolecular charge transfer character of the excited state was studied combining spectroscopic and theoretical methods.

Copper doped magnetic vortex nanoring based nanotherapeutics for bacterial infection tri-therapy: interplay of magnetic hyperthermia, chemodynamic therapy and photothermal therapy.

Infectious bacteria pose an increasing threat to public health, and hospital-acquired bacterial infections remain a significant challenge for wound healing. In this study, we developed an advanced nanoplatform utilizing copper doped magnetic vortex nanoring coated with polydopamine (Cu-MVNp) based nanotherapeutics for bacterial infection tri-therapy. This multifunctional nanoplatform exhibits remarkable dual-stimulus thermogenic capabilities and Fenton-like peroxidase activity. Exposure to an alternating magnetic field (AMF) and near-infrared (NIR) light allows the nanoring to elevate environmental temperatures through hysteresis losses and the non-radiative decay effects of the PDA coating. At a concentration of 150 μg mL-1, Cu-MVNp increases the temperature by 18.2 °C under an AMF, achieving a specific absorption rate (SAR) of 640.9 W g-1. On the other hand, under 808 nm NIR irradiation, the temperature rises by 42.6 °C, with a photothermal conversion efficiency of 46.45%. Furthermore, by incorporating copper ions (Cu), which can damage cell membranes themselves, Cu-MVNp was endowed with Fenton-like functions and can catalyze the formation of hydroxyl radicals (˙OH) from low concentrations (1 mM) of hydrogen peroxide (H2O2), thus enhancing the effectiveness of chemodynamic therapy (CDT). Cu-MVNp exhibits significant antibacterial efficacy, achieving notable kill rates against E. coli and S. aureus, with enhanced effects under NIR and nearly complete eradication with an AMF. In vivo tests using a mouse wound model confirm its potent bactericidal properties and good biocompatibility. The Cu-MVNp nanoring shows promise as an antibacterial treatment, potentially effective at inhibiting bacterial growth.

Highly efficient deep-red organic light emitting diodes based on acenaphthopyrazine derivatives via π-bridge with thermally activated delayed fluorescence

Two novel TADF emitters are obtained by combining acridine donor and AP acceptor to minimize non-radiative decay. Deep-red OLEDs are achieved with EQE over 14%, offering a promising strategy for efficient deep-red OLEDs.

Hydrogen Bond "Double-Edged Sword Effect" on Organic Room-Temperature Phosphorescence Properties: A Theoretical Perspective.

The strategy of designing efficient room-temperature phosphorescence (RTP) emitters based on hydrogen bond interactions has attracted great attention in recent years. However, the regulation mechanism of the hydrogen bond on the RTP property remains unclear, and corresponding theoretical investigations are highly desired. Herein, the structure-property relationship and the internal mechanism of the hydrogen bond effect in regulating the RTP property are studied through the combination of quantum mechanics and molecular mechanics methods (QM/MM) coupled with the thermal vibration correlation function method. Intermolecular interactions, excited-state transition properties, reorganization energies, radiative and nonradiative decay rates, and the intersystem crossing rates are analyzed in detail. Results show that intermolecular hydrogen bonds can effectively delocalize molecular orbitals, enhance spin-orbit coupling (SOC) effect, and thus accelerate intersystem crossing (ISC) processes. In addition, an intermolecular hydrogen bond can also suppress nonradiative transition by restricting molecular motion, thereby promoting generation of phosphorescence. However, an excessively enhanced intermolecular hydrogen bond effect promotes molecular vibrations, leading to increased reorganization energies and thus facilitating nonradiative energy consumption process. The hydrogen bond "double-edged sword" effect on RTP properties and nonradiative decay process is theoretically revealed. Therefore, reasonable control of the hydrogen bond strength is beneficial for the development of efficient RTP emitters. Our research provides rational explanations for previous measurements and highlights the hydrogen bond effect in constructing efficient RTP emitters.