Non-local Thermodynamic Equilibrium Model Research Articles

Composite hot subdwarf binaries – I. The spectroscopically confirmed sdB sample

Hot subdwarf-B (sdB) stars in long-period binaries are found to be on eccentric orbits, even though current binary-evolution theory predicts that these objects are circularized before the onset of Roche lobe overflow (RLOF). To increase our understanding of binary interaction processes during the RLOF phase, we started a long-term observing campaign to study wide sdB binaries. In this paper, we present a sample of composite binary sdBs, and the results of the spectral analysis of nine such systems. The grid search in stellar parameters (gssp) code is used to derive atmospheric parameters for the cool companions. To cross-check our results and also to characterize the hot subdwarfs, we used the independent XTgrid code, which employs Tlusty non-local thermodynamic equilibrium models to derive atmospheric parameters for the sdB component and phoenix synthetic spectra for the cool companions. The independent gssp and XTgrid codes are found to show good agreement for three test systems that have atmospheric parameters available in the literature. Based on the rotational velocity of the companions, we make an estimate for the mass accreted during the RLOF phase and the minimum duration of that phase. We find that the mass transfer to the companion is minimal during the subdwarf formation.

Photoionization and electron impact excitation cross sections for Fe I

Context. Iron is a major contributor to the opacity in the atmospheres of late-type stars, as well as a major contributor to the observed lines in their visible spectrum. Iron lines are commonly used to derive basic stellar parameters from medium/high resolution spectroscopy, that is, spectroscopy which shows metal content, effective temperature, and surface gravity. Aims. Here we present large R-matrix calculations for photoionization cross sections and electron impact collision strengths.Methods. The photoionization calculations included 35 configurations and 134 LS close coupling terms of the target ion. The eigenfunction expansion accounts for the photoionization of the outer nl subshells, with n ≥ 4, as well as the open inner 3d subshell. Our results include total and partial (term-to-term) photoionization cross sections for 936 energy terms of iron with principal quantum number ≤10, and total angular momentum from zero to seven. Our electron impact collision strengths include the lowest 46 LS terms of the atom.Results. The present photoionization cross sections should be considerably more accurate than those currently available in the literature. On the other hand, the electron impact cross sections, which are being reported for the first time, are needed in non-local thermodynamic equilibrium (NLTE) modeling of the solar spectrum and late-type stars in general.

Atomic data on inelastic processes in low-energy manganese-hydrogen collisions

Aims. The aim of this paper is to calculate cross sections and rate coefficients for inelastic processes in low-energy Mn + H and Mn+ + H− collisions, especially, for processes with high and moderate rate coefficients. These processes are required for non-local thermodynamic equilibrium (non-LTE) modeling of manganese spectra in cool stellar atmospheres, and in particular, for metal-poor stars.

ALMA multiline observations toward the central region of NGC 613

Abstract We report ALMA observations of molecular gas and continuum emission in the 90 and 350 GHz bands toward a nearby Seyfert galaxy, NGC 613. Radio continuum emissions were detected at 95 and 350 GHz from both the circumnuclear disk (CND) (r ≲ 90 pc) and a star-forming ring (250 ≲ r ≲ 340 pc), and the 95 GHz continuum was observed to extend from the center at a position angle of 20° ± 8°. The archival 4.9 GHz data and our 95 GHz data show spectral indices of α ≲ −0.6 and −0.2 along the jets and in the star-forming ring; these can be produced by synchrotron emission and free–free emission, respectively. In addition, we detected the emission of CO(3–2), HCN(1–0), HCN(4–3), HCO+(1–0), HCO+(4–3), CS(2–1), and CS(7–6) in both the CND and the ring. The rotational temperatures and column densities of molecules derived from J = 1–0 and 4–3 lines of HCN and HCO+ and J = 2–1 and 7–6 of CS in the CND and ring were derived. Furthermore, a non-local thermodynamic equilibrium model revealed that the kinetic temperature of Tk = 350–550 K in the CND is higher than Tk = 80–300 K in the ring, utilizing the intensity ratios of HCN, HCO+, and CS. The star-formation efficiency in the CND is almost an order of magnitude lower than those at the spots in the star-forming ring, while the dominant activity of the central region is star formation rather than active galactic nuclei. We determined that the large velocity dispersion of CO extending towards the north side of the CND and decomposing into blueshifted and redshifted features is probably explained by the effect of the radio jets. These results strongly suggest that the jets heat the gas in the CND, in which the feedback prevents star formation.

Influence of Xe and Kr impurities on x-ray yield from debris-free plasma x-ray sources with an Ar supersonic gas jet irradiated by femtosecond near-infrared-wavelength laser pulses.

Many aspects of physical phenomena occurring when an intense laser pulse with subpicosecond duration and an intensity of 10^{18}-10^{19}W/cm^{2} heats an underdense plasma in a supersonic clustered gas jet are studied to determine the relative contribution of thermal and nonthermal processes to soft- and hard-x-ray emission from debris-free plasmas. Experiments were performed at the University of Nevada, Reno (UNR) Leopard laser operated with a 15-J, 350-fs pulse and different pulse contrasts (10^{7} or 10^{5}). The supersonic linear (elongated) nozzle generated Xe cluster-monomer gas jets as well as jets with Kr-Ar or Xe-Kr-Ar mixtures with densities of 10^{18}-10^{19}cm^{-3}. Prior to laser heating experiments, all jets were probed with optical interferometry and Rayleigh scattering to measure jet density and cluster distribution parameters. The supersonic linear jet provides the capability to study the anisotropy of x-ray yield from laser plasma and also laser beam self-focusing in plasma, which leads to efficient x-ray generation. Plasma diagnostics included x-ray diodes, pinhole cameras, and spectrometers. Jet signatures of x-ray emission from pure Xe gas, as well as from a mixture with Ar and Kr, was found to be very different. The most intense x-ray emission in the 1-9 KeV spectral region was observed from gas mixtures rather than pure Xe. Also, this x-ray emission was strongly anisotropic with respect to the direction of laser beam polarization. Non-local thermodynamic equilibrium (Non-LTE) models have been implemented to analyze the x-ray spectra to determine the plasma temperature and election density. Evidence of electron beam generation in the supersonic jet plasma was found. The influence of the subpicosecond laser pulse contrast (a ratio between the laser peak intensity and pedestal pulse intensity) on the jets' x-ray emission characteristics is discussed. Surprisingly, it was found that the x-ray yield was not sensitive to the prepulse contrast ratio.

The gaseous debris disk of the white dwarf SDSS J1228+1040. HST/COS search for far-ultraviolet signatures

Context. Gaseous and dust debris disks around white dwarfs (WDs) are formed from tidally disrupted planetary bodies. This offers an opportunity to determine the composition of exoplanetary material by measuring element abundances in the accreting WD’s atmosphere. A more direct way to do this is through spectral analysis of the disks themselves. Aims. Currently, the number of chemical elements detected through disk emission-lines is smaller than that of species detected through lines in the WD atmospheres. We assess the far-ultraviolet (FUV) spectrum of one well-studied object (SDSS J122859.93+104032.9) to search for disk signatures at wavelengths Methods. We performed FUV observations (950−1240 A) with the Hubble Space Telescope/Cosmic Origins Spectrograph and used archival optical spectra. We compared them with non-local thermodynamic equilibrium model spectra. Results. No disk emission-lines were detected in the FUV spectrum, indicating that the disk effective temperature is T eff ≈ 5000 K. The long-time variability of the Ca ii IRT was reproduced with a precessing disk model of bulk Earth-like composition, having a surface mass density of 0.3 g cm -2 and an extension from 55 to 90 WD radii. The disk has a spiral shape that precesses with a period of approximately 37 years, confirming previous results.

The gaseous debris disk of the white dwarf SDSS J1228+1040

Gaseous and dust debris disks around white dwarfs (WDs) are formed from tidally disrupted planetary bodies. This offers an opportunity to determine the composition of exoplanetary material by measuring element abundances in the accreting WD's atmosphere. A more direct way to do this is through spectral analysis of the disks themselves. Currently, the number of chemical elements detected through disk emission-lines is smaller than that of species detected through lines in the WD atmospheres. We assess the far-ultraviolet (FUV) spectrum of one well-studied object (SDSS J122859.93+104032.9) to search for disk signatures at wavelengths <1050 angstrom, where the broad absorption lines of the Lyman series effectively block the WD photospheric flux. We performed FUV observations (950-1240 angstrom) with the Hubble Space Telescope/Cosmic Origins Spectrograph and used archival optical spectra. We compared them with non-local thermodynamic equilibrium model spectra. In addition, we investigate the Ca II infrared triplet (IRT) line profiles to constrain disk geometry and composition. No disk emission-lines were detected in the FUV spectrum, indicating that the disk effective temperature is about 5000K. The long-time variability of the Ca II IRT was reproduced with a precessing disk model of bulk Earth-like composition, having a surface mass density of 0.3g/cm2 and an extension from 55 to 90 WD radii. The disk has a spiral shape that precesses with a period of approximately 37 years, confirming previous results.

The far-ultraviolet spectra of two hot PG 1159 stars

PG1159 stars are hot, hydrogen-deficient (pre-) white dwarfs with atmospheres mainly composed of helium, carbon, and oxygen. The unusual surface chemistry is the result of a late helium-shell flash. Observed element abundances enable us to test stellar evolution models quantitatively with respect to their nucleosynthesis products formed near the helium-burning shell of the progenitor asymptotic giant branch stars. Because of the high effective temperatures (Teff), abundance determinations require ultraviolet spectroscopy and non-local thermodynamic equilibrium model atmosphere analyses. Up to now, we have presented results for the prototype of this spectral class and two cooler members (Teff in the range 85,000-140,000 K). Here we report on the results for two even hotter stars (PG1520+525 and PG1144+005, both with Teff = 150,000 K) which are the only two objects in this temperature-gravity region for which useful far-ultraviolet spectra are available, and revisit the prototype star. Previous results on the abundances of some species are confirmed, while results on others (Si, P, S) are revised. In particular, a solar abundance of sulphur is measured in contrast to earlier claims of a strong S deficiency that contradicted stellar evolution models. For the first time, we assess the abundances of Na, Al, and Cl with newly constructed non-LTE model atoms. Besides the main constituents (He, C, O), we determine the abundances (or upper limits) of N, F, Ne, Na, Al, Si, P, S, Cl, Ar, and Fe. Generally, good agreement with stellar models is found.

Atomic data on inelastic processes in low-energy beryllium-hydrogen collisions

Aims. Inelastic processes in low-energy Be + H and Be + + H − collisions are treated for the states from the ground and up to the ionic state with the aim to provide rate coefficients needed for non-local thermodynamic equilibrium (non-LTE) modeling of beryllium spectra in cool stellar atmospheres. Methods. The electronic molecular structure is determined by using a recently proposed model quantum approach that is based on an asymptotic method. Nonadiabatic nuclear dynamics is treated by means of multichannel formulas, based on the Landau-Zener model for nonadiabatic transition probabilities. Results. The cross sections and the rate coefficients for inelastic processes in Be + H and Be + + H − collisions are calculated for all transitions between 13 low-lying covalent states plus the ionic state. It is shown that the highest rate coefficient values correspond to the mutual neutralization processes with the final states Be(2s3s 1 S), Be(2s3p 1,3 P), Be(2s3d 3 D). These processes, as well as some of the excitation, de-excitation and ion-pair formation processes, are likely to be important for non-LTE modeling.

Stellar laboratories

For the spectral analysis of high-resolution and high-signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. New of Kr IV - VII oscillator strengths for a large number of lines allow to construct more detailed model atoms for our NLTE model-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. We calculated Kr IV - VII oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines exhibited in high-resolution and high-S/N ultraviolet (UV) observations of the hot white dwarf RE 0503-289. We reanalyzed the effective temperature and surface gravity and determined Teff = 70 000 +/- 2000 K and log (g / cm/s**2) = 7.5 +/- 0.1. We newly identified ten Kr V lines and one Kr VI line in the spectrum of RE 0503-289. We measured a Kr abundance of -3.3 +/- 0.3 (logarithmic mass fraction). We discovered that the interstellar absorption toward RE 0503-289 has a multi-velocity structure within a radial-velocity interval of -40 km/s < vrad < +18 km/s. Reliable measurements and calculations of atomic data are a prerequisite for state-of-the-art NLTE stellar-atmosphere modeling. Observed Kr V - VII line profiles in the UV spectrum of the white dwarf RE 0503-289 were simultaneously well reproduced with our newly calculated oscillator strengths.

VII. New Kr IV - VII oscillator strengths and an improved spectral analysis of the hot, hydrogen-deficient DO-type white dwarf RE 0503-289

For the spectral analysis of high-resolution and high signal-to-noise (SN) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. New Krivvii oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTEmodel-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods. We calculated Krivvii oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high SN ultraviolet (UV)observations of the hot white dwarf RE 0503.

CHROMOSPHERIC MODELS AND THE OXYGEN ABUNDANCE IN GIANT STARS

ABSTRACT Realistic stellar atmospheric models of two typical metal-poor giant stars in Omega Centauri, which include a chromosphere (CHR), influence the formation of optical lines of O i: the forbidden lines (λ6300, λ6363) and the infrared triplet (λλ7771−7775). One-dimensional semi-empirical non-local thermodynamic equilibrium (LTE) models are constructed based on observed Balmer lines. A full non-LTE formulation is applied for evaluating the line strengths of O i, including photoionization by the Lyman continuum and photoexcitation by Lyα and Lyβ. Chromospheric models (CHR) yield forbidden oxygen transitions that are stronger than those in radiative/convective equilibrium (RCE) models. The triplet oxygen lines from high levels also appear stronger than those produced in an RCE model. The inferred oxygen abundance from realistic CHR models for these two stars is decreased by factors of ∼3 as compared to values derived from RCE models. A lower oxygen abundance suggests that intermediate-mass AGB stars contribute to the observed abundance pattern in globular clusters. A change in the oxygen abundance of metal-poor field giants could affect models of deep mixing episodes on the red giant branch. Changes in the oxygen abundance can impact other abundance determinations that are critical to astrophysics, including chemical tagging techniques and galactic chemical evolution.

Stellar laboratories

For the spectral analysis of high-resolution and high-signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. To identify molybdenum lines in the ultraviolet (UV) spectra of the DA-type white dwarf G191-B2B and the DO-type white dwarf RE0503-289 and to determine their photospheric Mo abundances, newly calculated Mo IV - VII oscillator strengths are used. We identified twelve Mo V and nine Mo VI lines in the UV spectrum of RE0503-289 and measured a photospheric Mo abundance of 1.2 - 3.0 x 10**-4 (mass fraction, 22500 - 56400 times the solar abundance). In addition, from the As V and Sn IV resonance lines, we measured mass fractions of arsenic (0.5 - 1.3 x 10**-5, about 300 - 1200 times solar) and tin (1.3 - 3.2 x 10**-4, about 14300 35200 times solar). For G191-B2B, upper limits were determined for the abundances of Mo (5.3 x 10**-7, 100 times solar) and, in addition, for Kr (1.1 x 10**-6, 10 times solar) and Xe (1.7 x 10**-7, 10 times solar). The arsenic abundance was determined (2.3 - 5.9 x 10**-7, about 21 - 53 times solar). A new, registered German Astrophysical Virtual Observatory (GAVO) service, TOSS, has been constructed to provide weighted oscillator strengths and transition probabilities. Reliable measurements and calculations of atomic data are a prerequisite for stellar-atmosphere modeling. Observed Mo V - VI line profiles in the UV spectrum of the white dwarf RE0503-289 were well reproduced with our newly calculated oscillator strengths. For the first time, this allowed to determine the photospheric Mo abundance in a white dwarf.

Measurements and non-local thermodynamic equilibrium modeling of mid-Z plasma emission

The x-ray yields from laser-irradiated thin foils of iron, copper, zinc, and germanium have been measured in the soft and multi-keV x-ray ranges at the OMEGA laser at the Laboratory for Laser Energetics. The incident laser power had a pre-pulse to enhance the x-ray emission of a 1 ns flat-top main pulse. The experimental results have been compared with post-shot simulations performed with the two-dimensional radiation-hydrodynamics code FCI2. A new non-local thermodynamic equilibrium model, NOO-RAD, have been incorporated into FCI2. In this approach, the plasma ionization state is in-line calculated by the atomic physics NOHEL package. In the soft x-ray bands, both simulations using RADIOM [M. Busquet, Phys. Fluids B 5, 4191 (1993)] and NOO-RAD clearly over-predict the powers and energies measured by a broad-band spectrometer. In one case (the iron foil), the discrepancy between the measured and simulated x-ray output is nevertheless significantly reduced when NOO-RAD is used in the simulations. In the multi-keV x-ray bands, the simulations display a strong sensitivity to the coupling between the electron thermal conductivity and the NLTE models, and for some particular combinations of these, provide a close match to the measured emission. The comparison between the measured and simulated H-like to He-like line-intensity ratios deduced from high-resolution spectra indicates higher experimental electron temperatures were achieved, compared to the simulated ones. Measurements of the plasma conditions have been achieved using the Thomson-scattering diagnostic. The electron temperatures are found to range from 3 to 5 keV at the end of the laser pulse and are greater than predicted by the simulations. The measured flow velocities are in reasonable agreement with the calculated ones. This last finding gives us confidence in our numerical predictions for the plasma parameters, which are over that time mainly determined by hydrodynamics, such as the mass densities and the ion temperatures.

THE FORMATION OFIRISDIAGNOSTICS. VII. THE FORMATION OF THE O i 135.56 NM LINE IN THE SOLAR ATMOSPHERE

The O i 135.56 nm line is covered by NASA's Interface Region Imaging Spectrograph (IRIS) small explorer mission which studies how the solar atmosphere is energized. We study here the formation and diagnostic potential of this line by means of non-local thermodynamic equilibrium modeling employing both 1D semi-empirical and 3D radiation magnetohydrodynamic models. We study the basic formation mechanisms and derive a quintessential model atom that incorporates essential atomic physics for the formation of the O i 135.56 nm line. This atomic model has 16 levels and describes recombination cascades through highly excited levels by effective recombination rates. The ionization balance O i/O ii is set by the hydrogen ionization balance through charge exchange reactions. The emission in the O i 135.56 nm line is dominated by a recombination cascade and the line is optically thin. The Doppler shift of the maximum emission correlates strongly with the vertical velocity in its line forming region, which is typically located at 1.0–1.5 Mm height. The total intensity of the line emission is correlated with the square of the electron density. Since the O i 135.56 nm line is optically thin, the width of the emission line is a very good diagnostic of non-thermal velocities. We conclude that the O i 135.56 nm line is an excellent probe of the middle chromosphere, and compliments other powerful chromospheric diagnostics of IRIS such as the Mg ii h & k lines and the C ii lines around 133.5 nm.

Stellar laboratories

For the spectral analysis of spectra of hot stars with a high resolution and high signal-to-noise ratio (S/N), advanced non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that are used for their calculation. Reliable Xe VI oscillator strengths are used to identify Xe lines in the ultraviolet spectrum of the DO-type white dwarf RE0503-289 and to determine its photospheric Xe abundance. We publish newly calculated oscillator strengths that are based on a recently measured Xe VI laboratory line spectrum. These strengths were used to consider their radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models to analyze Xe VI lines exhibited in high-resolution and high S/N UV observations of RE0503-289. We identify three hitherto unknown Xe VI lines in the ultraviolet spectrum of RE0503-289 and confirm the previously measured photospheric Xe abundance of this white dwarf (log Xe = -4.2 +/- 0.6). Reliable measurements and calculations of atomic data are prerequisite for stellar-atmosphere modeling. Observed Xe VI line profiles in the ultraviolet spectrum of the white dwarf RE0503-289 were well reproduced with the newly calculated Xe VI oscillator strengths.

Stellar laboratories

For the spectral analysis of high-resolution and high-signal-to-noise (S/N) spectra of hot stars, advanced non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These atmospheres are strongly dependent on the reliability of the atomic data that are used to calculate them. Reliable Ga IV - VI oscillator strengths are used to identify Ga lines in the spectra of the DA-type white dwarf G191-B2B and the DO-type white dwarf RE0503-289 and to determine their photospheric Ga abundances. We newly calculated Ga IV - VI oscillator strengths to consider their radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for analyzing of Ga lines exhibited in high-resolution and high-S/N UV observations of G191-B2B and RE0503-289. We unambiguously detected 20 isolated and 6 blended (with lines of other species) Ga V lines in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectrum of RE0503-289. The identification of Ga IV and Ga VI lines is uncertain because they are weak and partly blended by other lines. The determined Ga abundance is 3.5 +/- 0.5 x 10**-5 (mass fraction, about 625 times solar). The Ga IV / GA V ionization equilibrium, which is a very sensitive indicator for the effective temperature, is well reproduced in RE0503-289. We identified the strongest Ga IV lines (1258.801, 1338.129 A) in the HST/STIS (Hubble Space Telescope / Space Telescope Imaging Spectrograph) spectrum of G191-B2B and measured a Ga abundance of 2.0 +/- 0.5 x 10**-6 (about 22 times solar). Reliable measurements and calculations of atomic data are a prerequisite for stellar-atmosphere modeling. Observed Ga IV - V line profiles in two white dwarf (G191-B2B and RE0503-289) ultraviolet spectra were well reproduced with our newly calculated oscillator strengths. For the first time, this allowed us to determine the photospheric Ga abundance in white dwarfs.

The prospective search for highly ionized technetium in hot (pre-) white dwarfs

The discovery of technetium (Tc) in the atmospheres of red giants by Merrill (1952, ApJ, 116, 21) constituted convincing proof that s-process nucleosynthesis is indeed occurring in evolved stars. In principle, Tc should still be present in the atmospheres of hot post-AGB stars and (pre-) white dwarfs although, due to radioactive decay, it should be present in decreasing quantities along post-AGB evolution. The recent discovery of a large number of trans-iron group elements in hot white dwarfs with atomic numbers in the range A = 30–56 (Zn to Ba) raises the prospect that Tc ( A = 43) may also be detected. However, this is currently not feasible because no atomic data exist for ionization stages beyond Tc ii. As an initial step, we calculated atomic energy levels and oscillator strengths of Tc iv–vi and used these data to compute non-local thermodynamic equilibrium (NLTE) model atmospheres to estimate at which minimum abundance level Tc could be detected. We show that Tc lines can be found in ultraviolet spectra of hot white dwarfs provided Tc is as abundant as other detected trans-Fe elements. We find that radiative levitation can keep Tc in large, easily detectable quantities in the atmosphere. A direct identification of Tc lines is still not feasible because wavelength positions cannot be computed with necessary precision. Laboratory measurements are necessary to overcome this problem. Our results suggest that such efforts are beneficial to the astrophysical community.

Modelling the spectrum of Mg in cool stars

The astrophysical importance of Mg, together with its unique range of spectral features in late-type stars, plus its relative simplicity from an atomic physics point of view, makes it a prime target and test bed for detailed ab initio non-local thermodynamic equilibrium (NLTE) modelling in stellar atmospheres. In this paper, we present example first results for calculations of NLTE Mg line based on a new model atom with significant improvements in the collision data for neutral Mg. We perform calculations for excitation of the lower-lying levels due to electron impacts using the R-matrix method. Recent data for excitation and charge transfer due to hydrogen atom impacts involving low-lying levels are now employed. Further, we have made efforts to use physically-motivated methods for calculating radiative and collisional data involving Rydberg states. The results are compared with observed spectra and the impact of the new calculations briefly explored.

Vibrational relaxation of O3(ν2) by O((3)P).

Laboratory measurements of the rate coefficient for quenching of O3(ν2) by ground-state atomic oxygen, kO(ν2), at room temperature are presented. kO(ν2) is currently not well known and is necessary for appropriate nonlocal thermodynamic equilibrium modeling of the upper mesosphere and lower thermosphere. In this work, a 266 nm laser pulse photolyzes a small amount of O3 in a slow-flowing gas mixture of O3, Xe, and Ar. This process simultaneously produces atomic oxygen and increases the temperature of the gas mixture slightly, thereby increasing the population in the O3(ν2) state. Transient diode laser absorption spectroscopy is used to monitor the populations of the O3(ν2) and ground vibrational states as the system re-equilibrates. Relaxation rates are measured over a range of quencher concentrations to extract the rate coefficient of interest. The value of kO(ν2) was determined to be (2.2 ± 0.5) × 10(-12) cm(3) s(-1).