Victoria blue thin films (VB) were produced using the spin coating technique (SCT) and subsequently annealed at temperatures ranging from 293 K to 463 K. The chemical structure and surface topography of VB films have been described using the Fourier-transform infrared (FT-IR) method and Scanning electron microscope (SEM). The transmittance and reflectance data were immediately used to derive optical features from 190 to 2500 nm in the wavelength range. The single oscillator model of Wemple-DiDomenico was used for determining the dispersion characteristics of VB films. Some dispersion parameters, such as dispersion energy (Ed), oscillator energy (Eο), optical conductivity (σ1, σ2) and dielectric constants (ε1and ε2) have been determined and clearly described. The values of χ3, f,M−1, M−3, ε∞,εL, N/m* , E0, Ed, n2andηopt for as deposited film are calculated as: 6.10 × 10-14, 71.30 (eV)2, 0.31, 0.040, 2.72, 4.04, 3.06 × 1046 kg−1 m−3, 6.34, 11.09, 7.6 × 10-13and 1.98, respectively. Based on this study, thermal annealing changes the optical properties of VB thin film, making it a preferable option for some photonic applications. On the other hand, the high values of these nonlinear parameters are crucial for creating low-power electronics such as optical computers. As a result, we strongly advise employing thermal annealing to change the linear and nonlinear properties of VB films, which might be the ideal choice for many photonic applications And nonlinear devices.
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