Simultaneous estimation of temperature-dependent thermal conductivity and spectral radiative properties in semitransparent medium is investigated in this work. The finite volume method (FVM) is used to solve the transient coupled radiative-conductive problem in one-dimensional emitting, absorbing and scattering nongray medium in the forward model. The time-varying temperature and exit radiative intensity on the right boundary are used as the measurement information for the inverse analysis. A novel Golden Sine Algorithm (Gold-SA) is introduced and the improved Gold-SA (IGold-SA) is developed to solve the inverse problems of coupled radiation-conduction heat transfer for the first time. Findings show that the proposed IGold-SA has better performance than the original Gold-SA in terms of global searching ability and searching accuracy. A multi-thickness-combination model based on laser irradiation is proposed to obtain more measurement information. All the retrieval results show that the temperature-dependent thermal conductivity, spectral extinction coefficient and spectral scattering albedo based on five-band model can be accurately reconstructed by the IGold-SA combined with a three-thickness-combination model even with measurement error.