Ethanol and biodiesel, which both belong to the first generation of biofuel technology, are the two most popular forms of biofuels now in use. In order to create next-generation biofuels using waste, cellulosic biomass, and algae-based resources, the Bioenergy Technologies Office (BETO) is working with business. The present article is designed to study the effect of tetra hybrid nanoparticles with the utilization of the novel Hamilton and Crosser model and catalytic reaction on binary fluid with the consideration of ethanol biofuel as a base fluid. Ethanol comprising tetra hybrid nanoparticles and heterogeneous catalytic reaction amplifies thermal conductivity and significantly increases brake thermal efficiency and reduces brake-specific fuel consumption in diesel engines. Therefore, the aim of this article is a theoretical checkup that is related to heat and mass transport of biofuel flow considering binary fluid accompanied with autocatalysis reaction and novel tetra hybrid nanoparticles on biofluid flow subjected to a Riga wedge. Transportation of heat via nonuniform heat source/sink, thermal radiation, and thermal conductivity are in our consideration. The mathematics of the assumed problem generates the system of non-linear partial differential equations from basic equations of momentum, energy, and mass. The usage of non-dimensional variables gave a system of non-linear ODEs with boundary conditions which are further dealt with in the Lobatto111A scheme. The results are obtained for stretching/shrinking wedge with several parameters. From obtained results, it is observed that the velocity field diminishes owing to magnification in Weissenberg number and Casson fluid parameter. The temperature field diminishes by amplifying heat generation, thermal radiation, and variable thermal conductivity parameter. Concentration distribution escalates by rising homogeneous reaction parameters.
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