Position, time and temperature are the fundamental variables that describe the local energy state of electrons. In general, ionization defined only in terms of the average behavior of the electrons over an atom. The velocity, acceleration and path type of the electron will be different for electrons at different position, time and temperature in the atom since electrons are known to occupy different orbits depending on shell-type that would vary from atom to atom. These variations when summed for millions and billions of electrons can be significant in situations where the assumed qualitative character of physical events will affect the quantitative outcome, particularly when the results are brought up to the engineering scale. The accuracy required for identifying the initiation mechanism of aging of metals in contrast to that of stress corrosion may be quite different, not to mention the added effects of the environment involving high temperature and/or irradiation. The activities of the electrons near the peripheral region of the atom have known to dominate the engineering properties of matter. They, however, are least known in quantum physics because past interest has been centered on releasing energy from the atomic nucleus. The advent of nanotechnology has given hopes to the engineers that they may soon find the answers to their problems at the subatomic scale level with the assistance of high resolution electron microscopes where the detail observation of electron behavior may be made possible in the not too distant future. It is with this spirit that an initial effort is made to find the interdependence relation for the position r, time t and temperature T of an electron traveling at constant velocity and constant acceleration. The difference is explored by keeping in mind that the long journey cannot start without taking the first step. In this respect, the behavior of electrons in a hydrogen atom will be taken as the model to show that electrons move rapidly in the atom at 2.188 × 10 8 cm/s. The approach applies to other atoms with valence bands. The electron velocity can change by one order of magnitude even without accounting for deformities due to vibrations and non-circular orbits. These details can be accounted for and are dictated by the activated energy state of the atoms and the ways with which masses and/or energies are converted from one form to another. The present objective is to determine the combined effects of r, t and T on the electron behavior. To reiterate, the method used to obtain the results or the hydrogen atom can be extended to other atoms having valence bands. With attention focused on the electrons, a r– t– T relation is found for the hydrogen similar to that of the Heisenberg uncertainty principle involving the momentum and position of a particle. For electrons traveling at constant velocity, the relation rtT = ( h / 2 π k ) r b ( n ) has been found with h and k being, respectively, the Planck’s and Boltzmann’s constant. The Bohr radius is r b ( n ) with n = 1, 2, … being the quantum number. The relation changes to r 3 T / t = ( h 3 / 8 π 2 k 2 m 2 ) ( 1 / r b ( n ) ) for electrons moving with constant acceleration. The mass of the electron is m. By holding one of the three variables r, t and T constant, uncertainty in the remaining two variables would still prevail with the same interpretation as the Heisenberg principle. To reiterate, different rtT relations can be found for different atoms. However, it suffices to use the hydrogen model to show that the movements of the atoms are highly active near the outer rim of the atoms. Those in the valence band region are of particular interest to the engineers because they dominate the mechanical strength of solids in addition to the macroscopic electrical and optical properties. Even with the current power resolution of TEM and SEM, the chemical decomposition for the alloy damaged at the nanometer scale, say caused by stress corrosion, has revealed the need to examine the detail behavior of the electrons. The available data has already provided useful quantitative information that will lead to the next step of investigation. As the calculations at the subatomic scale gain accuracy and better physical understanding, they can extend the results to larger scales at the atomic and molecular scale and hopefully will connect with results to the multiscale models and take them to the engineering scale.
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