The Kemper County Project demonstrated Transport Integrated Gasification (TRIG™) technology at a 2 x 1 Integrated Gasification Combined Cycle (IGCC) facility in Kemper County, Mississippi. Capable of generating up to 582 MW during syngas operations, the facility represents the largest IGCC project undertaken, the first to use lignite as fuel, the first to capture and sell CO2, and the first to produce multiple byproducts from initial startup. Featuring UOP’s SELEXOL™ (also known as SeparALL™) process, the acid gas removal (AGR) system at the plant captured carbon dioxide from the syngas and diverted it for use in enhanced oil recovery (EOR), making the Kemper facility’s carbon emissions comparable to those of a similarly sized natural-gas-fired combined cycle power plant. In addition to producing carbon dioxide, the plant also generated other saleable byproducts, including ammonia and sulfuric acid. The UOP SELEXOL process uses a physical solvent to remove acid gases from synthetic gas for the selective removal of H2S and COS and/or CO2 to very low levels in the treated gas. Very low sulfur levels of below 1 ppmv can be achieved with variable and optimized CO2 capture levels. The AGR at Kemper was the first and the largest carbon capture facility for IGCC in the world and also removed sulfur from the syngas. The process H2S absorbers remove over 99% of the sulfur. The captured H2S is later stripped from the solvent using steam heat, producing a concentrated H2S acid gas for producing sulfuric acid, while the purified solvent is refrigerated and recycled to the absorption units. Following sulfur removal, the syngas flows into CO2 absorbers, where a large portion of the CO2 in the syngas is removed. The CO2-laden solvent is regenerated by lowering the pressure of the solvent, allowing the CO2 to evolve. The removed CO2 stream was dehydrated and compressed and sold as a byproduct for EOR. The plant successfully produced electricity and all associated byproducts, while maintaining excellent safety records both during construction and plant operation. The AGR operated for over 3000 hours, processing around 1 million metric tons of syngas before the project was suspended, primarily due to the dramatic decrease in the long-term price forecast for natural gas since the time that the project was approved. Despite changes in project economics, the plant operated as intended, and just under 100,000 metric tons of carbon dioxide was delivered to the pipeline and used for enhanced oil recovery. The AGR system performed well, even at turndown conditions, processing the air-blown syngas without difficulty and making Kemper the first SELEXOL facility to process syngas produced from air-blown gasification. Syngas processing rates in the AGR were as high as 90% of full load syngas capacity, and the plant achieved the nominal design carbon capture rate of 65%, while maintaining stringent CO2 product quality requirements. The AGR sulfur capture rates were also excellent, with syngas sulfur content consistently below 0.5 ppmv, allowing the plant to easily meet its sulfur emission requirements. Commissioning on the byproduct processing systems also saw great success. The CO2 compressors, the largest two in the world with a rated power consumption of 21 MW each, performed well at supplying the CO2 to the pipeline at pressures of up to 122 barg. This paper provides a description of the process technology deployed at the Kemper Facility and discusses plant operational experience, including some of the challenges associated with commissioning a facility of this size and novelty, as well as the extended operation of the Acid Gas Removal system and CO2 compression unit.
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