Noble Gas Temperatures Research Articles

Fabric and Fluid Inclusions Characterization of a Stalagmite from Eastern Spain: A Precondition for Noble Gas Analysis by Step-Crushing Methodology

Fluid inclusions in stalagmites are becoming increasingly important for paleoclimate research. Within this framework, noble gas thermometry, based on noble gases dissolved in water from fluid inclusions, provides quantitative estimations of cave air paleotemperature. Two major issues of Noble Gas Temperature (NGT) determination on speleothems are (1) the potential lack of enough water for the analysis and (2) the presence of trapped gas not dissolved in water that can be released during the analysis from biphasic or all-gas fluid inclusions, as its contribution to the bulk noble gas signal can hinder NGT results. Although the step-crushing method helps to reduce the second issue, it also decreases the amount of water available for the calculations. In order to obtain reliable NGT results with low uncertainties, a major challenge is still to reach a balance between sufficient water for analysis and a small amount of “atmospheric” gas. The difficulty is that the extraction process cannot be standardized since it strongly depends on the type of sample. The objective of this work is to investigate how the characteristics of the speleothem can determine the adequacy of the extraction process. For this purpose, we consider a stalagmite from a Mediterranean cave that consists of columnar elongated calcite and contains a significant quantity of fluid inclusions, which suggests good potential for NGT analysis. Results, however, were poorly satisfactory. Trying to understand the source of the problems, an integrated study of petrography and petrophysical features was performed. The samples were found to be different depending on the stage of coalescence of crystals and thus separated into “open” and “closed” fabrics. Classic petrographic analysis and non-destructive (nuclear magnetic resonance) techniques were used to characterize the type and amount of fluid inclusions present in both types of fabrics. The study indicates that the closed fabric (total coalescence of calcite crystals) has most water trapped in water-filled, small intracrystalline fluid inclusions that usually contain very little gas. This fabric is very suitable for NGT determination, but since the amount of water is quite small, the sample should be crushed in only one step with a large number of beats to break all the inclusions. In contrast, samples with open fabric (partial coalescence of calcite crystals) contain a higher amount of water and, also, gas-filled large intercrystalline fluid inclusions. For this fabric, step-crushing of the sample is necessary. However, the low amount of water left for the second and third crushings could lead to flawed NGT results. Thus, we suggest modifying the method to get rid of part of the gas in the first crushing while leaving enough water for the following steps. This work shows the importance of characterizing speleothems and fluid inclusions, including their petrography and petrophysical characteristics, before starting NGT analysis, allowing the selection of the most favorable samples and the customization of the step-crushing procedure.

Reconstruction of the Pleistocene Paleoclimate From Deep Groundwater in Southern Germany From Noble Gas Temperatures Linked With Organic Radiocarbon Dating

AbstractThis study presents a 25 ka reconstruction of the Pleistocene paleoclimate in the South German Molasse Basin. Deep groundwater was sampled at 19 wells in the Upper Jurassic aquifer (UJA). Calculating gas temperatures (NGT) using the UA model with the noble gases Ar, Kr, and Xe led to groundwater recharge temperatures between 0.4 and 4.7°C. Combined with innovative 14CDOC groundwater dating, calculated NGTs revealed up to 8°C cooler soil temperatures during the Pleistocene compared with modern soil temperature. This interpretation agrees well with the observed depleted stable water isotope signature ranging from −83.3 to −86.1 for δ2H and from −10.66 to −11.77 for δ18O, which is characteristic of groundwater of Pleistocene origin in Southern Germany. The temperature differences (∆T) agree remarkably well with calculated NGTs within other European basins (∆T 6–9.5°C) and suggest widespread pronounced terrestrial cooling during the Last Glacial Maximum through the interior of the European continent.

Noble gases in groundwater reflect wet-season temperature in an arid, monsoonal, and mountainous environment

Comparing directly measured soil temperatures with noble gas recharge temperatures (NGTs) inferred from noble gas concentrations indicates that the infiltrating soil water equilibrates with soil air near the soil surface during the rainy season. Therefore, NGTs of groundwater recently recharged by the Indian Summer Monsoon (ISM) in the Dhofar Mountains in southern Oman reflect the soil temperatures of the 3-month period and do not represent an annual mean. This finding highlights the need to account for seasonality when interpreting NGT data in regions with pronounced dry and wet seasons.We extend the observations from the southern flank of the Dhofar Mountains to three wells situated on the northern flank of the Dhofar Mountains. Two of these wells yield water of Holocene age that was recharged by the monsoon, their NGT signals are therefore classified as seasonal. The NGT calculated from a third well for recharge conditions during the Last Glacial Maximum (LGM), when the ISM was absent, is approximately 3 °C lower than that of the two Holocene wells. The lower LGM noble gas temperature corresponds well with the lower annual Sea Surface Temperature (SST) in the nearby Arabian Sea.NGTs from published studies from northern Oman are 1–3 °C higher when compared with our data of the same period in the southern Oman. We explain this regional difference of reconstructed temperatures for the LGM and Holocene groundwater with a more continental climatic influence on the infiltration conditions further to the north. The published NGTs from northern Oman show a large temperature difference between the late Holocene and the LGM. In view of our finding of seasonal NGT signals under monsoonal climate, part of this difference may reflect a change in the precipitation regime rather than in air temperature.

Last glacial maximum cooling of 9 °C in continental Europe from a 40 kyr-long noble gas paleothermometry record

The Last Glacial Maximum (LGM; ∼26–18 kyr ago) is a time interval of great climatic interest characterized by substantial global cooling driven by radiative forcings and feedbacks associated with orbital changes, lower atmospheric CO2, and large ice sheets. However, reliable proxies of continental paleotemperatures are scarce and often qualitative, which has limited our understanding of the spatial structure of past climate changes. Here, we present a quantitative noble gas temperature (NGT) record of the last ∼40 kyr from the Albian aquifer in Eastern Paris Basin (France, ∼48°N). Our NGT data indicate that the mean annual surface temperature was ∼5 °C during the Marine Isotope Stage 3 (MIS3; ∼40–30 kyr ago), before cooling to ∼2 °C during the LGM, and warming to ∼11 °C in the Holocene, which closely matches modern ground surface temperatures in Eastern France. Combined with water stable isotope analyses, NGT data indicate δD/NGT and δ18O/NGT transfer functions of +1.6 ± 0.4‰/°C and +0.18 ± 0.04‰/°C, respectively. Our noble-gas derived LGM cooling of ∼9 °C (relative to the Holocene) is consistent with previous studies of noble gas paleothermometry in European groundwaters but larger than the low-to-mid latitude estimate of 5.8 ± 0.6 °C derived from a compilation of noble gas records, which supports the notion that continental LGM cooling was more extreme at higher latitudes. While an LGM cooling of ∼9 °C in Eastern France appears compatible with recent data assimilation studies, this value is greater than most estimates from current-generation climate model simulations of the LGM. Comparing our estimate for the temperature in Eastern France during MIS3 (6.4 ± 0.5 °C) with GCM outputs presents a promising avenue to further evaluate climate model simulations and constrain European climate evolution over the last glacial cycle.

Regional-Scale Distribution of Helium Isotopes in Aquifers: How Informative Are They as Groundwater Tracers and Chronometers?

This study presents an almost entirely unpublished dataset of 121 samples of groundwater analyzed for helium concentration and its isotopic ratio (3He/4He) in two adjacent watersheds of the St. Lawrence Lowlands, in a region with intensive agricultural activities in the southern Québec Province, Eastern Canada. Most of the samples were collected in the regional bedrock fractured aquifer hosted in mid-Ordovician siliciclastic shales, on a total surface of 7500 km2. Even with this low-density sampling, and in a heterogeneous and fractured aquifer, the helium isotopes bring precious information on the recharge conditions and on chemical evolution of water. The helium spatial interpolation does not show a clear isotopic gradient through the basin. However, it shows progressive enrichment of radiogenic 4He in the confined part of the aquifer. The atmospheric and/or tritiogenic-rich helium occurs at the recharge in the Appalachians and in the middle of the plain, where impermeable cover is limited, and local infiltration of meteoric freshwater reaches the bedrock aquifer. The relation between the total dissolved solids (TDS) and 3He/4He ratios remains elusive. However, on discriminating the samples with the dominant chemistry of water, a clear trend is observed with 3He/4He ratio, suggesting that radiogenic 4He accumulates together with dissolved solids and with increasing time (indicated by progressively older 14C ages). Finally, the noble gas temperatures (NGTs) obtained from concentrations of the other noble gases (Ne, Ar, Kr and Xe) brings constraints on the earlier recharge conditions during the Holocene. Particularly, the NGTs showed that the studied aquifers were continuously replenished, even under ice-sheet cover in the last 10,000 years.

Upwelling of Mantle‐derived Material in Southeast China: Evidence from Noble Gas Isotopes

AbstractShallow groundwater collected in Chaozhou, Huizhou, and Guangzhou allowed testing of concentrations and the isotope ratios of noble gases. Based on the calculated noble gas temperature (NGT) and the ratio of noble gas isotopes, the recharge temperature, recharge source, and residence time of groundwater can be calculated. In addition, the contribution of noble gas components from different sources to the sample components can be assessed. In the Huizhou area, according to the 1/Xe vs. Ne/Xe and NGT data, the shallow sandstone‐confined water samples in the Shiba area and the unconfined water samples of the Huangshadong are in different temperature ranges, indicating that they have different recharge sources, both in time or space. The He components in the samples are calculated to obtain the content of radiogenic 4He in the crust and to simulate the groundwater ages. The noble gas isotope ratios show the addition of mantle components into the basalt aquifers and sandstone aquifers in Chaozhou and Huizhou. Except for atmospheric and crustal sources, there is a certain proportion of mantle‐derived components in the shallow underground cold water in Huizhou and Chaozhou. The noble gases in the Chaozhou groundwater have an obvious mantle signature, allowing speculation that there is a deep fluid carrying mantle characteristics. This upwelling of mantle‐derived material might be caused by the India‐Eurasia collision or that between the Philippine Sea Plate and the Eurasian Plate.

Comparison of Noble Gas Temperature with Recent Mean Annual Air and Soil Temperature in different regions of Hungary

This paper describes the relation of noble gas temperature (NGT) and mean annual air (MAAT) and soil (MAST) temperature through studying water samples and meteorological data from six Hungarian regions. Alluvial plains, hilly and mountainous regions were studied to investigate the effects of geomorphological, hydrogeological and micro-climatic conditions. Water samples were collected from springs and wells fed from different aquifers. Comparing NGTs derived from these water samples with the MAAT and MAST values of the given region, we identified differences between the sampled areas. In case of the Geresd Hills, Mezőföld, Danube-Tisza Interfluves and Nyírség, the NGTs (13.0 ± 0.9 °C, 12.1 ± 1.1 °C, 12.1 ± 0.6 °C and 12.7 ± 1.6 °C, respectively) generally reflect MAST, however in karstic Bükk Mts. (6.8 ± 0.6 °C) and Mecsek Mts. (10.7 ± 1.9 °C) they are closer to MAAT. Consequently, it can be concluded that the direct relationship between noble gas temperature and mean annual air temperature is not always as well-defined as it is often assumed. It is shown that MAAT and MAST should be distinguished, especially when using NGT as a paleoclimate proxy.

Anomalous Noble Gas Solubility in Liquid Cloud Water: Possible Implications for Noble Gas Temperatures and Cloud Physics

AbstractThe noble gas temperature climate proxy is an established tool that has previously been applied to determine the source of groundwater recharge, however, unanswered questions remain. In fractured media (e.g., volcanic islands) recharge can be so rapid that groundwater is significantly depleted in heavy noble gases, indicating that the water has retained noble gas concentrations from higher elevations. Previous studies of rain samples have confirmed a match to patterns seen in fractured‐rock groundwater for heavy noble gases along with a significant helium excess. Snow has been shown to be a credible source for both the helium excess and the observed heavy noble gas pattern. Here, liquid cloud water samples were collected at two mountainous sites and analyzed for noble gas concentrations. A pattern like that of rainwater was found. However, an analysis of diffusive uptake of noble gases into cloud water demonstrates that droplets of 1 mm diameter and smaller should be in constant solubility equilibrium with the atmosphere. To explain this, we present a novel hypothesis that relies on the assumption that liquid water consists of two types of water molecule clusters bounded by hydrogen bonds: a low‐density ice‐like structure and a high‐density condensed structure. In this model, the pressure gradient near the surface of a droplet resulting from surface tension could allow for the formation of a surface layer that is rich in ice‐like low density clusters. This can explain both the helium excess and the heavy noble gas depletion seen in the samples.

Paleoclimate Signals and Groundwater Age Distributions From 39 Public Water Works in the Netherlands; Insights From Noble Gases and Carbon, Hydrogen and Oxygen Isotope Tracers

AbstractKnowing the age distribution of water abstracted from public water supply wells helps to ensure customer trust in drinking water sources and underpin predictions of water quality evolution. We sampled the mixed water of 39 large public supply well fields for major ion chemistry, 3H, 3He, 18O, 2H, 14CDIC, 13CDIC and noble gases and determined the Noble Gas Temperature (NGT). We used a discrete travel time distribution model to quantify the age distributions using 3H, 4He, 14C apparent age and NGT as the 4 distinctive tracers. Helium‐4 and NGT provided information on the older part of the age distributions and showed that the 14C apparent ages are often the result of mixing of waters ranging between 2,000 and 35,000 years old, instead of being discrete ages with a limited variance as previously assumed. The results reveal a large range of age distributions, comprising vulnerable well fields with >60% young water (<100 years) and well fields with >30% paleo groundwater (>25,000 years) and all forms of intermediate distributions. The age distributions match the hydrogeological setting; well fields with age distributions skewed towards older ages appear in the Roer Valley Graben structure, where fluvial and marine aquitards and sealed faults provide protection from recent recharge. Waters from this graben exhibit paleoclimate signals, with a clear relation between NGT (range 3.2–9.3 °C), 4He (up to 3.3 × 10−6 ccSTP/g) and δ18O (range −8.5‰ to −5.9‰VSMOW). Moreover, 3He/4He ratios of these graben waters suggest a certain influx of He from mantle origin.

Transfer of dissolved gases through a thick karstic vadose zone – Implications for recharge characterisation and groundwater age dating in karstic aquifers

This study analyses the impact of a thick vadose zone on gaseous transfers and Excess Air (EA) formation using dissolved noble and anthropogenic gas tracers (Ne, Ar, N2, CFC, SF6, O2 and CO2). Understanding gas transfers integrates the issues of equilibrium and water/air exchanges along the vadose zone. In this study, the noble and anthropogenic gases were analysed in air and water over vadose zone depths of 120 m and over two contrasted hydrodynamic periods therefore enabling a rare insight into the spatial and seasonal variations of equilibrium and water/air exchanges in a heterogeneous karst environment. The results highlight that both noble and anthropogenic gases of the caves are in equilibrium with the atmosphere up to at least depths of 120 m. In water, the Noble Gas Temperature (NGT) remains stable at 8 °C whilst some EA is formed (up to 1.3 cm3 STP/kg at 120 m) during transfers in the vadose zone. The high EA concentrations measured at the spring outlet, until 10.7 cm3 STP/kg, cannot be explained by an increase during transfers via the vadose zone. This high EA concentration is due to rapid and high water level variations during recharge. The implications of these results are important to advance our understanding in the use of noble and anthropogenic gases in characterising recharge and quantifying groundwater residence times. In particular, these results help to identify the parts of the aquifer actively involved in dissolved gas transfers, highlight the futility of using a time-lag factor for groundwater residence times in karstic systems, and improve our understanding of the EA formation processes.

A multi-tracer and well-bore flow profile approach to determine occurrence, movement, and sources of perchlorate in groundwater

The purpose of this study is to determine the occurrence, movement, and sources of perchlorate in groundwater using a comprehensive set of environmental tracers coupled with discrete borehole data. Potential sources of perchlorate to groundwater at the study site have been attributed to waste disposal and industrial activities as well as to past agricultural operations. Perchlorate concentrations in samples ranged from <1 to 40 μg/l, with a median of 6.1 μg/l. Concentrations were relativity consistent with depth except at one site where dilution may be occurring due to the infiltration of surface water from Pyrite Creek. Well-bore flow profiles indicated that perchlorate redistribution was occurring via intra-well bore flow at one site where up to 14,000 mg/year of perchlorate could be moving from the shallower to the deeper zones of the alluvial aquifer. Natural attenuation processes of perchlorate do not appear to be widespread in groundwater but do occur in portions of the aquifer adjacent to the Santa Ana River, likely limiting the mobility of perchlorate from the southernmost extent of the mapped plume to areas farther down-gradient. Age dating tracers indicate that the advective transport of perchlorate originating from the waste disposal ponds has largely moved through the zones of the aquifer sampled. Age distributions, noble gas temperature, delta neon values and stable isotopes of water indicate that a substantial fraction of perchlorate in groundwater may have been mobilized from the unsaturated zone and/or is from the infiltration of storm water runoff originating from Pyrite Canyon.

Kinetic Barriers and Microscopic Mechanisms of Noble Gas Adsorption by Nanoporous γ‐Mg(BH4)2 Obtained by Means of Sub‐Second X‐Ray Diffraction

AbstractGas adsorption by porous frameworks sometimes results in structure “breathing”, “pores opening/closing”, “negative gas adsorption”, and other phenomena. Time‐dependent diffraction can address both kinetics of the guest uptake and structural response of the host framework. Using sub‐second in situ powder X‐ray diffraction, three intracrystalline diffusion scenarios have been evaluated from the isothermal kinetics of Ar, Kr, and Xe adsorption by nanoporous γ‐Mg(BH4)2. These scenarios are dictated by two possible simultaneous transport mechanisms: diffusion through the intra‐ (i) and interchannel apertures (ii) of γ‐Mg(BH4)2 crystal structure. The contribution of (i) and (ii) changes depending on the kinetic diameter of the noble gas molecule and temperature regime. The lowest single activation barrier for the smallest Ar suggests equal diffusion of the atoms trough both pathways. Contrary, for the medium sized Kr we resolve the contributions of two parallel transport mechanisms, which tentatively can be attributed to the smaller barrier of the migration paths via the channel like pores and the higher barrier for the diffusion via narrow aperture between these channels. The largest Xe atoms diffuse only along 1D channels and show the highest single activation barrier.

Kinetic Barriers and Microscopic Mechanisms of Noble Gas Adsorption by Nanoporous γ-Mg(BH4 )2 Obtained by Means of Sub-Second X-Ray Diffraction.

Gas adsorption by porous frameworks sometimes results in structure "breathing", "pores opening/closing", "negative gas adsorption", and other phenomena. Time-dependent diffraction can address both kinetics of the guest uptake and structural response of the host framework. Using sub-second in situ powder X-ray diffraction, three intracrystalline diffusion scenarios have been evaluated from the isothermal kinetics of Ar, Kr, and Xe adsorption by nanoporous γ-Mg(BH4 )2 . These scenarios are dictated by two possible simultaneous transport mechanisms: diffusion through the intra- (i) and interchannel apertures (ii) of γ-Mg(BH4 )2 crystal structure. The contribution of (i) and (ii) changes depending on the kinetic diameter of the noble gas molecule and temperature regime. The lowest single activation barrier for the smallest Ar suggests equal diffusion of the atoms trough both pathways. Contrary, for the medium sized Kr we resolve the contributions of two parallel transport mechanisms, which tentatively can be attributed to the smaller barrier of the migration paths via the channel like pores and the higher barrier for the diffusion via narrow aperture between these channels. The largest Xe atoms diffuse only along 1D channels and show the highest single activation barrier.

Estimation of temperature – altitude gradients during the Pleistocene–Holocene transition from Swiss stalagmites

Experimental reconstruction of temperature - altitude in the past remain often elusive. With the development of a combined vacuum crushing and sieving system (CVCS), it is now possible to determine paleotemperatures from the noble gases dissolved in minute amounts of water from inclusions in speleothems that have grown under a broad range of climatic conditions. Here we present noble gas temperature (NGT) estimates during the last deglaciation, which are based on two stalagmites from Milandre Cave (stalagmite M6) and Grotte aux Fées de Vallorbe (stalagmite GEF1), Jura Mountains, Switzerland. The caves are located at different geographical altitudes (Milandre Cave: 373 m a.s.l. and Grotte aux Fées de Vallorbe: 895 m a.s.l.) and thus allow for a reconstruction of the respective temperature – altitude gradients within Switzerland during the last deglaciation. Our reconstruction shows that the past temperature – altitude gradients are within 1σ error in agreement with the modern temperature – altitude gradient, suggesting that the local temperature – altitude gradient was rather stable over time.In addition to the noble gas analysis, we complemented our study with deuterium (δDFI) and oxygen isotope (δ18OFI) measurements of fluid inclusion water. In combination with NGTs, this allows us to reconstruct the past δ18OFI – δDFI / temperature relation. These reconstructions show that the temporal temperature sensitivity of δ18OFI and δDFI (Δ(δ18OFI) / Δ(T) and Δ(δDFI) / Δ(T)) seems to be stable over time and therefore support the use of water isotopes for temperature reconstructions in Switzerland.

Paleotemperature reconstruction using environmental isotopes and noble gases in groundwater in Morocco

A Turonian limestone-dolomite aquifer from the Tadla basin of Morocco was analysed using a multi-tracer approach (δ18O, δ2H, δ13C, 3H, 14C and noble gases) to reconstruct the paleotemperature evolution from the late Pleistocene to the Holocene. The Turonian aquifer was found to be suitable for a groundwater-based paleoclimate reconstruction, representing the Holocene–late Pleistocene epochs. After correction for young water contribution, mean residence times (MRTs) of groundwater were calculated using the Pearson radiocarbon model. Additionally, terrigenic helium content was used as an age indicator. Noble gas temperature (NGT) results from wells with groundwater ages corresponding to glacial periods showed an average of 17.2 ± 1.7°C. In contrast, samples of recent recharge water gave a mean NGT of 25.2 ± 1.3°C. This reveals a temperature difference of 8.0 ± 2.1 °C between the Holocene and late Pleistocene. This significant Pleistocene–Holocene temperature difference observed in Africa has considerable significance and can be extended to address an important topic relating to the nature of the wet epochs during which the fossil aquifers of North Africa were recharged. It is evident that this aquifer was recharged during both interglacial (warm) and glacial (cool) wet periods.

A palaeoclimatic record from the Ledo-Paniselian Aquifer in Belgium – Indications for groundwater recharge and flow in a periglacial environment

Understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. Methane releases from melting permafrost in a warming world are a hot topic in contemporary climate research. Noble gas analyses have been proposed to study methane-driven degassing in lakes as well as in permafrost terrains. The Ledo-Paniselian aquifer is shown to provide an analogue for such processes, from the last period of global warming after the LGM. It is postulated that recharge from methane bubbling thermokarst lakes to groundwater took place, and can be recognized by a specific signature in the groundwater. The Ledo-Paniselian aquifer offers unique opportunities to study periglacial groundwater recharge during the LGM, as it was located in the permanent permafrost area to the south of the ice sheet at that time. It contains Holocene and Pleistocene groundwaters, which are separated by a recharge gap, referring to permafrost during the LGM. This is confirmed by noble gas temperature (NGT) data. In the samples immediately upstream of this gap, several potential indicators for the specific methanogenic recharge conditions from thawing permafrost are being put forward, based on noble gases, chemical and isotopic data.Immediately upstream of the age gap, groundwaters show strikingly deviating HCO3−, SO42−, δ13C, δ18O and δ2H compared to the regional trend, while their 14C model ages are too young, and NGTs seem too high. These samples are affected by degassing, which is not an artefact of sampling, and which, according to their radiogenic helium concentrations, occurred early on, during recharge or shortly thereafter. The origin of these samples could be explained by the conditions prevailing as the permafrost thawed, and groundwater recharge could resume. It is inferred that the degassed samples were infiltrated during or shortly after the LGM, when recharge from methane bubbling thermokarst lakes to groundwater took place, associated to the melting permafrost.

Multitracer determination of apparent groundwater ages in peridotite aquifers within the Samail ophiolite, Sultanate of Oman

CO2 sequestration in the form of carbonate minerals via alteration of oceanic crust and upper mantle is an important part of the global carbon cycle, but the annual rate of CO2 mineralization is not well quantified. This study aimed to constrain groundwater ages within the Samail ophiolite, Sultanate of Oman. Such ages could provide upper bounds on the time required for ongoing low temperature CO2 mineralization. While we were able to estimate apparent groundwater ages for modern waters, results from hyperalkaline boreholes and springs were disappointing. Waters from boreholes and hyperalkaline springs within the ophiolite were characterized using multiple environmental tracers including tritium (3H), noble gases (3He, 4He, Ne, Ar, Kr, Xe), stable isotopes (δ18O, δ2H), and chemical parameters (pH, Ca, Mg, DIC, etc.). Shallow peridotite groundwater and samples from boreholes near the mantle transition zone have a pH < 9.3, are 4-40 yrs old, have little to no non-atmospheric He accumulation, NGTs (noble gas temperatures) equivalent to the modern mean annual ground temperature, and stable isotopes within the range of current local precipitation. In contrast, hyperalkaline springs and deeper samples from peridotite boreholes have pH > 10, are pre-H-bomb (older than 1952), have significant non-atmospheric helium accumulation (30-70% of dissolved helium), often are isotopically heavier (enriched in δ18O), and can have NGTs 6-7°C lower than the modern ground temperature. These differences suggest that groundwater in deep (>50 m) peridotite aquifers is considerably older than shallow groundwater in peridotite and water in deeper aquifers near the mantle transition zone. Unfortunately, how much older remains an open question. The low NGT of groundwater from one deep (300 m) peridotite borehole indicates it is probably glacial in origin. If so, it must date back to at least the late Pleistocene, the most recent glacial period; He accumulation suggests it could be from 20-220 ka. The inefficacy of this suite of environmental tracers to quantitatively estimate apparent groundwater age for hyperalkaline fluids necessitates the use of different techniques. Future work to constrain groundwater ages should utilize a packer system to isolate discrete depth intervals within boreholes and less common environmental tracers such as 39Ar and 81Kr.

Investigation of paleoclimate signatures in Sfax deep groundwater (Southeastern Tunisia) using environmental isotopes and noble gases

To investigate paleoclimate conditions and mean annual ground temperatures at the time of infiltration, concentrations of dissolved atmospheric noble gases, 18O, 2H and 14C were studied in Sfax deep groundwater in southeastern of Tunisia. Carbon-14 corrected ages are up to 40 Ka BP suggesting that most of this water infiltrated during Late Pleistocene. Noble gas temperatures (NGTs) clearly show the presence of water that infiltrated under much cooler conditions than at present. According to the NGT's, the mean annual temperature in this mid latitude coastal site during the last glacial maximum (LGM) was 5.5 ± 1.0 °C colder than during the Holocene. This transition of Holocene –Pleistocene is well marked by a depletion of oxygen-18 isotope composition by 1.5‰ when compared to the modern rain water signature. Furthermore, the amount of excess air, which is closely linked to the magnitude of groundwater table fluctuations, provides further information on drought and wet period alternations during Late Pleistocene in Northern Africa.

Surface corrugation of carbon fiber via high-fluence nitrogen ion irradiation

SEM and laser goniophotometry were used to study a corrugation of VMN-4 carbon fiber shell of KUP-VM composite after high-fluence 30 keV N2+ ion irradiation at temperatures range from 100 to 600°C. It has been found that the angles of an inclination of corrugated structure increase with temperature so that at temperature ∼270 °C reach maximum values ∼40°, staying at this level at subsequent temperature elevation up to 600 °C. Spatial period of corrugations alternation is about 1 µ m for temperatures range 100-200°C and 0.6 µ m for higher temperatures. Qualitative difference of nitrogen from noble gas temperature dependences of a corrugation is connected with a nitrogen chemical activity and creation of C-N bonds due to implantation.

Noble gas based temperature reconstruction on a Swiss stalagmite from the last glacial–interglacial transition and its comparison with other climate records

Here we present the results of a first application of a “Combined Vacuum Crushing and Sieving (CVCS)” system to determine past (cave/soil) temperatures from dissolved noble gas concentrations in stalagmite samples grown under ‘cold’ climatic conditions (e.g. close to freezing point of water) during the last glacial–interglacial transition. To establish noble gas temperatures (NGTs) also for stalagmites grown in cold regions, we applied the CVCS system to samples from stalagmite M2 precipitated in the Milandre Cave, located in the Swiss Jura Mountains. The investigated stalagmite M2 covers the Allerød–Younger Dryas–Holocene transitions. Noble gas temperatures are determined by using a new algorithm based on noble gas and water abundances and not from concentrations. Noble gas results indicate annual mean temperatures in the Milandre Cave were 2.2±1.8 °C during the late stages of the Allerød, then dropping to 0(−)+2.6°C at the onset of the Younger Dryas. Such temperatures indicate conditions near to the freezing point of water during the first part of the Younger Dryas. During the last part of the Younger Dryas, the temperature increased to 6.3±2.3 °C. No early Holocene temperature could be determined due the non-detectable water abundances in these samples, however one late Holocene sample indicates a cave temperature of 8.7±2.7 °C which is close to the present day annual mean temperature. NGTs estimated for the Allerød–Younger Dryas–Holocene are in good agreement with paleo-temperature reconstructions from geochemical and biological proxies in lake sediments. The observed deviations between the different paleo-temperature reconstructions are minor if the according temperatures are rescaled to annual mean temperatures and are primarily attributed to the chronological tuning of the different records. As in other stalagmites, NGT reconstructions of the recently precipitated stalagmite (‘young’) samples again are biased, most likely due to diffusive gas loss during sample processing. We speculate that a reduced retentivity of noble gases during experimental sample processing is a general feature of recently precipitated stalagmite fabrics. Therefore, the recently precipitated stalagmite samples do not allow the reliable NGT determination given the currently available experimental methods. Nevertheless, this study makes the case that noble gas thermometry can be applied to stalagmites for paleo-temperature reconstruction based on a physical method including stalagmites that grew during cold climatic conditions.