The distinction between homogeneous and heterogeneous chemical reactions is crucial because many chemically reactive systems, such as hydrometallurgical processes, cooling towers, biological systems, fog dispersion, catalysis, etc., involve both types of reactions. Thus, this study analyzes the heat transmission (HT) characteristics in an MHD stagnant flow of power-law fluid caused by a spinning disk that is stretched and saturated in a porous medium. The study considers homogeneous-heterogeneous (HH) reactions and nonlinear thermal radiation subject to no-slip and convection boundary conditions. The leading equations are switched into ordinary differential equations (ODEs) employing similarity variables. The study focuses on the dimensionless concentration, velocity, temperature, Nusselt number, and skin friction coefficient, which are discussed in detail in the results and discussion section. The study observes that for power-law fluids with an index value less than 1, the skin friction coefficient decays as the power-law index grows. It also notes that the dimensionless skin friction of power-law fluids decreases as the velocity ratio increases. The dimensionless concentration increases with Schmidt and modified Prandtl numbers for both power-law fluids over a stretching spinning porous disk. The HH reaction parameters decline the concentration of power-law fluids.