Nitryl Fluoride Research Articles

The evidence of conductivity, density, and viscosity on the reaction of nitryl fluoride with sulphuric acid. The conductivity of solutions of nitryl fluoride in selenic and phosphoric acids

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Nitryl fluoride as a nitrating agent

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The preparation and some reactions of nitryl fluoride

The preparation and some reactions of nitryl fluoride

Kinetics of the Fast Reaction between Nitrogen Dioxide and Fluorine

The rate of the reaction between nitrogen dioxide and fluorine to form nitryl fluoride has been measured at 27.7, 50.4, and 70.2°. Light absorption by nitrogen dioxide was used to follow the reaction. By using a 22-liter Pyrex flask and by going to low concentrations of reactants, between 0.5 and 20×10−8 moles cc−1, the rate of this fast reaction was reduced to a convenient value. The rate was found to be first order in each reactant, and it showed no dependence on nitryl fluoride. The proposed mechanism is NO2+F2→ lim k1NO2F+F (slow),NO2+F+M→ lim k2NO2F+M (fast).The empirical second order rate constant is k1, that of an elementary bimolecular reaction. If the rate constant is written as Ae−E/RT then A is 1.6×1012 cc moles−1 sec−1 and E is 10.5 kcal.

The Preparation of Nitrosyl Fluoride and Nitryl Fluoride1

The Preparation of Nitrosyl Fluoride and Nitryl Fluoride¹