Nitrogen Vibrational Temperature Research Articles

Ignition of an ionic liquid dual-mode monopropellant using a microwave plasma torch

The blend of hydroxylammonium nitrate (HAN) and imidazole-based ionic liquid has shown good feasibility in chemical and electric dual-mode green space propulsion. As conventional catalyst-driven ignition faces challenges arising from long preheat delay and catalyst failure, this work designs a novel ignition actuator using a microwave plasma torch. The precise tuning of the ¼-λ resonant cavity and improvement in the quality factor (QF) of the microwave igniter make the device efficient and thus allow the propellant to be ignited at a power of approximately 100 W. In the present reduced test rig, the maximum fuel flow rate corresponds to 0.1 N chemical thrusters, and the plasma-assisted ignition is mainly attributed to thermal and kinetic effects. The temperature of the actuator and the plasma torch is investigated by infrared thermometry and spectral fitting of excited molecule nitrogen, respectively. First, the hot electrode tube helps evaporate water molecules and accelerate the liquid jet through rapid gas expansion. Then, the ionic liquid quickly decomposes to small species when the flow reaches the torch with a nitrogen vibrational temperature above 4000 K and rotational temperature above 2000 K. Meanwhile, the nonequilibrium plasma-excited species enhance the combustion of gaseous intermediates by direct impact dissociation, where the OH radical profile is visualized using the planar laser-induced fluorescence technique. In addition, the copper atoms released by plasma erosion are expected to exhibit a significant catalytic effect on ionic liquid decomposition, which is a critical step in controlling the overall reaction rate. It is also noted that such mild erosion does not affect the multi-start operations during the firing test that lasts for at least 30 min.

Partial Least-Squares Regression as a Tool To Predict Fluoropolymer Surface Modification by Dielectric Barrier Discharge in a Corona Process Configuration in a Nitrogen–Organic Gaseous Precursor Environment

A dielectric barrier discharge in a corona process configuration is used to treat the surface of fluoropolymers in a nitrogen–organic precursor environment. The surface chemistry, thickness, and water contact angle of the deposited coatings are measured and used to build up an output matrix to be correlated with an input matrix built using electrical parameters of the discharge, the gas mixture chemical composition, and spectroscopic parameters measured in both the infrared and ultraviolet–visible emission spectral regions. A partial least-squares regression (PLSR) model enables determining the most important plasma parameters to drive the coating physicochemical characteristics. From the PLSR model, it is determined that the plasma electrical parameters drive the surface modification process, at the expense of other plasma characteristics such as gas flow, gaseous precursor concentration, nitrogen vibrational temperature, and the level of gaseous precursor conversion within the plasma.

Simulation study on the spatial and temporal characteristics of focused microwave beam discharge in nitrogen

This paper reports a simulation study on a focused microwave (frequency 9.4 GHz, pulse width 2.5 μs, and peak electric field 1.2 kV/cm) discharge in 200 Pa nitrogen. A one-dimensional (1D) fluid model is based on the wave equation for the microwave field propagating through the gas breakdown plasma, the continuity equations for electron, ion and neutral particle densities, and the energy balance equations for mean electron temperature, and nitrogen vibrational and translational temperatures. These equations are numerically solved in a self-consistent manner with a simplified plasma chemistry set, in which the reaction rates involving electrons are calculated from the electron energy distribution function (EEDF) using a two-term expansion method. The spatial and temporal characteristics of the focused microwave breakdown in nitrogen are demonstrated, which include the amplitude of the microwave electric field, and the densities and temperatures of the plasma components. The temporal evolution of the plasma electron density agrees reasonably well with that measured with a microwave interferometer. The spatial-temporal distributions of metastable states are discussed on the plasma chemistry and the character of mean electron temperature. The spatially integrated N2(C3) density shows similar trends with the measured temporal intensity of optical emission spectroscopy, except for a time delay of 100–300 ns. The quantitative discrepancies are explained in light of limitations of the 1D model with a two-term expansion of EEDF. The theoretical model is found to describe the gas breakdown plasma generated by focused microwave beams at least qualitatively.

OH radical kinetics in hydrogen-air mixtures at the conditions of strong vibrational nonequilibrium

This work presents results of time-resolved, absolute measurements of OH number density, nitrogen vibrational temperature, and translational-rotational temperature in air and lean hydrogen-air mixtures excited by a diffuse filament nanosecond pulse discharge, at a pressure of 100 Torr and high specific energy loading. The main objective of these measurements is to study kinetics of OH radicals at the conditions of strong vibrational excitation of nitrogen, below autoignition temperature. N2 vibrational temperature and gas temperature in the discharge and the afterglow are measured by ns broadband coherent anti-Stokes Raman scattering. Hydroxyl radical number density is measured by laser induced fluorescence, calibrated by Rayleigh scattering. The results show that the discharge generates strong vibrational nonequilibrium in air and H2-air mixtures for delay times after the discharge pulse of up to ~1 ms, with a peak vibrational temperature of Tv ≈ 1900 K at T ≈ 500 K. Nitrogen vibrational temperature peaks at 100–200 µs after the discharge pulse, before decreasing due to vibrational-translational relaxation by O atoms (on the time scale of several hundred µs) and diffusion (on ms time scale). OH number density increases gradually after the discharge pulse, peaking at t ~ 100–300 µs and decaying on a longer time scale, until t ~ 1 ms. Both OH rise time and decay time decrease as H2 fraction in the mixture is increased from 1% to 5%. Comparison of the experimental data with kinetic modeling predictions shows that OH kinetics is controlled primarily by reactions of H2 and O2 with O and H atoms generated during the discharge. At the present conditions, OH number density is not affected by N2 vibrational excitation directly, i.e. via vibrational energy transfer to HO2. The effect of a reaction between vibrationally excited H2 and O atoms on OH kinetics is also shown to be insignificant. As the discharge pulse coupled energy is increased, the model predicts transient OH number density overshoot due to the temperature rise caused by N2 vibrational relaxation by O atoms, which may well be a dominant effect in discharges with specific energy loading.

Temperature measurements in a manufactured RF plasma jet in various Ar/N$_{2}$ mixtures

In this paper, using the optical emission spectroscopy technique, a comparative study is performed on the argon excitation and nitrogen vibrational temperatures in the plasma discharge medium of a manufactured RF plasma jet. The argon contribution in the Ar/N$_{2}$ mixture is varied from 70% to 98% and the obtained optical emission spectra from argon and molecular nitrogen are analyzed. The highest emission intensities of neutral argon (Ar I) are recorded in the wavelength range of 790-850 nm. It is seen that, at the higher argon percentages in the mixture, the emission intensity from all the formed species in the plasma discharge medium of the RF plasma jet will increase. In addition, at the lower Ar contributions in the mixture, both the argon excitation and nitrogen vibrational temperatures are higher. Furthermore, it is shown that, at the higher Ar percentages in the mixture, both of the electronic temperatures are decreased.

Simulation study on nitrogen vibrational and translational temperature in air breakdown plasma generated by 110 GHz focused microwave pulse

We report a simulation study on nitrogen vibrational and translational temperature in 3 μs pulse 110 GHz microwave air breakdown at pressure from 1 Torr to 100 Torr. The one-dimensional model is based on a self-consistent solution to Helmholtz equation for microwave field, electron density equation, and the average energy equation for electrons, nitrogen vibrational, and translational degrees. The breakdown threshold is calculated from the transmitted microwave profile, and it agrees well with that from experiment. The spatio-temporal characteristics of vibrational and translational temperature are shown, and the peak values at the end of pulse are compared to the results fitted from optical emission spectroscopy. The dependences of vibrational and translational temperature on normalized microwave fields and gas pressure are investigated, and the underlying mechanisms are unveiled.

Experimental and theoretical study of an atmospheric air plasma-jet

In this work, we present an experimental and theoretical study of a low frequency, atmospheric plasma-jet discharge in air. Voltage-current characteristics and spectroscopic data were experimentally obtained, and a theoretical model developed to gain information of different aspects of the discharge. The discharge is modeled as a cathode layer with different mechanisms of electron emission and a main discharge channel that includes the most important kinetic reactions and species. From the electric measurements, it is determined that high electric field magnitudes are attained in the main channel, depending on the gas flow rate. Using the voltage-current characteristics as an input, the model allows to determine the plasma state in the discharge, including electron, gas, and molecular nitrogen vibrational temperatures. The model also allows to infer the mechanisms of secondary electron emission that sustain the discharge.

Effects of Continuous Volumetric Direct-Coupled Nonequilibrium Atmospheric Microwave Plasma Discharge on Swirl-Stabilized Premixed Flames

The effect of continuous volumetric direct-coupled nonequilibrium atmospheric microwave plasma discharge on swirl-stabilized premixed methane–air flames was investigated using quantitative OH planar laser-induced fluorescence and spectrally resolved emission. The plasma discharge was found to influence the dynamics of flame stabilization, i.e., plasma-assisted flames stabilized in the quiescent center body wake were relatively stable while swirl flames stabilized in the active inner shear layer were prone to local extinction due to aerodynamic shear. At coupled plasma powers corresponding to less than 3% of the thermal power output, in addition to the improved flame stability, significant improvement in the lean blow-out limit ( $\sim 43$ %) and OH number density ( $\sim 150$ %) was observed. The enhancements are shown to be nonequilibrium plasma effects and not predominantly ohmic heating as significant equivalence ratio dependence of OH number density in plasma-assisted flames was observed. Spectrographic measurements indicated nitrogen vibrational temperatures as high as 6100 K, suggesting both vibrational and electronic excitation of nitrogen molecules in the presence of a plasma discharge. The activation of highly reactive species through vibrational–vibrational relaxation and direct impact dissociation accelerates the combustion chemistry. It is demonstrated that microwave direct plasma coupling can drastically enhance the dynamic flame stability of swirl-stabilized flames, especially at very lean operating conditions.

Numerical simulation of nanosecond-pulse electrical discharges

Recent experiments with a nanosecond-pulse, dielectric barrier discharge at the stagnation point of a Mach 5 cylinder flow have demonstrated the formation of weak shock waves near the electrode edge, which propagate upstream and perturb the bow shock. This is a promising means of flow control, and understanding the detailed physics of the conversion of electrical energy into gas motion will aid in the design of efficient actuators based on the concept. In this work, a simplified configuration with planar symmetry was chosen as a vehicle to develop a physics-based model of nanosecond-pulse discharges, including realistic air kinetics, electron energy transport, and compressible bulk gas flow. A reduced plasma kinetic model (23 species and 50 processes) was developed to capture the dominant species and reactions for energy storage and thermalization in the discharge. The kinetic model included electronically and vibrationally excited species, and several species of ions and ground state neutrals. The governing equations included the Poisson equation for the electric potential, diffusion equations for each neutral species, conservation equations for each charged species, and mass-averaged conservation equations for the bulk gas flow. The results of calculations with this model highlighted the path of energy transfer in the discharge. At breakdown, the input electrical energy was transformed over a time scale on the order of 1 ns into chemical energy of ions, dissociation products, and vibrationally and electronically excited particles. About 30% of this energy was subsequently thermalized over a time scale of 10 µs. Since the thermalization time scale was faster than the acoustic time scale, the heat release led to the formation of weak shock waves originating near the sheath edge, consistent with experimental observations. The computed translational temperature rise (40 K) and nitrogen vibrational temperature rise (370 K) were of the same order of magnitude as experimental measurements (50 K and 500 K, respectively), and the approach appears promising for future multi-dimensional calculations. The effectiveness of flow control actuators based on nanosecond-pulse, dielectric barrier discharges is seen to depend crucially on the rapid thermalization of input energy, in particular the rate of quenching of excited electronic states and the rate of electron–ion recombination.

Development of a Mach 5 Nonequilibrium-Flow Wind Tunnel

A small-scale Mach 5 blow down wind tunnel, with ample access for optical diagnostics and ability to generate steady-state nonequilibrium flows, has been designed and operated. The wind tunnel uses transverse repetitively pulsed nanosecond discharge, fully overlapped with a transverse DC discharge and operated at high plenum pressures (P0=0.5-1.0 atm) to load internal energy modes of nitrogen and oxygen molecules. The discharge remains stable at energy loadings of up to ~0.1 eV/molecule in nitrogen (discharge power up to 2.5 kW). The wind tunnel generates nonequilibrium nitrogen and air flows with steady-state run time of 5-10 seconds, translational / rotational temperature of T0~300-400 K, and estimated upper bound nitrogen vibrational temperature of Tv0~2,000 K. Internal energy mode disequilibrium in the flow is controlled by injecting nitric oxide, hydrogen, or water vapor into the subsonic flow between the discharge section and the nozzle throat. The effect of energy mode disequilibrium is studied in a flow over a cylinder model placed in the Mach 5 test section. The flow field in the supersonic test section is well predicted by a 3-D compressible Navier-Stokes flow code, indicating good flow quality. The supersonic flow field over the model is visualized by schlieren imaging and NO PLIF imaging, using a burst mode laser operated in the vicinity of 226 nm, at a pulse repetition rate of 10-20 kHz. The laser was operated in the injection-seeded mode, generating narrow linewidth (~0.1 cm -1 ) output for single-line NO excitation in the flow. Nitric oxide was either injected into the flow in the plenum or generated in a repetitively pulsed nanosecond discharge in dry air. Both single-pulse PLIF images and images integrated over 10-50 laser pulses have been obtained. Two single-line NO PLIF images on a NO(X,v˝=0→A,v´=0) transition are used for measurements of 2-D temperature distributions in nitrogen flows in the supersonic test section. Another single-line NO PLIF image on a NO(X,v˝=1→A,v´=1) transition is used to estimate NO vibrational temperature behind the bow shock, TV(NO)=550 ± 100 K. The NO vibrational temperature increases when the energy loading in the discharge is increased. Kinetic modeling calculations indicate that low NO vibrational temperature is due to fairly low vibrational energy loading per nitrogen molecule in the discharge. Schlieren images of a supersonic flow over the cylinder model demonstrate that the shock stand-off distance is reduced by approximately 5% when the discharge in the wind tunnel is in operation and water vapor or hydrogen are injected into the flow between the discharge section and the nozzle throat. This effect is attributed to additional heating of the flow in the plenum during relaxation of vibrationally excited nitrogen in the presence of water vapor or hydrogen.

Nonlinear CARS measurement of nitrogen vibrational and rotational temperatures behind hypervelocity strong shock wave

The hypervelocity strong shock waves are generated, when the space vehicles reenter the atmosphere from space. Behind the shock wave radiative and non-equilibrium flow is generated in front of the surface of the space vehicle. Many studies have been reported to investigate the phenomena for the aerospace exploit and reentry. The research information and data on the high temperature flows have been available to the rational heatproof design of the space vehicles. Recent development of measurement techniques with laser systems and photo-electronics now enables us to investigate the hypervelocity phenomena with greatly advanced accuracy. In this research strong shock waves are generated in low-density gas to simulate the reentry range gas flow with a free-piston double-diaphragm shock tube, and CARS (Coherent Anti-stokes Raman Spectroscopy) measurement method is applied to the hypervelocity flows behind the shock waves, where spectral signals of high space/time resolution are acquired. The CARS system consists of YAG and dye lasers, a spectroscope, and a CCD camera system. We obtain the CARS signal spectrum data by this special time-resolving experiment, and the vibrational and rotational temperatures of N2 are determined by fitting between the experimental spectroscopic profile data and theoretically estimated spectroscopic data.

Experimental investigation of ultraviolet laser induced plasma density and temperature evolution in air

We present measurements and analysis of laser induced plasma neutral densities and temperatures in dry air by focusing 200 mJ, 10 MW high power, 193 nm ultraviolet ArF (argon fluoride) laser radiation to a 30 μm radius spot size. We examine these properties that result from multiphoton and collisional cascade processes for pressures ranging from 40 Torr to 5 atm. A laser shadowgraphy diagnostic technique is used to obtain the plasma electron temperature just after the shock front and this is compared with optical emission spectroscopic measurements of nitrogen rotational and vibrational temperatures. Two-color laser interferometry is employed to measure time resolved spatial electron and neutral density decay in initial local thermodynamic equilibrium (LTE) and non-LTE conditions. The radiating species and thermodynamic characteristics of the plasma are analyzed by means of optical emission spectroscopy (OES) supported by SPECAIR, a special OES program for air constituent plasmas. Core plasma rotational and vibrational temperatures are obtained from the emission spectra from the N2C-B(2+) transitions by matching the experimental spectrum results with the SPECAIR simulation results and the results are compared with the electron temperature just behind the shock wave. The plasma density decay measurements are compared with a simplified electron density decay model that illustrates the dominant three-and two-body recombination terms with good correlation.

Molecular Nitrogen Vibrational Temperature in an Inductively Coupled Plasma

Using a technique applied previously to vibrationally excitedmolecular nitrogen (N2*) in the region of daytime andnighttime aurora, the emission intensity of the N2 secondpositive band system in an inductively coupled plasma (ICP) has beenanalysed and the vibrational temperature of nitrogen molecules in theICP is thus determined. The result shows that the vibrationaltemperature increases with the increase of the neutral gas pressurefrom 0.04Pa to 10Pa, then decreases with the further increase of thepressure from 10Pa to 100Pa. Also, this is explained by using theBoltzmann relation between the vibrational temperature and theconcentration of the vibrationally excitedN2*(X1Σg+) molecules.

B 2Σ u + excited states of the N + 2 ion and the electron temperature in the discharge afterglow of an Ar-N2 mixture

The electron energy distribution function in the afterglow of a low-pressure discharge in an Ar-N2 mixture was experimentally found. The values of electron temperature were determined. At the initial stage of plasma decay, the electron temperature was shown to be close to the nitrogen vibrational temperature. A study was made of the afterglow observed in the bands of the first negative system of N+2, and it is shown that this afterglow may be attributed to collisions of argon ions with nitrogen molecules found on higher vibrational levels.

Computational Model of Nitrogen Vibrational Relaxation by Electron Collisions

Nitrogen vibrational relaxation by electron collisions has been studied by developing a complete vibrational state-to-state rate coefficient database for electron temperatures of 0.1-5.0 eV. This database was used to model a wide range of N 2 -e vibrational relaxation processes by solving and numerically integrating the master equation with respect to time. These results were used to develop a simple set of equations that accurately model nitrogen vibrational relaxation by electron collisions for electron and nitrogen vibrational temperatures ranging from 0.0 to 5.0 eV. The results are presented in the form of polynomial equations that could be easily incorporated into numerical models of more complex systems.

Effects of soft electron precipitation on the distribution of vibrational energy of N2

The paper investigates the direct effect of soft electron precipitation on the nitrogen vibrational distribution and on the rate coefficient for the ion-atom interchange reaction between O(+) and N2, using a spectrum of the precipitating electrons characteristic of the dayside cusp region. Substantial increases in the nitrogen vibrational temperature and in the rate of the O(+) destruction reaction do not occur unless the flux of incident electrons is as large as 1 trillion per sq cm/sec. For such large fluxes, departures of the vibrational distribution from a Boltzmann distribution have a significant effect on the rate coefficient. Incident fluxes less than 100 billion per sq cm/sec, such as are usually observed, have little direct effect on nitrogen vibration, although the indirect effect resulting from enhanced electron temperatures might be important.

Sodium excitation in non-equilibrium conditions behind shock waves in nitrogen

The mechanism of sodium excitation by collision with vibrationally excited nitrogen has been investigated in non-equilibrium conditions behind reflected shock waves. Experiments showed that the coupling between the sodium excitation temperature and the nitrogen vibrational temperature corresponds quite well with that calculated with the Fisher—Smith distribution of partial cross sections.

Free electron and vibrational temperature nonequilibrium in high temperature nitrogen

The degree of coupling between free electron and nitrogen vibrational temperatures in weakly ionized nozzle expansions of shock-heated nitrogen has been determined. Free electron temperatures were measured with Langmuir probes while nitrogen vibrational temperatures were determined with a new instrument based on the electron beam technique. The resultant data were analytically correlated by coupling chemical nonequilibrium with nitrogen vibrational and free electron temperature nonequilibrium. It was found that a vibrational loss factor of 7 × 10−4 and an effective translational-rotational loss factor of 4.26 × 10−4 best predicted the measured electron temperature distributions.

A simplified model for predicting gain, saturation, and pulse length for gas dynamic lasers

A single time-scale model is developed to describe the 10.6-μ laser energy extraction from an initially inverted N 2 -CO 2 catalyst mixture where the energy is stored primarily in the N 2 vibration. This condition is typical of high-pressure gas dynamic lasers, but the methods are general and applicable to other systems. In the absence of external pumping, the nitrogen can be regarded as an energy source that is depleted on a time scale \tau = \tauNAT(1 + I_{0}/I), \tauNAT being the minimum possible time scale governed by collisional processes, τ determines the pulse time for Q -switched laser mixtures or the required streamwise cavity length for CW gas dynamic lasers. The derived saturation intensity I 0 also appears in the expression for saturated gain (for collision broadened cases) g = g_{0}/(1 + I/I_{0}) , where g 0 is approximately the small signal gain at a given nitrogen vibrational temperature, g 0 decays on the same intensity-dependent time scale τ as the nitrogen vibrational energy.

Electron and nitrogen vibrational temperature in the E-region of the ionosphere

There is considerable evidence that electron temperatures in the E-region are greater than neutral gas temperatures by several hundred degrees. It is suggested that these temperatures reflect nitrogen vibrational temperatures of about 3100°K. Nitrogen vibrational energy may be provided by the reaction which quenches metastable 1 D oxygen atoms produced by photodissociation of oxygen in the Schumann-Runge continuum. Vibrational exchange collisions redistribute the energy leading to a Boltzmann vibrational distribution for the nitrogen molecules. Vibrational energy is lost mainly in collisions with the ambient electrons, and the lifetime of a vibrating molecule is about 5 × 10 5 sec in the E-region.