Nitrene, as an important and intriguing versatile synthon, is widely utilized for the formation of diverse nitrogenous skeletons under thermal or photochemical conditions. Typically, the N-sulfonyl nitrenes could be smoothly generated from iminoiodinanes at relatively low reaction temperatures to generate N-sulfonyl nitrenes. Herein, we described the direct immidation reaction of iminoiodinanes with sulfoxides through a blue-light-induced nitrenes transfer process. This strategy offers an efficient and gentle pathway for directly obtaining sulfoximines within a reaction time of only 10 minutes. Moreover, the reaction conditions do not necessitate the exclusion of moisture or air, rendering this photocatalytic amination reaction highly practical. A broad range of iminoiodinanes were well tolerated and reacted with sulfoxides smoothly to give the corresponding products in moderate to good yields, which provides a practical and green protocol to access N-sulfonyl architectures.